ABSTRACT

The densities, n, viscosities, c, ultrasonic speeds, u, and refractive indices, nD, of pure benzene, methyl acrylate (MA), ethyl acrylate (EA), butyl acrylate (BA), styrene (STY), and their binary liquid mixtures have been measured over the entire composition range at 298.15 K, 303.15 K, 308.15 K, and 313.15 K. The experimental data have been used to calculate excess molar volumes. Partial molar volumes of MA/EA/BA/STY in benzene at infinite dilution and at different temperatures have also been evaluated. The results were discussed in terms of molecular interactions prevailing in the mixtures.

Compounds

#	Formula	Name
1	C4H6O2	methyl propenoate
2	C5H8O2	ethyl propenoate
3	C7H12O2	butyl 2-propenoate
4	C8H8	styrene
5	C6H6	benzene

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:4	4
POMD	1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:2	4
POMD	1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LVPAI::UFactor:2	4
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:6	4
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:4	4
POMD	2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:2	4
POMD	2	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LVPAI::UFactor:2	4
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:6	4
POMD	3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:4	4
POMD	3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:2	4
POMD	3	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LVPAI::UFactor:2	4
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:6	4
POMD	4	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:4	4
POMD	4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:2	4
POMD	4	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LVPAI::UFactor:2	4
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:6	4
POMD	5	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:4	4
POMD	5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	4
POMD	5	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LVPAI::UFactor:2	4
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:6	7
POMD	5 2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	44
POMD	5 2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:4	44
POMD	5 2	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	LVPAI:UFactor:2	44
POMD	5 2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:6	44
POMD	5 3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	44
POMD	5 3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:4	44
POMD	5 3	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	LVPAI:UFactor:2	44
POMD	5 3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:6	44
POMD	5 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	44
POMD	5 1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:4	44
POMD	5 1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	LVPAI:UFactor:2	44
POMD	5 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:6	44
POMD	5 4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	44
POMD	5 4	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:4	44
POMD	5 4	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	LVPAI:UFactor:2	44
POMD	5 4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:6	44

Thermodynamics Research Center / ThermoML | International Journal of Thermophysics

Volumetric, Viscometric, Ultrasonic, and Refractive Index Properties of Liquid Mixtures of Benzene with Industrially Important Monomers at Different Temperatures

Ali, A., Nabi, F., Tariq, M.

ABSTRACT