2
0
2009
wei
che
4
journal
Original
Wei, D.[Dongwei]
Chen, L.[Limei]
Xu, J.[Jingjing]
Li, F.[Fusheng]
J. Chem. Eng. Data
2009
2020-09-29
Solubility of Irganox 1010 in (Alcohol + Water) Mixtures from (293.15 to 333.15) K
The solubility of Irganox 1010 in (methanol + water), (ethanol + water), and (2-propanol + water) mixed solvents was determined in the temperature range from (293.15 to 333.15) K by a static analytical method. The concentrations of the investigated Irganox 1010 in saturated solution were analyzed by UV spectrometry. A semiempirical equation was proposed to correlate the experimental data. The apparent molar enthalpies of Irganox 1010 in the three systems were determined from the temperature dependence of the solubilities.
10.1021/je900435t
8
54
2304-2306
1
InChI=1S/C73H108O12/c1-65(2,3)49-33-45(34-50(61(49)78)66(4,5)6)25-29-57(74)82-41-73(42-83-58(75)30-26-46-35-51(67(7,8)9)62(79)52(36-46)68(10,11)12,43-84-59(76)31-27-47-37-53(69(13,14)15)63(80)54(38-47)70(16,17)18)44-85-60(77)32-28-48-39-55(71(19,20)21)64(81)56(40-48)72(22,23)24/h33-40,78-81H,25-32,41-44H2,1-24H3
BGYHLZZASRKEJE-UHFFFAOYSA-N
pentaerythritol tetra(3,5-di-tert-butyl-4-hydroxyhydrocinnamate)
irganox 1010
C73H108O12
1
Commercial source
1
Crystallization from solution
2
99.5
3
Fraction melting in an adiabatic calorimeter
2
InChI=1S/CH4O/c1-2/h2H,1H3
OKKJLVBELUTLKV-UHFFFAOYSA-N
methanol
methyl alcohol
CH4O
1
Commercial source
1
99.5
3
Stated by supplier
3
InChI=1S/C2H6O/c1-2-3/h3H,2H2,1H3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N
ethanol
ethyl alcohol
C2H6O
1
Commercial source
1
99.5
3
Stated by supplier
4
InChI=1S/C3H8O/c1-3(2)4/h3-4H,1-2H3
KFZMGEQAYNKOFK-UHFFFAOYSA-N
propan-2-ol
2-propanol
isopropanol
isopropyl alcohol
sec-propyl alcohol
C3H8O
1
Commercial source
1
99.5
3
Stated by supplier
5
InChI=1S/H2O/h1H2
XLYOFNOQVPJJNP-UHFFFAOYSA-N
water
H2O
1
Not stated in the document
1
2
1
1
1
Principal objective of the work
RDC
TRC
8/19/2009
1
Mass fraction
UV Spectrometry
1
Liquid
Direct value, X
2
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
293.15
5
1
0.0002208
4
1
1.19e-05
1
298.15
5
1
0.0003324
4
1
1.8e-05
1
303.15
5
1
0.000544
4
1
2.94e-05
1
308.15
5
1
0.0008123
4
1
4.39e-05
1
313.15
5
1
0.001258
4
1
6.8e-05
1
318.15
5
1
0.002031
4
1
0.00011
1
323.15
5
1
0.002873
4
1
0.000155
1
328.15
5
1
0.00429
4
1
0.000232
1
333.15
5
1
0.00726
4
1
0.000392
2
3
1
1
1
Principal objective of the work
RDC
TRC
8/19/2009
1
Mass fraction
UV Spectrometry
1
Liquid
Direct value, X
3
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
293.15
5
1
0.0003022
4
1
1.66e-05
1
298.15
5
1
0.0004452
4
1
2.44e-05
1
303.15
5
1
0.0006846
4
1
3.75e-05
1
308.15
5
1
0.001051
4
1
7.7e-05
1
313.15
5
1
0.001595
4
1
8.7e-05
1
318.15
5
1
0.002378
4
1
0.00013
1
323.15
5
1
0.003508
4
1
0.000192
1
328.15
5
1
0.0051
4
1
0.000278
1
333.15
5
1
0.007403
4
1
0.000403
3
4
1
1
1
Principal objective of the work
RDC
TRC
8/19/2009
1
Mass fraction
UV Spectrometry
1
Liquid
Direct value, X
4
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
293.15
5
1
0.0001475
4
1
8.2e-06
1
298.15
5
1
0.0002388
4
1
1.32e-05
1
303.15
5
1
0.0004061
4
1
2.23e-05
1
308.15
5
1
0.00063174
5
1
3.465e-05
1
313.15
5
1
0.0009978
4
1
5.47e-05
1
318.15
5
1
0.001579
4
1
8.7e-05
1
323.15
5
1
0.002524
4
1
0.000139
1
328.15
5
1
0.004108
4
1
0.000225
1
333.15
5
1
0.006378
4
1
0.000348
4
2
1
1
1
5
1
Principal objective of the work
LA
TRC
8/19/2009
1
Mass fraction
UV Spectrometry
1
Liquid
Direct value, X
2
5
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
2
Solvent: Mass fraction
5
Liquid
1
293.15
5
2
0
2
1
0.0002208
4
1
1.19e-05
1
293.15
5
2
0.03
1
1
0.0001265
4
1
6.8e-06
1
293.15
5
2
0.05
1
1
0.04156
4
1
0.00225
1
298.15
5
2
0
2
1
0.0003324
4
1
1.8e-05
1
298.15
5
2
0.03
1
1
0.0001924
4
1
1.04e-05
1
298.15
5
2
0.05
1
1
0.06188
4
1
0.00334
1
303.15
5
2
0
2
1
0.000544
4
1
2.94e-05
1
303.15
5
2
0.03
1
1
0.0002907
4
1
1.57e-05
1
303.15
5
2
0.05
1
1
0.0927
3
1
0.005
1
308.15
5
2
0
2
1
0.0008123
4
1
4.39e-05
1
308.15
5
2
0.03
1
1
0.0004327
4
1
2.34e-05
1
308.15
5
2
0.05
1
1
0.1314
4
1
0.0071
1
313.15
5
2
0
2
1
0.001258
4
1
6.8e-05
1
313.15
5
2
0.03
1
1
0.0006464
4
1
3.49e-05
1
313.15
5
2
0.05
1
1
0.2058
4
1
0.0111
1
318.15
5
2
0
2
1
0.002031
4
1
0.00011
1
318.15
5
2
0.03
1
1
0.001003
4
1
5.4e-05
1
318.15
5
2
0.05
1
1
0.3194
4
1
0.0173
1
323.15
5
2
0
2
1
0.002873
4
1
0.000155
1
323.15
5
2
0.03
1
1
0.001539
4
1
8.3e-05
1
323.15
5
2
0.05
1
1
0.4504
4
1
0.0244
1
328.15
5
2
0
2
1
0.00429
4
1
0.000232
1
328.15
5
2
0.03
1
1
0.002292
4
1
0.000124
1
328.15
5
2
0.05
1
1
0.6692
4
1
0.0364
1
333.15
5
2
0
2
1
0.00726
4
1
0.000392
1
333.15
5
2
0.03
1
1
0.003299
4
1
0.000178
1
333.15
5
2
0.05
1
1
0.9166
4
1
0.0547
5
3
1
1
1
5
1
Principal objective of the work
LA
TRC
8/19/2009
1
Mass fraction
UV Spectrometry
1
Liquid
Direct value, X
3
5
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
2
Solvent: Mass fraction
5
Liquid
1
293.15
5
2
0
2
1
0.0003022
4
1
1.63e-05
1
293.15
5
2
0.03
1
1
0.000163
4
1
8.8e-06
1
293.15
5
2
0.05
1
1
0.0001389
4
1
7.5e-06
1
298.15
5
2
0
2
1
0.0004452
4
1
2.41e-05
1
298.15
5
2
0.03
1
1
0.0002787
4
1
1.51e-05
1
298.15
5
2
0.05
1
1
0.0002078
4
1
1.12e-05
1
303.15
5
2
0
2
1
0.0006846
4
1
3.7e-05
1
303.15
5
2
0.03
1
1
0.0004117
4
1
2.22e-05
1
303.15
5
2
0.05
1
1
0.0003024
4
1
1.63e-05
1
308.15
5
2
0
2
1
0.001051
4
1
7.6e-05
1
308.15
5
2
0.03
1
1
0.0005517
4
1
2.98e-05
1
308.15
5
2
0.05
1
1
0.0004497
4
1
2.43e-05
1
313.15
5
2
0
2
1
0.001595
4
1
8.6e-05
1
313.15
5
2
0.03
1
1
0.0008454
4
1
4.57e-05
1
313.15
5
2
0.05
1
1
0.0006601
4
1
3.57e-05
1
318.15
5
2
0
2
1
0.002378
4
1
0.000129
1
318.15
5
2
0.03
1
1
0.001201
4
1
6.5e-05
1
318.15
5
2
0.05
1
1
0.0009991
4
1
5.4e-05
1
323.15
5
2
0
2
1
0.003508
4
1
0.00019
1
323.15
5
2
0.03
1
1
0.001748
4
1
9.4e-05
1
323.15
5
2
0.05
1
1
0.001485
4
1
8e-05
1
328.15
5
2
0
2
1
0.0051
4
1
0.000276
1
328.15
5
2
0.03
1
1
0.002655
4
1
0.000143
1
328.15
5
2
0.05
1
1
0.002213
4
1
0.00012
1
333.15
5
2
0
2
1
0.007403
4
1
0.0004
1
333.15
5
2
0.03
1
1
0.004025
4
1
0.000218
1
333.15
5
2
0.05
1
1
0.003096
4
1
0.000167
6
4
1
1
1
5
1
Principal objective of the work
LA
TRC
8/19/2009
1
Mass fraction
UV Spectrometry
1
Liquid
Direct value, X
4
5
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
2
Solvent: Mass fraction
5
Liquid
1
293.15
5
2
0
2
1
0.0001475
4
1
8.2e-06
1
293.15
5
2
0.03
1
1
0.0001287
4
1
7.2e-06
1
293.15
5
2
0.05
1
1
9.455e-05
4
1
5.17e-06
1
298.15
5
2
0
2
1
0.0002388
4
1
1.32e-05
1
298.15
5
2
0.03
1
1
0.0002084
4
1
1.15e-05
1
298.15
5
2
0.05
1
1
0.0001346
4
1
7.4e-06
1
303.15
5
2
0
2
1
0.0004061
4
1
2.23e-05
1
303.15
5
2
0.03
1
1
0.0003385
4
1
1.86e-05
1
303.15
5
2
0.05
1
1
0.0002041
4
1
1.12e-05
1
308.15
5
2
0
2
1
0.00063174
5
1
3.465e-05
1
308.15
5
2
0.03
1
1
0.000521
4
1
2.85e-05
1
308.15
5
2
0.05
1
1
0.0003166
4
1
1.74e-05
1
313.15
5
2
0
2
1
0.0009978
4
1
5.47e-05
1
313.15
5
2
0.03
1
1
0.0008069
4
1
4.42e-05
1
313.15
5
2
0.05
1
1
0.0005089
4
1
2.79e-05
1
318.15
5
2
0
2
1
0.001579
4
1
8.7e-05
1
318.15
5
2
0.03
1
1
0.001223
4
1
6.7e-05
1
318.15
5
2
0.05
1
1
0.0008014
4
1
4.39e-05
1
323.15
5
2
0
2
1
0.002524
4
1
0.000139
1
323.15
5
2
0.03
1
1
0.002166
4
1
0.000119
1
323.15
5
2
0.05
1
1
0.001244
4
1
6.9e-05
1
328.15
5
2
0
2
1
0.004108
4
1
0.000225
1
328.15
5
2
0.03
1
1
0.003221
4
1
0.000176
1
328.15
5
2
0.05
1
1
0.002158
4
1
0.000118
1
333.15
5
2
0
2
1
0.006378
4
1
0.000348
1
333.15
5
2
0.03
1
1
0.004898
4
1
0.000266
1
333.15
5
2
0.05
1
1
0.002928
4
1
0.000159