2
0
2010
red
swa
0
journal
Original
Reddy, K. S.
Swamy, A. V. N.
Prasad, T. E. V.[T. E. Vittal]
Prasad, D. H. L.
J. Chem. Eng. Data
2010
2020-09-29
Vapor-Liquid Equilibria of Binary Mixtures Formed by Hexan-1-ol with Chloroethanes and Chloroethenes at 95.6 kPa
Bubble-point temperatures (at 95.6 kPa) over the entire composition range are measured for the binary mixtures formed by hexan-1-ol with 1,2-dichloroethane, 1,1,2,2-tetrachloroethane, trichloroethene, and tetrachloroehene, employing a Swietoslawski type ebulliometer. Both Wilson and nonrandom two-liquid (NRTL) models are found to represent the measured liquid-phase composition versus bubble-point temperature data well. The computed values of the vapor-phase mole fractions, liquid-phase activity coefficients, and excess Gibbs energies are tabulated and briefly discussed.
10.1021/je9000608
6
55
2073-2076
1
InChI=1S/C6H14O/c1-2-3-4-5-6-7/h7H,2-6H2,1H3
ZSIAUFGUXNUGDI-UHFFFAOYSA-N
hexan-1-ol
1-hexanol
1-hydroxyhexane
amylcarbinol
hexyl alcohol
n-hexanol
n-hexyl alcohol
pentylcarbinol
C6H14O
1
Commercial source
1
Fractional distillation
Molecular sieve treatment
Fractional distillation
Molecular sieve treatment
2
99
2
Gas chromatography
2
InChI=1S/C2H4Cl2/c3-1-2-4/h1-2H2
WSLDOOZREJYCGB-UHFFFAOYSA-N
1,2-dichloroethane
1,2-ethylene dichloride
Freon 150
R-150
C2H4Cl2
1
Commercial source
1
Dried with chemical reagent
Solvent extraction
Fractional distillation
Dried with chemical reagent
Solvent extraction
Fractional distillation
Dried with chemical reagent
Solvent extraction
Fractional distillation
2
99
2
Gas chromatography
3
InChI=1S/C2H2Cl4/c3-1(4)2(5)6/h1-2H
QPFMBZIOSGYJDE-UHFFFAOYSA-N
1,1,2,2-tetrachloroethane
Freon 130
R-130
acetylene tetrachloride
sym-tetrachloroethane
C2H2Cl4
1
Commercial source
1
Chemical reagent treatment
Dried with chemical reagent
Solvent extraction
Fractional distillation
Chemical reagent treatment
Dried with chemical reagent
Solvent extraction
Fractional distillation
Chemical reagent treatment
Dried with chemical reagent
Solvent extraction
Fractional distillation
Chemical reagent treatment
Dried with chemical reagent
Solvent extraction
Fractional distillation
2
99
2
Gas chromatography
4
InChI=1S/C2HCl3/c3-1-2(4)5/h1H
XSTXAVWGXDQKEL-UHFFFAOYSA-N
trichloroethene
1,1,2-trichloroethylene
trichloroethylene
C2HCl3
1
Commercial source
1
Fractional distillation
2
99
2
Gas chromatography
5
InChI=1S/C2Cl4/c3-1(4)2(5)6
CYTYCFOTNPOANT-UHFFFAOYSA-N
tetrachloroethene
perchloroethylene
tetrachloroethylene
C2Cl4
1
Commercial source
1
Dried with chemical reagent
Fractional distillation
Dried with chemical reagent
Fractional distillation
2
99
2
Gas chromatography
1
1
1
Principal objective of the work
KNA
TRC
6/15/2010
1
Refractive index (Na D-line)
Standard Abbe refractometry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.325
6
1
1.4157
5
1
0.0008
2
1
1
Principal objective of the work
KNA
TRC
6/15/2010
1
Mass density, kg/m3
Pycnometric method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.325
6
1
815.3
4
1
0.8
3
1
1
Principal objective of the work
PW
TRC
6/15/2010
1
Vapor or sublimation pressure, kPa
Ebulliometric method (Recirculating still)
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Temperature, K
Liquid
1
428.45
5
1
95.6
3
1
1
4
2
1
Principal objective of the work
KNA
TRC
6/15/2010
1
Refractive index (Na D-line)
Standard Abbe refractometry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
293.15
5
2
101.325
6
1
1.4196
5
1
0.0008
5
2
1
Principal objective of the work
KNA
TRC
6/15/2010
1
Mass density, kg/m3
Pycnometric method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
293.15
5
2
101.325
6
1
1252.9
5
1
1.3
6
2
1
Principal objective of the work
PW
TRC
6/15/2010
1
Vapor or sublimation pressure, kPa
Ebulliometric method (Recirculating still)
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Temperature, K
Liquid
1
355.15
5
1
95.6
3
1
1
7
3
1
Principal objective of the work
KNA
TRC
6/15/2010
1
Refractive index (Na D-line)
Standard Abbe refractometry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
293.15
5
2
101.325
6
1
1.494
4
1
0.0008
8
3
1
Principal objective of the work
KNA
TRC
6/15/2010
1
Mass density, kg/m3
Pycnometric method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
293.15
5
2
101.325
6
1
1593
4
1
1.8
9
3
1
Principal objective of the work
PW
TRC
6/15/2010
1
Vapor or sublimation pressure, kPa
Ebulliometric method (Recirculating still)
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Temperature, K
Liquid
1
417.25
5
1
95.6
3
1
1
10
4
1
Principal objective of the work
KNA
TRC
6/15/2010
1
Refractive index (Na D-line)
Standard Abbe refractometry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
303.15
5
2
101.325
6
1
1.475
4
1
0.0008
11
4
1
Principal objective of the work
KNA
TRC
6/15/2010
1
Mass density, kg/m3
Pycnometric method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
303.15
5
2
101.325
6
1
1451.3
5
1
1.6
12
4
1
Principal objective of the work
PW
TRC
6/15/2010
1
Vapor or sublimation pressure, kPa
Ebulliometric method (Recirculating still)
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Temperature, K
Liquid
1
358.45
5
1
95.6
3
1
1
13
5
1
Principal objective of the work
KNA
TRC
6/15/2010
1
Refractive index (Na D-line)
Standard Abbe refractometry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
293.15
5
2
101.325
6
1
1.5058
5
1
0.0008
14
5
1
Principal objective of the work
KNA
TRC
6/15/2010
1
Mass density, kg/m3
Pycnometric method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
293.15
5
2
101.325
6
1
1623
4
1
1.8
15
5
1
Principal objective of the work
PW
TRC
6/15/2010
1
Vapor or sublimation pressure, kPa
Ebulliometric method (Recirculating still)
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Temperature, K
Liquid
1
392.15
5
1
95.6
3
1
1
16
2
1
1
1
Principal objective of the work
KNA
TRC
6/15/2010
1
Boiling temperature at pressure P, K
Ebulliometric method (Recirculating still)
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Pressure, kPa
Liquid
95.6
3
1
Mole fraction
2
Liquid
1
0
2
1
428.45
5
1
0.12
1
0.0625
3
1
414.55
5
1
0.12
1
0.1497
4
1
400.25
5
1
0.12
1
0.2122
4
1
392.75
5
1
0.12
1
0.2604
4
1
388.05
5
1
0.12
1
0.3229
4
1
383.05
5
1
0.12
1
0.4132
4
1
377.15
5
1
0.12
1
0.4757
4
1
373.85
5
1
0.12
1
0.5137
4
1
371.95
5
1
0.12
1
0.5762
4
1
369.25
5
1
0.12
1
0.6138
4
1
367.75
5
1
0.12
1
0.6763
4
1
365.45
5
1
0.12
1
0.7406
4
1
363.15
5
1
0.12
1
0.8031
4
1
361.15
5
1
0.12
1
0.8656
4
1
359.25
5
1
0.12
1
0.9345
4
1
357.15
5
1
0.12
1
1
5
1
355.15
5
1
0.12
17
3
1
1
1
Principal objective of the work
KNA
TRC
6/15/2010
1
Boiling temperature at pressure P, K
Ebulliometric method (Recirculating still)
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Pressure, kPa
Liquid
95.6
3
1
Mole fraction
3
Liquid
1
0
2
1
428.45
5
1
0.12
1
0.0625
3
1
425.15
5
1
0.12
1
0.1164
4
1
423.95
5
1
0.12
1
0.1792
4
1
422.65
5
1
0.12
1
0.2832
4
1
421.35
5
1
0.12
1
0.3457
4
1
420.75
5
1
0.12
1
0.4082
4
1
420.25
5
1
0.12
1
0.5131
4
1
419.65
5
1
0.12
1
0.5756
4
1
419.15
5
1
0.12
1
0.6381
4
1
418.85
5
1
0.12
1
0.7006
4
1
418.55
5
1
0.12
1
0.7631
4
1
418.25
5
1
0.12
1
0.8256
4
1
417.95
5
1
0.12
1
0.8881
4
1
417.65
5
1
0.12
1
0.9131
4
1
417.55
5
1
0.12
1
1
5
1
417.25
5
1
0.12
18
4
1
1
1
Principal objective of the work
KNA
TRC
6/15/2010
1
Boiling temperature at pressure P, K
Ebulliometric method (Recirculating still)
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Pressure, kPa
Liquid
95.6
3
1
Mole fraction
4
Liquid
1
0
2
1
428.45
5
1
0.12
1
0.0625
3
1
419.35
5
1
0.12
1
0.1343
4
1
410.25
5
1
0.12
1
0.1968
4
1
403.55
5
1
0.12
1
0.2368
4
1
399.95
5
1
0.12
1
0.2993
4
1
393.95
5
1
0.12
1
0.3829
4
1
387.45
5
1
0.12
1
0.4454
4
1
383.25
5
1
0.12
1
0.5206
4
1
378.65
5
1
0.12
1
0.5831
4
1
375.25
5
1
0.12
1
0.6768
4
1
370.65
5
1
0.12
1
0.7393
4
1
367.85
5
1
0.12
1
0.8072
4
1
365.15
5
1
0.12
1
0.8697
4
1
362.75
5
1
0.12
1
0.9262
4
1
360.85
5
1
0.12
1
1
5
1
358.45
5
1
0.12
19
1
1
5
1
Principal objective of the work
KNA
TRC
6/15/2010
1
Boiling temperature at pressure P, K
Ebulliometric method (Recirculating still)
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Pressure, kPa
Liquid
95.6
3
1
Mole fraction
5
Liquid
1
0
2
1
428.45
5
1
0.12
1
0.0625
3
1
422.05
5
1
0.12
1
0.1198
4
1
417.75
5
1
0.12
1
0.1823
4
1
414.25
5
1
0.12
1
0.29
4
1
409.65
5
1
0.12
1
0.3525
4
1
407.45
5
1
0.12
1
0.4051
4
1
405.85
5
1
0.12
1
0.4676
4
1
404.85
5
1
0.12
1
0.5214
4
1
402.75
5
1
0.12
1
0.5839
4
1
401.15
5
1
0.12
1
0.6476
4
1
399.65
5
1
0.12
1
0.7101
4
1
398.25
5
1
0.12
1
0.7861
4
1
396.65
5
1
0.12
1
0.8351
4
1
395.55
5
1
0.12
1
0.9168
4
1
393.85
5
1
0.12
1
1
5
1
392.15
5
1
0.12