Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solid Liquid Equilibria of the Ternary Sodium 3-Nitrobenzenesulfonate + Sodium 4-Nitrobenzenesulfonate + Water System

Li, R.-R.[Rong-Rong], Zhao, H.-k.[Hong-kun], Jiang, M.[Ming], Wang, Y.[Yong], Wang, Q.-F.[Qing-Feng]
J. Chem. Eng. Data 2011, 56, 6, 2955-2959
ABSTRACT
In this investigation, the mutual solubility for the ternary sodium 3-nitrobenzenesulfonate + sodium 4-nitrobenzenesulfonate + water system was determined at (283.15, 303.15, and 323.15) K. The phase diagrams of the system were constructed based on the measured solubility. The solid phases formed in the studied system were confirmed by Schreinemaker's wet residue method. In addition, the density of the equilibrium liquid phase was obtained. At (283.15, 303.15, and 323.15) K, there are two pure solids formed which correspond to sodium 3-nitrobenzenesulfonate and sodium 4-nitrobenzenesulfonate in the ternary sodium 3-nitrobenzenesulfonate + sodium 4-nitrobenzenesulfonate + water system. Besides, the adduct of sodium 3-nitrobenzenesulfonate with sodium 4-nitrobenzenesulfonate, in which the mole ratio of the two compositions is 1:1, was formed at 323.15 K.
Compounds
# Formula Name
1 C6H4NNaO5S sodium 3-nitrobenzenesulfonate
2 C6H4NNaO5S sodium 4-nitrobenzenesulfonate
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Mass fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Pycnometric method
  • 4
  • POMD
  • 1
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Crystal - 1
  • Pycnometric method
  • 1
  • POMD
  • 1
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Mass fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Pycnometric method
  • 7
  • POMD
  • 1
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • Crystal - 1
  • Pycnometric method
  • 1
  • POMD
  • 1
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Crystal - 1
  • Pycnometric method
  • 1
  • POMD
  • 1
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Mass fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Pycnometric method
  • 9
  • POMD
  • 1
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Mass fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Pycnometric method
  • 4
  • POMD
  • 1
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Mass fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Pycnometric method
  • 6
  • POMD
  • 1
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Mass fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Pycnometric method
  • 7
  • POMD
  • 1
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • Crystal - 2
  • Pycnometric method
  • 1
  • POMD
  • 1
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Mass fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • Pycnometric method
  • 5
  • POMD
  • 1
  • 2
  • 3
  • Mass fraction - 1 ; Liquid
  • Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 4
  • POMD
  • 1
  • 2
  • 3
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Crystal - 1
  • Chromatography
  • 1
  • POMD
  • 1
  • 2
  • 3
  • Mass fraction - 1 ; Liquid
  • Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 2
  • Chromatography
  • 7
  • POMD
  • 1
  • 2
  • 3
  • Mass fraction - 1 ; Liquid
  • Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 7
  • POMD
  • 1
  • 2
  • 3
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Crystal - 1
  • Chromatography
  • 1
  • POMD
  • 1
  • 2
  • 3
  • Mass fraction - 1 ; Liquid
  • Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 2
  • Chromatography
  • 9
  • POMD
  • 1
  • 2
  • 3
  • Mass fraction - 1 ; Liquid
  • Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 4
  • POMD
  • 1
  • 2
  • 3
  • Mass fraction - 1 ; Liquid
  • Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 2
  • Chromatography
  • 6
  • POMD
  • 1
  • 2
  • 3
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • Crystal - 1
  • Chromatography
  • 1
  • POMD
  • 1
  • 2
  • 3
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • Crystal - 2
  • Chromatography
  • 1
  • POMD
  • 1
  • 2
  • 3
  • Mass fraction - 1 ; Liquid
  • Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • Chromatography
  • 5
  • POMD
  • 1
  • 2
  • 3
  • Mass fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Crystal - 1
  • Chromatography
  • 1
  • POMD
  • 1
  • 2
  • 3
  • Mass fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Crystal - 1
  • Chromatography
  • 1
  • POMD
  • 1
  • 2
  • 3
  • Mass fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • Crystal - 1
  • Chromatography
  • 1
  • POMD
  • 1
  • 2
  • 3
  • Mass fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • Crystal - 2
  • Chromatography
  • 1