Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Speed of Sound, Density, and Derivative Properties of Tris(2-ethylhexyl) Trimellitate under High Pressure

Bazile, J.-P.[Jean-Patrick], Nasri, D.[Djamel], Daridon, J. L.[Jean Luc]
J. Chem. Eng. Data 2017, 62, 5, 1708-1715
ABSTRACT
Speed of sound measurements were carried out in liquid Tris(2-ethylhexyl) trimellitate (TOTM) at pressures up to 200 MPa along isotherms ranging from (293.15 to 373.15) K in order to report data of density and its derivatives. The measurements were performed with a pulse echo technique working at 3 MHz. Additional density and heat capacity measurements were carried out at atmospheric pressure in order to initiate the estimation procedure of volumetric properties from speed of sound integration. Results were compared with density measurements performed with a U-tube densimeter at pressures up to 140 MPa on the same sample. Finally, an equation that correlates density and its derivatives within their estimated uncertainties is given.
Compounds
# Formula Name
1 C33H54O6 tris(2-ethylhexyl) trimellitate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Speed of sound, m/s ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • Pulse-echo method
  • 120
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Vibrating tube method
  • 135
  • POMD
  • 1
  • Molar heat capacity at constant pressure, J/K/mol ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Extra sensitive DSC
  • 10