Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

ABSTRACT

(Solid + liquid) equilibria for the binary systems (N-methyl-2-pyrrolidinone + phenol, or 3,5-dimethylphenol) have been determined using a cryometric dynamic method. Congruently melting compounds form with the formulae: C5H9NO*C6H5OH, or C5H9NO*(C6H5OH)2, and C5H9NO*C8H9OH, or C5H9NO*(C8H9OH)2. Compound formation is attributed to a charge-transfer interaction of N-methyl-2-pyrrolidinone with phenol or 3,5-dimethylphenol, or is attributed to a strongO H* * *Ohydrogen bond between the oxygen atom of N-methyl-2-pyrrolidinone and hydroxyl group of phenol. The larger intermolecular interaction is observed for the (N-methyl-2-pyrrolidinone + phenol) binary mixture, where the melting temperature of the 1:1 congruently melting compound is higher. Experimental solubility results are compared with values calculated by means of the Ott equation using parameters derived from the SLE results. The correlation of the solubility data is obtained with a average root-mean-square deviation in temperature oT = 0.25K and oT = 0.19K for the systems with phenol or 3,5-dimethylphenol, respectively.