Thermodynamics Research Center / ThermoML | International Journal of Thermophysics

Thermal Diffusivity and Speed of Sound of Saturated Pentane from Light Scattering

Wang, S.[Sheng], Zhang, Y.[Ying], He, M.-G.[Mao-Gang], Zheng, X.[Xiong], Chen, L.-B.[Li-Bin]
Int. J. Thermophys. 2014, 35, 8, 1450-1464
ABSTRACT
Transport and thermodynamic properties of pentane are necessary for the design and verification of reactors in pentane isomerization and degradation processes. However, there are few experimental data of these properties, especially in the high-temperature region. In this work, the thermal diffusivity and the sound speed of pentane have measured by dynamic light scattering and Brillouin light scattering, respectively. Pentane has been investigated under saturated conditions over a wide temperature range, from about 300 K up to the liquid vapor critical point. It is estimated that: the standard uncertainty of temperature is u(T)=0.01 K for the hydrodynamic region and u(T)=0.026 K for the critical region; the relative expanded uncertainty in the thermal diffusivity is U r (a)=0.03 and the relative expanded uncertainty in the speed of sound is U r (c s )=0.005 with a coverage factor of k=2 . The thermal diffusivity and the sound-speed experimental data are also represented as functions of temperature. Finally, the results are discussed in detail in comparison with literature results and various prediction methods.
Compounds
# Formula Name
1 C5H12 pentane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Thermal diffusivity, m2/s ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Optical interferometry
  • 32
  • POMD
  • 1
  • Thermal diffusivity, m2/s ; Gas
  • Temperature, K; Gas
  • Gas
  • Liquid
  • Optical interferometry
  • 15
  • POMD
  • 1
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Light diffraction method
  • 19
  • POMD
  • 1
  • Speed of sound, m/s ; Gas
  • Temperature, K; Gas
  • Gas
  • Liquid
  • Light diffraction method
  • 16