Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Isothermal vapour liquid equilibria in the binary and ternary systems composed of 2-propanol, diisopropyl ether and 4-methyl-2-pentanone

Psutka, S.[Stepan], Wichterle, I.[Ivan]
Fluid Phase Equilib. 2005, 235, 1, 58-63
ABSTRACT
Vapour liquid equilibrium data in the two binary 2-propanol + 4-methyl-2-pentanone, and diisopropyl ether + 4-methyl-2-pentanone systems, and in the ternary 2-propanol + diisopropyl ether + 4-methyl-2-pentanone system are reported. The data were measured isothermally at 330.00 and 340.00K covering the pressure range 12 100 kPa. The binary vapour liquid equilibrium data were correlated using the Wilson, NRTL and Redlich Kister equations; resulting parameters were then used for calculation of phase behaviour in the ternary system and for subsequent comparison with experimental data.
Compounds
# Formula Name
1 C3H8O propan-2-ol
2 C6H14O diisopropyl ether
3 C6H12O 4-methylpentan-2-one
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:2
  • 1
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:4
  • 2
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:3
  • 1
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:4
  • 2
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:3
  • 1
  • POMD
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:4
  • 2
  • POMD
  • 1
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:4
  • 47
  • POMD
  • 1
  • 3
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • CHROM:UFactor:4
  • 47
  • POMD
  • 3
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:4
  • 27
  • POMD
  • 3
  • 2
  • Mole fraction - 2 ; Gas
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • CHROM:UFactor:4
  • 27
  • POMD
  • 1
  • 3
  • 2
  • Mole fraction - 1 ; Gas
  • Mole fraction - 2 ; Liquid
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 2; Gas
  • Gas
  • Liquid
  • CHROM:UFactor:4
  • CHROM:UFactor:4
  • CHROM:UFactor:4
  • 90