2
0
2010
wan
wu
1
journal
Original
Wang, J.[Jun]
Wu, S.-D.[Shi-De]
Yang, X.-Z.[Xu-Zhao]
J. Chem. Eng. Data
2010
2020-09-29
Solubility of 1,1'-(Butane-1,4-diyl)-bis(3-methylpyridinium) Dihexafluorophosphate in Different Solvents from (288.15 to 333.15) K
Using a laser monitoring technique, the solubilities of 1,1'-(butane-1,4-diyl)-bis(3-methylpyridinium) dihexafluorophosphate in water, acetylacetone, acetophenone, cyclohexanone, 2-butanone, and acetone + water were determined at temperatures from (288.15 to 333.15) K at atmospheric pressure. The experimental data were correlated with the modified Apelblat equation and the ?h model.
10.1021/je9010954
9
55
3942-3945
1
InChI=1S/C16H22N2.2F6P/c1-15-7-5-11-17(13-15)9-3-4-10-18-12-6-8-16(2)14-18;2*1-7(2,3,4,5)6/h5-8,11-14H,3-4,9-10H2,1-2H3;;/q+2;2*-1
KLIQSFDIQOZOHK-UHFFFAOYSA-N
1,1'-(butane-1,4-diyl)bis(3-methylpyridinium) hexafluorophosphate(V)
1,1'-(butane-1,4-diyl)bis(3-methylpyridinium) dihexafluorophosphate
C16H22F12N2P2
1
Synthesized by others
1
99
2
HPLC
2
0.01
1
Karl Fischer titration
2
InChI=1S/H2O/h1H2
XLYOFNOQVPJJNP-UHFFFAOYSA-N
water
H2O
1
Synthesized by the authors
1
Fractional distillation
2
99.9
3
Estimated by the compiler
3
InChI=1S/C5H8O2/c1-4(6)3-5(2)7/h3H2,1-2H3
YRKCREAYFQTBPV-UHFFFAOYSA-N
2,4-pentanedione
acetylacetone
pentan-2,4-dione
C5H8O2
1
Commercial source
1
99.5
3
Stated by supplier
4
InChI=1S/C8H8O/c1-7(9)8-5-3-2-4-6-8/h2-6H,1H3
KWOLFJPFCHCOCG-UHFFFAOYSA-N
acetophenone
1-phenyl-1-ethanone
1-phenylethanone
methyl phenyl ketone
phenyl methyl ketone
C8H8O
1
Commercial source
1
99.5
3
Stated by supplier
5
InChI=1S/C6H10O/c7-6-4-2-1-3-5-6/h1-5H2
JHIVVAPYMSGYDF-UHFFFAOYSA-N
cyclohexanone
C6H10O
1
Commercial source
1
99.5
3
Stated by supplier
6
InChI=1S/C4H8O/c1-3-4(2)5/h3H2,1-2H3
ZWEHNKRNPOVVGH-UHFFFAOYSA-N
butanone
2-butanone
butan-2-one
ethyl methyl ketone
methyl ethyl ketone
C4H8O
1
Commercial source
1
99.5
3
Stated by supplier
7
InChI=1S/C3H6O/c1-3(2)4/h1-2H3
CSCPPACGZOOCGX-UHFFFAOYSA-N
acetone
2-propanone
dimethyl ketone
propan-2-one
propanone
pyroacetic ether
C3H6O
1
Commercial source
1
99.5
3
Stated by supplier
1
1
1
Principal objective of the work
PW
TRC
9/27/2010
1
Normal melting temperature, K
VISOBS
Crystal
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Crystal
Liquid
Air at 1 atmosphere
1
435.4
4
1
2.51
2
2
1
1
1
Principal objective of the work
PW
TRC
9/27/2010
1
Mole fraction
laser monitering observation technique
1
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
288.15
5
1
1.6e-06
2
1
1e-07
1
293.15
5
1
2.8e-06
2
1
2e-07
1
298.15
5
1
4.9e-06
2
1
4e-07
1
303.15
5
1
8.4e-06
2
1
6e-07
1
308.15
5
1
1.43e-05
3
1
1e-06
1
313.15
5
1
2.44e-05
3
1
1.7e-06
1
318.15
5
1
3.93e-05
3
1
2.8e-06
1
323.15
5
1
6.25e-05
3
1
4.4e-06
1
328.15
5
1
9.76e-05
3
1
7e-06
1
333.15
5
1
0.0001569
4
1
1.1e-05
3
3
1
1
1
Principal objective of the work
PW
TRC
9/27/2010
1
Mole fraction
laser monitering observation technique
1
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
288.15
5
1
0.0011941
5
1
3.14e-05
1
293.15
5
1
0.0015742
5
1
4.08e-05
1
298.15
5
1
0.0021387
5
1
5.51e-05
1
303.15
5
1
0.0028182
5
1
7.17e-05
1
308.15
5
1
0.003683
5
1
9.2e-05
1
313.15
5
1
0.0046235
5
1
0.0001158
1
318.15
5
1
0.0059848
5
1
0.0001539
1
323.15
5
1
0.0080714
5
1
0.0002031
1
328.15
5
1
0.0100944
6
1
0.0002569
1
333.15
5
1
0.0135558
6
1
0.0003416
4
4
1
1
1
Principal objective of the work
PW
TRC
9/27/2010
1
Mole fraction
laser monitering observation technique
1
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
298.15
5
1
0.0007482
4
1
1.99e-05
1
303.15
5
1
0.0010248
5
1
2.59e-05
1
308.15
5
1
0.0013802
5
1
3.45e-05
1
313.15
5
1
0.0018274
5
1
4.52e-05
1
318.15
5
1
0.0023982
5
1
5.89e-05
1
323.15
5
1
0.0031084
5
1
7.84e-05
1
328.15
5
1
0.0042833
5
1
0.0001066
1
333.15
5
1
0.0055574
5
1
0.0001331
5
5
1
1
1
Principal objective of the work
PW
TRC
9/27/2010
1
Mole fraction
laser monitering observation technique
1
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
288.15
5
1
0.0002048
4
1
7e-06
1
293.15
5
1
0.0003327
4
1
9.8e-06
1
298.15
5
1
0.0005101
4
1
1.44e-05
1
303.15
5
1
0.0007462
4
1
1.95e-05
1
308.15
5
1
0.0009673
4
1
2.42e-05
1
313.15
5
1
0.0012091
5
1
2.96e-05
1
318.15
5
1
0.001463
5
1
3.49e-05
1
323.15
5
1
0.0016401
5
1
3.85e-05
1
328.15
5
1
0.0017998
5
1
4.18e-05
1
333.15
5
1
0.0018545
5
1
4.29e-05
6
6
1
1
1
Principal objective of the work
PW
TRC
9/27/2010
1
Mole fraction
laser monitering observation technique
1
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
288.15
5
1
0.0028868
5
1
7.51e-05
1
293.15
5
1
0.0032793
5
1
8.53e-05
1
298.15
5
1
0.0037927
5
1
9.9e-05
1
303.15
5
1
0.0043895
5
1
0.0001141
1
308.15
5
1
0.0049596
5
1
0.0001284
1
313.15
5
1
0.0055646
5
1
0.0001439
1
318.15
5
1
0.0062319
5
1
0.0001615
1
323.15
5
1
0.0070588
5
1
0.0001822
1
328.15
5
1
0.0077092
5
1
0.0001987
1
333.15
5
1
0.0085638
5
1
0.0002209
7
7
1
2
1
1
1
Principal objective of the work
PW
TRC
9/27/2010
1
Mole fraction
laser monitoring observation technique
1
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
2
Mole fraction
2
Liquid
1
288.35
5
2
0.6
2
1
0.001772
4
1
6.9e-05
1
288.55
5
2
0.3
2
1
0.013259
5
1
0.000432
1
288.65
5
2
0.2
2
1
0.02059
5
1
0.000658
1
289.15
5
2
0.8
2
1
0.0001
3
1
6e-06
1
289.15
5
2
0.9
2
1
3.6e-05
2
1
3e-06
1
290.15
5
2
0.7
2
1
0.000647
3
1
2.9e-05
1
290.35
5
2
0.1
2
1
0.033367
5
1
0.001006
1
292.15
5
2
0.2
2
1
0.023982
5
1
0.000756
1
292.15
5
2
0.5
2
1
0.005531
4
1
0.000199
1
293.15
5
2
0.8
2
1
0.000167
3
1
9e-06
1
293.15
5
2
0.9
2
1
8e-05
2
1
6e-06
1
293.95
5
2
0.4
2
1
0.010671
5
1
0.000367
1
294.15
5
2
0.3
2
1
0.017234
5
1
0.000571
1
294.85
5
2
0.6
2
1
0.002597
4
1
0.000106
1
294.95
5
2
0.1
2
1
0.038205
5
1
0.001151
1
295.15
5
2
0.7
2
1
0.0009
3
1
4e-05
1
298.55
5
2
0.5
2
1
0.006794
4
1
0.00025
1
298.85
5
2
0.8
2
1
0.000315
3
1
1.7e-05
1
298.95
5
2
0.6
2
1
0.003218
4
1
0.00013
1
299.05
5
2
0.9
2
1
0.000216
3
1
1.4e-05
1
299.15
5
2
0.4
2
1
0.013253
5
1
0.000461
1
299.15
5
2
0.7
2
1
0.001161
4
1
5.1e-05
1
299.85
5
2
0.1
2
1
0.043876
5
1
0.001324
1
299.95
5
2
0.3
2
1
0.021437
5
1
0.000706
1
300.15
5
2
0.2
2
1
0.032386
5
1
0.00102
1
303.15
5
2
0.5
2
1
0.008085
4
1
0.000299
1
303.35
5
2
0.2
2
1
0.035598
5
1
0.001113
1
303.35
5
2
0.6
2
1
0.00407
4
1
0.000164
1
303.35
5
2
0.7
2
1
0.001525
4
1
6.8e-05
1
303.35
5
2
0.8
2
1
0.000484
3
1
2.5e-05
1
303.45
5
2
0.9
2
1
0.000395
3
1
2.4e-05
1
303.55
5
2
0.4
2
1
0.015659
5
1
0.000546
1
303.65
5
2
0.1
2
1
0.048703
5
1
0.001468
1
304.15
5
2
0.3
2
1
0.02463
5
1
0.000807
1
307.15
5
2
0.3
2
1
0.026601
5
1
0.00087
1
307.65
5
2
0.4
2
1
0.018533
5
1
0.000649
1
307.65
5
2
0.6
2
1
0.004992
4
1
0.000201
1
307.65
5
2
0.7
2
1
0.001963
4
1
8.7e-05
1
307.85
5
2
0.5
2
1
0.009655
4
1
0.000358
1
308.15
5
2
0.2
2
1
0.039492
5
1
0.00123
1
308.15
5
2
0.8
2
1
0.000703
3
1
3.5e-05
1
308.35
5
2
0.9
2
1
0.000655
3
1
3.8e-05
1
308.45
5
2
0.1
2
1
0.053974
5
1
0.001628
1
312.15
5
2
0.1
2
1
0.058682
5
1
0.001772
1
312.15
5
2
0.5
2
1
0.011619
5
1
0.000435
1
312.15
5
2
0.8
2
1
0.000918
3
1
4.5e-05
1
312.35
5
2
0.4
2
1
0.022266
5
1
0.000781
1
312.55
5
2
0.7
2
1
0.002542
4
1
0.000112
1
312.65
5
2
0.3
2
1
0.030457
5
1
0.000997
1
313.15
5
2
0.6
2
1
0.006494
4
1
0.000261
1
313.45
5
2
0.9
2
1
0.000945
3
1
5.4e-05
1
314.15
5
2
0.2
2
1
0.043234
5
1
0.001348
1
316.65
5
2
0.4
2
1
0.026589
5
1
0.000936
1
316.65
5
2
0.5
2
1
0.014245
5
1
0.000535
1
317.15
5
2
0.1
2
1
0.063817
5
1
0.001927
1
317.15
5
2
0.2
2
1
0.044836
5
1
0.001394
1
317.35
5
2
0.6
2
1
0.007941
4
1
0.000319
1
318.15
5
2
0.3
2
1
0.034286
5
1
0.001122
1
318.15
5
2
0.7
2
1
0.003369
4
1
0.000148
1
319.15
5
2
0.8
2
1
0.00128
4
1
6.2e-05
1
319.15
5
2
0.9
2
1
0.001206
4
1
6.8e-05
1
320.35
5
2
0.5
2
1
0.016642
5
1
0.000626
1
320.45
5
2
0.4
2
1
0.030792
5
1
0.001085
1
322.15
5
2
0.2
2
1
0.046696
5
1
0.001491
1
323.15
5
2
0.1
2
1
0.069262
5
1
0.002096
1
323.15
5
2
0.5
2
1
0.019126
5
1
0.000721
1
323.15
5
2
0.6
2
1
0.010373
5
1
0.000423
1
323.15
5
2
0.8
2
1
0.001485
4
1
9.2e-05
1
323.15
5
2
0.9
2
1
0.001313
4
1
7.4e-05
1
323.65
5
2
0.7
2
1
0.004436
4
1
0.000204
1
324.15
5
2
0.3
2
1
0.038036
5
1
0.001246
1
325.25
5
2
0.4
2
1
0.036367
5
1
0.001268