Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Vapor liquid equilibria for nitrogen with 2-propanol, 2-butanol, or 2-pentanol binary systems

Weng, W. L.[Wen-Lu], Chen, J. -T.[Jui-Tang], Chang, J. S.[Ji-Sheng], Yang, C.-H.[Chih-Hao]
Fluid Phase Equilib. 2006, 239, 2, 200-205
ABSTRACT
Isothermal vapor liquid equilibrium (VLE) data were measured for the binary systems of nitrogen with 2-propanol, 2-butanol, or 2-pentanol at temperatures from 333.15 to 393.15K and pressure up to 100 bar. Henry s constants of nitrogen in these three sec-alcohols were determined by using the Krichevesky Ilinskaya equation. The experimental VLE data were also correlated by the Peng Robinson and the Patel Teja equations of state with various mixing rules.
Compounds
# Formula Name
1 N2 nitrogen
2 C3H8O propan-2-ol
3 C4H10O butan-2-ol
4 C5H12O pentan-2-ol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 27
  • POMD
  • 2
  • 1
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Temperature, K; Gas
  • Gas
  • Liquid
  • Chromatography
  • 27
  • POMD
  • 3
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 27
  • POMD
  • 3
  • 1
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Temperature, K; Gas
  • Gas
  • Liquid
  • Chromatography
  • 27
  • POMD
  • 4
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 27
  • POMD
  • 4
  • 1
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Temperature, K; Gas
  • Gas
  • Liquid
  • Chromatography
  • 27