Activity Coefficient Model: Van Laar

The model is described in: J.J. Van Laar, The Vapor Pressure of Binary Mixtures, Z. Phys. Chem., 1910, Vol. 72, p. 723.

GEX/(R ×T) = a1 ×a2 ×x1 ×x2/(a1 ×x1 + a2 ×x2) Parameters determined in TDE are a1 and a2 .

For the symmetric form of the model, a1 = a2.

Temperature dependencies for activity-coefficient model parameters are expressed with: TDE-TSeries1.

annotated equation parameter window showing locations of a_1 and a_2 in A table under Parameters:

Details of the model implementation in TDE, including ThermoML-Equation representation are available. (See the ThermoML web site for details of this IUPAC communication standard.)