2
0
2017
buc
har
0
journal
Original
Bucherl, M.[Markus]
Hardock, F.[Fabian]
Kaiser, E.[Elisa]
Netsch, A.[Andreas]
Schaber, K.[Karlheinz]
J. Chem. Eng. Data
2017
2020-09-29
Density, viscosity and vapor-liquid equilibrium of the ternary system water - 1-ethyl-3-methylimidazolium acetate - 1-ethyl-3-methylimidazolium trifluoromethanesulfonate
Mixtures of ionic liquids and water offer an interesting opportunity to replace corrosive and/or partly miscible working pairs like lithium bromide water in absorption chillers. Such an alternative must feature both a high depression of the water vapor pressure and a low viscosity to be feasible. However, hitherto published literature data of binary systems of ionic liquids and water fulfill only one of the two criteria. A mixture of two different ionic liquids may exhibit a solution for this dilemma. In this work, a ternary system consisting of water, 1-ethyl-3-methylimidazolium acetate ([EMIm][OAc], high reduction of vapor pressure), and 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([EMIm][OTf], low viscosity) was investigated. Experimental data for density, dynamic viscosity, and vapor liquid equilibrium in the temperature range from 293.15 to 353.15 K at water mass fractions between 5% and 20% and different mass fractions of [EMIm][OTf] are presented. The viscosity of the ternary mixture measured with a falling ball viscometer range between 90.9 and 1.9 mPa*s at a relative mean deviation below 3.6%. The density measured with a glass pycnometer range between 1087 and 1285 kg*m 3 at a relative mean deviation of 0.33%. The water vapor pressure measured by infrared spectroscopy range between 293 and 15164 Pa. The relative mean deviation is below 15.1%. The water vapor pressure data are correlated using a nonrandom two liquid model. The thermodynamic properties show that the considered ternary system can indeed be used as a suitable working mixture in absorption refrigerators.
Ionic liquids
density
viscosity
vapor-liquid equilibria
ternary mixtures
10.1021/acs.jced.6b00801
2
62
720-728
1
InChI=1S/C6H11N2.C2H4O2/c1-3-8-5-4-7(2)6-8;1-2(3)4/h4-6H,3H2,1-2H3;1H3,(H,3,4)/q+1;/p-1
XIYUIMLQTKODPS-UHFFFAOYSA-M
1-ethyl-3-methylimidazolium acetate
C8H14N2O2
1
Commercial source
1
99.2
3
Stated by supplier
2
InChI=1S/C6H11N2.CHF3O3S/c1-3-8-5-4-7(2)6-8;2-1(3,4)8(5,6)7/h4-6H,3H2,1-2H3;(H,5,6,7)/q+1;/p-1
ZPTRYWVRCNOTAS-UHFFFAOYSA-M
1-ethyl-3-methylimidazolium trifluoromethanesulfonate
1-ethyl-3-methyl-1H-imidazol-3-ium trifluoromethanesulfonate
1-ethyl-3-methylimidazolium triflate
C7H11F3N2O3S
1
Commercial source
1
99.1
3
Stated by supplier
3
InChI=1S/H2O/h1H2
XLYOFNOQVPJJNP-UHFFFAOYSA-N
water
H2O
1
Commercial source
1
99.9
3
Stated by supplier
1
3
1
1
1
2
1
Principal objective of the work
EP
EP
12/2/2016
1
Mass density, kg/m3
Pycnometric method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
100
1
1
Temperature, K
Liquid
2
Mole fraction
3
Liquid
3
Mole fraction
1
Liquid
1
293.15
5
2
0.337
3
3
0.64
3
1
1116.69
6
1
5.74
1
313.15
5
2
0.337
3
3
0.64
3
1
1106.91
6
1
5.63
1
333.15
5
2
0.337
3
3
0.64
3
1
1097.24
6
1
5.58
1
353.15
5
2
0.337
3
3
0.64
3
1
1087.35
6
1
5.5
1
293.15
5
2
0.341
3
3
0.612
3
1
1127.62
6
1
5.79
1
313.15
5
2
0.341
3
3
0.612
3
1
1117.07
6
1
5.69
1
333.15
5
2
0.341
3
3
0.612
3
1
1107.03
6
1
5.62
1
353.15
5
2
0.341
3
3
0.612
3
1
1096.92
6
1
5.54
1
313.15
5
2
0.348
3
3
0.555
3
1
1140.91
6
1
5.92
1
293.15
5
2
0.348
3
3
0.555
3
1
1153.34
6
1
6.05
1
333.15
5
2
0.348
3
3
0.555
3
1
1128.84
6
1
5.8
1
353.15
5
2
0.348
3
3
0.555
3
1
1117.86
6
1
5.68
1
313.15
5
2
0.359
3
3
0.492
3
1
1165.49
6
1
5.95
1
333.15
5
2
0.359
3
3
0.492
3
1
1154.09
6
1
5.97
1
293.15
5
2
0.359
3
3
0.492
3
1
1174
4
1
6
1
353.15
5
2
0.359
3
3
0.492
3
1
1142.73
6
1
5.88
1
293.15
5
2
0.371
3
3
0.426
3
1
1183.79
6
1
6.99
1
313.15
5
2
0.371
3
3
0.426
3
1
1173.24
6
1
6.76
1
333.15
5
2
0.371
3
3
0.426
3
1
1163.82
6
1
6.68
1
353.15
5
2
0.371
3
3
0.426
3
1
1149.42
6
1
6.84
1
293.15
5
2
0.373
3
3
0.395
3
1
1215.88
6
1
7.26
1
313.15
5
2
0.373
3
3
0.395
3
1
1202.99
6
1
7.05
1
333.15
5
2
0.373
3
3
0.395
3
1
1190.71
6
1
6.83
1
353.15
5
2
0.373
3
3
0.395
3
1
1180.63
6
1
7.06
1
313.15
5
2
0.385
3
3
0.324
3
1
1232.1
5
1
6.2
1
293.15
5
2
0.385
3
3
0.324
3
1
1244.8
5
1
6.2
1
333.15
5
2
0.385
3
3
0.324
3
1
1217.27
6
1
6.12
1
353.15
5
2
0.385
3
3
0.324
3
1
1204.49
6
1
6.06
1
313.15
5
2
0.395
3
3
0.25
3
1
1259.84
6
1
6.23
1
333.15
5
2
0.395
3
3
0.25
3
1
1246.08
6
1
6.19
1
293.15
5
2
0.395
3
3
0.25
3
1
1273.45
6
1
6.31
1
353.15
5
2
0.395
3
3
0.25
3
1
1233.52
6
1
6.17
1
293.15
5
2
0.406
3
3
0.172
3
1
1301.77
6
1
6.37
1
313.15
5
2
0.406
3
3
0.172
3
1
1288.27
6
1
6.31
1
333.15
5
2
0.406
3
3
0.172
3
1
1273.27
6
1
6.25
1
353.15
5
2
0.406
3
3
0.172
3
1
1261.14
6
1
6.21
1
313.15
5
2
0.419
3
3
0.089
2
1
1316.08
6
1
6.36
1
293.15
5
2
0.419
3
3
0.089
2
1
1327.17
6
1
6.42
1
333.15
5
2
0.419
3
3
0.089
2
1
1300.76
6
1
6.39
1
353.15
5
2
0.419
3
3
0.089
2
1
1280.49
6
1
6.26
1
313.15
5
2
0.426
3
3
0.045
2
1
1329.24
6
1
6.39
1
293.15
5
2
0.426
3
3
0.045
2
1
1343.71
6
1
6.53
1
333.15
5
2
0.426
3
3
0.045
2
1
1315.9
5
1
6.4
1
353.15
5
2
0.426
3
3
0.045
2
1
1293.72
6
1
6.35
1
313.15
5
2
0.518
3
3
0.465
3
1
1110.29
6
1
5.65
1
333.15
5
2
0.518
3
3
0.465
3
1
1098.64
6
1
5.54
1
293.15
5
2
0.518
3
3
0.465
3
1
1120.74
6
1
5.71
1
353.15
5
2
0.518
3
3
0.465
3
1
1090.7
5
1
5.4
1
313.15
5
2
0.522
3
3
0.442
3
1
1119.66
6
1
5.67
1
333.15
5
2
0.522
3
3
0.442
3
1
1108.23
6
1
5.67
1
293.15
5
2
0.522
3
3
0.442
3
1
1131.07
6
1
5.76
1
353.15
5
2
0.522
3
3
0.442
3
1
1098.62
6
1
5.48
1
313.15
5
2
0.533
3
3
0.393
3
1
1143.03
6
1
5.94
1
293.15
5
2
0.533
3
3
0.393
3
1
1154.78
6
1
6.06
1
333.15
5
2
0.533
3
3
0.393
3
1
1130.58
6
1
5.85
1
353.15
5
2
0.533
3
3
0.393
3
1
1118.65
6
1
6.02
1
313.15
5
2
0.543
3
3
0.344
3
1
1166.61
6
1
5.99
1
333.15
5
2
0.543
3
3
0.344
3
1
1153
4
1
6
1
293.15
5
2
0.543
3
3
0.344
3
1
1177.54
6
1
5.92
1
353.15
5
2
0.543
3
3
0.344
3
1
1141.92
6
1
5.9
1
333.15
5
2
0.554
3
3
0.292
3
1
1176.75
6
1
6.31
1
293.15
5
2
0.554
3
3
0.292
3
1
1201.4
5
1
6.4
1
313.15
5
2
0.554
3
3
0.292
3
1
1189.25
6
1
6.37
1
353.15
5
2
0.554
3
3
0.292
3
1
1165.36
6
1
6.08
1
313.15
5
2
0.564
3
3
0.24
3
1
1214.8
5
1
6.2
1
333.15
5
2
0.564
3
3
0.24
3
1
1202.2
5
1
6.2
1
293.15
5
2
0.564
3
3
0.24
3
1
1226.03
6
1
6.14
1
353.15
5
2
0.564
3
3
0.24
3
1
1182.28
6
1
6.04
1
313.15
5
2
0.585
3
3
0.18
3
1
1239.06
6
1
6.39
1
333.15
5
2
0.585
3
3
0.18
3
1
1224.86
6
1
6.39
1
293.15
5
2
0.585
3
3
0.18
3
1
1251.31
6
1
6.54
1
353.15
5
2
0.585
3
3
0.18
3
1
1205.11
6
1
6.59
1
293.15
5
2
0.59
3
3
0.125
3
1
1281.78
6
1
6.21
1
333.15
5
2
0.59
3
3
0.125
3
1
1252.26
6
1
6.19
1
313.15
5
2
0.59
3
3
0.125
3
1
1266.56
6
1
6.27
1
353.15
5
2
0.59
3
3
0.125
3
1
1239.32
6
1
6.3
1
333.15
5
2
0.602
3
3
0.064
2
1
1277.72
6
1
6.28
1
293.15
5
2
0.602
3
3
0.064
2
1
1303.65
6
1
6.53
1
313.15
5
2
0.602
3
3
0.064
2
1
1292.56
6
1
6.3
1
353.15
5
2
0.602
3
3
0.064
2
1
1258.54
6
1
6.53
1
293.15
5
2
0.609
3
3
0.032
2
1
1321.2
5
1
6.6
1
313.15
5
2
0.609
3
3
0.032
2
1
1305.6
5
1
6.5
1
333.15
5
2
0.609
3
3
0.032
2
1
1290.31
6
1
6.46
1
353.15
5
2
0.609
3
3
0.032
2
1
1275.59
6
1
6.52
1
293.15
5
2
0.63
3
3
0.355
3
1
1120.74
6
1
6.31
1
333.15
5
2
0.63
3
3
0.355
3
1
1099.38
6
1
6.08
1
313.15
5
2
0.63
3
3
0.355
3
1
1109.97
6
1
6.23
1
353.15
5
2
0.63
3
3
0.355
3
1
1088.07
6
1
6.01
1
293.15
5
2
0.635
3
3
0.335
3
1
1131.57
6
1
6.36
1
333.15
5
2
0.635
3
3
0.335
3
1
1108.59
6
1
6.1
1
313.15
5
2
0.635
3
3
0.335
3
1
1120.3
5
1
6.3
1
353.15
5
2
0.635
3
3
0.335
3
1
1097.06
6
1
6.04
1
333.15
5
2
0.645
3
3
0.295
3
1
1128.72
6
1
6.15
1
293.15
5
2
0.645
3
3
0.295
3
1
1153.42
6
1
6.23
1
313.15
5
2
0.645
3
3
0.295
3
1
1141.13
6
1
6.21
1
353.15
5
2
0.645
3
3
0.295
3
1
1116.06
6
1
6.11
1
333.15
5
2
0.655
3
3
0.255
3
1
1150.33
6
1
6.28
1
293.15
5
2
0.655
3
3
0.255
3
1
1177.22
6
1
6.28
1
313.15
5
2
0.655
3
3
0.255
3
1
1163.57
6
1
6.35
1
353.15
5
2
0.655
3
3
0.255
3
1
1138.87
6
1
6.13
1
293.15
5
2
0.666
3
3
0.211
3
1
1198.35
6
1
6.64
1
313.15
5
2
0.671
3
3
0.189
3
1
1197.95
6
1
6.56
1
333.15
5
2
0.671
3
3
0.189
3
1
1184.48
6
1
6.55
1
333.15
5
2
0.671
3
3
0.189
3
1
1172.98
6
1
6.61
1
293.15
5
2
0.671
3
3
0.189
3
1
1208.62
6
1
6.2
1
313.15
5
2
0.671
3
3
0.189
3
1
1186.02
6
1
6.62
1
353.15
5
2
0.671
3
3
0.189
3
1
1166.4
5
1
6.5
1
353.15
5
2
0.671
3
3
0.189
3
1
1160.71
6
1
6.55
1
293.15
5
2
0.683
3
3
0.144
3
1
1233.85
6
1
6.67
1
313.15
5
2
0.683
3
3
0.144
3
1
1221.69
6
1
6.59
1
333.15
5
2
0.683
3
3
0.144
3
1
1207.74
6
1
6.57
1
353.15
5
2
0.683
3
3
0.144
3
1
1188.53
6
1
6.4
1
333.15
5
2
0.694
3
3
0.098
2
1
1232.16
6
1
6.61
1
293.15
5
2
0.694
3
3
0.098
2
1
1259.41
6
1
6.76
1
313.15
5
2
0.694
3
3
0.098
2
1
1246.68
6
1
6.68
1
353.15
5
2
0.694
3
3
0.098
2
1
1210.65
6
1
6.49
1
313.15
5
2
0.706
3
3
0.05
2
1
1270.9
5
1
6.4
1
333.15
5
2
0.706
3
3
0.05
2
1
1254.78
6
1
6.42
1
293.15
5
2
0.706
3
3
0.05
2
1
1282.51
6
1
6.57
1
353.15
5
2
0.706
3
3
0.05
2
1
1235.36
6
1
6.38
1
293.15
5
2
0.707
3
3
0.281
3
1
1119.62
6
1
6.69
1
313.15
5
2
0.707
3
3
0.281
3
1
1108.55
6
1
6.43
1
333.15
5
2
0.707
3
3
0.281
3
1
1097.68
6
1
6.2
1
353.15
5
2
0.707
3
3
0.281
3
1
1087.09
6
1
6.04
1
333.15
5
2
0.711
3
3
0.264
3
1
1105.48
6
1
6.39
1
293.15
5
2
0.711
3
3
0.264
3
1
1129.71
6
1
6.75
1
313.15
5
2
0.711
3
3
0.264
3
1
1117.39
6
1
6.56
1
353.15
5
2
0.711
3
3
0.264
3
1
1094.33
6
1
6.29
1
313.15
5
2
0.712
3
3
0.025
2
1
1282.89
6
1
6.38
1
293.15
5
2
0.712
3
3
0.025
2
1
1296.01
6
1
6.52
1
333.15
5
2
0.712
3
3
0.025
2
1
1267.19
6
1
6.37
1
353.15
5
2
0.712
3
3
0.025
2
1
1247.07
6
1
6.46
1
313.15
5
2
0.721
3
3
0.229
3
1
1141.21
6
1
6.7
1
293.15
5
2
0.721
3
3
0.229
3
1
1151.08
6
1
6.64
1
333.15
5
2
0.721
3
3
0.229
3
1
1125.06
6
1
6.56
1
353.15
5
2
0.721
3
3
0.229
3
1
1112.55
6
1
6.6
1
293.15
5
2
0.731
3
3
0.193
3
1
1172.87
6
1
6.55
1
313.15
5
2
0.731
3
3
0.193
3
1
1159.77
6
1
6.63
1
333.15
5
2
0.731
3
3
0.193
3
1
1145.86
6
1
6.59
1
353.15
5
2
0.731
3
3
0.193
3
1
1132.3
5
1
6.4
1
293.15
5
2
0.741
3
3
0.157
3
1
1192.86
6
1
6.72
1
333.15
5
2
0.741
3
3
0.157
3
1
1166.93
6
1
6.52
1
313.15
5
2
0.741
3
3
0.157
3
1
1180.36
6
1
6.7
1
353.15
5
2
0.741
3
3
0.157
3
1
1153.97
6
1
6.23
1
313.15
5
2
0.751
3
3
0.119
3
1
1204.31
6
1
6.65
1
293.15
5
2
0.751
3
3
0.119
3
1
1217.09
6
1
6.7
1
333.15
5
2
0.751
3
3
0.119
3
1
1188.46
6
1
6.58
1
353.15
5
2
0.751
3
3
0.119
3
1
1173.18
6
1
6.29
1
333.15
5
2
0.762
3
3
0.08
2
1
1210.19
6
1
6.67
1
313.15
5
2
0.762
3
3
0.08
2
1
1225.94
6
1
6.66
1
293.15
5
2
0.762
3
3
0.08
2
1
1240.27
6
1
6.76
1
353.15
5
2
0.762
3
3
0.08
2
1
1195.6
5
1
6.5
1
313.15
5
2
0.773
3
3
0.041
2
1
1248.16
6
1
6.78
1
293.15
5
2
0.773
3
3
0.041
2
1
1261.77
6
1
6.88
1
333.15
5
2
0.773
3
3
0.041
2
1
1233.52
6
1
6.54
1
353.15
5
2
0.773
3
3
0.041
2
1
1218.62
6
1
6.45
1
333.15
5
2
0.778
3
3
0.021
2
1
1244.4
5
1
6.6
1
313.15
5
2
0.778
3
3
0.021
2
1
1260.37
6
1
6.71
1
293.15
5
2
0.778
3
3
0.021
2
1
1275.39
6
1
6.87
1
353.15
5
2
0.778
3
3
0.021
2
1
1230.23
6
1
6.44
2
3
1
1
1
2
1
Principal objective of the work
EP
EP
12/2/2016
1
Viscosity, Pa*s
Falling or rolling sphere viscometry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
100
1
1
Temperature, K
Liquid
2
Mole fraction
3
Liquid
3
Mole fraction
1
Liquid
1
293.15
5
2
0.337
3
3
0.64
3
1
0.0909
3
1
0.0127
1
293.15
5
2
0.341
3
3
0.612
3
1
0.0871
3
1
0.0122
1
293.15
5
2
0.348
3
3
0.555
3
1
0.0797
3
1
0.0111
1
293.15
5
2
0.359
3
3
0.492
3
1
0.0721
3
1
0.01
1
293.15
5
2
0.371
3
3
0.426
3
1
0.0623
3
1
0.0087
1
293.15
5
2
0.373
3
3
0.395
3
1
0.0585
3
1
0.0081
1
293.15
5
2
0.385
3
3
0.324
3
1
0.05
3
1
0.0069
1
293.15
5
2
0.395
3
3
0.25
3
1
0.0419
3
1
0.0058
1
293.15
5
2
0.406
3
3
0.172
3
1
0.0341
3
1
0.0047
1
293.15
5
2
0.419
3
3
0.089
2
1
0.0282
3
1
0.0039
1
293.15
5
2
0.426
3
3
0.045
2
1
0.0239
3
1
0.0033
1
293.15
5
2
0.518
3
3
0.465
3
1
0.0575
3
1
0.008
1
293.15
5
2
0.522
3
3
0.442
3
1
0.0549
3
1
0.0076
1
293.15
5
2
0.533
3
3
0.393
3
1
0.0487
3
1
0.0068
1
293.15
5
2
0.543
3
3
0.344
3
1
0.0426
3
1
0.0059
1
293.15
5
2
0.554
3
3
0.292
3
1
0.0366
3
1
0.0051
1
293.15
5
2
0.564
3
3
0.24
3
1
0.0324
3
1
0.0045
1
293.15
5
2
0.585
3
3
0.18
3
1
0.0261
3
1
0.0036
1
293.15
5
2
0.59
3
3
0.125
3
1
0.0204
3
1
0.0029
1
293.15
5
2
0.602
3
3
0.064
2
1
0.0166
3
1
0.0023
1
293.15
5
2
0.609
3
3
0.032
2
1
0.0133
3
1
0.0019
1
293.15
5
2
0.63
3
3
0.355
3
1
0.0406
3
1
0.0056
1
293.15
5
2
0.635
3
3
0.335
3
1
0.0384
3
1
0.0053
1
293.15
5
2
0.645
3
3
0.295
3
1
0.0333
3
1
0.0046
1
293.15
5
2
0.655
3
3
0.255
3
1
0.0289
3
1
0.004
1
293.15
5
2
0.666
3
3
0.211
3
1
0.0245
3
1
0.0034
1
293.15
5
2
0.671
3
3
0.189
3
1
0.023
3
1
0.0032
1
293.15
5
2
0.683
3
3
0.144
3
1
0.0189
3
1
0.0026
1
293.15
5
2
0.694
3
3
0.098
2
1
0.015
3
1
0.0021
1
293.15
5
2
0.706
3
3
0.05
2
1
0.0114
3
1
0.0016
1
293.15
5
2
0.707
3
3
0.281
3
1
0.0307
3
1
0.0043
1
293.15
5
2
0.711
3
3
0.264
3
1
0.0284
3
1
0.004
1
293.15
5
2
0.712
3
3
0.025
2
1
0.0097
2
1
0.0014
1
293.15
5
2
0.721
3
3
0.229
3
1
0.0249
3
1
0.0035
1
293.15
5
2
0.731
3
3
0.193
3
1
0.024
3
1
0.0034
1
293.15
5
2
0.741
3
3
0.157
3
1
0.0172
3
1
0.0024
1
293.15
5
2
0.751
3
3
0.119
3
1
0.0139
3
1
0.002
1
293.15
5
2
0.762
3
3
0.08
2
1
0.011
3
1
0.0016
1
293.15
5
2
0.773
3
3
0.041
2
1
0.0084
2
1
0.0012
1
293.15
5
2
0.778
3
3
0.021
2
1
0.0072
2
1
0.001
1
313.15
5
2
0.426
3
3
0.045
2
1
0.0129
3
1
0.0018
1
313.15
5
2
0.518
3
3
0.465
3
1
0.0239
3
1
0.0036
1
313.15
5
2
0.522
3
3
0.442
3
1
0.0228
3
1
0.0033
1
313.15
5
2
0.359
3
3
0.492
3
1
0.0289
3
1
0.0041
1
313.15
5
2
0.533
3
3
0.393
3
1
0.0207
3
1
0.003
1
313.15
5
2
0.543
3
3
0.344
3
1
0.0187
3
1
0.0026
1
313.15
5
2
0.554
3
3
0.292
3
1
0.0167
3
1
0.0024
1
313.15
5
2
0.564
3
3
0.24
3
1
0.0151
3
1
0.0021
1
313.15
5
2
0.337
3
3
0.64
3
1
0.0343
3
1
0.0055
1
313.15
5
2
0.585
3
3
0.18
3
1
0.0126
3
1
0.0018
1
313.15
5
2
0.371
3
3
0.426
3
1
0.0258
3
1
0.0038
1
313.15
5
2
0.59
3
3
0.125
3
1
0.0105
3
1
0.0015
1
313.15
5
2
0.602
3
3
0.064
2
1
0.0088
2
1
0.0013
1
313.15
5
2
0.341
3
3
0.612
3
1
0.0333
3
1
0.0054
1
313.15
5
2
0.609
3
3
0.032
2
1
0.0074
2
1
0.001
1
313.15
5
2
0.373
3
3
0.395
3
1
0.025
3
1
0.0036
1
313.15
5
2
0.63
3
3
0.355
3
1
0.0173
3
1
0.0027
1
313.15
5
2
0.635
3
3
0.335
3
1
0.0166
3
1
0.0024
1
313.15
5
2
0.645
3
3
0.295
3
1
0.0148
3
1
0.0021
1
313.15
5
2
0.385
3
3
0.324
3
1
0.0221
3
1
0.0031
1
313.15
5
2
0.655
3
3
0.255
3
1
0.0132
3
1
0.0018
1
313.15
5
2
0.671
3
3
0.189
3
1
0.011
3
1
0.0016
1
313.15
5
2
0.671
3
3
0.189
3
1
0.0115
3
1
0.0016
1
313.15
5
2
0.683
3
3
0.144
3
1
0.0093
2
1
0.0013
1
313.15
5
2
0.395
3
3
0.25
3
1
0.0195
3
1
0.0027
1
313.15
5
2
0.694
3
3
0.098
2
1
0.0078
2
1
0.0011
1
313.15
5
2
0.706
3
3
0.05
2
1
0.0062
2
1
0.0009
1
313.15
5
2
0.707
3
3
0.281
3
1
0.0135
3
1
0.0023
1
313.15
5
2
0.711
3
3
0.264
3
1
0.0125
3
1
0.0018
1
313.15
5
2
0.712
3
3
0.025
2
1
0.0055
2
1
0.0008
1
313.15
5
2
0.348
3
3
0.555
3
1
0.0314
3
1
0.0045
1
313.15
5
2
0.721
3
3
0.229
3
1
0.011
3
1
0.0016
1
313.15
5
2
0.406
3
3
0.172
3
1
0.0167
3
1
0.0023
1
313.15
5
2
0.731
3
3
0.193
3
1
0.0096
2
1
0.0014
1
313.15
5
2
0.741
3
3
0.157
3
1
0.0083
2
1
0.0012
1
313.15
5
2
0.751
3
3
0.119
3
1
0.0069
2
1
0.001
1
313.15
5
2
0.419
3
3
0.089
2
1
0.0144
3
1
0.002
1
313.15
5
2
0.762
3
3
0.08
2
1
0.0058
2
1
0.0008
1
313.15
5
2
0.773
3
3
0.041
2
1
0.0046
2
1
0.0007
1
313.15
5
2
0.778
3
3
0.021
2
1
0.0041
2
1
0.0006
1
333.15
5
2
0.359
3
3
0.492
3
1
0.0146
3
1
0.002
1
333.15
5
2
0.533
3
3
0.393
3
1
0.0109
3
1
0.0015
1
333.15
5
2
0.609
3
3
0.032
2
1
0.0047
2
1
0.0007
1
333.15
5
2
0.63
3
3
0.355
3
1
0.009
2
1
0.0013
1
333.15
5
2
0.518
3
3
0.465
3
1
0.0121
3
1
0.0017
1
333.15
5
2
0.373
3
3
0.395
3
1
0.0132
3
1
0.0019
1
333.15
5
2
0.635
3
3
0.335
3
1
0.0087
2
1
0.0012
1
333.15
5
2
0.543
3
3
0.344
3
1
0.01
3
1
0.0014
1
333.15
5
2
0.645
3
3
0.295
3
1
0.008
2
1
0.0011
1
333.15
5
2
0.655
3
3
0.255
3
1
0.0072
2
1
0.001
1
333.15
5
2
0.554
3
3
0.292
3
1
0.0091
2
1
0.0013
1
333.15
5
2
0.341
3
3
0.612
3
1
0.0163
3
1
0.0024
1
333.15
5
2
0.671
3
3
0.189
3
1
0.0062
2
1
0.0009
1
333.15
5
2
0.671
3
3
0.189
3
1
0.0065
2
1
0.0009
1
333.15
5
2
0.385
3
3
0.324
3
1
0.012
3
1
0.0017
1
333.15
5
2
0.683
3
3
0.144
3
1
0.0054
2
1
0.0008
1
333.15
5
2
0.694
3
3
0.098
2
1
0.0047
2
1
0.0007
1
333.15
5
2
0.564
3
3
0.24
3
1
0.0084
2
1
0.0012
1
333.15
5
2
0.426
3
3
0.045
2
1
0.0078
2
1
0.0011
1
333.15
5
2
0.706
3
3
0.05
2
1
0.0039
2
1
0.0006
1
333.15
5
2
0.395
3
3
0.25
3
1
0.0108
3
1
0.0015
1
333.15
5
2
0.707
3
3
0.281
3
1
0.0071
2
1
0.0011
1
333.15
5
2
0.711
3
3
0.264
3
1
0.0067
2
1
0.0009
1
333.15
5
2
0.522
3
3
0.442
3
1
0.0117
3
1
0.0016
1
333.15
5
2
0.585
3
3
0.18
3
1
0.0072
2
1
0.001
1
333.15
5
2
0.712
3
3
0.025
2
1
0.0035
2
1
0.0005
1
333.15
5
2
0.371
3
3
0.426
3
1
0.0132
3
1
0.0019
1
333.15
5
2
0.721
3
3
0.229
3
1
0.006
2
1
0.0009
1
333.15
5
2
0.406
3
3
0.172
3
1
0.0096
2
1
0.0013
1
333.15
5
2
0.59
3
3
0.125
3
1
0.0062
2
1
0.0009
1
333.15
5
2
0.731
3
3
0.193
3
1
0.0054
2
1
0.0008
1
333.15
5
2
0.741
3
3
0.157
3
1
0.0048
2
1
0.0007
1
333.15
5
2
0.602
3
3
0.064
2
1
0.0054
2
1
0.0008
1
333.15
5
2
0.751
3
3
0.119
3
1
0.0041
2
1
0.0006
1
333.15
5
2
0.762
3
3
0.08
2
1
0.0035
2
1
0.0005
1
333.15
5
2
0.337
3
3
0.64
3
1
0.0166
3
1
0.0024
1
333.15
5
2
0.348
3
3
0.555
3
1
0.0157
3
1
0.0022
1
333.15
5
2
0.419
3
3
0.089
2
1
0.0086
2
1
0.0012
1
333.15
5
2
0.773
3
3
0.041
2
1
0.0029
2
1
0.0004
1
333.15
5
2
0.778
3
3
0.021
2
1
0.0027
2
1
0.0004
1
353.15
5
2
0.341
3
3
0.612
3
1
0.0094
2
1
0.0013
1
353.15
5
2
0.564
3
3
0.24
3
1
0.0053
2
1
0.0007
1
353.15
5
2
0.359
3
3
0.492
3
1
0.0086
2
1
0.0012
1
353.15
5
2
0.707
3
3
0.281
3
1
0.0043
2
1
0.0006
1
353.15
5
2
0.609
3
3
0.032
2
1
0.0033
2
1
0.0005
1
353.15
5
2
0.395
3
3
0.25
3
1
0.0068
2
1
0.0009
1
353.15
5
2
0.373
3
3
0.395
3
1
0.0079
2
1
0.0011
1
353.15
5
2
0.711
3
3
0.264
3
1
0.0041
2
1
0.0006
1
353.15
5
2
0.337
3
3
0.64
3
1
0.0095
2
1
0.0013
1
353.15
5
2
0.426
3
3
0.045
2
1
0.0053
2
1
0.0007
1
353.15
5
2
0.348
3
3
0.555
3
1
0.009
2
1
0.0012
1
353.15
5
2
0.712
3
3
0.025
2
1
0.0025
2
1
0.0004
1
353.15
5
2
0.585
3
3
0.18
3
1
0.0047
2
1
0.0007
1
353.15
5
2
0.671
3
3
0.189
3
1
0.004
2
1
0.0006
1
353.15
5
2
0.671
3
3
0.189
3
1
0.0041
2
1
0.0006
1
353.15
5
2
0.721
3
3
0.229
3
1
0.0038
2
1
0.0005
1
353.15
5
2
0.385
3
3
0.324
3
1
0.0073
2
1
0.001
1
353.15
5
2
0.554
3
3
0.292
3
1
0.0056
2
1
0.0008
1
353.15
5
2
0.645
3
3
0.295
3
1
0.0049
2
1
0.0007
1
353.15
5
2
0.731
3
3
0.193
3
1
0.0034
2
1
0.0005
1
353.15
5
2
0.406
3
3
0.172
3
1
0.0061
2
1
0.0008
1
353.15
5
2
0.683
3
3
0.144
3
1
0.0036
2
1
0.0005
1
353.15
5
2
0.522
3
3
0.442
3
1
0.0069
2
1
0.001
1
353.15
5
2
0.741
3
3
0.157
3
1
0.0031
2
1
0.0004
1
353.15
5
2
0.59
3
3
0.125
3
1
0.0041
2
1
0.0006
1
353.15
5
2
0.533
3
3
0.393
3
1
0.0065
2
1
0.0009
1
353.15
5
2
0.518
3
3
0.465
3
1
0.0071
2
1
0.001
1
353.15
5
2
0.751
3
3
0.119
3
1
0.0027
2
1
0.0004
1
353.15
5
2
0.543
3
3
0.344
3
1
0.006
2
1
0.0008
1
353.15
5
2
0.371
3
3
0.426
3
1
0.0079
2
1
0.0011
1
353.15
5
2
0.694
3
3
0.098
2
1
0.0031
2
1
0.0004
1
353.15
5
2
0.762
3
3
0.08
2
1
0.0024
2
1
0.0003
1
353.15
5
2
0.63
3
3
0.355
3
1
0.0054
2
1
0.0008
1
353.15
5
2
0.655
3
3
0.255
3
1
0.0045
2
1
0.0006
1
353.15
5
2
0.635
3
3
0.335
3
1
0.0053
2
1
0.0007
1
353.15
5
2
0.773
3
3
0.041
2
1
0.0021
2
1
0.0003
1
353.15
5
2
0.706
3
3
0.05
2
1
0.0027
2
1
0.0004
1
353.15
5
2
0.602
3
3
0.064
2
1
0.0037
2
1
0.0005
1
353.15
5
2
0.419
3
3
0.089
2
1
0.0057
2
1
0.0008
1
353.15
5
2
0.778
3
3
0.021
2
1
0.0019
2
1
0.0003
3
3
1
1
1
2
1
Principal objective of the work
EP
EP
12/12/2016
1
Vapor or sublimation pressure, kPa
spectroscopy
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Temperature, K
Liquid
2
Mole fraction
3
Liquid
3
Mole fraction
1
Liquid
1
293.13
5
2
0.337
3
3
0.64
3
1
0.293
3
1
0.119
1
293.13
5
2
0.399
3
3
0.512
3
1
0.313
3
1
0.127
1
293.12
5
2
0.517
3
3
0.465
3
1
0.319
3
1
0.13
1
293.12
5
2
0.399
3
3
0.379
3
1
0.321
3
1
0.13
1
303.12
5
2
0.337
3
3
0.64
3
1
0.349
3
1
0.142
1
293.17
5
2
0.63
3
3
0.355
3
1
0.359
3
1
0.146
1
293.15
5
2
0.645
3
3
0.296
3
1
0.368
3
1
0.15
1
293.11
5
2
0.707
3
3
0.281
3
1
0.371
3
1
0.151
1
293.13
5
2
0.532
3
3
0.394
3
1
0.374
3
1
0.152
1
303.18
5
2
0.399
3
3
0.512
3
1
0.377
3
1
0.153
1
313.13
5
2
0.337
3
3
0.64
3
1
0.395
3
1
0.161
1
293.13
5
2
0.552
3
3
0.292
3
1
0.411
3
1
0.167
1
303.11
5
2
0.517
3
3
0.465
3
1
0.414
3
1
0.168
1
303.19
5
2
0.399
3
3
0.379
3
1
0.418
3
1
0.17
1
293.12
5
2
0.72
3
3
0.23
3
1
0.438
3
1
0.178
1
323.19
5
2
0.337
3
3
0.64
3
1
0.449
3
1
0.184
1
303.12
5
2
0.63
3
3
0.355
3
1
0.464
3
1
0.189
1
303.16
5
2
0.532
3
3
0.394
3
1
0.504
3
1
0.205
1
313.14
5
2
0.399
3
3
0.512
3
1
0.506
3
1
0.206
1
313.18
5
2
0.399
3
3
0.379
3
1
0.508
3
1
0.207
1
313.16
5
2
0.517
3
3
0.465
3
1
0.516
3
1
0.21
1
303.15
5
2
0.645
3
3
0.296
3
1
0.523
3
1
0.213
1
303.11
5
2
0.552
3
3
0.292
3
1
0.534
3
1
0.218
1
333.17
5
2
0.337
3
3
0.64
3
1
0.534
3
1
0.22
1
303.12
5
2
0.707
3
3
0.281
3
1
0.578
3
1
0.236
1
323.16
5
2
0.399
3
3
0.512
3
1
0.627
3
1
0.255
1
313.19
5
2
0.532
3
3
0.394
3
1
0.723
3
1
0.295
1
313.13
5
2
0.63
3
3
0.356
3
1
0.826
3
1
0.336
1
303.13
5
2
0.72
3
3
0.23
3
1
0.834
3
1
0.341
1
333.16
5
2
0.398
3
3
0.512
3
1
1.045
4
1
0.426
1
323.14
5
2
0.517
3
3
0.465
3
1
1.165
4
1
0.474
1
343.18
5
2
0.336
3
3
0.64
3
1
1.238
4
1
0.504
1
313.17
5
2
0.644
3
3
0.296
3
1
1.257
4
1
0.513
1
323.11
5
2
0.398
3
3
0.38
3
1
1.29
3
1
0.525
1
323.16
5
2
0.531
3
3
0.395
3
1
1.369
4
1
0.556
1
313.19
5
2
0.706
3
3
0.281
3
1
1.613
4
1
0.657
1
313.15
5
2
0.551
3
3
0.292
3
1
1.614
4
1
0.657
1
323.15
5
2
0.629
3
3
0.356
3
1
1.934
4
1
0.412
1
313.13
5
2
0.719
3
3
0.23
3
1
1.942
4
1
0.414
1
333.16
5
2
0.516
3
3
0.466
3
1
2.024
4
1
0.432
1
353.15
5
2
0.336
3
3
0.641
3
1
2.025
4
1
0.433
1
333.17
5
2
0.531
3
3
0.395
3
1
2.12
3
1
0.45
1
333.11
5
2
0.398
3
3
0.38
3
1
2.136
4
1
0.455
1
343.17
5
2
0.397
3
3
0.513
3
1
2.191
4
1
0.467
1
323.18
5
2
0.644
3
3
0.296
3
1
2.453
4
1
0.524
1
323.15
5
2
0.55
3
3
0.292
3
1
2.609
4
1
0.557
1
353.17
5
2
0.396
3
3
0.513
3
1
3.094
4
1
0.66
1
343.17
5
2
0.515
3
3
0.466
3
1
3.228
4
1
0.686
1
323.18
5
2
0.706
3
3
0.281
3
1
3.266
4
1
0.696
1
333.12
5
2
0.628
3
3
0.356
3
1
3.278
4
1
0.698
1
323.12
5
2
0.719
3
3
0.23
3
1
3.321
4
1
0.705
1
343.11
5
2
0.396
3
3
0.381
3
1
3.421
4
1
0.727
1
343.12
5
2
0.53
3
3
0.395
3
1
3.569
4
1
0.758
1
333.16
5
2
0.549
3
3
0.293
3
1
4.05
3
1
0.864
1
333.11
5
2
0.643
3
3
0.297
3
1
4.19
3
1
0.893
1
353.16
5
2
0.514
3
3
0.467
3
1
4.728
4
1
1.005
1
353.13
5
2
0.395
3
3
0.381
3
1
4.845
4
1
1.029
1
343.15
5
2
0.627
3
3
0.357
3
1
5.038
4
1
1.072
1
353.15
5
2
0.529
3
3
0.396
3
1
5.064
4
1
1.075
1
333.19
5
2
0.718
3
3
0.23
3
1
5.139
4
1
1.092
1
333.2
5
2
0.705
3
3
0.282
3
1
5.171
4
1
1.102
1
343.15
5
2
0.548
3
3
0.293
3
1
6.117
4
1
1.303
1
343.11
5
2
0.641
3
3
0.297
3
1
6.245
4
1
1.33
1
353.15
5
2
0.626
3
3
0.357
3
1
7.479
4
1
1.593
1
343.11
5
2
0.704
3
3
0.282
3
1
7.862
4
1
1.673
1
343.15
5
2
0.716
3
3
0.231
3
1
8.979
4
1
1.912
1
353.19
5
2
0.546
3
3
0.294
3
1
9.051
4
1
1.927
1
353.15
5
2
0.64
3
3
0.298
3
1
9.5
2
1
2.023
1
353.14
5
2
0.702
3
3
0.283
3
1
11.576
5
1
2.472
1
353.14
5
2
0.702
3
3
0.283
3
1
11.619
5
1
2.48
1
353.15
5
2
0.713
3
3
0.232
3
1
15.164
5
1
3.23
4
3
1
1
1
2
1
Principal objective of the work
EP
EP
12/12/2016
1
Mole fraction
spectroscopy
1
Gas
Direct value, X
Gas
Liquid
1
Temperature, K
Liquid
2
Mole fraction
3
Liquid
3
Mole fraction
1
Liquid
1
293.13
5
2
0.337
3
3
0.64
3
1
0
1
1
303.12
5
2
0.337
3
3
0.64
3
1
0
1
1
313.13
5
2
0.337
3
3
0.64
3
1
0
1
1
323.19
5
2
0.337
3
3
0.64
3
1
0
1
1
333.17
5
2
0.337
3
3
0.64
3
1
0
1
1
343.18
5
2
0.336
3
3
0.64
3
1
0
1
1
353.15
5
2
0.336
3
3
0.641
3
1
0
1
1
293.17
5
2
0.63
3
3
0.355
3
1
0
1
1
303.12
5
2
0.63
3
3
0.355
3
1
0
1
1
313.13
5
2
0.63
3
3
0.356
3
1
0
1
1
323.15
5
2
0.629
3
3
0.356
3
1
0
1
1
333.12
5
2
0.628
3
3
0.356
3
1
0
1
1
343.15
5
2
0.627
3
3
0.357
3
1
0
1
1
353.15
5
2
0.626
3
3
0.357
3
1
0
1
1
293.12
5
2
0.517
3
3
0.465
3
1
0
1
1
303.11
5
2
0.517
3
3
0.465
3
1
0
1
1
313.16
5
2
0.517
3
3
0.465
3
1
0
1
1
323.14
5
2
0.517
3
3
0.465
3
1
0
1
1
333.16
5
2
0.516
3
3
0.466
3
1
0
1
1
343.17
5
2
0.515
3
3
0.466
3
1
0
1
1
353.16
5
2
0.514
3
3
0.467
3
1
0
1
1
293.11
5
2
0.707
3
3
0.281
3
1
0
1
1
303.12
5
2
0.707
3
3
0.281
3
1
0
1
1
313.19
5
2
0.706
3
3
0.281
3
1
0
1
1
323.18
5
2
0.706
3
3
0.281
3
1
0
1
1
333.2
5
2
0.705
3
3
0.282
3
1
0
1
1
343.11
5
2
0.704
3
3
0.282
3
1
0
1
1
353.14
5
2
0.702
3
3
0.283
3
1
0
1
1
353.14
5
2
0.702
3
3
0.283
3
1
0
1
1
293.13
5
2
0.399
3
3
0.512
3
1
0
1
1
303.18
5
2
0.399
3
3
0.512
3
1
0
1
1
313.14
5
2
0.399
3
3
0.512
3
1
0
1
1
323.16
5
2
0.399
3
3
0.512
3
1
0
1
1
333.16
5
2
0.398
3
3
0.512
3
1
0
1
1
343.17
5
2
0.397
3
3
0.513
3
1
0
1
1
353.17
5
2
0.396
3
3
0.513
3
1
0
1
1
293.13
5
2
0.532
3
3
0.394
3
1
0
1
1
303.16
5
2
0.532
3
3
0.394
3
1
0
1
1
313.19
5
2
0.532
3
3
0.394
3
1
0
1
1
323.16
5
2
0.531
3
3
0.395
3
1
0
1
1
333.17
5
2
0.531
3
3
0.395
3
1
0
1
1
343.12
5
2
0.53
3
3
0.395
3
1
0
1
1
353.15
5
2
0.529
3
3
0.396
3
1
0
1
1
293.15
5
2
0.645
3
3
0.296
3
1
0
1
1
303.15
5
2
0.645
3
3
0.296
3
1
0
1
1
313.17
5
2
0.644
3
3
0.296
3
1
0
1
1
323.18
5
2
0.644
3
3
0.296
3
1
0
1
1
333.11
5
2
0.643
3
3
0.297
3
1
0
1
1
343.11
5
2
0.641
3
3
0.297
3
1
0
1
1
353.15
5
2
0.64
3
3
0.298
3
1
0
1
1
293.12
5
2
0.72
3
3
0.23
3
1
0
1
1
303.13
5
2
0.72
3
3
0.23
3
1
0
1
1
313.13
5
2
0.719
3
3
0.23
3
1
0
1
1
323.12
5
2
0.719
3
3
0.23
3
1
0
1
1
333.19
5
2
0.718
3
3
0.23
3
1
0
1
1
343.15
5
2
0.716
3
3
0.231
3
1
0
1
1
353.15
5
2
0.713
3
3
0.232
3
1
0
1
1
293.12
5
2
0.399
3
3
0.379
3
1
0
1
1
303.19
5
2
0.399
3
3
0.379
3
1
0
1
1
313.18
5
2
0.399
3
3
0.379
3
1
0
1
1
323.11
5
2
0.398
3
3
0.38
3
1
0
1
1
333.11
5
2
0.398
3
3
0.38
3
1
0
1
1
343.11
5
2
0.396
3
3
0.381
3
1
0
1
1
353.13
5
2
0.395
3
3
0.381
3
1
0
1
1
293.13
5
2
0.552
3
3
0.292
3
1
0
1
1
303.11
5
2
0.552
3
3
0.292
3
1
0
1
1
313.15
5
2
0.551
3
3
0.292
3
1
0
1
1
323.15
5
2
0.55
3
3
0.292
3
1
0
1
1
333.16
5
2
0.549
3
3
0.293
3
1
0
1
1
343.15
5
2
0.548
3
3
0.293
3
1
0
1
1
353.19
5
2
0.546
3
3
0.294
3
1
0
1
5
3
1
1
1
2
1
Principal objective of the work
EP
EP
12/12/2016
1
Mole fraction
spectroscopy
2
Gas
Direct value, X
Gas
Liquid
1
Temperature, K
Liquid
2
Mole fraction
3
Liquid
3
Mole fraction
1
Liquid
1
293.13
5
2
0.337
3
3
0.64
3
1
0
1
1
303.12
5
2
0.337
3
3
0.64
3
1
0
1
1
313.13
5
2
0.337
3
3
0.64
3
1
0
1
1
323.19
5
2
0.337
3
3
0.64
3
1
0
1
1
333.17
5
2
0.337
3
3
0.64
3
1
0
1
1
343.18
5
2
0.336
3
3
0.64
3
1
0
1
1
353.15
5
2
0.336
3
3
0.641
3
1
0
1
1
293.17
5
2
0.63
3
3
0.355
3
1
0
1
1
303.12
5
2
0.63
3
3
0.355
3
1
0
1
1
313.13
5
2
0.63
3
3
0.356
3
1
0
1
1
323.15
5
2
0.629
3
3
0.356
3
1
0
1
1
333.12
5
2
0.628
3
3
0.356
3
1
0
1
1
343.15
5
2
0.627
3
3
0.357
3
1
0
1
1
353.15
5
2
0.626
3
3
0.357
3
1
0
1
1
293.12
5
2
0.517
3
3
0.465
3
1
0
1
1
303.11
5
2
0.517
3
3
0.465
3
1
0
1
1
313.16
5
2
0.517
3
3
0.465
3
1
0
1
1
323.14
5
2
0.517
3
3
0.465
3
1
0
1
1
333.16
5
2
0.516
3
3
0.466
3
1
0
1
1
343.17
5
2
0.515
3
3
0.466
3
1
0
1
1
353.16
5
2
0.514
3
3
0.467
3
1
0
1
1
293.11
5
2
0.707
3
3
0.281
3
1
0
1
1
303.12
5
2
0.707
3
3
0.281
3
1
0
1
1
313.19
5
2
0.706
3
3
0.281
3
1
0
1
1
323.18
5
2
0.706
3
3
0.281
3
1
0
1
1
333.2
5
2
0.705
3
3
0.282
3
1
0
1
1
343.11
5
2
0.704
3
3
0.282
3
1
0
1
1
353.14
5
2
0.702
3
3
0.283
3
1
0
1
1
353.14
5
2
0.702
3
3
0.283
3
1
0
1
1
293.13
5
2
0.399
3
3
0.512
3
1
0
1
1
303.18
5
2
0.399
3
3
0.512
3
1
0
1
1
313.14
5
2
0.399
3
3
0.512
3
1
0
1
1
323.16
5
2
0.399
3
3
0.512
3
1
0
1
1
333.16
5
2
0.398
3
3
0.512
3
1
0
1
1
343.17
5
2
0.397
3
3
0.513
3
1
0
1
1
353.17
5
2
0.396
3
3
0.513
3
1
0
1
1
293.13
5
2
0.532
3
3
0.394
3
1
0
1
1
303.16
5
2
0.532
3
3
0.394
3
1
0
1
1
313.19
5
2
0.532
3
3
0.394
3
1
0
1
1
323.16
5
2
0.531
3
3
0.395
3
1
0
1
1
333.17
5
2
0.531
3
3
0.395
3
1
0
1
1
343.12
5
2
0.53
3
3
0.395
3
1
0
1
1
353.15
5
2
0.529
3
3
0.396
3
1
0
1
1
293.15
5
2
0.645
3
3
0.296
3
1
0
1
1
303.15
5
2
0.645
3
3
0.296
3
1
0
1
1
313.17
5
2
0.644
3
3
0.296
3
1
0
1
1
323.18
5
2
0.644
3
3
0.296
3
1
0
1
1
333.11
5
2
0.643
3
3
0.297
3
1
0
1
1
343.11
5
2
0.641
3
3
0.297
3
1
0
1
1
353.15
5
2
0.64
3
3
0.298
3
1
0
1
1
293.12
5
2
0.72
3
3
0.23
3
1
0
1
1
303.13
5
2
0.72
3
3
0.23
3
1
0
1
1
313.13
5
2
0.719
3
3
0.23
3
1
0
1
1
323.12
5
2
0.719
3
3
0.23
3
1
0
1
1
333.19
5
2
0.718
3
3
0.23
3
1
0
1
1
343.15
5
2
0.716
3
3
0.231
3
1
0
1
1
353.15
5
2
0.713
3
3
0.232
3
1
0
1
1
293.12
5
2
0.399
3
3
0.379
3
1
0
1
1
303.19
5
2
0.399
3
3
0.379
3
1
0
1
1
313.18
5
2
0.399
3
3
0.379
3
1
0
1
1
323.11
5
2
0.398
3
3
0.38
3
1
0
1
1
333.11
5
2
0.398
3
3
0.38
3
1
0
1
1
343.11
5
2
0.396
3
3
0.381
3
1
0
1
1
353.13
5
2
0.395
3
3
0.381
3
1
0
1
1
293.13
5
2
0.552
3
3
0.292
3
1
0
1
1
303.11
5
2
0.552
3
3
0.292
3
1
0
1
1
313.15
5
2
0.551
3
3
0.292
3
1
0
1
1
323.15
5
2
0.55
3
3
0.292
3
1
0
1
1
333.16
5
2
0.549
3
3
0.293
3
1
0
1
1
343.15
5
2
0.548
3
3
0.293
3
1
0
1
1
353.19
5
2
0.546
3
3
0.294
3
1
0
1