Cpo(Ideal Gas)
-
DEFAULT 1: Wilhoit Equation
Cpo / R =
a0 +
(a1 /T 2) × exp( -a2 /T ) +
a3 × y2 +
{a4 - a5 /(T - a7)2} × y 8
where y = (T - a7)/(T + a6)
and R is the gas constant.
See Thermodynamics of Organic Compounds in the Gas State (Volumes I and II) by
M. Frenkel, G. J. Kabo, K. N. Marsh, G. N. Roganov, and R. C. Wilhoit. Publsihed by the Thermodynamics Research Center (TRC), College Station: TX. 1994.
- DEFAULT 2: PolynomialHC: (Output details)
Cpo = å ai×
T i, where the summation is from i = 0 to nTerms - 1.
- Alternative 1: Yaws.PolynomialExpansion (Output details)
Cpo = å ai×
T i, where the summation is from i = 0 to nTerms - 1.
- Alternative 2: AlyLee (which is also DIPPR 107) (Output details)
Cpo = a + b×{(c/T)/sinh(c/T)}2 +
d×{(e/T)/cosh(e/T)}2
- Alternative 3: PPDS2 (Output details)
Cpo/R = Clow + (Clow -
C¥)×y2
×{1 + (y - 1) å(ai
× yi)} ; where the summation is from i = 0 to 4.
Clow and C¥ are equation constants, R is the gas constant, and
y = T / (T + TS), where TS is a constant.
- Alternative 4: Helmholtz (Output details)
Cpo/R =
1 + t - {åai×ni×(ni - 1)×tni}(ni¹ 0 or 1)
+ åbi×(ci×t)2×exp(ci×t) / {exp(ci×t) - 1}2;
where t = Tc/T, Tc = the critical temperature, R is the gas constant, and the summations are from i = 1 to nTerms.
- Alternative 5: Yaws.HighIG (Output details) for high-temperature applications
Cpo = å ai×
T ni , where the summation is from i = 1 to 4.