2
0
2017
lia
wan
0
journal
Original
Liang, A.[Aizhen]
Wang, S.[Shui]
Qu, Y.[Yixin]
J. Chem. Eng. Data
2017
2020-09-29
Determination and Correlation of Solubility of Phenylbutazone in Monosolvents and Binary Solvent Mixtures
In this paper, we focused on the solubility of phenylbutazone, which was characterized by FT-IR spectra and X-ray diffraction. By the method of a laser technique, the solubility of phenylbutazone was measured in 10 monosolvents (methanol, ethanol, 2-propanol, n-butanol, 1-pentanol, n-hexanol, acetonitrile, ethyl acetate, acetone, and DMF) and 2 binary solvent mixtures of methanol + acetone and ethanol + acetonitrile from 283 to 323 K at about 5 K intervals under atmospheric pressure. The results show that the solubility of phenylbutazone in monosolvents and mixed solvents increases with the increase of temperature. However, it decreases with the increasing initial mole fraction of alcohols in the selected mixed solvents at constant temperature. The experimental data were correlated by the modified three-parameter van t Hoff equation and the modified Jouyban Acree equation.
solubility
phenylbutazone
mono-solvents
binary solvent mixtures
10.1021/acs.jced.6b00911
2
62
864-871
1
InChI=1S/C19H20N2O2/c1-2-3-14-17-18(22)20(15-10-6-4-7-11-15)21(19(17)23)16-12-8-5-9-13-16/h4-13,17H,2-3,14H2,1H3
VYMDGNCVAMGZFE-UHFFFAOYSA-N
4-butyl-1,2-diphenyl-3,5-pyrazolidinedione
4-butyl-1,2-diphenyl-3,5-dioxopyrazolidine
phenylbutazone
C19H20N2O2
1
Commercial source
1
99.7
3
Stated by supplier
2
InChI=1S/CH4O/c1-2/h2H,1H3
OKKJLVBELUTLKV-UHFFFAOYSA-N
methanol
methyl alcohol
CH4O
1
Commercial source
1
99.5
3
Stated by supplier
3
InChI=1S/C2H6O/c1-2-3/h3H,2H2,1H3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N
ethanol
ethyl alcohol
C2H6O
1
Commercial source
1
99.7
3
Stated by supplier
4
InChI=1S/C3H8O/c1-3(2)4/h3-4H,1-2H3
KFZMGEQAYNKOFK-UHFFFAOYSA-N
propan-2-ol
2-propanol
isopropanol
isopropyl alcohol
sec-propyl alcohol
C3H8O
1
Commercial source
1
99.5
3
Stated by supplier
5
InChI=1S/C4H10O/c1-2-3-4-5/h5H,2-4H2,1H3
LRHPLDYGYMQRHN-UHFFFAOYSA-N
butan-1-ol
1-butanol
n-butanol
n-butyl alcohol
C4H10O
1
Commercial source
1
99.5
3
Stated by supplier
6
InChI=1S/C5H12O/c1-2-3-4-5-6/h6H,2-5H2,1H3
AMQJEAYHLZJPGS-UHFFFAOYSA-N
pentan-1-ol
1-pentanol
amyl alcohol
n-amyl alcohol
n-pentyl alcohol
pentyl alcohol
C5H12O
1
Commercial source
1
99.5
3
Stated by supplier
7
InChI=1S/C6H14O/c1-2-3-4-5-6-7/h7H,2-6H2,1H3
ZSIAUFGUXNUGDI-UHFFFAOYSA-N
hexan-1-ol
1-hexanol
1-hydroxyhexane
amylcarbinol
hexyl alcohol
n-hexanol
n-hexyl alcohol
pentylcarbinol
C6H14O
1
Commercial source
1
99.5
3
Stated by supplier
8
InChI=1S/C2H3N/c1-2-3/h1H3
WEVYAHXRMPXWCK-UHFFFAOYSA-N
acetonitrile
cyanomethane
ethanenitrile
ethanonitrile
methanecarbonitrile
methyl cyanide
C2H3N
1
Commercial source
1
99.5
3
Stated by supplier
9
InChI=1S/C4H8O2/c1-3-6-4(2)5/h3H2,1-2H3
XEKOWRVHYACXOJ-UHFFFAOYSA-N
ethyl acetate
ethyl ethanoate
C4H8O2
1
Commercial source
1
99.5
3
Stated by supplier
10
InChI=1S/C3H6O/c1-3(2)4/h1-2H3
CSCPPACGZOOCGX-UHFFFAOYSA-N
acetone
2-propanone
dimethyl ketone
propan-2-one
propanone
pyroacetic ether
C3H6O
1
Commercial source
1
99.5
3
Stated by supplier
11
InChI=1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3
ZMXDDKWLCZADIW-UHFFFAOYSA-N
dimethylformamide
DMF
DMFA
N,N-dimethylformamide
N,N-dimethylmethanamide
dimethylformamide (DMF)
C3H7NO
1
Commercial source
1
99.5
3
Stated by supplier
1
1
1
2
1
Principal objective of the work
EP
EP
12/21/2016
1
Mole fraction
Titration method
1
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
283.12
5
1
0.0042
3
1
0.0005
1
288.03
5
1
0.00518
3
1
0.00062
1
293.13
5
1
0.00654
3
1
0.00079
1
298.16
5
1
0.00831
3
1
0.001
1
303.14
5
1
0.01073
4
1
0.00129
1
308.15
5
1
0.01414
4
1
0.0017
1
313.15
5
1
0.0189
4
1
0.00227
1
318.15
5
1
0.02614
4
1
0.00314
1
323.15
5
1
0.03772
4
1
0.00453
2
1
1
3
1
Principal objective of the work
EP
EP
12/21/2016
1
Mole fraction
Titration method
1
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
283.13
5
1
0.00396
3
1
0.00048
1
288.1
5
1
0.00472
3
1
0.00057
1
293.2
5
1
0.00605
3
1
0.00073
1
298.15
5
1
0.00773
3
1
0.00093
1
303.15
5
1
0.01
4
1
0.0012
1
308.15
5
1
0.01322
4
1
0.00159
1
313.2
5
1
0.01779
4
1
0.00214
1
318.15
5
1
0.02511
4
1
0.00302
1
323.15
5
1
0.03709
4
1
0.00446
3
1
1
4
1
Principal objective of the work
EP
EP
12/20/2016
1
Mole fraction
Titration method
1
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
283.15
5
1
0.00249
3
1
0.0003
1
288.15
5
1
0.00302
3
1
0.00036
1
293.05
5
1
0.00403
3
1
0.00048
1
298.15
5
1
0.00562
3
1
0.00068
1
303.9
5
1
0.00819
3
1
0.00098
1
308.15
5
1
0.01094
4
1
0.00132
1
313.13
5
1
0.01646
4
1
0.00198
1
318.65
5
1
0.02541
4
1
0.00306
1
323.15
5
1
0.0398
4
1
0.00479
4
1
1
5
1
Principal objective of the work
EP
EP
12/20/2016
1
Mole fraction
Titration method
1
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
283.14
5
1
0.00408
3
1
0.00049
1
288.15
5
1
0.00541
3
1
0.00065
1
293.15
5
1
0.00703
3
1
0.00084
1
298.15
5
1
0.00914
3
1
0.0011
1
303.15
5
1
0.01223
4
1
0.00147
1
308.15
5
1
0.01664
4
1
0.002
1
313.15
5
1
0.02362
4
1
0.00284
1
318.15
5
1
0.03333
4
1
0.00401
1
323.15
5
1
0.04828
4
1
0.0058
5
1
1
6
1
Principal objective of the work
EP
EP
12/20/2016
1
Mole fraction
Titration method
1
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
283.15
5
1
0.00412
3
1
0.0005
1
288.15
5
1
0.00539
3
1
0.00065
1
293.12
5
1
0.00693
3
1
0.00083
1
298.11
5
1
0.00885
3
1
0.00106
1
303.15
5
1
0.01211
4
1
0.00146
1
308.15
5
1
0.01654
4
1
0.00199
1
313.15
5
1
0.0221
4
1
0.00266
1
318.13
5
1
0.032
4
1
0.00385
1
323.16
5
1
0.04814
4
1
0.00579
6
1
1
7
1
Principal objective of the work
EP
EP
12/20/2016
1
Mole fraction
Titration method
1
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
283.15
5
1
0.00394
3
1
0.00047
1
288.05
5
1
0.00467
3
1
0.00056
1
293.05
5
1
0.00632
3
1
0.00076
1
298.15
5
1
0.00845
3
1
0.00102
1
303.15
5
1
0.01253
4
1
0.00151
1
308.15
5
1
0.01761
4
1
0.00212
1
313.15
5
1
0.02389
4
1
0.00287
1
318.15
5
1
0.03426
4
1
0.00412
1
323.15
5
1
0.04732
4
1
0.00569
7
1
1
8
1
Principal objective of the work
EP
EP
1/11/2017
1
Mole fraction
Titration method
1
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
283.12
5
1
0.03367
4
1
0.00405
1
288.15
5
1
0.04568
4
1
0.00549
1
293.15
5
1
0.06317
4
1
0.00759
1
298.17
5
1
0.08952
4
1
0.01076
1
303.15
5
1
0.11199
5
1
0.01345
1
308.13
5
1
0.13645
5
1
0.01638
1
313.1
5
1
0.16405
5
1
0.0197
1
318.17
5
1
0.19414
5
1
0.02331
1
323.16
5
1
0.2254
5
1
0.02706
8
1
1
9
1
Principal objective of the work
EP
EP
12/20/2016
1
Mole fraction
Titration method
1
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
283.15
5
1
0.0638
4
1
0.00766
1
288.15
5
1
0.07647
4
1
0.00918
1
293.15
5
1
0.08967
4
1
0.01077
1
298.13
5
1
0.1041
5
1
0.0125
1
303.15
5
1
0.12177
5
1
0.01462
1
308.15
5
1
0.14333
5
1
0.01721
1
313.37
5
1
0.16904
5
1
0.02029
1
318.3
5
1
0.1949
5
1
0.0234
1
323.17
5
1
0.22301
5
1
0.02677
9
1
1
10
1
Principal objective of the work
EP
EP
12/20/2016
1
Mole fraction
Titration method
1
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
283.15
5
1
0.07053
4
1
0.00847
1
288.13
5
1
0.08281
4
1
0.00994
1
293.15
5
1
0.09664
4
1
0.0116
1
298.17
5
1
0.11321
5
1
0.01359
1
303.15
5
1
0.13258
5
1
0.01592
1
308.13
5
1
0.15325
5
1
0.0184
1
313.15
5
1
0.17631
5
1
0.02117
1
318.15
5
1
0.20117
5
1
0.02415
1
323.15
5
1
0.22616
5
1
0.02715
10
1
1
11
1
Principal objective of the work
EP
EP
12/20/2016
1
Mole fraction
Titration method
1
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
283.13
5
1
0.11422
5
1
0.01371
1
288.15
5
1
0.13047
5
1
0.01566
1
293.15
5
1
0.1474
5
1
0.01769
1
298.13
5
1
0.16646
5
1
0.01998
1
303.15
5
1
0.18687
5
1
0.02243
1
308.15
5
1
0.20844
5
1
0.02502
1
313.15
5
1
0.23254
5
1
0.02791
1
318.6
5
1
0.25974
5
1
0.03118
1
323.17
5
1
0.28688
5
1
0.03444
11
1
1
2
1
10
1
Principal objective of the work
EP
EP
12/20/2016
1
Mole fraction
Titration method
1
Liquid
Direct value, X
2
10
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
2
Solvent: Mole fraction
10
Liquid
1
283.12
5
2
0
5
1
0.0042
3
1
0.0005
1
288.03
5
2
0
5
1
0.00518
3
1
0.00062
1
293.13
5
2
0
5
1
0.00654
3
1
0.00079
1
298.16
5
2
0
5
1
0.00831
3
1
0.001
1
303.14
5
2
0
5
1
0.01073
4
1
0.00129
1
308.15
5
2
0
5
1
0.01414
4
1
0.0017
1
313.15
5
2
0
5
1
0.0189
4
1
0.00227
1
318.15
5
2
0
5
1
0.02614
4
1
0.00314
1
323.15
5
2
0
5
1
0.03772
4
1
0.00453
1
283.15
5
2
0.1002
4
1
0.00773
3
1
0.00093
1
288.15
5
2
0.1002
4
1
0.00954
3
1
0.00115
1
293.15
5
2
0.1002
4
1
0.01164
4
1
0.0014
1
298.15
5
2
0.1002
4
1
0.01469
4
1
0.00176
1
303.15
5
2
0.1002
4
1
0.01897
4
1
0.00228
1
308.15
5
2
0.1002
4
1
0.02509
4
1
0.00301
1
313.15
5
2
0.1002
4
1
0.03376
4
1
0.00406
1
318.27
5
2
0.1002
4
1
0.04731
4
1
0.00569
1
323.17
5
2
0.1002
4
1
0.06755
4
1
0.00812
1
283.15
5
2
0.1999
4
1
0.01258
4
1
0.00151
1
288.15
5
2
0.1999
4
1
0.01532
4
1
0.00184
1
293.12
5
2
0.1999
4
1
0.01896
4
1
0.00228
1
298.15
5
2
0.1999
4
1
0.02411
4
1
0.0029
1
303.15
5
2
0.1999
4
1
0.03111
4
1
0.00374
1
308.15
5
2
0.1999
4
1
0.04077
4
1
0.0049
1
313.15
5
2
0.1999
4
1
0.05439
4
1
0.00654
1
318.15
5
2
0.1999
4
1
0.07394
4
1
0.00889
1
323.15
5
2
0.1999
4
1
0.10115
5
1
0.01215
1
283.15
5
2
0.3
4
1
0.01885
4
1
0.00226
1
288.15
5
2
0.3
4
1
0.02337
4
1
0.00281
1
293.15
5
2
0.3
4
1
0.02884
4
1
0.00346
1
298.15
5
2
0.3
4
1
0.03594
4
1
0.00432
1
303.17
5
2
0.3
4
1
0.0459
4
1
0.00551
1
308.15
5
2
0.3
4
1
0.0588
4
1
0.00706
1
313.15
5
2
0.3
4
1
0.07642
4
1
0.00918
1
318.13
5
2
0.3
4
1
0.09925
4
1
0.01192
1
323.15
5
2
0.3
4
1
0.12846
5
1
0.01543
1
283.13
5
2
0.4008
4
1
0.02665
4
1
0.0032
1
288.15
5
2
0.4008
4
1
0.03262
4
1
0.00392
1
293.15
5
2
0.4008
4
1
0.04012
4
1
0.00482
1
298.15
5
2
0.4008
4
1
0.04954
4
1
0.00595
1
303.15
5
2
0.4008
4
1
0.06167
4
1
0.00741
1
308.15
5
2
0.4008
4
1
0.07811
4
1
0.00938
1
313.23
5
2
0.4008
4
1
0.09989
4
1
0.012
1
318.65
5
2
0.4008
4
1
0.12806
5
1
0.01538
1
323.15
5
2
0.4008
4
1
0.1559
5
1
0.01872
1
283.15
5
2
0.5008
4
1
0.03499
4
1
0.0042
1
288.17
5
2
0.5008
4
1
0.04267
4
1
0.00512
1
293.15
5
2
0.5008
4
1
0.05185
4
1
0.00623
1
298.15
5
2
0.5008
4
1
0.06318
4
1
0.00759
1
303.16
5
2
0.5008
4
1
0.07761
4
1
0.00932
1
308.15
5
2
0.5008
4
1
0.09601
4
1
0.01153
1
313.15
5
2
0.5008
4
1
0.11838
5
1
0.01422
1
318.15
5
2
0.5008
4
1
0.1448
5
1
0.01739
1
323.15
5
2
0.5008
4
1
0.17295
5
1
0.02076
1
283.15
5
2
0.6006
4
1
0.04321
4
1
0.00519
1
288.15
5
2
0.6006
4
1
0.05222
4
1
0.00627
1
293.15
5
2
0.6006
4
1
0.06324
4
1
0.00759
1
298.15
5
2
0.6006
4
1
0.0764
4
1
0.00917
1
303.15
5
2
0.6006
4
1
0.09243
4
1
0.0111
1
308.15
5
2
0.6006
4
1
0.11248
5
1
0.01351
1
313.15
5
2
0.6006
4
1
0.13621
5
1
0.01636
1
318.15
5
2
0.6006
4
1
0.16305
5
1
0.01958
1
323.15
5
2
0.6006
4
1
0.18578
5
1
0.0223
1
283.15
5
2
0.7019
4
1
0.05151
4
1
0.00619
1
288.15
5
2
0.7019
4
1
0.06219
4
1
0.00747
1
293.15
5
2
0.7019
4
1
0.07437
4
1
0.00893
1
298.15
5
2
0.7019
4
1
0.08878
4
1
0.01066
1
303.15
5
2
0.7019
4
1
0.10647
5
1
0.01278
1
308.15
5
2
0.7019
4
1
0.12769
5
1
0.01533
1
313.15
5
2
0.7019
4
1
0.15234
5
1
0.01829
1
318.15
5
2
0.7019
4
1
0.17966
5
1
0.02157
1
323.15
5
2
0.7019
4
1
0.20853
5
1
0.02503
1
283.15
5
2
0.8007
4
1
0.05928
4
1
0.00712
1
288.13
5
2
0.8007
4
1
0.07067
4
1
0.00849
1
293.16
5
2
0.8007
4
1
0.0841
4
1
0.0101
1
298.15
5
2
0.8007
4
1
0.10006
5
1
0.01201
1
303.13
5
2
0.8007
4
1
0.11914
5
1
0.0143
1
308.15
5
2
0.8007
4
1
0.14127
5
1
0.01696
1
313.28
5
2
0.8007
4
1
0.16658
5
1
0.02
1
318.13
5
2
0.8007
4
1
0.1929
5
1
0.02316
1
323.23
5
2
0.8007
4
1
0.21981
5
1
0.02639
1
283.12
5
2
0.8991
4
1
0.0657
4
1
0.00789
1
288.15
5
2
0.8991
4
1
0.07784
4
1
0.00935
1
293.16
5
2
0.8991
4
1
0.092
4
1
0.01105
1
298.14
5
2
0.8991
4
1
0.10816
5
1
0.01299
1
303.17
5
2
0.8991
4
1
0.12766
5
1
0.01533
1
308.15
5
2
0.8991
4
1
0.1498
5
1
0.01799
1
313.18
5
2
0.8991
4
1
0.17492
5
1
0.021
1
318.16
5
2
0.8991
4
1
0.20188
5
1
0.02424
1
323.15
5
2
0.8991
4
1
0.23047
5
1
0.02766
1
283.15
5
2
1
5
1
0.07053
4
1
0.00847
1
288.13
5
2
1
5
1
0.08281
4
1
0.00994
1
293.15
5
2
1
5
1
0.09664
4
1
0.0116
1
298.17
5
2
1
5
1
0.11321
5
1
0.01359
1
303.15
5
2
1
5
1
0.13258
5
1
0.01592
1
308.13
5
2
1
5
1
0.15325
5
1
0.0184
1
313.15
5
2
1
5
1
0.17631
5
1
0.02117
1
318.15
5
2
1
5
1
0.20117
5
1
0.02415
1
323.15
5
2
1
5
1
0.22616
5
1
0.02715
12
1
1
3
1
8
1
Principal objective of the work
EP
EP
12/21/2016
1
Mole fraction
Titration method
1
Liquid
Direct value, X
3
8
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Crystal
1
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
2
Solvent: Mole fraction
3
Liquid
1
283.12
5
2
0
5
1
0.03367
4
1
0.00405
1
288.15
5
2
0
5
1
0.04568
4
1
0.00549
1
293.15
5
2
0
5
1
0.06317
4
1
0.00759
1
298.17
5
2
0
5
1
0.08952
4
1
0.01076
1
303.15
5
2
0
5
1
0.11199
5
1
0.01345
1
308.13
5
2
0
5
1
0.13645
5
1
0.01638
1
313.1
5
2
0
5
1
0.16405
5
1
0.0197
1
318.17
5
2
0
5
1
0.19414
5
1
0.02331
1
323.16
5
2
0
5
1
0.2254
5
1
0.02706
1
283.13
5
2
0.1076
4
1
0.04276
4
1
0.00514
1
288.11
5
2
0.1076
4
1
0.05625
4
1
0.00676
1
293.15
5
2
0.1076
4
1
0.076
4
1
0.00913
1
298.35
5
2
0.1076
4
1
0.09563
4
1
0.01148
1
303.15
5
2
0.1076
4
1
0.11554
5
1
0.01387
1
308.15
5
2
0.1076
4
1
0.13898
5
1
0.01669
1
313.25
5
2
0.1076
4
1
0.16591
5
1
0.01992
1
318.15
5
2
0.1076
4
1
0.19469
5
1
0.02337
1
323.15
5
2
0.1076
4
1
0.22532
5
1
0.02705
1
283.13
5
2
0.2006
4
1
0.04599
4
1
0.00553
1
288.15
5
2
0.2006
4
1
0.06325
4
1
0.0076
1
293.16
5
2
0.2006
4
1
0.07642
4
1
0.00918
1
298.15
5
2
0.2006
4
1
0.09489
4
1
0.0114
1
303.14
5
2
0.2006
4
1
0.11667
5
1
0.01401
1
308.13
5
2
0.2006
4
1
0.14164
5
1
0.01701
1
313.15
5
2
0.2006
4
1
0.16961
5
1
0.02036
1
318.15
5
2
0.2006
4
1
0.19912
5
1
0.02391
1
323.16
5
2
0.2006
4
1
0.2296
5
1
0.02756
1
283.13
5
2
0.2988
4
1
0.04856
4
1
0.00584
1
288.47
5
2
0.2988
4
1
0.06134
4
1
0.00737
1
293.2
5
2
0.2988
4
1
0.07423
4
1
0.00891
1
298.13
5
2
0.2988
4
1
0.08978
4
1
0.01078
1
303.15
5
2
0.2988
4
1
0.10945
5
1
0.01314
1
308.15
5
2
0.2988
4
1
0.13258
5
1
0.01592
1
313.15
5
2
0.2988
4
1
0.15898
5
1
0.01909
1
318.15
5
2
0.2988
4
1
0.18756
5
1
0.02252
1
323.15
5
2
0.2988
4
1
0.21868
5
1
0.02625
1
283.12
5
2
0.4005
4
1
0.044
4
1
0.00529
1
288.2
5
2
0.4005
4
1
0.05418
4
1
0.00651
1
293.13
5
2
0.4005
4
1
0.06608
4
1
0.00794
1
298.15
5
2
0.4005
4
1
0.08081
4
1
0.0097
1
303.15
5
2
0.4005
4
1
0.099
4
1
0.01189
1
308.11
5
2
0.4005
4
1
0.12088
5
1
0.01452
1
313.15
5
2
0.4005
4
1
0.14631
5
1
0.01757
1
318.15
5
2
0.4005
4
1
0.17525
5
1
0.02104
1
323.22
5
2
0.4005
4
1
0.20754
5
1
0.02492
1
283.15
5
2
0.5018
4
1
0.03672
4
1
0.00441
1
288.15
5
2
0.5018
4
1
0.04613
4
1
0.00554
1
293.15
5
2
0.5018
4
1
0.05676
4
1
0.00682
1
298.2
5
2
0.5018
4
1
0.06976
4
1
0.00838
1
303.15
5
2
0.5018
4
1
0.08628
4
1
0.01036
1
308.15
5
2
0.5018
4
1
0.10689
5
1
0.01284
1
313.15
5
2
0.5018
4
1
0.13195
5
1
0.01585
1
318.15
5
2
0.5018
4
1
0.16137
5
1
0.01938
1
323.16
5
2
0.5018
4
1
0.19439
5
1
0.02334
1
283.15
5
2
0.6019
4
1
0.02951
4
1
0.00355
1
288.15
5
2
0.6019
4
1
0.03716
4
1
0.00446
1
293.2
5
2
0.6019
4
1
0.04601
4
1
0.00553
1
298.15
5
2
0.6019
4
1
0.05701
4
1
0.00685
1
303.15
5
2
0.6019
4
1
0.07115
4
1
0.00855
1
308.15
5
2
0.6019
4
1
0.08945
4
1
0.01074
1
313.15
5
2
0.6019
4
1
0.11233
5
1
0.01349
1
318.15
5
2
0.6019
4
1
0.13952
5
1
0.01676
1
323.15
5
2
0.6019
4
1
0.17135
5
1
0.02057
1
283.15
5
2
0.7017
4
1
0.02252
4
1
0.00271
1
288.32
5
2
0.7017
4
1
0.0279
4
1
0.00335
1
293.15
5
2
0.7017
4
1
0.03444
4
1
0.00414
1
298.15
5
2
0.7017
4
1
0.04304
4
1
0.00517
1
303.15
5
2
0.7017
4
1
0.05432
4
1
0.00652
1
308.15
5
2
0.7017
4
1
0.06937
4
1
0.00833
1
313.15
5
2
0.7017
4
1
0.08922
4
1
0.01072
1
318.15
5
2
0.7017
4
1
0.11484
5
1
0.01379
1
323.15
5
2
0.7017
4
1
0.14628
5
1
0.01757
1
283.15
5
2
0.8024
4
1
0.01456
4
1
0.00175
1
288.15
5
2
0.8024
4
1
0.01839
4
1
0.00221
1
293.15
5
2
0.8024
4
1
0.02301
4
1
0.00276
1
298.15
5
2
0.8024
4
1
0.02893
4
1
0.00347
1
303.15
5
2
0.8024
4
1
0.03683
4
1
0.00442
1
308.15
5
2
0.8024
4
1
0.04784
4
1
0.00575
1
313.15
5
2
0.8024
4
1
0.063
4
1
0.00757
1
318.15
5
2
0.8024
4
1
0.08358
4
1
0.01004
1
323.15
5
2
0.8024
4
1
0.11259
5
1
0.01352
1
283.13
5
2
0.9016
4
1
0.00832
3
1
0.001
1
288.15
5
2
0.9016
4
1
0.01054
4
1
0.00127
1
293.15
5
2
0.9016
4
1
0.01322
4
1
0.00159
1
298.15
5
2
0.9016
4
1
0.01675
4
1
0.00201
1
303.15
5
2
0.9016
4
1
0.0216
4
1
0.00259
1
308.15
5
2
0.9016
4
1
0.02829
4
1
0.0034
1
313.15
5
2
0.9016
4
1
0.03771
4
1
0.00453
1
318.15
5
2
0.9016
4
1
0.05126
4
1
0.00616
1
323.15
5
2
0.9016
4
1
0.07315
4
1
0.00879
1
283.13
5
2
1
5
1
0.00396
3
1
0.00048
1
288.1
5
2
1
5
1
0.00472
3
1
0.00057
1
293.2
5
2
1
5
1
0.00605
3
1
0.00073
1
298.15
5
2
1
5
1
0.00773
3
1
0.00093
1
303.15
5
2
1
5
1
0.01
4
1
0.0012
1
308.15
5
2
1
5
1
0.01322
4
1
0.00159
1
313.2
5
2
1
5
1
0.01779
4
1
0.00214
1
318.15
5
2
1
5
1
0.02511
4
1
0.00302
1
323.15
5
2
1
5
1
0.03709
4
1
0.00446