Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Vapour pressures and enthalpies of vaporization of a series of substituted phenyl isobutyl ethers

Strutynskaa, A.[Agata], Sporzynski, A.[Andrzej], Serwatowski, J.[Janusz], Verevkin, S. P.[Sergey P.]
Fluid Phase Equilib. 2005, 227, 2, 283-286
ABSTRACT
Molar enthalpies of vaporization of 2-Br-phenyl isobutyl ether, 3-Br-phenyl isobutyl ether, 4-Br-phenyl isobutyl ether, and 2-Br-4-Mephenyl isobutyl ether were obtained from the temperature dependence of the vapor pressure measured by the transpiration method. The measured data sets were successfully checked for internal consistency. The values of enthalpies of vaporization and vapor pressures of ortho-, meta-, and para-substituted benzenes are discussed in the context.
Compounds
# Formula Name
1 C10H13BrO 1-bromo-2-isobutoxybenzene
2 C10H13BrO 1-bromo-3-isobutoxybenzene
3 C10H13BrO 1-bromo-4-isobutoxybenzene
4 C11H15BrO 2-bromo-1-isobutoxy-4-methylbenzene
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Transpiration method
  • 13
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Transpiration method
  • 14
  • POMD
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Transpiration method
  • 16
  • POMD
  • 4
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Transpiration method
  • 25