Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Measurement and modeling of vapor liquid equilibria at high salt concentrations

Kolar, P., Nakata, H., Tsuboi, A., Wang, P., Anderko, A.
Fluid Phase Equilib. 2005, 228-229, 493-497
ABSTRACT
Isobaric vapor liquid equilibrium data are reported for binary and ternary aqueous mixtures containing LiCl and ZnCl2 at total salt concentrations between 10 and 50 wt.%. The measurements were carried out at 5.3, 9.3, 20, 40, and 101.3 kPa in a computer-controlled glass apparatus. Particular care was taken to ensure proper equilibration of the high-density, high-viscosity salt mixtures. The equilibrium data spanning temperatures between 303 and 423K were successfully correlated using the electrolyte model by Wang and Anderko
Compounds
# Formula Name
1 ClLi lithium chloride
2 Cl2Zn zinc chloride
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • 3
  • Boiling temperature at pressure P, K ; Liquid
  • Mass fraction - 1; Liquid
  • Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:8
  • 48