Thermodynamics Research Center / ThermoML | International Journal of Thermophysics

Densities and Volumetric Properties of Binary Mixtures of Butyl Acrylate with Benzene, Toluene, o-Xylene, m-Xylene, p-Xylene, and Mesitylene at Temperatures from 288.15 K to 318.15 K

Nain, A. K.[Anil Kumar], Sharma, R.[Rajni], Ali, A.[Anwar], Gopal, S.[Swarita]
Int. J. Thermophys. 2010, 31, 6, 1073-1091
ABSTRACT
The densities, ?, of binary mixtures of butyl acrylate (BA) with benzene, toluene, o-xylene, m-xylene, p-xylene, and mesitylene, including those of pure liquids, over the entire composition range were measured at the temperatures (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, and 318.15) K and atmospheric pressure. From the experimental data, the excess molar volumes, were calculated. The values were negative over the whole composition range for all the mixtures and at each temperature studied, except for BA + mesitylene which exhibit positive values, indicating the presence of specific interactions between BA and aromatic hydrocarbon molecules. The deviations in values follow the order: benzeneless thantolueneless thanp-xyleneless thanm-xyleneless thano-xyleneless thanmesitylene. It is observed that values depend upon the number and position of the methyl groups in these aromatic hydrocarbons.
Compounds
# Formula Name
1 C6H6 benzene
2 C7H8 toluene
3 C8H10 1,2-dimethylbenzene
4 C8H10 1,3-dimethylbenzene
5 C8H10 1,4-dimethylbenzene
6 C9H12 1,3,5-trimethylbenzene
7 C7H12O2 butyl 2-propenoate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 7
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 7
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 7
  • POMD
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 7
  • POMD
  • 5
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 7
  • POMD
  • 6
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 7
  • POMD
  • 7
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 7
  • POMD
  • 1
  • 7
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 7; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 105
  • POMD
  • 2
  • 7
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 7; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 105
  • POMD
  • 3
  • 7
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 7; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 105
  • POMD
  • 4
  • 7
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 7; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 105
  • POMD
  • 5
  • 7
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 7; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 105
  • POMD
  • 6
  • 7
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 7; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 105