Name: ThermoML Representation of Published Experimental Data from International Journal of Thermophysics (0195-928X, Springer Science+Business Media B.V. (Formerly Kluwer Academic Publishers B.V.))
Creator: Thermodynamics Research Center
License: https://www.nist.gov/open/license

Thermodynamics Research Center / ThermoML | International Journal of Thermophysics

Temperature Dependence of Densities and Excess Molar Volumes of the Ternary Mixture (1-Butanol + Chloroform + Benzene) and its Binary Constituents (1-Butanol + Chloroform and 1-Butanol + Benzene)

Smiljanic, J. D.[Jelena D.], Kijevcanin, M. L.[Mirjana Lj.], Djordjevic, B. D.[Bojan D.], Grozdanic, D. K.[Dusan K.], Serbanovic, S. P.[Slobodan P.]

Int. J. Thermophys. 2008, 29, 2, 586-609

ABSTRACT

Densities ? of the 1-butanol + chloroform + benzene ternary mixture and the 1-butanol + chloroform and 1-butanol + benzene binaries have been measured at six temperatures (288.15, 293.15, 298.15, 303.15, 308.15, and 313.15) K and atmospheric pressure, using an oscillating U-tube densimeter. From these densities, excess molar volumes (VE) were calculated and fitted to the Redlich-Kister equation for all binary mixtures and to the Nagata and Tamura equation for the ternary system. The Radojkovi? et al. equation has been used to predict excess molar volumes of the ternary mixtures. Also, VE data of the binary systems were correlated by the van der Waals (vdW1) and Twu-Coon-Bluck-Tilton (TCBT) mixing rules coupled with the Peng-Robinson-Stryjek-Vera (PRSV) equation of state. The prediction and correlation of VE data for the ternary system were performed by the same models.

Compounds

#	Formula	Name
1	C4H10O	butan-1-ol
2	CHCl3	trichloromethane
3	C6H6	benzene

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:2	6
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:2	6
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:2	6
POMD	2 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:2	126
POMD	1 3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:2	138
POMD	2 1 3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:2	312