ABSTRACT

The work presents results of the experimental measurements of the isobaric heat capacity for 1-bromohexane, 1-bromoheptane, 1-bromooctane, 1-bromononane, 1- bromodecane, 1-bromoundecane, 1-bromododecane, 1-bromotetradecane at normal pressure and the speed of sound the density at for 1-bromotetradecane wihin the temperature range 298.15~K--423.15~K. Using these data and literature-based ones, the isothermal compressibility and the inverse reduced fluctuations are calculated. Basing on the comparison with results for pure n-alkanes and $\alpha,\omega$- dibromoalkanes, we discuss the influence of bromine atom on the volume fluctuations.

Compounds

#	Formula	Name
1	C6H13Br	1-bromohexane
2	C7H15Br	1-bromoheptane
3	C8H17Br	1-bromooctane
4	C12H25Br	1-bromododecane
5	C14H29Br	1-tetradecyl bromide
6	C9H19Br	1-bromononane
7	C10H21Br	1-bromodecane
8	C11H23Br	1-bromoundecane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Large sample (1 g) DSC	26
POMD	2	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Large sample (1 g) DSC	26
POMD	3	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Large sample (1 g) DSC	26
POMD	4	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Large sample (1 g) DSC	26
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	26
POMD	5	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Pulse-echo method	26
POMD	5	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Large sample (1 g) DSC	26
POMD	6	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Large sample (1 g) DSC	26
POMD	7	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Large sample (1 g) DSC	26
POMD	8	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Large sample (1 g) DSC	26

Thermodynamics Research Center / ThermoML | International Journal of Thermophysics

Isobaric heat capacity, isothermal compressibility and fluctuational properties of 1- bromoalkanes

Korotkovskii, V. I., Ryshkova, O. S., Neruchev, Y. A.[Yu.A.], Goncharov, A. L., Postnikov, E. B.

ABSTRACT