Ameasurement method for PVT properties of high-temperature and highpressure gases was developed by simplifying the Burnett method and revising the data acquisition procedure. Instead of a differential pressure transducer, which is traditionally used, an absolute pressure transducer is used in the present method, and the measurement of pressure becomes easier. However, the absolute pressure transducer is placed outside the constant temperature bath because of the difficulty of its use in high-temperature surroundings, and some parts with different temperatures from the sample vessels exist as dead space. The present method takes into account the effect of the dead space in the data acquisition procedure. Nitrogen was measured in the temperature range from 353K to 473K and at pressures up to 100MPa to determine the apparatus constants, and then, hydrogenwasmeasured at 473Kand up to 100MPa. The determined densities are in agreement within uncertainties of 0.07% to 0.24% (k = 2), both with the latest equation of state and existing measured data.
Compounds
#
Formula
Name
1
N2
nitrogen
2
H2
hydrogen
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.