This work reports the measured density, n, and viscosity, c, values of liquid mixtures of tetrahydrofuran (1) + 1-chlorobutane (2) + 2-butanol (3) at temperatures of 283.15, 298.15 and 313.15K over a range of mole fractions and atmospheric pressure. Excess molar volume, VE, viscosity deviations and excess free energies of activation of viscous flow have been calculated from experimental data and fitted to Cibulka, Singh et al. and Nagata and Sakura equations. The results were analyzed in terms of the molecular interaction between the components of the mixtures. Excess molar volumes and viscosity deviations were predicted from binary contributions using geometrical solution models, Tsao and Smith; Jacob and Fitzner; Kholer; Rastogi et al.; Radojkovic et al. Finally, experimental results are compared with those obtained by applying group-contribution method proposed by Wu.
Compounds
#
Formula
Name
1
C4H10O
butan-2-ol
2
C4H8O
tetrahydrofuran
3
C4H9Cl
1-chlorobutane
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.