Thermodynamics Research Center / ThermoML | International Journal of Thermophysics

A Novel Instrument for the Measurement of the Thermal Conductivity of Molten Metals. Part II: Measurements

Peralta-Martinez, M. V., Assael, M. J., Dix, M. J., Karagiannidis, L., Wakeham, W. A.
Int. J. Thermophys. 2006, 27, 3, 681-698
ABSTRACT
New measurements of the thermal conductivity of molten mercury, gallium, tin, and indium are reported up to 750 K. The measurements are performed in a novel transient hot-wire instrument described elsewhere. The present experimental technique overcomes problems of convection, and it is shown that it operates in an absolute way in accord with a theoretical model. The uncertainty of the thermal conductivity results is estimated to be +- 2%, which is superior to that achieved in most earlier work. The low uncertainty of the present experimental results has allowed us to test the only significant theory for the thermal conductivity of molten metals, which relates this property to the electrical conductivity. The pattern of results among the four metals indicates that further theoretical developments would be warranted.
Compounds
# Formula Name
1 Hg mercury
2 Ga gallium
3 Sn tin
4 In indium
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Thermal conductivity, W/m/K ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Hot wire method
  • 11
  • POMD
  • 2
  • Thermal conductivity, W/m/K ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Hot wire method
  • 7
  • POMD
  • 3
  • Thermal conductivity, W/m/K ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Hot wire method
  • 7
  • POMD
  • 4
  • Thermal conductivity, W/m/K ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Hot wire method
  • 9