ABSTRACT

Solubility data were measured for eight different n-alkanes ranging from tetracosane to tetratetracontane (C24H50-C44H90). Included are: 1) solubility data in toluene for all the n-alkanes studied and (2) solubility data of n-hexatriacontane (C36H74) in several solvent and solvent mixture systems. Illustrated in the data are the effects on solubility of alkane chain length, alkane odd versus even carbon number structures, and solvent chemistry. The measurements were made to provide fundamental equilibrium data.

Compounds

#	Formula	Name
1	C24H50	tetracosane
2	C28H58	octacosane
3	C32H66	dotriacontane
4	C33H68	tritriacontane
5	C34H70	tetratriacontane
6	C40H82	tetracontane
7	C44H90	tetratetracontane
8	C7H16	heptane
9	C7H8	toluene
10	C11H10	1-methylnaphthalene
11	C10H18	decahydronaphthalene
12	C6H12	cyclohexane
13	CS2	carbon disulfide
14	C36H74	hexatriacontane
15	C4H10S2	3,4-dithiahexane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	9 1	Solid-liquid equilibrium temperature, K ; Liquid	Mass fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	VISOBS	5
POMD	9 2	Solid-liquid equilibrium temperature, K ; Liquid	Mass fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 2	VISOBS	7
POMD	9 3	Solid-liquid equilibrium temperature, K ; Liquid	Mass fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 3	VISOBS	8
POMD	9 4	Solid-liquid equilibrium temperature, K ; Liquid	Mass fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 4	VISOBS	6
POMD	9 5	Solid-liquid equilibrium temperature, K ; Liquid	Mass fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 5	VISOBS	6
POMD	9 14	Solid-liquid equilibrium temperature, K ; Liquid	Mass fraction - 14; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 14	VISOBS	8
POMD	9 6	Solid-liquid equilibrium temperature, K ; Liquid	Mass fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 6	VISOBS	6
POMD	9 7	Solid-liquid equilibrium temperature, K ; Liquid	Mass fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 7	VISOBS	6
POMD	13 14	Solid-liquid equilibrium temperature, K ; Liquid	Mass fraction - 14; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 14	VISOBS	7
POMD	12 14	Solid-liquid equilibrium temperature, K ; Liquid	Mass fraction - 14; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 14	VISOBS	7
POMD	11 14	Solid-liquid equilibrium temperature, K ; Liquid	Mass fraction - 14; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 14	VISOBS	8
POMD	8 14	Solid-liquid equilibrium temperature, K ; Liquid	Mass fraction - 14; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 14	VISOBS	8
POMD	10 14	Solid-liquid equilibrium temperature, K ; Liquid	Mass fraction - 14; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 14	VISOBS	8
POMD	15 14	Solid-liquid equilibrium temperature, K ; Liquid	Mass fraction - 14; Liquid Pressure, kPa; Liquid		Liquid Crystal - 14	VISOBS	1
POMD	13 10 14	Solid-liquid equilibrium temperature, K ; Liquid	Mass fraction - 14; Liquid	Pressure, kPa; Liquid Solvent: Mass fraction - 13; Liquid	Liquid Crystal - 14	VISOBS	6
POMD	10 11 14	Solid-liquid equilibrium temperature, K ; Liquid	Mass fraction - 14; Liquid	Pressure, kPa; Liquid Solvent: Mass fraction - 11; Liquid	Liquid Crystal - 14	VISOBS	6
POMD	11 15 14	Solid-liquid equilibrium temperature, K ; Liquid	Mass fraction - 14; Liquid	Pressure, kPa; Liquid Solvent: Mass fraction - 11; Liquid	Liquid Crystal - 14	VISOBS	2

Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Experimental solubility data of various n-alkane waxes: effects of alkane chain length, alkane odd versus even carbon number structures, and solvent chemistry on solubility

Jennings, D. W.[David W.], Weispfennig, K.[Klaus]

ABSTRACT