2
0
2017
gao
guo
0
journal
Original
Gao, J.[Jing]
Guo, J.[Jieyi]
Nie, F.[Fanghong]
Ji, H.[Hongwu]
Liu, S.[Shucheng]
J. Chem. Eng. Data
2017
2020-09-29
LCST-Type Phase Behavior of Aqueous Biphasic Systems Composed of Phosphonium-Based Ionic Liquids and Potassium Phosphate
Although aqueous biphasic systems (ABS) composed of phosphonium-based ionic liquids (ILs) have demonstrated superior performance as viable media for biocompatible extraction processes, the formation of ABS with tetrabutylphosphonium trifluoroacetate ([P4444]CF3COO) and tributyloctylphosphonium bromide ([P4448]Br) were seldom investigated. To evaluate the hydrophilicity of [P4444]CF3COO and [P4448]Br, the solubility curves for the mixture of the ILs and water were determined. The influence of temperature on the phase behavior for the [P4448]Br + K3PO4 + H2O and [P4444] CF3COO + K3PO4 + H2O systems were also obtained. Results show that both [P4448]Br + H2O and [P4444]CF3COO + H2O binary systems undergo lower critical solution temperature-type phase transition, and the ABS composed of [P4444]CF3COO and [P4448]Br can be formed with K3PO4 at a wide range of temperatures. Moreover, the ABS are highly temperature dependent, and biphasic region expands with an increase in temperature. On the other hand, the capability of the ILs to induce ABS follows the tread [P4448]Br greater than [P4444]CF3COO. This suggests that the lower cation hydrophilicity of ILs results in greater biphasic area in the ABS formed by phosphonium-based ILs.
Ionic liquid
Aqueous biphasic system
Thermoresponsive
Lower critical solution temperature
10.1021/acs.jced.6b00884
4
62
1335-1340
1
InChI=1S/C16H36P.C2HF3O2/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;3-2(4,5)1(6)7/h5-16H2,1-4H3;(H,6,7)/q+1;/p-1
TXMIUMUSEKVUBH-UHFFFAOYSA-M
tetrabutylphosphonium trifluoroacetate
C18H36F3O2P
1
Commercial source
1
98
2
Stated by supplier
2
0.15
2
Mass loss on drying
2
InChI=1S/C20H44P.BrH/c1-5-9-13-14-15-16-20-21(17-10-6-2,18-11-7-3)19-12-8-4;/h5-20H2,1-4H3;1H/q+1;/p-1
UJMLRSWRUXXZEW-UHFFFAOYSA-M
tributyloctylphosphonium bromide
C20H44BrP
1
Commercial source
1
98
2
Stated by supplier
2
0.42
2
Mass loss on drying
3
InChI=1S/3K.H3O4P/c;;;1-5(2,3)4/h;;;(H3,1,2,3,4)/q3*+1;/p-3
LWIHDJKSTIGBAC-UHFFFAOYSA-K
tripotassium phosphate
phosphoric acid, potassium salt (1:3)
potassium phosphate
K3O4P
1
Commercial source
1
98
2
Stated by supplier
2
0.05
1
Mass loss on drying
4
InChI=1S/H2O/h1H2
XLYOFNOQVPJJNP-UHFFFAOYSA-N
water
H2O
1
Commercial source
1
99.8
3
Estimated by the compiler
1
4
1
1
1
Principal objective of the work
EP
EP
3/2/2017
1
Mass fraction
Chromatography
1
Liquid mixture 2
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid mixture 2
Liquid mixture 1
1
Mass fraction
1
Liquid mixture 1
2
Temperature, K
Liquid mixture 1
1
0.2352
4
2
303.15
5
1
0.6213
4
1
0.0104
1
0.1561
4
2
313.15
5
1
0.6705
4
1
0.0107
1
0.1315
4
2
323.15
5
1
0.7041
4
1
0.0102
1
0.1106
4
2
333.15
5
1
0.708
4
1
0.0102
1
0.1038
4
2
343.15
5
1
0.7127
4
1
0.0124
2
4
1
2
1
Principal objective of the work
EP
EP
2/3/2017
1
Mass fraction
Chromatography
2
Liquid mixture 2
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid mixture 2
Liquid mixture 1
1
Mass fraction
2
Liquid mixture 1
2
Temperature, K
Liquid mixture 1
1
0.1154
4
2
293.15
5
1
0.703
4
1
0.0102
1
0.0899
3
2
303.15
5
1
0.7377
4
1
0.0162
1
0.0463
3
2
313.15
5
1
0.7496
4
1
0.0104
1
0.0423
3
2
323.15
5
1
0.7521
4
1
0.0864
1
0.0395
3
2
333.15
5
1
0.7649
4
1
0.0103
3
4
1
3
1
1
1
Principal objective of the work
EP
EP
3/2/2017
1
Mass fraction
Titration method
1
Liquid mixture 1
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid mixture 1
Liquid mixture 2
1
Pressure, kPa
Liquid mixture 1
100
1
1
Temperature, K
Liquid mixture 1
2
Mass fraction
3
Liquid mixture 1
1
293.15
5
2
0.0749
3
1
0.0557
3
1
0.0101
1
293.15
5
2
0.0777
3
1
0.0531
3
1
0.0101
1
293.15
5
2
0.0806
3
1
0.0506
3
1
0.0101
1
293.15
5
2
0.0848
3
1
0.0479
3
1
0.0101
1
293.15
5
2
0.0888
3
1
0.0457
3
1
0.0101
1
293.15
5
2
0.0929
3
1
0.0435
3
1
0.0101
1
293.15
5
2
0.0963
3
1
0.0417
3
1
0.0101
1
293.15
5
2
0.0992
3
1
0.0399
3
1
0.0101
1
293.15
5
2
0.1025
4
1
0.0383
3
1
0.0101
1
293.15
5
2
0.105
4
1
0.0368
3
1
0.0101
1
293.15
5
2
0.1098
4
1
0.0343
3
1
0.01
1
293.15
5
2
0.1148
4
1
0.0318
3
1
0.01
1
293.15
5
2
0.1196
4
1
0.0295
3
1
0.01
1
293.15
5
2
0.1245
4
1
0.0276
3
1
0.01
1
293.15
5
2
0.1287
4
1
0.0258
3
1
0.01
1
293.15
5
2
0.1327
4
1
0.0242
3
1
0.01
1
293.15
5
2
0.1377
4
1
0.022
3
1
0.01
1
293.15
5
2
0.142
4
1
0.0201
3
1
0.01
1
293.15
5
2
0.1477
4
1
0.0183
3
1
0.01
1
293.15
5
2
0.1531
4
1
0.0168
3
1
0.01
1
293.15
5
2
0.1577
4
1
0.0155
3
1
0.01
1
293.15
5
2
0.1621
4
1
0.0143
3
1
0.01
1
293.15
5
2
0.166
4
1
0.0133
3
1
0.01
1
293.15
5
2
0.1697
4
1
0.0125
3
1
0.01
1
293.15
5
2
0.1741
4
1
0.0116
3
1
0.01
1
293.15
5
2
0.1779
4
1
0.011
3
1
0.01
1
293.15
5
2
0.1817
4
1
0.0103
3
1
0.01
1
293.15
5
2
0.1853
4
1
0.0097
2
1
0.0097
1
293.15
5
2
0.1884
4
1
0.0092
2
1
0.0092
1
293.15
5
2
0.1912
4
1
0.0087
2
1
0.0087
1
293.15
5
2
0.1936
4
1
0.0083
2
1
0.0083
1
293.15
5
2
0.1959
4
1
0.0079
2
1
0.0079
1
298.15
5
2
0.0231
3
1
0.1229
4
1
0.0106
1
298.15
5
2
0.0265
3
1
0.113
4
1
0.0105
1
298.15
5
2
0.031
3
1
0.1042
4
1
0.0104
1
298.15
5
2
0.0372
3
1
0.0951
3
1
0.0104
1
298.15
5
2
0.0415
3
1
0.0884
3
1
0.0103
1
298.15
5
2
0.045
3
1
0.0822
3
1
0.0103
1
298.15
5
2
0.0507
3
1
0.0753
3
1
0.0102
1
298.15
5
2
0.0557
3
1
0.0697
3
1
0.0102
1
298.15
5
2
0.0605
3
1
0.0655
3
1
0.0102
1
298.15
5
2
0.0647
3
1
0.0617
3
1
0.0102
1
298.15
5
2
0.0683
3
1
0.0582
3
1
0.0101
1
298.15
5
2
0.0732
3
1
0.055
3
1
0.0101
1
298.15
5
2
0.0776
3
1
0.0522
3
1
0.0101
1
298.15
5
2
0.0821
3
1
0.049
3
1
0.0101
1
298.15
5
2
0.0861
3
1
0.0462
3
1
0.0101
1
298.15
5
2
0.0896
3
1
0.0431
3
1
0.0101
1
298.15
5
2
0.0929
3
1
0.0404
3
1
0.0101
1
298.15
5
2
0.0974
3
1
0.0384
3
1
0.0101
1
298.15
5
2
0.1019
4
1
0.0362
3
1
0.0101
1
298.15
5
2
0.1068
4
1
0.0338
3
1
0.01
1
298.15
5
2
0.1105
4
1
0.0318
3
1
0.01
1
298.15
5
2
0.1132
4
1
0.0299
3
1
0.01
1
298.15
5
2
0.1164
4
1
0.0282
3
1
0.01
1
298.15
5
2
0.1197
4
1
0.0267
3
1
0.01
1
298.15
5
2
0.1236
4
1
0.0255
3
1
0.01
1
298.15
5
2
0.1275
4
1
0.0243
3
1
0.01
1
298.15
5
2
0.1312
4
1
0.0232
3
1
0.01
1
298.15
5
2
0.1341
4
1
0.0221
3
1
0.01
1
298.15
5
2
0.1368
4
1
0.0211
3
1
0.01
1
298.15
5
2
0.1394
4
1
0.0201
3
1
0.01
1
298.15
5
2
0.1416
4
1
0.0193
3
1
0.01
1
298.15
5
2
0.1441
4
1
0.0184
3
1
0.01
1
298.15
5
2
0.1468
4
1
0.0177
3
1
0.01
1
298.15
5
2
0.1491
4
1
0.017
3
1
0.01
1
298.15
5
2
0.1513
4
1
0.0163
3
1
0.01
1
298.15
5
2
0.1559
4
1
0.0149
3
1
0.01
1
298.15
5
2
0.1609
4
1
0.0135
3
1
0.01
1
298.15
5
2
0.1661
4
1
0.0123
3
1
0.01
1
303.15
5
2
0.0274
3
1
0.0973
3
1
0.0104
1
303.15
5
2
0.0299
3
1
0.0936
3
1
0.0103
1
303.15
5
2
0.0321
3
1
0.0897
3
1
0.0103
1
303.15
5
2
0.034
3
1
0.0856
3
1
0.0103
1
303.15
5
2
0.0356
3
1
0.0819
3
1
0.0103
1
303.15
5
2
0.0375
3
1
0.0792
3
1
0.0102
1
303.15
5
2
0.0402
3
1
0.0766
3
1
0.0102
1
303.15
5
2
0.0446
3
1
0.0741
3
1
0.0102
1
303.15
5
2
0.048
3
1
0.0707
3
1
0.0102
1
303.15
5
2
0.0512
3
1
0.0678
3
1
0.0102
1
303.15
5
2
0.0543
3
1
0.0653
3
1
0.0102
1
303.15
5
2
0.0572
3
1
0.063
3
1
0.0102
1
303.15
5
2
0.0598
3
1
0.0607
3
1
0.0101
1
303.15
5
2
0.0625
3
1
0.0588
3
1
0.0101
1
303.15
5
2
0.0651
3
1
0.0565
3
1
0.0101
1
303.15
5
2
0.0679
3
1
0.0547
3
1
0.0101
1
303.15
5
2
0.0753
3
1
0.0494
3
1
0.0101
1
303.15
5
2
0.0812
3
1
0.0453
3
1
0.0101
1
303.15
5
2
0.0867
3
1
0.0415
3
1
0.0101
1
303.15
5
2
0.0922
3
1
0.0383
3
1
0.0101
1
303.15
5
2
0.0973
3
1
0.0355
3
1
0.0101
1
303.15
5
2
0.102
4
1
0.0332
3
1
0.01
1
303.15
5
2
0.1067
4
1
0.0311
3
1
0.01
1
303.15
5
2
0.1111
4
1
0.0291
3
1
0.01
1
303.15
5
2
0.1196
4
1
0.0262
3
1
0.01
1
303.15
5
2
0.1256
4
1
0.024
3
1
0.01
1
303.15
5
2
0.1307
4
1
0.0221
3
1
0.01
1
303.15
5
2
0.1353
4
1
0.0203
3
1
0.01
1
303.15
5
2
0.1399
4
1
0.0187
3
1
0.01
1
303.15
5
2
0.1443
4
1
0.0172
3
1
0.01
1
303.15
5
2
0.1487
4
1
0.0159
3
1
0.01
1
303.15
5
2
0.1527
4
1
0.0148
3
1
0.01
1
303.15
5
2
0.1564
4
1
0.0138
3
1
0.01
1
303.15
5
2
0.1599
4
1
0.0129
3
1
0.01
1
303.15
5
2
0.1637
4
1
0.012
3
1
0.01
1
303.15
5
2
0.1675
4
1
0.0112
3
1
0.01
1
303.15
5
2
0.1714
4
1
0.0105
3
1
0.01
1
308.15
5
2
0.0178
3
1
0.0888
3
1
0.0103
1
308.15
5
2
0.0217
3
1
0.0841
3
1
0.0103
1
308.15
5
2
0.025
3
1
0.0795
3
1
0.0102
1
308.15
5
2
0.028
3
1
0.0754
3
1
0.0102
1
308.15
5
2
0.0319
3
1
0.0719
3
1
0.0102
1
308.15
5
2
0.0351
3
1
0.0681
3
1
0.0102
1
308.15
5
2
0.039
3
1
0.0648
3
1
0.0102
1
308.15
5
2
0.0425
3
1
0.0619
3
1
0.0102
1
308.15
5
2
0.0457
3
1
0.0591
3
1
0.0101
1
308.15
5
2
0.051
3
1
0.0557
3
1
0.0101
1
308.15
5
2
0.0551
3
1
0.0527
3
1
0.0101
1
308.15
5
2
0.0591
3
1
0.0498
3
1
0.0101
1
308.15
5
2
0.0631
3
1
0.0469
3
1
0.0101
1
308.15
5
2
0.0682
3
1
0.0442
3
1
0.0101
1
308.15
5
2
0.0728
3
1
0.0417
3
1
0.0101
1
308.15
5
2
0.0769
3
1
0.0395
3
1
0.0101
1
308.15
5
2
0.0804
3
1
0.0375
3
1
0.0101
1
308.15
5
2
0.084
3
1
0.0358
3
1
0.0101
1
308.15
5
2
0.0879
3
1
0.0341
3
1
0.01
1
308.15
5
2
0.0907
3
1
0.0323
3
1
0.01
1
308.15
5
2
0.0943
3
1
0.0308
3
1
0.01
1
308.15
5
2
0.0992
3
1
0.0303
3
1
0.01
1
308.15
5
2
0.1025
4
1
0.0289
3
1
0.01
1
308.15
5
2
0.1052
4
1
0.0276
3
1
0.01
1
308.15
5
2
0.1089
4
1
0.0265
3
1
0.01
1
308.15
5
2
0.1115
4
1
0.0255
3
1
0.01
1
308.15
5
2
0.1139
4
1
0.0245
3
1
0.01
1
308.15
5
2
0.116
4
1
0.0236
3
1
0.01
1
308.15
5
2
0.1183
4
1
0.0227
3
1
0.01
1
308.15
5
2
0.1211
4
1
0.0219
3
1
0.01
1
308.15
5
2
0.1233
4
1
0.0212
3
1
0.01
1
308.15
5
2
0.1253
4
1
0.0204
3
1
0.01
1
308.15
5
2
0.1267
4
1
0.0196
3
1
0.01
1
308.15
5
2
0.1282
4
1
0.0189
3
1
0.01
1
308.15
5
2
0.1311
4
1
0.0182
3
1
0.01
1
308.15
5
2
0.134
4
1
0.0176
3
1
0.01
1
308.15
5
2
0.1363
4
1
0.017
3
1
0.01
1
308.15
5
2
0.1385
4
1
0.0164
3
1
0.01
1
308.15
5
2
0.1403
4
1
0.0158
3
1
0.01
1
308.15
5
2
0.142
4
1
0.0153
3
1
0.01
1
308.15
5
2
0.1441
4
1
0.0148
3
1
0.01
1
308.15
5
2
0.1466
4
1
0.0143
3
1
0.01
1
308.15
5
2
0.1489
4
1
0.0138
3
1
0.01
1
308.15
5
2
0.151
4
1
0.0134
3
1
0.01
1
308.15
5
2
0.153
4
1
0.0129
3
1
0.01
1
308.15
5
2
0.155
4
1
0.0125
3
1
0.01
1
308.15
5
2
0.157
4
1
0.0121
3
1
0.01
1
308.15
5
2
0.1591
4
1
0.0117
3
1
0.01
1
308.15
5
2
0.1607
4
1
0.0113
3
1
0.01
1
308.15
5
2
0.1627
4
1
0.011
3
1
0.01
1
323.15
5
2
0.0023
2
1
0.0922
3
1
0.0103
1
323.15
5
2
0.0063
2
1
0.0855
3
1
0.0103
1
323.15
5
2
0.0089
2
1
0.0802
3
1
0.0103
1
323.15
5
2
0.0113
3
1
0.0761
3
1
0.0102
1
323.15
5
2
0.0143
3
1
0.0724
3
1
0.0102
1
323.15
5
2
0.018
3
1
0.0697
3
1
0.0102
1
323.15
5
2
0.0217
3
1
0.0653
3
1
0.0102
1
323.15
5
2
0.0253
3
1
0.0621
3
1
0.0102
1
323.15
5
2
0.03
3
1
0.0594
3
1
0.0101
1
323.15
5
2
0.0341
3
1
0.0565
3
1
0.0101
1
323.15
5
2
0.0377
3
1
0.0537
3
1
0.0101
1
323.15
5
2
0.042
3
1
0.0509
3
1
0.0101
1
323.15
5
2
0.0469
3
1
0.0481
3
1
0.0101
1
323.15
5
2
0.0512
3
1
0.0457
3
1
0.0101
1
323.15
5
2
0.0553
3
1
0.0432
3
1
0.0101
1
323.15
5
2
0.0598
3
1
0.0411
3
1
0.0101
1
323.15
5
2
0.064
3
1
0.0388
3
1
0.0101
1
323.15
5
2
0.0682
3
1
0.0369
3
1
0.0101
1
323.15
5
2
0.0721
3
1
0.0353
3
1
0.01
1
323.15
5
2
0.0756
3
1
0.0335
3
1
0.01
1
323.15
5
2
0.0789
3
1
0.0319
3
1
0.01
1
323.15
5
2
0.0826
3
1
0.0306
3
1
0.01
1
323.15
5
2
0.0859
3
1
0.0294
3
1
0.01
1
323.15
5
2
0.0895
3
1
0.0283
3
1
0.01
1
323.15
5
2
0.0929
3
1
0.0272
3
1
0.01
1
323.15
5
2
0.0961
3
1
0.0263
3
1
0.01
1
323.15
5
2
0.0989
3
1
0.0253
3
1
0.01
1
323.15
5
2
0.1016
4
1
0.0245
3
1
0.01
1
323.15
5
2
0.1041
4
1
0.0237
3
1
0.01
1
323.15
5
2
0.1074
4
1
0.0228
3
1
0.01
1
323.15
5
2
0.1111
4
1
0.022
3
1
0.01
1
323.15
5
2
0.1146
4
1
0.0211
3
1
0.01
1
323.15
5
2
0.1179
4
1
0.0203
3
1
0.01
1
323.15
5
2
0.1206
4
1
0.0196
3
1
0.01
1
323.15
5
2
0.1229
4
1
0.0188
3
1
0.01
1
323.15
5
2
0.1255
4
1
0.0182
3
1
0.01
1
323.15
5
2
0.1277
4
1
0.0176
3
1
0.01
1
323.15
5
2
0.1294
4
1
0.0169
3
1
0.01
1
323.15
5
2
0.1311
4
1
0.0163
3
1
0.01
1
323.15
5
2
0.1329
4
1
0.0158
3
1
0.01
1
323.15
5
2
0.1341
4
1
0.0153
3
1
0.01
1
323.15
5
2
0.1355
4
1
0.0148
3
1
0.01
1
323.15
5
2
0.1369
4
1
0.0144
3
1
0.01
1
323.15
5
2
0.1379
4
1
0.014
3
1
0.01
1
323.15
5
2
0.1394
4
1
0.0135
3
1
0.01
1
323.15
5
2
0.1449
4
1
0.0126
3
1
0.01
1
323.15
5
2
0.1497
4
1
0.0117
3
1
0.01
1
323.15
5
2
0.1527
4
1
0.0109
3
1
0.01
1
323.15
5
2
0.1617
4
1
0.0091
2
1
0.0091
1
323.15
5
2
0.1702
4
1
0.0075
2
1
0.0075
1
333.15
5
2
0.0132
3
1
0.0685
3
1
0.0102
1
333.15
5
2
0.0187
3
1
0.0647
3
1
0.0102
1
333.15
5
2
0.0227
3
1
0.0613
3
1
0.0101
1
333.15
5
2
0.0267
3
1
0.0573
3
1
0.0101
1
333.15
5
2
0.031
3
1
0.0536
3
1
0.0101
1
333.15
5
2
0.0345
3
1
0.0499
3
1
0.0101
1
333.15
5
2
0.0374
3
1
0.0465
3
1
0.0101
1
333.15
5
2
0.0406
3
1
0.0435
3
1
0.0101
1
333.15
5
2
0.0449
3
1
0.0405
3
1
0.0101
1
333.15
5
2
0.0501
3
1
0.0376
3
1
0.0101
1
333.15
5
2
0.0564
3
1
0.0354
3
1
0.0101
1
333.15
5
2
0.0615
3
1
0.0333
3
1
0.01
1
333.15
5
2
0.0669
3
1
0.0313
3
1
0.01
1
333.15
5
2
0.0726
3
1
0.0295
3
1
0.01
1
333.15
5
2
0.0837
3
1
0.0259
3
1
0.01
1
333.15
5
2
0.0926
3
1
0.0229
3
1
0.01
1
333.15
5
2
0.0998
3
1
0.0204
3
1
0.01
1
333.15
5
2
0.1077
4
1
0.0181
3
1
0.01
1
333.15
5
2
0.1184
4
1
0.016
3
1
0.01
1
333.15
5
2
0.1271
4
1
0.0144
3
1
0.01
1
333.15
5
2
0.1341
4
1
0.013
3
1
0.01
1
333.15
5
2
0.14
4
1
0.0119
3
1
0.01
1
333.15
5
2
0.145
4
1
0.011
3
1
0.01
1
333.15
5
2
0.1495
4
1
0.0102
3
1
0.01
1
333.15
5
2
0.1537
4
1
0.0095
2
1
0.0095
1
333.15
5
2
0.157
4
1
0.0089
2
1
0.0089
1
333.15
5
2
0.1621
4
1
0.0083
2
1
0.0083
1
333.15
5
2
0.1667
4
1
0.0077
2
1
0.0077
1
333.15
5
2
0.1706
4
1
0.0072
2
1
0.0072
1
333.15
5
2
0.1742
4
1
0.0068
2
1
0.0068
1
333.15
5
2
0.1773
4
1
0.0064
2
1
0.0064
1
333.15
5
2
0.1808
4
1
0.0061
2
1
0.0061
1
343.15
5
2
0.0037
2
1
0.0719
3
1
0.0102
1
343.15
5
2
0.0112
3
1
0.0623
3
1
0.0102
1
343.15
5
2
0.0232
3
1
0.0532
3
1
0.0101
1
343.15
5
2
0.0342
3
1
0.0459
3
1
0.0101
1
343.15
5
2
0.043
3
1
0.0403
3
1
0.0101
1
343.15
5
2
0.0513
3
1
0.0353
3
1
0.01
1
343.15
5
2
0.061
3
1
0.031
3
1
0.01
1
343.15
5
2
0.0719
3
1
0.0275
3
1
0.01
1
343.15
5
2
0.0825
3
1
0.0246
3
1
0.01
1
343.15
5
2
0.0913
3
1
0.0221
3
1
0.01
1
343.15
5
2
0.0992
3
1
0.0198
3
1
0.01
1
343.15
5
2
0.105
4
1
0.0178
3
1
0.01
1
343.15
5
2
0.113
3
1
0.0163
3
1
0.01
1
343.15
5
2
0.12
4
1
0.0148
3
1
0.01
1
343.15
5
2
0.1257
4
1
0.0136
3
1
0.01
1
343.15
5
2
0.1305
4
1
0.0125
3
1
0.01
1
343.15
5
2
0.134
4
1
0.0117
3
1
0.01
1
343.15
5
2
0.1385
4
1
0.0108
3
1
0.01
1
343.15
5
2
0.1437
4
1
0.0101
3
1
0.01
4
4
1
3
1
2
1
Principal objective of the work
EP
EP
2/3/2017
1
Mass fraction
Titration method
2
Liquid mixture 1
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid mixture 1
Liquid mixture 2
1
Pressure, kPa
Liquid mixture 1
100
1
1
Temperature, K
Liquid mixture 1
2
Mass fraction
3
Liquid mixture 1
1
293.15
5
2
0.0039
2
1
0.274
4
1
0.0127
1
293.15
5
2
0.0068
2
1
0.2369
4
1
0.012
1
293.15
5
2
0.0089
2
1
0.2086
4
1
0.0116
1
293.15
5
2
0.0106
3
1
0.1863
4
1
0.0113
1
293.15
5
2
0.0121
3
1
0.1692
4
1
0.0111
1
293.15
5
2
0.0134
3
1
0.1562
4
1
0.0109
1
293.15
5
2
0.0144
3
1
0.1439
4
1
0.0108
1
293.15
5
2
0.0172
3
1
0.1342
4
1
0.0107
1
293.15
5
2
0.0259
3
1
0.1069
4
1
0.0104
1
293.15
5
2
0.0321
3
1
0.0865
3
1
0.0103
1
293.15
5
2
0.0406
3
1
0.0711
3
1
0.0102
1
293.15
5
2
0.0468
3
1
0.0607
3
1
0.0101
1
293.15
5
2
0.0541
3
1
0.0526
3
1
0.0101
1
293.15
5
2
0.0606
3
1
0.0462
3
1
0.0101
1
293.15
5
2
0.0658
3
1
0.0412
3
1
0.0101
1
293.15
5
2
0.0726
3
1
0.0369
3
1
0.0101
1
293.15
5
2
0.0788
3
1
0.0333
3
1
0.01
1
293.15
5
2
0.0839
3
1
0.0303
3
1
0.01
1
293.15
5
2
0.0885
3
1
0.0277
3
1
0.01
1
293.15
5
2
0.0952
3
1
0.0255
3
1
0.01
1
293.15
5
2
0.1004
4
1
0.0233
3
1
0.01
1
293.15
5
2
0.1049
4
1
0.0215
3
1
0.01
1
293.15
5
2
0.1091
4
1
0.02
3
1
0.01
1
293.15
5
2
0.1138
4
1
0.0187
3
1
0.01
1
293.15
5
2
0.1179
4
1
0.0175
3
1
0.01
1
293.15
5
2
0.122
4
1
0.0164
3
1
0.01
1
293.15
5
2
0.1254
4
1
0.0154
3
1
0.01
1
293.15
5
2
0.129
4
1
0.0146
3
1
0.01
1
293.15
5
2
0.1319
4
1
0.0137
3
1
0.01
1
293.15
5
2
0.1353
4
1
0.013
3
1
0.01
1
293.15
5
2
0.1385
4
1
0.0123
3
1
0.01
1
293.15
5
2
0.1417
4
1
0.0117
3
1
0.01
1
293.15
5
2
0.1445
4
1
0.0111
3
1
0.01
1
293.15
5
2
0.1472
4
1
0.0106
3
1
0.01
1
293.15
5
2
0.1501
4
1
0.0101
3
1
0.01
1
293.15
5
2
0.1524
4
1
0.0097
2
1
0.0097
1
293.15
5
2
0.1548
4
1
0.0093
2
1
0.0093
1
293.15
5
2
0.1577
4
1
0.0089
2
1
0.0089
1
298.15
5
2
0.0016
2
1
0.2019
4
1
0.0115
1
298.15
5
2
0.0066
2
1
0.1694
4
1
0.0111
1
298.15
5
2
0.0075
2
1
0.1609
4
1
0.011
1
298.15
5
2
0.0085
2
1
0.1532
4
1
0.0109
1
298.15
5
2
0.0099
2
1
0.146
4
1
0.0108
1
298.15
5
2
0.0114
3
1
0.1393
4
1
0.0107
1
298.15
5
2
0.0127
3
1
0.1307
4
1
0.0107
1
298.15
5
2
0.0198
3
1
0.1038
4
1
0.0104
1
298.15
5
2
0.028
3
1
0.085
3
1
0.0103
1
298.15
5
2
0.0358
3
1
0.0717
3
1
0.0102
1
298.15
5
2
0.0421
3
1
0.0614
3
1
0.0101
1
298.15
5
2
0.0488
3
1
0.0532
3
1
0.0101
1
298.15
5
2
0.0558
3
1
0.0467
3
1
0.0101
1
298.15
5
2
0.0622
3
1
0.0413
3
1
0.0101
1
298.15
5
2
0.0689
3
1
0.0367
3
1
0.0101
1
298.15
5
2
0.0752
3
1
0.033
3
1
0.01
1
298.15
5
2
0.0807
3
1
0.0299
3
1
0.01
1
298.15
5
2
0.0855
3
1
0.0273
3
1
0.01
1
298.15
5
2
0.0919
3
1
0.0249
3
1
0.01
1
298.15
5
2
0.0975
3
1
0.0229
3
1
0.01
1
298.15
5
2
0.1026
4
1
0.0212
3
1
0.01
1
298.15
5
2
0.1069
4
1
0.0197
3
1
0.01
1
298.15
5
2
0.1107
4
1
0.0184
3
1
0.01
1
298.15
5
2
0.1147
4
1
0.0172
3
1
0.01
1
298.15
5
2
0.1185
4
1
0.0161
3
1
0.01
1
298.15
5
2
0.1224
4
1
0.0151
3
1
0.01
1
298.15
5
2
0.1262
4
1
0.0142
3
1
0.01
1
298.15
5
2
0.1296
4
1
0.0134
3
1
0.01
1
298.15
5
2
0.1328
4
1
0.0127
3
1
0.01
1
298.15
5
2
0.1361
4
1
0.0121
3
1
0.01
1
298.15
5
2
0.139
4
1
0.0115
3
1
0.01
1
298.15
5
2
0.1419
4
1
0.0109
3
1
0.01
1
298.15
5
2
0.1444
4
1
0.0104
3
1
0.01
1
298.15
5
2
0.147
4
1
0.0099
2
1
0.0099
1
298.15
5
2
0.1495
4
1
0.0095
2
1
0.0095
1
303.15
5
2
0.0082
2
1
0.1078
4
1
0.0105
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