2
0
2010
ano
jac
1
journal
Original
Anouti, M.[Meriem]
Jacquemin, J.[Johan]
Lemordant, D.[Daniel]
J. Chem. Eng. Data
2010
2020-09-29
Volumetric Properties, Viscosities, and Isobaric Heat Capacities of Imidazolium Octanoate Protic Ionic Liquid in Molecular Solvents
Densities (?), viscosities (?), and isobaric heat molar capacities (Cp) of binary mixtures containing imidazolium octanoate, [Im][C7CO2], a protic ionic liquid (PIL), with four molecular solvents, water, acetonitrile, ethanol, and 1-octanol, are determined as a function of temperature from (298.15 to 323.15) K and within the whole composition range at atmospheric pressure. Excess molar volumes, VE, excess molar heat capacities, CpE, and the deviation from additivity rules of viscosities, ??, of imidazolium octanoate solutions were then deduced from the experimental results, as well as apparent molar volumes, Vi, and partial molar volumes, m,i. Results are discussed according to the nature of the interaction between the PIL and the molecules and the effect of temperature. The excess Gibbs energies of activation of viscous flow (?G*E) for these systems were then calculated at 298.15 K. The excess isobaric heat capacities, CpE, of binary ([Im][C7CO2] + solvent) systems, depend also of the nature of the molecular solvent in mixture. The excess properties were then correlated, at each temperature, as a function of composition by a Redlich-Kister-type equation. Finally results have been discussed in terms of molecular interactions and molecular structures in these binary mixtures, and thermodynamic properties of investigated binary mixtures were then compared to literature values together to investigate the impact of the nature of the solvent on these reported properties.
10.1021/je100671v
12
55
5719-5728
1
InChI=1S/C2H6O/c1-2-3/h3H,2H2,1H3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N
ethanol
ethyl alcohol
C2H6O
1
Commercial source
1
99
2
Stated by supplier
2
InChI=1S/C8H18O/c1-2-3-4-5-6-7-8-9/h9H,2-8H2,1H3
KBPLFHHGFOOTCA-UHFFFAOYSA-N
octan-1-ol
1-octanol
capryl alcohol
caprylic alcohol
n-octyl alcohol
octanol
octyl alcohol
C8H18O
1
Commercial source
1
99
2
Stated by supplier
3
InChI=1S/C2H3N/c1-2-3/h1H3
WEVYAHXRMPXWCK-UHFFFAOYSA-N
acetonitrile
cyanomethane
ethanenitrile
ethanonitrile
methanecarbonitrile
methyl cyanide
C2H3N
1
Commercial source
1
99
2
Stated by supplier
4
InChI=1S/H2O/h1H2
XLYOFNOQVPJJNP-UHFFFAOYSA-N
water
H2O
1
Commercial source
1
99.9
3
Estimated by the compiler
2
Fractional distillation
5
InChI=1S/C8H16O2.C3H4N2/c1-2-3-4-5-6-7-8(9)10;1-2-5-3-4-1/h2-7H2,1H3,(H,9,10);1-3H,(H,4,5)
NBCNEMVRIAPBNV-UHFFFAOYSA-N
1H-imidazolium octanoate
imidazolium octanoate
C11H20N2O2
1
Commercial source
1
Dried by vacuum heating
2
98.7
3
NMR (proton)
3
0.006
1
Karl Fischer titration
1
1
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Molar heat capacity at constant pressure, J/K/mol
Flow calorimetry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
1
298.15
5
1
112
4
1
0.4
1
303.15
5
1
114
4
1
0.4
1
308.15
5
1
116
4
1
0.4
1
313.15
5
1
118
4
1
0.4
2
1
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Viscosity, Pa*s
CAPTUB::UFactor:4
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
1
293.15
5
1
0.00121
3
1
4e-05
1
298.15
5
1
0.0011
4
1
3.5e-05
1
303.15
5
1
0.001
4
1
3.2e-05
1
308.15
5
1
0.00091
3
1
3e-05
1
313.15
5
1
0.00083
3
1
2.8e-05
1
318.15
5
1
0.00072
3
1
2.5e-05
1
323.15
5
1
0.000615
3
1
2.2e-05
3
1
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Mass density, kg/m3
Pycnometric method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.3
4
1
790
4
1
3.2
4
2
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Molar heat capacity at constant pressure, J/K/mol
Flow calorimetry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
1
298.15
5
1
304
4
1
1.4
1
303.15
5
1
329
4
1
1.5
1
308.15
5
1
354
4
1
1.5
1
313.15
5
1
379
4
1
1.6
5
2
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Viscosity, Pa*s
CAPTUB::UFactor:4
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
1
293.15
5
1
0.009183
4
1
0.000235
1
298.15
5
1
0.00784
4
1
0.000208
1
303.15
5
1
0.00642
4
1
0.000179
1
308.15
5
1
0.005341
4
1
0.000153
1
313.15
5
1
0.004661
4
1
0.000137
1
318.15
5
1
0.003701
4
1
0.000113
1
323.15
5
1
0.00284
4
1
9e-05
6
2
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Mass density, kg/m3
Pycnometric method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.3
4
1
824.5
4
1
3.3
7
3
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Molar heat capacity at constant pressure, J/K/mol
Flow calorimetry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
1
298.15
5
1
91.69
4
1
0.31
1
303.15
5
1
92.21
4
1
0.31
1
308.15
5
1
92.4
4
1
0.31
1
313.15
5
1
92.82
4
1
0.31
8
3
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Viscosity, Pa*s
CAPTUB:UFactor:4
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
1
293.15
5
1
0.00035
3
1
1.4e-05
1
298.15
5
1
0.000333
4
1
1.34e-05
1
303.15
5
1
0.000325
3
1
1.3e-05
1
308.15
5
1
0.000292
3
1
1.2e-05
1
313.15
5
1
0.000279
3
1
1.2e-05
1
318.15
5
1
0.000245
3
1
1.1e-05
1
323.15
5
1
0.000223
3
1
1e-05
9
3
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Mass density, kg/m3
Pycnometric method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.3
4
1
771.5
4
1
3.1
10
4
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Viscosity, Pa*s
CAPTUB::UFactor:4
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
1
293.15
5
1
0.001002
4
1
3.2e-05
1
298.15
5
1
0.00089
3
1
2.9e-05
1
303.15
5
1
0.000797
3
1
2.6e-05
1
308.15
5
1
0.000718
3
1
2.4e-05
1
313.15
5
1
0.000651
3
1
2.2e-05
1
318.15
5
1
0.000587
3
1
2e-05
1
323.15
5
1
0.000556
3
1
2e-05
11
4
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Mass density, kg/m3
Pycnometric method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.3
4
1
997.1
4
1
4
12
5
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Surface tension liquid-gas, N/m
UNKNOWN
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Air at 1 atmosphere
1
Temperature, K
Liquid
1
298.15
5
1
0.0328
3
1
0.0027
13
5
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Molar heat capacity at constant pressure, J/K/mol
Flow calorimetry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
1
298.15
5
1
769
4
1
2.6
1
303.15
5
1
772.4
4
1
2.6
1
303.15
5
1
772.6
4
1
2.6
1
308.15
5
1
782.2
4
1
2.6
1
308.15
5
1
782.3
4
1
2.6
1
313.15
5
1
788.1
4
1
2.6
1
313.15
5
1
788.2
4
1
2.6
14
5
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Viscosity, Pa*s
CAPTUB::UFactor:4
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
1
293.15
5
1
0.08848
4
1
0.00457
1
298.15
5
1
0.07127
4
1
0.00239
1
303.15
5
1
0.05648
4
1
0.00089
1
308.15
5
1
0.0453
4
1
0.00107
1
313.15
5
1
0.03692
4
1
0.00087
1
318.15
5
1
0.03056
4
1
0.00072
1
323.15
5
1
0.02533
4
1
0.00061
15
5
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Mass density, kg/m3
Pycnometric method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.3
4
1
987
4
1
4
16
1
1
5
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Mass density, kg/m3
Pycnometric method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
298.15
5
2
Pressure, kPa
Liquid
101.3
4
1
Mole fraction
5
Liquid
1
0
2
1
790
4
1
3.2
1
0.1011
4
1
853.9
4
1
3.4
1
0.2001
4
1
891.8
4
1
3.6
1
0.2994
4
1
918.8
4
1
3.7
1
0.4001
4
1
938.1
4
1
3.8
1
0.5214
4
1
954.6
4
1
3.9
1
0.6
4
1
962.7
4
1
3.9
1
0.699
4
1
970.1
4
1
3.9
1
0.8016
4
1
976.3
4
1
3.9
1
0.8957
4
1
981.6
4
1
4
1
1
5
1
987
4
1
4
17
1
1
5
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Molar heat capacity at constant pressure, J/K/mol
FLOW:UFactor:2
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mole fraction
5
Liquid
1
298.15
5
2
0
2
1
112
4
1
0.5
1
298.15
5
2
0.1011
4
1
188.6
4
1
0.8
1
298.15
5
2
0.2001
4
1
256.6
4
1
1.1
1
298.15
5
2
0.2994
4
1
317.3
4
1
1.3
1
298.15
5
2
0.4001
4
1
364.9
4
1
1.5
1
298.15
5
2
0.5214
4
1
420
4
1
1.7
1
298.15
5
2
0.6
4
1
458.2
4
1
1.9
1
298.15
5
2
0.699
4
1
516.2
4
1
2.1
1
298.15
5
2
0.8016
4
1
591
4
1
2.4
1
298.15
5
2
0.8957
4
1
667.5
4
1
2.8
1
298.15
5
2
1
1
1
769
4
1
3.2
1
303.15
5
2
0
2
1
114
4
1
0.5
1
303.15
5
2
0.1011
4
1
187.3
4
1
0.8
1
303.15
5
2
0.2001
4
1
255.1
4
1
1.1
1
303.15
5
2
0.2994
4
1
315.6
4
1
1.3
1
303.15
5
2
0.4001
4
1
360.4
4
1
1.5
1
303.15
5
2
0.5214
4
1
419.9
4
1
1.7
1
303.15
5
2
0.6
4
1
459.4
4
1
1.9
1
303.15
5
2
0.699
4
1
517.1
4
1
2.1
1
303.15
5
2
0.8016
4
1
591.6
4
1
2.5
1
303.15
5
2
0.8957
4
1
673.1
4
1
2.8
1
303.15
5
2
1
1
1
772.6
4
1
3.2
1
308.15
5
2
0
2
1
116
4
1
0.5
1
308.15
5
2
0.1011
4
1
187.1
4
1
0.8
1
308.15
5
2
0.2001
4
1
254.3
4
1
1.1
1
308.15
5
2
0.2994
4
1
312.3
4
1
1.3
1
308.15
5
2
0.4001
4
1
358.7
4
1
1.5
1
308.15
5
2
0.5214
4
1
421.1
4
1
1.7
1
308.15
5
2
0.6
4
1
462.5
4
1
1.9
1
308.15
5
2
0.699
4
1
520.9
4
1
2.2
1
308.15
5
2
0.8016
4
1
596.5
4
1
2.5
1
308.15
5
2
0.8957
4
1
681.9
4
1
2.8
1
308.15
5
2
1
1
1
782.3
4
1
3.3
1
313.15
5
2
0
2
1
118
4
1
0.5
1
313.15
5
2
0.1011
4
1
186.6
4
1
0.8
1
313.15
5
2
0.2001
4
1
253.8
4
1
1.1
1
313.15
5
2
0.2994
4
1
308.3
4
1
1.3
1
313.15
5
2
0.4001
4
1
357
4
1
1.5
1
313.15
5
2
0.5214
4
1
419.7
4
1
1.7
1
313.15
5
2
0.6
4
1
464.1
4
1
1.9
1
313.15
5
2
0.699
4
1
523.8
4
1
2.2
1
313.15
5
2
0.8016
4
1
599.4
4
1
2.5
1
313.15
5
2
0.8957
4
1
683.6
4
1
2.8
1
313.15
5
2
1
1
1
788.2
4
1
3.3
18
1
1
5
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Viscosity, Pa*s
CAPTUB:UFactor:4
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mole fraction
5
Liquid
1
293.15
5
2
0
2
1
0.00121
3
1
4e-05
1
293.15
5
2
0.1011
4
1
0.003236
4
1
9.7e-05
1
293.15
5
2
0.2001
4
1
0.006029
4
1
0.000169
1
293.15
5
2
0.2994
4
1
0.01032
4
1
0.00026
1
293.15
5
2
0.4001
4
1
0.0145
3
1
0.0004
1
293.15
5
2
0.5214
4
1
0.0229
3
1
0.0005
1
293.15
5
2
0.6
4
1
0.0298
3
1
0.0007
1
293.15
5
2
0.699
4
1
0.0404
3
1
0.0009
1
293.15
5
2
0.8016
4
1
0.05379
4
1
0.00064
1
293.15
5
2
0.8957
4
1
0.06868
4
1
0.00207
1
293.15
5
2
1
1
1
0.08848
4
1
0.00457
1
298.15
5
2
0
2
1
0.0011
4
1
3.5e-05
1
298.15
5
2
0.1011
4
1
0.002949
4
1
8.7e-05
1
298.15
5
2
0.2001
4
1
0.005466
4
1
0.000154
1
298.15
5
2
0.2994
4
1
0.009322
4
1
0.000236
1
298.15
5
2
0.4001
4
1
0.0133
4
1
0.00032
1
298.15
5
2
0.5214
4
1
0.02
4
1
0.00047
1
298.15
5
2
0.6
4
1
0.0255
4
1
0.00059
1
298.15
5
2
0.699
4
1
0.034
4
1
0.00078
1
298.15
5
2
0.8016
4
1
0.04447
4
1
0.00103
1
298.15
5
2
0.8957
4
1
0.05578
4
1
0.00081
1
298.15
5
2
1
1
1
0.07127
4
1
0.00239
1
303.15
5
2
0
2
1
0.001
4
1
3.2e-05
1
303.15
5
2
0.1011
4
1
0.002686
4
1
8e-05
1
303.15
5
2
0.2001
4
1
0.004927
4
1
0.000142
1
303.15
5
2
0.2994
4
1
0.008398
4
1
0.000215
1
303.15
5
2
0.4001
4
1
0.012
4
1
0.00029
1
303.15
5
2
0.5214
4
1
0.0178
4
1
0.00042
1
303.15
5
2
0.6
4
1
0.0223
4
1
0.00052
1
303.15
5
2
0.699
4
1
0.0289
4
1
0.00067
1
303.15
5
2
0.8016
4
1
0.03653
4
1
0.00085
1
303.15
5
2
0.8957
4
1
0.04496
4
1
0.00105
1
303.15
5
2
1
1
1
0.05648
4
1
0.00089
1
308.15
5
2
0
2
1
0.00091
3
1
3e-05
1
308.15
5
2
0.1011
4
1
0.002471
4
1
7.4e-05
1
308.15
5
2
0.2001
4
1
0.00454
4
1
0.000131
1
308.15
5
2
0.2994
4
1
0.007772
4
1
0.000202
1
308.15
5
2
0.4001
4
1
0.0114
4
1
0.00028
1
308.15
5
2
0.5214
4
1
0.0164
4
1
0.00039
1
308.15
5
2
0.6
4
1
0.0199
4
1
0.00047
1
308.15
5
2
0.699
4
1
0.0248
4
1
0.00058
1
308.15
5
2
0.8016
4
1
0.03043
4
1
0.00071
1
308.15
5
2
0.8957
4
1
0.03681
4
1
0.00086
1
308.15
5
2
1
1
1
0.0453
4
1
0.00107
1
313.15
5
2
0
2
1
0.00083
3
1
2.8e-05
1
313.15
5
2
0.1011
4
1
0.002278
4
1
6.8e-05
1
313.15
5
2
0.2001
4
1
0.004194
4
1
0.000121
1
313.15
5
2
0.2994
4
1
0.0069
4
1
0.000184
1
313.15
5
2
0.4001
4
1
0.0099
4
1
0.000249
1
313.15
5
2
0.5214
4
1
0.014
4
1
0.00034
1
313.15
5
2
0.6
4
1
0.0172
4
1
0.00041
1
313.15
5
2
0.699
4
1
0.0215
4
1
0.0005
1
313.15
5
2
0.8016
4
1
0.02609
4
1
0.00061
1
313.15
5
2
0.8957
4
1
0.031
4
1
0.00072
1
313.15
5
2
1
1
1
0.03692
4
1
0.00087
1
318.15
5
2
0
2
1
0.00072
3
1
2.5e-05
1
318.15
5
2
0.1011
4
1
0.002125
4
1
6.4e-05
1
318.15
5
2
0.2001
4
1
0.003962
4
1
0.000115
1
318.15
5
2
0.2994
4
1
0.0063
4
1
0.00017
1
318.15
5
2
0.4001
4
1
0.009
4
1
0.000227
1
318.15
5
2
0.5214
4
1
0.0126
4
1
0.0003
1
318.15
5
2
0.6
4
1
0.0153
4
1
0.00036
1
318.15
5
2
0.699
4
1
0.0188
4
1
0.00044
1
318.15
5
2
0.8016
4
1
0.0224
4
1
0.00052
1
318.15
5
2
0.8957
4
1
0.0262
4
1
0.00061
1
318.15
5
2
1
1
1
0.03056
4
1
0.00072
1
323.15
5
2
0
2
1
0.000615
3
1
2.2e-05
1
323.15
5
2
0.2001
4
1
0.004433
4
1
0.000129
1
323.15
5
2
0.2994
4
1
0.0064
4
1
0.000172
1
323.15
5
2
0.4001
4
1
0.0089
4
1
0.000224
1
323.15
5
2
0.5214
4
1
0.012
4
1
0.00029
1
323.15
5
2
0.6
4
1
0.0141
4
1
0.00034
1
323.15
5
2
0.699
4
1
0.0167
4
1
0.0004
1
323.15
5
2
0.8016
4
1
0.0196
4
1
0.00046
1
323.15
5
2
0.8957
4
1
0.0223
4
1
0.00053
1
323.15
5
2
1
1
1
0.02533
4
1
0.00061
19
3
1
5
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Mass density, kg/m3
Pycnometric method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
298.15
5
2
Pressure, kPa
Liquid
101.3
4
1
Mole fraction
5
Liquid
1
0
2
1
771.5
4
1
3.1
1
0.1004
4
1
846.7
4
1
3.4
1
0.2012
4
1
891.6
4
1
3.6
1
0.3076
4
1
923
4
1
3.7
1
0.4005
4
1
942.5
4
1
3.8
1
0.501
4
1
957.9
4
1
3.9
1
0.5995
4
1
969.6
4
1
3.9
1
0.702
4
1
978.9
4
1
4
1
0.8014
4
1
985.2
4
1
4
1
0.8956
4
1
988.1
4
1
4
1
1
5
1
987
4
1
4
20
3
1
5
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Molar heat capacity at constant pressure, J/K/mol
FLOW:UFactor:2
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mole fraction
5
Liquid
1
298.15
5
2
0
2
1
91.69
4
1
0.39
1
298.15
5
2
0.1004
4
1
137.6
4
1
0.6
1
298.15
5
2
0.2012
4
1
215.8
4
1
1.2
1
298.15
5
2
0.3076
4
1
337.2
4
1
2.1
1
298.15
5
2
0.4005
4
1
499.6
4
1
2.7
1
298.15
5
2
0.501
4
1
675.7
4
1
3.5
1
298.15
5
2
0.5995
4
1
845.9
4
1
4.1
1
298.15
5
2
0.702
4
1
995.6
4
1
5.3
1
298.15
5
2
0.8014
4
1
1046
4
1
5
1
298.15
5
2
0.8956
4
1
1020
3
1
6
1
298.15
5
2
1
1
1
769
4
1
3.2
1
303.15
5
2
0
2
1
92.21
4
1
0.39
1
303.15
5
2
0.1004
4
1
154.1
4
1
1
1
303.15
5
2
0.2012
4
1
248.1
4
1
1.7
1
303.15
5
2
0.3076
4
1
395.8
4
1
2.5
1
303.15
5
2
0.4005
4
1
544
4
1
2.7
1
303.15
5
2
0.501
4
1
725.8
4
1
3.4
1
303.15
5
2
0.5995
4
1
890.8
4
1
4
1
303.15
5
2
0.702
4
1
1047
4
1
5
1
303.15
5
2
0.8014
4
1
1100
2
1
5
1
303.15
5
2
0.8956
4
1
1045
4
1
4
1
303.15
5
2
1
1
1
772.4
4
1
3.2
1
308.15
5
2
0
2
1
92.4
4
1
0.39
1
308.15
5
2
0.1004
4
1
173.2
4
1
0.9
1
308.15
5
2
0.2012
4
1
280.7
4
1
1.7
1
308.15
5
2
0.3076
4
1
430.2
4
1
2.2
1
308.15
5
2
0.4005
4
1
574.1
4
1
2.7
1
308.15
5
2
0.501
4
1
751.8
4
1
3.4
1
308.15
5
2
0.5995
4
1
924.9
4
1
4.2
1
308.15
5
2
0.702
4
1
1083
4
1
5
1
308.15
5
2
0.8014
4
1
1149
4
1
5
1
308.15
5
2
0.8956
4
1
1052
4
1
4
1
308.15
5
2
1
1
1
782.2
4
1
3.3
1
313.15
5
2
0
2
1
92.82
4
1
0.39
1
313.15
5
2
0.1004
4
1
183.8
4
1
1.1
1
313.15
5
2
0.2012
4
1
307.4
4
1
1.8
1
313.15
5
2
0.3076
4
1
457.1
4
1
2.3
1
313.15
5
2
0.4005
4
1
609
4
1
3
1
313.15
5
2
0.501
4
1
791.1
4
1
3.7
1
313.15
5
2
0.5995
4
1
979.9
4
1
4.3
1
313.15
5
2
0.702
4
1
1120
3
1
5
1
313.15
5
2
0.8014
4
1
1185
4
1
5
1
313.15
5
2
0.8956
4
1
1054
4
1
5
1
313.15
5
2
1
1
1
788.1
4
1
3.3
21
3
1
5
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Viscosity, Pa*s
CAPTUB:UFactor:4
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mole fraction
5
Liquid
1
293.15
5
2
0
2
1
0.00035
3
1
1.4e-05
1
293.15
5
2
0.1004
4
1
0.001201
4
1
3.9e-05
1
293.15
5
2
0.2012
4
1
0.002747
4
1
8.1e-05
1
293.15
5
2
0.3076
4
1
0.0058
4
1
0.00016
1
293.15
5
2
0.4005
4
1
0.0106
4
1
0.00027
1
293.15
5
2
0.501
4
1
0.01794
4
1
0.00042
1
293.15
5
2
0.5995
4
1
0.02596
4
1
0.00061
1
293.15
5
2
0.702
4
1
0.03782
4
1
0.00087
1
293.15
5
2
0.8014
4
1
0.05042
4
1
0.0005
1
293.15
5
2
0.8956
4
1
0.066
4
1
0.00177
1
293.15
5
2
1
1
1
0.08848
4
1
0.00457
1
298.15
5
2
0
2
1
0.000333
4
1
1.34e-05
1
298.15
5
2
0.1004
4
1
0.001199
4
1
3.8e-05
1
298.15
5
2
0.2012
4
1
0.0033
4
1
9.7e-05
1
298.15
5
2
0.3076
4
1
0.0063
4
1
0.00017
1
298.15
5
2
0.4005
4
1
0.01
4
1
0.00025
1
298.15
5
2
0.501
4
1
0.01611
4
1
0.00038
1
298.15
5
2
0.5995
4
1
0.0227
4
1
0.00053
1
298.15
5
2
0.702
4
1
0.032
4
1
0.00074
1
298.15
5
2
0.8014
4
1
0.04188
4
1
0.00096
1
298.15
5
2
0.8956
4
1
0.0543
4
1
0.00067
1
298.15
5
2
1
1
1
0.07127
4
1
0.00239
1
303.15
5
2
0
2
1
0.000325
3
1
1.3e-05
1
303.15
5
2
0.1004
4
1
0.00121
4
1
3.8e-05
1
303.15
5
2
0.2012
4
1
0.002402
4
1
7.2e-05
1
303.15
5
2
0.3076
4
1
0.0056
4
1
0.000156
1
303.15
5
2
0.4005
4
1
0.0096
4
1
0.000241
1
303.15
5
2
0.501
4
1
0.01467
4
1
0.00035
1
303.15
5
2
0.5995
4
1
0.02017
4
1
0.00047
1
303.15
5
2
0.702
4
1
0.02747
4
1
0.00064
1
303.15
5
2
0.8014
4
1
0.0353
4
1
0.00081
1
303.15
5
2
0.8956
4
1
0.0454
4
1
0.00105
1
303.15
5
2
1
1
1
0.05648
4
1
0.00089
1
308.15
5
2
0
2
1
0.000292
3
1
1.2e-05
1
308.15
5
2
0.1004
4
1
0.001241
4
1
3.9e-05
1
308.15
5
2
0.2012
4
1
0.002808
4
1
8.3e-05
1
308.15
5
2
0.3076
4
1
0.0055
4
1
0.000155
1
308.15
5
2
0.4005
4
1
0.0084
4
1
0.000218
1
308.15
5
2
0.501
4
1
0.0128
4
1
0.00031
1
308.15
5
2
0.5995
4
1
0.01789
4
1
0.00042
1
308.15
5
2
0.702
4
1
0.02368
4
1
0.00055
1
308.15
5
2
0.8014
4
1
0.03004
4
1
0.00069
1
308.15
5
2
0.8956
4
1
0.037
4
1
0.00086
1
308.15
5
2
1
1
1
0.0453
4
1
0.00107
1
313.15
5
2
0
2
1
0.000279
3
1
1.2e-05
1
313.15
5
2
0.1004
4
1
0.001397
4
1
4.5e-05
1
313.15
5
2
0.2012
4
1
0.00223
4
1
6.7e-05
1
313.15
5
2
0.3076
4
1
0.0044
4
1
0.000127
1
313.15
5
2
0.4005
4
1
0.007398
4
1
0.000194
1
313.15
5
2
0.501
4
1
0.0114
4
1
0.00028
1
313.15
5
2
0.5995
4
1
0.0156
4
1
0.00037
1
313.15
5
2
0.702
4
1
0.02083
4
1
0.00049
1
313.15
5
2
0.8014
4
1
0.0261
4
1
0.00061
1
313.15
5
2
0.8956
4
1
0.0314
4
1
0.00073
1
313.15
5
2
1
1
1
0.03692
4
1
0.00087
1
318.15
5
2
0
2
1
0.000245
3
1
1.1e-05
1
318.15
5
2
0.1004
4
1
0.00177
4
1
5.4e-05
1
318.15
5
2
0.2012
4
1
0.0031
4
1
9.3e-05
1
318.15
5
2
0.3076
4
1
0.0051
4
1
0.000146
1
318.15
5
2
0.4005
4
1
0.007511
4
1
0.000195
1
318.15
5
2
0.501
4
1
0.0107
4
1
0.00026
1
318.15
5
2
0.5995
4
1
0.0141
4
1
0.00034
1
318.15
5
2
0.702
4
1
0.01821
4
1
0.00043
1
318.15
5
2
0.8014
4
1
0.0223
4
1
0.00052
1
318.15
5
2
0.8956
4
1
0.02631
4
1
0.00062
1
318.15
5
2
1
1
1
0.03056
4
1
0.00072
1
323.15
5
2
0
2
1
0.000223
3
1
1e-05
1
323.15
5
2
0.1004
4
1
0.0016
4
1
4.9e-05
1
323.15
5
2
0.2012
4
1
0.003223
4
1
9.5e-05
1
323.15
5
2
0.3076
4
1
0.005376
4
1
0.000151
1
323.15
5
2
0.4005
4
1
0.0076
4
1
0.000197
1
323.15
5
2
0.501
4
1
0.0102
4
1
0.00025
1
323.15
5
2
0.5995
4
1
0.0132
4
1
0.00032
1
323.15
5
2
0.702
4
1
0.01621
4
1
0.00038
1
323.15
5
2
0.8014
4
1
0.01955
4
1
0.00046
1
323.15
5
2
0.8956
4
1
0.02252
4
1
0.00053
1
323.15
5
2
1
1
1
0.02533
4
1
0.00061
22
2
1
5
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Mass density, kg/m3
Pycnometric method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
298.15
5
2
Pressure, kPa
Liquid
101.3
4
1
Mole fraction
5
Liquid
1
0
2
1
824.5
4
1
3.3
1
0.1003
4
1
844.8
4
1
3.4
1
0.201
4
1
863.9
4
1
3.5
1
0.3001
4
1
881.8
4
1
3.6
1
0.3995
4
1
898.9
4
1
3.6
1
0.4993
4
1
915.6
4
1
3.7
1
0.6
4
1
931.7
4
1
3.8
1
0.7009
4
1
947
4
1
3.8
1
0.8001
4
1
961.2
4
1
3.9
1
0.8989
4
1
974.4
4
1
3.9
1
1
5
1
987
4
1
4
23
2
1
5
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Molar heat capacity at constant pressure, J/K/mol
FLOW:UFactor:2
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mole fraction
5
Liquid
1
298.15
5
2
0
2
1
304
4
1
1.6
1
298.15
5
2
0.1003
4
1
469
4
1
2.3
1
298.15
5
2
0.201
4
1
570.9
4
1
2.5
1
298.15
5
2
0.3001
4
1
603.8
4
1
2.6
1
298.15
5
2
0.3995
4
1
591.7
4
1
2.5
1
298.15
5
2
0.4993
4
1
571.6
4
1
2.4
1
298.15
5
2
0.6
4
1
547.5
4
1
2.3
1
298.15
5
2
0.7009
4
1
540.4
4
1
2.3
1
298.15
5
2
0.8001
4
1
534.8
4
1
2.2
1
298.15
5
2
0.8989
4
1
606.3
4
1
2.5
1
298.15
5
2
1
1
1
769
4
1
3.2
1
303.15
5
2
0
2
1
329
4
1
1.7
1
303.15
5
2
0.1003
4
1
479
4
1
2
1
303.15
5
2
0.201
4
1
566.2
4
1
2.4
1
303.15
5
2
0.3001
4
1
601.4
4
1
2.5
1
303.15
5
2
0.3995
4
1
599.3
4
1
2.5
1
303.15
5
2
0.4993
4
1
579.9
4
1
2.4
1
303.15
5
2
0.6
4
1
565.6
4
1
2.5
1
303.15
5
2
0.7009
4
1
534.5
4
1
30
1
303.15
5
2
0.8001
4
1
557.8
4
1
2.7
1
303.15
5
2
0.8989
4
1
638.3
4
1
2.8
1
303.15
5
2
1
1
1
772.6
4
1
3.2
1
308.15
5
2
0
2
1
354
4
1
1.8
1
308.15
5
2
0.1003
4
1
483
4
1
2
1
308.15
5
2
0.201
4
1
556.1
4
1
2.3
1
308.15
5
2
0.3001
4
1
598.1
4
1
2.5
1
308.15
5
2
0.3995
4
1
613.1
4
1
2.5
1
308.15
5
2
0.4993
4
1
594.4
4
1
2.5
1
308.15
5
2
0.6
4
1
587.6
4
1
2.5
1
308.15
5
2
0.7009
4
1
585.6
4
1
2.8
1
308.15
5
2
0.8001
4
1
605.7
4
1
2.9
1
308.15
5
2
0.8989
4
1
656.8
4
1
2.9
1
308.15
5
2
1
1
1
782.3
4
1
3.3
1
313.15
5
2
0
2
1
379
4
1
1.9
1
313.15
5
2
0.1003
4
1
497
4
1
2.1
1
313.15
5
2
0.201
4
1
561.1
4
1
2.3
1
313.15
5
2
0.3001
4
1
592.2
4
1
2.5
1
313.15
5
2
0.3995
4
1
606.7
4
1
2.6
1
313.15
5
2
0.4993
4
1
604.1
4
1
2.5
1
313.15
5
2
0.6
4
1
596.3
4
1
2.5
1
313.15
5
2
0.7009
4
1
607
4
1
2.7
1
313.15
5
2
0.8001
4
1
633.3
4
1
3
1
313.15
5
2
0.8989
4
1
681.9
4
1
3.3
1
313.15
5
2
1
1
1
788.2
4
1
3.3
24
2
1
5
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Viscosity, Pa*s
CAPTUB:UFactor:4
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mole fraction
5
Liquid
1
293.15
5
2
0
2
1
0.009183
4
1
0.000235
1
293.15
5
2
0.1003
4
1
0.0105
4
1
0.00027
1
293.15
5
2
0.201
4
1
0.0134
4
1
0.00033
1
293.15
5
2
0.3001
4
1
0.018
4
1
0.00043
1
293.15
5
2
0.3995
4
1
0.024
4
1
0.00056
1
293.15
5
2
0.4993
4
1
0.03085
4
1
0.00072
1
293.15
5
2
0.6
4
1
0.03942
4
1
0.00091
1
293.15
5
2
0.7009
4
1
0.05103
4
1
0.00051
1
293.15
5
2
0.8001
4
1
0.06444
4
1
0.00159
1
293.15
5
2
0.8989
4
1
0.07805
4
1
0.00318
1
293.15
5
2
1
1
1
0.08848
4
1
0.00457
1
298.15
5
2
0
2
1
0.00784
4
1
0.000208
1
298.15
5
2
0.1003
4
1
0.0091
4
1
0.000231
1
298.15
5
2
0.201
4
1
0.0117
4
1
0.00029
1
298.15
5
2
0.3001
4
1
0.01539
4
1
0.00037
1
298.15
5
2
0.3995
4
1
0.0203
4
1
0.00048
1
298.15
5
2
0.4993
4
1
0.0259
4
1
0.00061
1
298.15
5
2
0.6
4
1
0.0333
4
1
0.00077
1
298.15
5
2
0.7009
4
1
0.0419
4
1
0.00097
1
298.15
5
2
0.8001
4
1
0.05231
4
1
0.00059
1
298.15
5
2
0.8989
4
1
0.06319
4
1
0.00149
1
298.15
5
2
1
1
1
0.07127
4
1
0.00239
1
303.15
5
2
0
2
1
0.00642
4
1
0.000179
1
303.15
5
2
0.1003
4
1
0.00833
4
1
0.000213
1
303.15
5
2
0.201
4
1
0.01
4
1
0.00025
1
303.15
5
2
0.3001
4
1
0.01324
4
1
0.00032
1
303.15
5
2
0.3995
4
1
0.0172
4
1
0.00041
1
303.15
5
2
0.4993
4
1
0.02167
4
1
0.00051
1
303.15
5
2
0.6
4
1
0.0275
4
1
0.00064
1
303.15
5
2
0.7009
4
1
0.03444
4
1
0.0008
1
303.15
5
2
0.8001
4
1
0.0422
4
1
0.00099
1
303.15
5
2
0.8989
4
1
0.05026
4
1
0.00055
1
303.15
5
2
1
1
1
0.05648
4
1
0.00089
1
308.15
5
2
0
2
1
0.005341
4
1
0.000153
1
308.15
5
2
0.1003
4
1
0.007641
4
1
0.000203
1
308.15
5
2
0.201
4
1
0.009401
4
1
0.000239
1
308.15
5
2
0.3001
4
1
0.01172
4
1
0.00029
1
308.15
5
2
0.3995
4
1
0.01495
4
1
0.00036
1
308.15
5
2
0.4993
4
1
0.01876
4
1
0.00045
1
308.15
5
2
0.6
4
1
0.02323
4
1
0.00055
1
308.15
5
2
0.7009
4
1
0.02856
4
1
0.00067
1
308.15
5
2
0.8001
4
1
0.03463
4
1
0.00081
1
308.15
5
2
0.8989
4
1
0.04069
4
1
0.00096
1
308.15
5
2
1
1
1
0.0453
4
1
0.00107
1
313.15
5
2
0
2
1
0.004661
4
1
0.000137
1
313.15
5
2
0.1003
4
1
0.005937
4
1
0.000168
1
313.15
5
2
0.201
4
1
0.0075
4
1
0.000202
1
313.15
5
2
0.3001
4
1
0.009786
4
1
0.00025
1
313.15
5
2
0.3995
4
1
0.0123
4
1
0.00031
1
313.15
5
2
0.4993
4
1
0.01557
4
1
0.00038
1
313.15
5
2
0.6
4
1
0.0194
4
1
0.00046
1
313.15
5
2
0.7009
4
1
0.02344
4
1
0.00056
1
313.15
5
2
0.8001
4
1
0.0285
4
1
0.00067
1
313.15
5
2
0.8989
4
1
0.03314
4
1
0.00078
1
313.15
5
2
1
1
1
0.03692
4
1
0.00087
1
318.15
5
2
0
2
1
0.003701
4
1
0.000113
1
318.15
5
2
0.1003
4
1
0.005377
4
1
0.000152
1
318.15
5
2
0.201
4
1
0.0067
4
1
0.00018
1
318.15
5
2
0.3001
4
1
0.008459
4
1
0.000219
1
318.15
5
2
0.3995
4
1
0.0107
4
1
0.00027
1
318.15
5
2
0.4993
4
1
0.01305
4
1
0.00032
1
318.15
5
2
0.6
4
1
0.0164
4
1
0.00039
1
318.15
5
2
0.7009
4
1
0.0198
4
1
0.00047
1
318.15
5
2
0.8001
4
1
0.02363
4
1
0.00056
1
318.15
5
2
0.8989
4
1
0.02768
4
1
0.00065
1
318.15
5
2
1
1
1
0.03056
4
1
0.00072
1
323.15
5
2
0
2
1
0.00284
4
1
9e-05
1
323.15
5
2
0.1003
4
1
0.004821
4
1
0.000142
1
323.15
5
2
0.201
4
1
0.0059
4
1
0.000163
1
323.15
5
2
0.3001
4
1
0.00748
4
1
0.000197
1
323.15
5
2
0.3995
4
1
0.0094
4
1
0.000239
1
323.15
5
2
0.4993
4
1
0.0116
4
1
0.00029
1
323.15
5
2
0.6
4
1
0.01421
4
1
0.00035
1
323.15
5
2
0.7009
4
1
0.0171
4
1
0.00041
1
323.15
5
2
0.8001
4
1
0.02017
4
1
0.00048
1
323.15
5
2
0.8989
4
1
0.0229
4
1
0.00055
1
323.15
5
2
1
1
1
0.02533
4
1
0.00061
25
4
1
5
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Mass density, kg/m3
Pycnometric method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
298.15
5
2
Pressure, kPa
Liquid
101.3
4
1
Mole fraction
5
Liquid
1
0
2
1
997.1
4
1
4
1
0.1846
4
1
1002.9
5
1
4
1
0.2005
4
1
1003.1
5
1
4
1
0.3357
4
1
998.6
4
1
4
1
0.3983
4
1
996.6
4
1
4
1
0.4881
4
1
994.1
4
1
4
1
0.5909
4
1
991.7
4
1
4
1
0.6958
4
1
990
4
1
4
1
0.8036
4
1
988.8
4
1
4
1
0.9011
4
1
987.9
4
1
4
1
1
5
1
987
4
1
4
26
4
1
5
1
Principal objective of the work
VVD
XXX
3/14/2013
1
Viscosity, Pa*s
CAPTUB:UFactor:4
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mole fraction
5
Liquid
1
293.15
5
2
0
2
1
0.001002
4
1
3.2e-05
1
293.15
5
2
0.1846
4
1
0.02063
4
1
0.00047
1
293.15
5
2
0.2005
4
1
0.02218
4
1
0.00051
1
293.15
5
2
0.3357
4
1
0.0349
4
1
0.00077
1
293.15
5
2
0.3983
4
1
0.03983
4
1
0.00088
1
293.15
5
2
0.4881
4
1
0.04574
4
1
0.00102
1
293.15
5
2
0.5909
4
1
0.05043
4
1
0.00041
1
293.15
5
2
0.6958
4
1
0.05353
4
1
0.0006
1
293.15
5
2
0.8036
4
1
0.05859
4
1
0.00105
1
293.15
5
2
0.9011
4
1
0.0679
4
1
0.00203
1
293.15
5
2
1
1
1
0.08848
4
1
0.00457
1
298.15
5
2
0
2
1
0.00089
3
1
2.9e-05
1
298.15
5
2
0.1846
4
1
0.01759
4
1
0.00041
1
298.15
5
2
0.2005
4
1
0.01869
4
1
0.00043
1
298.15
5
2
0.3357
4
1
0.02909
4
1
0.00066
1
298.15
5
2
0.3983
4
1
0.03299
4
1
0.00075
1
298.15
5
2
0.4881
4
1
0.0374
4
1
0.00086
1
298.15
5
2
0.5909
4
1
0.0411
4
1
0.00094
1
298.15
5
2
0.6958
4
1
0.0433
4
1
0.001
1
298.15
5
2
0.8036
4
1
0.0463
4
1
0.00109
1
298.15
5
2
0.9011
4
1
0.05406
4
1
0.00072
1
298.15
5
2
1
1
1
0.07127
4
1
0.00239
1
303.15
5
2
0
2
1
0.000797
3
1
2.6e-05
1
303.15
5
2
0.1846
4
1
0.01475
4
1
0.00035
1
303.15
5
2
0.2005
4
1
0.016
4
1
0.00038
1
303.15
5
2
0.3357
4
1
0.02426
4
1
0.00056
1
303.15
5
2
0.3983
4
1
0.02723
4
1
0.00063
1
303.15
5
2
0.4881
4
1
0.0304
4
1
0.0007
1
303.15
5
2
0.5909
4
1
0.033
4
1
0.00077
1
303.15
5
2
0.6958
4
1
0.0346
4
1
0.00081
1
303.15
5
2
0.8036
4
1
0.03657
4
1
0.00087
1
303.15
5
2
0.9011
4
1
0.0417
4
1
0.001
1
303.15
5
2
1
1
1
0.05648
4
1
0.00089
1
308.15
5
2
0
2
1
0.000718
3
1
2.4e-05
1
308.15
5
2
0.1846
4
1
0.01262
4
1
0.0003
1
308.15
5
2
0.2005
4
1
0.01352
4
1
0.00032
1
308.15
5
2
0.3357
4
1
0.02032
4
1
0.00047
1
308.15
5
2
0.3983
4
1
0.0223
4
1
0.00052
1
308.15
5
2
0.4881
4
1
0.025
4
1
0.00058
1
308.15
5
2
0.5909
4
1
0.0265
4
1
0.00062
1
308.15
5
2
0.6958
4
1
0.0276
4
1
0.00065
1
308.15
5
2
0.8036
4
1
0.02922
4
1
0.00069
1
308.15
5
2
0.9011
4
1
0.03319
4
1
0.00079
1
308.15
5
2
1
1
1
0.0453
4
1
0.00107
1
313.15
5
2
0
2
1
0.000651
3
1
2.2e-05
1
313.15
5
2
0.1846
4
1
0.01093
4
1
0.00026
1
313.15
5
2
0.2005
4
1
0.01172
4
1
0.00028
1
313.15
5
2
0.3357
4
1
0.01717
4
1
0.0004
1
313.15
5
2
0.3983
4
1
0.01894
4
1
0.00044
1
313.15
5
2
0.4881
4
1
0.02082
4
1
0.00048
1
313.15
5
2
0.5909
4
1
0.02189
4
1
0.00051
1
313.15
5
2
0.6958
4
1
0.0228
4
1
0.00053
1
313.15
5
2
0.8036
4
1
0.02417
4
1
0.00057
1
313.15
5
2
0.9011
4
1
0.02732
4
1
0.00064
1
313.15
5
2
1
1
1
0.03692
4
1
0.00087
1
318.15
5
2
0
2
1
0.000587
3
1
2e-05
1
318.15
5
2
0.1846
4
1
0.009916
4
1
0.000241
1
318.15
5
2
0.2005
4
1
0.0104
4
1
0.00025
1
318.15
5
2
0.3357
4
1
0.0149
4
1
0.00035
1
318.15
5
2
0.3983
4
1
0.01616
4
1
0.00038
1
318.15
5
2
0.4881
4
1
0.01787
4
1
0.00041
1
318.15
5
2
0.5909
4
1
0.0186
4
1
0.00043
1
318.15
5
2
0.6958
4
1
0.01922
4
1
0.00045
1
318.15
5
2
0.8036
4
1
0.02039
4
1
0.00048
1
318.15
5
2
0.9011
4
1
0.02317
4
1
0.00054
1
318.15
5
2
1
1
1
0.03056
4
1
0.00072
1
323.15
5
2
0
2
1
0.000556
3
1
2e-05
1
323.15
5
2
0.1846
4
1
0.009303
4
1
0.000228
1
323.15
5
2
0.2005
4
1
0.009764
4
1
0.000237
1
323.15
5
2
0.3357
4
1
0.0134
4
1
0.00032
1
323.15
5
2
0.3983
4
1
0.01435
4
1
0.00034
1
323.15
5
2
0.4881
4
1
0.01572
4
1
0.00037
1
323.15
5
2
0.5909
4
1
0.01617
4
1
0.00038
1
323.15
5
2
0.6958
4
1
0.01685
4
1
0.0004
1
323.15
5
2
0.8036
4
1
0.01755
4
1
0.00041
1
323.15
5
2
0.9011
4
1
0.01977
4
1
0.00046
1
323.15
5
2
1
1
1
0.02533
4
1
0.00061