2
0
2009
yos
bay
0
journal
Original
Yoshimura, M.[Masatoshi]
Baylaucq, A.[Antoine]
Bazile, J.-P.[Jean-Patrick]
Ushiki, H.[Hideharu]
Boned, C.[Christian]
J. Chem. Eng. Data
2009
2020-09-29
Volumetric Properties of 2-Alkylamines (2-Aminobutane and 2-Aminooctane) at Pressures up to 140 MPa and Temperatures between (293.15 and 403.15) K
This work reports the density data (352 points) of two 2-alkylamines (2-aminobutane and 2-aminooctane; branched amines) at 12 temperatures between (293.15 and 403.15) K and pressures up to 140 MPa (every 10 MPa) which allows studying the influence of the chain length. An Anton Paar vibrating tube densimeter, calibrated with an uncertainty of ( 5 * 10-4 g *cm-3 was used to perform these measurements. The experimental density data were fitted with the Tait-like equation with low standard deviations (less than 2 * 10-4 g *cm-3). These data were used to derive the isobaric thermal expansivity and the isothermal compressibility.
10.1021/je800786k
6
54
1702-1709
1
InChI=1S/C4H11N/c1-3-4(2)5/h4H,3,5H2,1-2H3
BHRZNVHARXXAHW-UHFFFAOYSA-N
2-butanamine
1-methyl-1-propanamine
2-aminobutane
sec-butylamine
C4H11N
1
Commercial source
1
99.9
3
Gas chromatography
2
InChI=1S/C8H19N/c1-3-4-5-6-7-8(2)9/h8H,3-7,9H2,1-2H3
HBXNJMZWGSCKPW-UHFFFAOYSA-N
1-methylheptylamine
2-aminooctane
2-octanamine
C8H19N
1
Commercial source
1
99.41
4
Gas chromatography
1
1
1
Principal objective of the work
DCT
TRC
7/22/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
293.15
5
2
100
1
1
725.3
4
1
1.1
1
293.15
5
2
10000
1
1
733.6
4
1
1.1
1
293.15
5
2
20000
1
1
741.2
4
1
1.1
1
293.15
5
2
30000
1
1
748.1
4
1
1.1
1
293.15
5
2
40000
1
1
754.5
4
1
1.1
1
293.15
5
2
50000
1
1
760.4
4
1
1.2
1
293.15
5
2
60000
1
1
766.1
4
1
1.2
1
293.15
5
2
70000
1
1
771.3
4
1
1.2
1
293.15
5
2
80000
1
1
776.3
4
1
1.3
1
293.15
5
2
90000
1
1
781.1
4
1
1.3
1
293.15
5
2
100000
1
1
785.5
4
1
1.3
1
293.15
5
2
110000
2
1
789.7
4
1
1.4
1
293.15
5
2
120000
2
1
793.9
4
1
1.4
1
293.15
5
2
130000
2
1
797.8
4
1
1.4
1
293.15
5
2
140000
2
1
801.5
4
1
1.5
1
303.15
5
2
100
1
1
715.1
4
1
1.1
1
303.15
5
2
10000
1
1
724.3
4
1
1.1
1
303.15
5
2
20000
1
1
732.4
4
1
1.1
1
303.15
5
2
30000
1
1
739.7
4
1
1.1
1
303.15
5
2
40000
1
1
746.3
4
1
1.1
1
303.15
5
2
50000
1
1
752.5
4
1
1.2
1
303.15
5
2
60000
1
1
758.3
4
1
1.2
1
303.15
5
2
70000
1
1
763.7
4
1
1.2
1
303.15
5
2
80000
1
1
768.9
4
1
1.3
1
303.15
5
2
90000
1
1
773.8
4
1
1.3
1
303.15
5
2
100000
1
1
778.4
4
1
1.4
1
303.15
5
2
110000
2
1
782.9
4
1
1.4
1
303.15
5
2
120000
2
1
787.2
4
1
1.4
1
303.15
5
2
130000
2
1
791.2
4
1
1.5
1
303.15
5
2
140000
2
1
795.2
4
1
1.5
1
313.15
5
2
100
1
1
705
4
1
1.1
1
313.15
5
2
10000
1
1
714.8
4
1
1.1
1
313.15
5
2
20000
1
1
723.4
4
1
1.1
1
313.15
5
2
30000
1
1
731.1
4
1
1.1
1
313.15
5
2
40000
1
1
738.2
4
1
1.1
1
313.15
5
2
50000
1
1
744.7
4
1
1.2
1
313.15
5
2
60000
1
1
750.8
4
1
1.2
1
313.15
5
2
70000
1
1
756.5
4
1
1.3
1
313.15
5
2
80000
1
1
761.9
4
1
1.3
1
313.15
5
2
90000
1
1
767
4
1
1.3
1
313.15
5
2
100000
1
1
771.8
4
1
1.4
1
313.15
5
2
110000
2
1
776.4
4
1
1.4
1
313.15
5
2
120000
2
1
780.8
4
1
1.5
1
313.15
5
2
130000
2
1
785.1
4
1
1.5
1
313.15
5
2
140000
2
1
789.1
4
1
1.5
1
323.15
5
2
100
1
1
694.7
4
1
1.1
1
323.15
5
2
10000
1
1
705.4
4
1
1.1
1
323.15
5
2
20000
1
1
714.5
4
1
1.1
1
323.15
5
2
30000
1
1
722.8
4
1
1.1
1
323.15
5
2
40000
1
1
730.4
4
1
1.2
1
323.15
5
2
50000
1
1
737.2
4
1
1.2
1
323.15
5
2
60000
1
1
743.6
4
1
1.2
1
323.15
5
2
70000
1
1
749.5
4
1
1.3
1
323.15
5
2
80000
1
1
755.2
4
1
1.3
1
323.15
5
2
90000
1
1
760.4
4
1
1.3
1
323.15
5
2
100000
1
1
765.4
4
1
1.4
1
323.15
5
2
110000
2
1
770.2
4
1
1.4
1
323.15
5
2
120000
2
1
774.7
4
1
1.5
1
323.15
5
2
130000
2
1
779
4
1
1.5
1
323.15
5
2
140000
2
1
783.2
4
1
1.6
1
333.15
5
2
10000
1
1
695.4
4
1
1.1
1
333.15
5
2
20000
1
1
705.2
4
1
1.1
1
333.15
5
2
30000
1
1
714
4
1
1.1
1
333.15
5
2
40000
1
1
722
4
1
1.2
1
333.15
5
2
50000
1
1
729.2
4
1
1.2
1
333.15
5
2
60000
1
1
735.8
4
1
1.2
1
333.15
5
2
70000
1
1
742.1
4
1
1.3
1
333.15
5
2
80000
1
1
748
4
1
1.3
1
333.15
5
2
90000
1
1
753.4
4
1
1.4
1
333.15
5
2
100000
1
1
758.6
4
1
1.4
1
333.15
5
2
110000
2
1
763.5
4
1
1.5
1
333.15
5
2
120000
2
1
768.1
4
1
1.5
1
333.15
5
2
130000
2
1
772.5
4
1
1.5
1
333.15
5
2
140000
2
1
776.9
4
1
1.6
1
343.15
5
2
10000
1
1
685.9
4
1
1.1
1
343.15
5
2
20000
1
1
696.6
4
1
1.1
1
343.15
5
2
30000
1
1
706
4
1
1.2
1
343.15
5
2
40000
1
1
714.3
4
1
1.2
1
343.15
5
2
50000
1
1
721.9
4
1
1.2
1
343.15
5
2
60000
1
1
728.8
4
1
1.3
1
343.15
5
2
70000
1
1
735.3
4
1
1.3
1
343.15
5
2
80000
1
1
741.3
4
1
1.3
1
343.15
5
2
90000
1
1
747.1
4
1
1.4
1
343.15
5
2
100000
1
1
752.4
4
1
1.4
1
343.15
5
2
110000
2
1
757.4
4
1
1.5
1
343.15
5
2
120000
2
1
762.3
4
1
1.5
1
343.15
5
2
130000
2
1
767
4
1
1.6
1
343.15
5
2
140000
2
1
771.3
4
1
1.6
1
353.15
5
2
10000
1
1
675.8
4
1
1.1
1
353.15
5
2
20000
1
1
687.1
4
1
1.1
1
353.15
5
2
30000
1
1
697.2
4
1
1.2
1
353.15
5
2
40000
1
1
705.8
4
1
1.2
1
353.15
5
2
50000
1
1
714
4
1
1.2
1
353.15
5
2
60000
1
1
721.2
4
1
1.3
1
353.15
5
2
70000
1
1
728
4
1
1.3
1
353.15
5
2
80000
1
1
734.2
4
1
1.4
1
353.15
5
2
90000
1
1
740.1
4
1
1.4
1
353.15
5
2
100000
1
1
745.7
4
1
1.4
1
353.15
5
2
110000
2
1
751
4
1
1.5
1
353.15
5
2
120000
2
1
756
4
1
1.5
1
353.15
5
2
130000
2
1
760.7
4
1
1.6
1
353.15
5
2
140000
2
1
765.3
4
1
1.6
1
363.15
5
2
10000
1
1
665.7
4
1
1.2
1
363.15
5
2
20000
1
1
678
4
1
1.2
1
363.15
5
2
30000
1
1
688.5
4
1
1.2
1
363.15
5
2
40000
1
1
697.8
4
1
1.2
1
363.15
5
2
50000
1
1
706.2
4
1
1.2
1
363.15
5
2
60000
1
1
713.9
4
1
1.3
1
363.15
5
2
70000
1
1
721
4
1
1.3
1
363.15
5
2
80000
1
1
727.5
4
1
1.4
1
363.15
5
2
90000
1
1
733.6
4
1
1.4
1
363.15
5
2
100000
1
1
739.4
4
1
1.5
1
363.15
5
2
110000
2
1
744.8
4
1
1.5
1
363.15
5
2
120000
2
1
749.9
4
1
1.6
1
363.15
5
2
130000
2
1
754.8
4
1
1.6
1
363.15
5
2
140000
2
1
759.5
4
1
1.7
1
373.15
5
2
10000
1
1
655.5
4
1
1.2
1
373.15
5
2
20000
1
1
668.9
4
1
1.2
1
373.15
5
2
30000
1
1
680.1
4
1
1.2
1
373.15
5
2
40000
1
1
690
4
1
1.2
1
373.15
5
2
50000
1
1
698.2
4
1
1.3
1
373.15
5
2
60000
1
1
707
4
1
1.3
1
373.15
5
2
70000
1
1
714
4
1
1.3
1
373.15
5
2
80000
1
1
720.9
4
1
1.4
1
373.15
5
2
90000
1
1
727.2
4
1
1.4
1
373.15
5
2
100000
1
1
733.2
4
1
1.5
1
373.15
5
2
110000
2
1
738.7
4
1
1.5
1
373.15
5
2
120000
2
1
744
4
1
1.6
1
373.15
5
2
130000
2
1
749.1
4
1
1.6
1
373.15
5
2
140000
2
1
753.9
4
1
1.7
1
383.15
5
2
10000
1
1
645.5
4
1
1.2
1
383.15
5
2
20000
1
1
659.9
4
1
1.2
1
383.15
5
2
30000
1
1
671.9
4
1
1.2
1
383.15
5
2
40000
1
1
682.3
4
1
1.2
1
383.15
5
2
50000
1
1
691.4
4
1
1.3
1
383.15
5
2
60000
1
1
699.6
4
1
1.3
1
383.15
5
2
70000
1
1
707.3
4
1
1.4
1
383.15
5
2
80000
1
1
714.4
4
1
1.4
1
383.15
5
2
90000
1
1
720.8
4
1
1.5
1
383.15
5
2
100000
1
1
726.9
4
1
1.5
1
383.15
5
2
110000
2
1
732.7
4
1
1.6
1
383.15
5
2
120000
2
1
738.2
4
1
1.6
1
383.15
5
2
130000
2
1
743.3
4
1
1.7
1
383.15
5
2
140000
2
1
748.2
4
1
1.7
1
393.15
5
2
10000
1
1
634.9
4
1
1.2
1
393.15
5
2
20000
1
1
650.5
4
1
1.2
1
393.15
5
2
30000
1
1
663.1
4
1
1.2
1
393.15
5
2
40000
1
1
674.3
4
1
1.2
1
393.15
5
2
50000
1
1
684.3
4
1
1.3
1
393.15
5
2
60000
1
1
693
4
1
1.3
1
393.15
5
2
70000
1
1
700.9
4
1
1.4
1
393.15
5
2
80000
1
1
708.2
4
1
1.4
1
393.15
5
2
90000
1
1
714.9
4
1
1.5
1
393.15
5
2
100000
1
1
721.2
4
1
1.5
1
393.15
5
2
110000
2
1
727.2
4
1
1.6
1
393.15
5
2
120000
2
1
732.8
4
1
1.6
1
393.15
5
2
130000
2
1
738.1
4
1
1.7
1
393.15
5
2
140000
2
1
742.9
4
1
1.7
1
403.15
5
2
10000
1
1
623.9
4
1
1.2
1
403.15
5
2
20000
1
1
640.6
4
1
1.2
1
403.15
5
2
30000
1
1
654.5
4
1
1.2
1
403.15
5
2
40000
1
1
666.1
4
1
1.3
1
403.15
5
2
50000
1
1
676.3
4
1
1.3
1
403.15
5
2
60000
1
1
685.3
4
1
1.3
1
403.15
5
2
70000
1
1
693.6
4
1
1.4
1
403.15
5
2
80000
1
1
701.1
4
1
1.4
1
403.15
5
2
90000
1
1
708.2
4
1
1.5
1
403.15
5
2
100000
1
1
714.9
4
1
1.5
1
403.15
5
2
110000
2
1
721.1
4
1
1.6
1
403.15
5
2
120000
2
1
726.9
4
1
1.6
1
403.15
5
2
130000
2
1
732.3
4
1
1.7
1
403.15
5
2
140000
2
1
737.4
4
1
1.8
2
2
1
Principal objective of the work
DCT
TRC
7/22/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
293.15
5
2
100
1
1
772
4
1
1
1
293.15
5
2
10000
1
1
778.7
4
1
1.1
1
293.15
5
2
20000
1
1
784.8
4
1
1.1
1
293.15
5
2
30000
1
1
790.6
4
1
1.1
1
293.15
5
2
40000
1
1
796.1
4
1
1.1
1
293.15
5
2
50000
1
1
801.2
4
1
1.1
1
293.15
5
2
60000
1
1
806
4
1
1.2
1
293.15
5
2
70000
1
1
810.6
4
1
1.2
1
293.15
5
2
80000
1
1
815
4
1
1.2
1
293.15
5
2
90000
1
1
819.1
4
1
1.2
1
293.15
5
2
100000
1
1
823.2
4
1
1.3
1
293.15
5
2
110000
2
1
826.9
4
1
1.3
1
293.15
5
2
120000
2
1
830.6
4
1
1.3
1
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4
1
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