2
0
2009
kar
pla
0
journal
Original
Karasek, P.[Pavel]
Planeta, J.[Josef]
Roth, M.[Michal]
J. Chem. Eng. Data
2009
2020-09-29
Solubilities of Oxygenated Aromatic Solids in Pressurized Hot Water
Aqueous solubilities of xanthene (C13H10O), anthrone (C14H10O), xanthone (C13H8O2), thioxanthone (C13H8OS), 9,10-anthraquinone (C14H8O2), and 9,10-phenanthrenequinone (C14H8O2) were measured at temperatures from 313 K to the solute melting point and pressures close to 5 MPa by a dynamic method combined with gas chromatography/mass spectrometry. The experimental solubilities were used to estimate the activity coefficients of the solutes in the aqueous solutions at saturation. Relative rates of increase of solute solubility (mole fraction) with temperature ranged from 0.049 K-1 to 0.056 K-1.
10.1021/je800707x
5
54
1457-1461
1
InChI=1S/C13H10O/c1-3-7-12-10(5-1)9-11-6-2-4-8-13(11)14-12/h1-8H,9H2
GJCOSYZMQJWQCA-UHFFFAOYSA-N
10H-9-oxaanthracene
9H-xanthene
dibenzopyran
xanthene
C13H10O
1
Commercial source
1
Crystallization from solution
2
99
2
Gas chromatography
2
InChI=1S/C14H10O/c15-14-12-7-3-1-5-10(12)9-11-6-2-4-8-13(11)14/h1-8H,9H2
RJGDLRCDCYRQOQ-UHFFFAOYSA-N
9(10H)-anthracenone
9,10-dihydro-9-anthracenone
anthrone
C14H10O
1
Commercial source
1
Crystallization from solution
2
99
2
Gas chromatography
3
InChI=1S/C13H8O2/c14-13-9-5-1-3-7-11(9)15-12-8-4-2-6-10(12)13/h1-8H
JNELGWHKGNBSMD-UHFFFAOYSA-N
9H-xanthen-9-one
9-oxoxanthene
xanthone
C13H8O2
1
Commercial source
1
Crystallization from solution
2
99
2
Gas chromatography
4
InChI=1S/C13H8OS/c14-13-9-5-1-3-7-11(9)15-12-8-4-2-6-10(12)13/h1-8H
YRHRIQCWCFGUEQ-UHFFFAOYSA-N
thioxanthone
C13H8OS
1
Commercial source
1
Crystallization from solution
2
99
2
Gas chromatography
5
InChI=1S/C14H8O2/c15-13-9-5-1-2-6-10(9)14(16)12-8-4-3-7-11(12)13/h1-8H
RZVHIXYEVGDQDX-UHFFFAOYSA-N
9,10(9H,10H)-anthracenedione
9,10-anthracenedione
9,10-anthraquinone
9,10-dioxoanthracene
anthraquinone
C14H8O2
1
Commercial source
1
Crystallization from solution
2
99
2
Gas chromatography
6
InChI=1S/C14H8O2/c15-13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)14(13)16/h1-8H
YYVYAPXYZVYDHN-UHFFFAOYSA-N
9,10-phenanthrenedione
9,10-phenanthrenequinone
phenanthrene, 9,10-dihydro-9,10-dioxo-
phenanthrenequinone
C14H8O2
1
Commercial source
1
Crystallization from solution
2
99
2
Gas chromatography
7
InChI=1S/H2O/h1H2
XLYOFNOQVPJJNP-UHFFFAOYSA-N
water
H2O
1
Commercial source
1
Dried in a desiccator
(Reverse Osmosis)
2
99.9
3
Estimated by the compiler
1
1
1
7
1
Principal objective of the work
GC
TRC
7/21/2009
1
Mole fraction
Chromatography
1
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
313.2
4
2
5.3e-06
2
1
2.52e-07
3
1
3.1e-08
1
323.2
4
2
5.3e-06
2
1
4.71e-07
3
1
5.7e-08
1
333.2
4
2
5.1e-06
2
1
8.44e-07
3
1
1.03e-07
1
343.2
4
2
5.1e-06
2
1
1.45e-06
4
1
1.77e-07
1
353.2
4
2
5e-06
2
1
2.57e-06
4
1
3.13e-07
1
363.2
4
2
5e-06
2
1
4.27e-06
4
1
5.21e-07
1
368.2
4
2
5e-06
2
1
5.56e-06
4
1
6.78e-07
2
2
1
7
1
Principal objective of the work
GC
TRC
7/21/2009
1
Mole fraction
Chromatography
2
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
2
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
313.2
4
2
5100
2
1
3.45e-07
3
1
4.2e-08
1
333.2
4
2
5000
1
1
1.06e-06
4
1
1.29e-07
1
353.2
4
2
5800
2
1
3.18e-06
4
1
3.88e-07
1
373.2
4
2
5000
1
1
9.49e-06
4
1
1.159e-06
1
393.2
4
2
5000
1
1
2.79e-05
5
1
3.408e-06
1
413.2
4
2
5000
1
1
9.89e-05
5
1
1.2082e-05
1
423.2
4
2
5000
1
1
0.000126
6
1
1.5392e-05
3
3
1
7
1
Principal objective of the work
GC
TRC
7/21/2009
1
Mole fraction
Chromatography
3
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
3
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
313.2
4
2
5300
2
1
7.09e-07
3
1
8.7e-08
1
333.2
4
2
5100
2
1
1.93e-06
4
1
2.36e-07
1
353.2
4
2
5000
1
1
5.44e-06
4
1
6.65e-07
1
373.2
4
2
5000
1
1
1.29e-05
5
1
1.576e-06
1
393.2
4
2
5100
2
1
3.7e-05
5
1
4.522e-06
1
413.2
4
2
5000
1
1
9.13e-05
5
1
1.1157e-05
1
433.2
4
2
5000
1
1
0.000271
6
1
3.3118e-05
4
4
1
7
1
Principal objective of the work
GC
TRC
7/21/2009
1
Mole fraction
Chromatography
4
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
4
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
313.2
4
2
5400
2
1
1.18e-07
3
1
1.4e-08
1
333.2
4
2
5200
2
1
3.13e-07
3
1
3.8e-08
1
353.2
4
2
5100
2
1
8.79e-07
3
1
1.08e-07
1
373.2
4
2
5100
2
1
2.22e-06
4
1
2.72e-07
1
393.2
4
2
5300
2
1
6.44e-06
4
1
7.89e-07
1
413.2
4
2
5200
2
1
1.98e-05
5
1
2.427e-06
1
433.2
4
2
5300
2
1
5.5e-05
5
1
6.742e-06
1
453.2
4
2
5300
2
1
0.000135
6
1
1.6548e-05
1
473.2
4
2
6400
2
1
0.000383
6
1
4.6947e-05
5
5
1
7
1
Principal objective of the work
GC
TRC
7/21/2009
1
Mole fraction
Chromatography
5
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
5
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
313.2
4
2
5000
1
1
7.25e-08
3
1
8.9e-09
1
333.2
4
2
5000
1
1
2.05e-07
3
1
2.5e-08
1
353.2
4
2
5000
1
1
5.92e-07
3
1
7.3e-08
1
373.2
4
2
5100
2
1
1.56e-06
4
1
2.07e-07
1
393.2
4
2
5200
2
1
4.1e-06
4
1
5.02e-07
1
413.2
4
2
5000
1
1
1.06e-05
5
1
1.298e-06
1
433.2
4
2
5800
2
1
2.96e-05
5
1
3.625e-06
6
6
1
7
1
Principal objective of the work
GC
TRC
7/21/2009
1
Mole fraction
Chromatography
6
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
6
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
313.2
4
2
5200
2
1
5.5e-07
3
1
6.7e-08
1
333.2
4
2
5000
1
1
1.63e-06
4
1
2e-07
1
353.2
4
2
5000
1
1
4.18e-06
4
1
5.12e-07
1
373.2
4
2
5000
1
1
1.06e-05
5
1
1.298e-06
1
393.2
4
2
5000
1
1
3.94e-05
5
1
4.826e-06
1
413.2
4
2
5000
1
1
8.46e-05
5
1
1.0362e-05
1
433.2
4
2
5100
2
1
0.000255
6
1
3.1232e-05
1
453.2
4
2
5300
2
1
0.000842
6
1
0.000103131
1
473.2
4
2
5400
2
1
0.00183
7
1
0.000224153