2
0
2017
pan
sin
0
journal
Original
Panda, S.[Somenath]
Singh, D.[Dharmendra]
Sharma, G.[Gyanendra]
Basaiahgari, A.[Anusha]
Gardas, R.[Ramesh]
J. Chem. Eng. Data
2017
2020-09-29
Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
In this study, we have reported precise high-temperature volumetric data of industrially important benzylamines, namely, benzylamine, N-methylbenzylamine, N,N-dimethylbenzylamine, and dibenzylamine. The effect of temperature and methyl or benzyl substitution on benzylamines have been discussed. Other physicochemical properties such as speed of sound, viscosity, and refractive index have been measured in the temperature range from 293.15 to 343.15 K and used to calculate several derived properties. Temperature dependence of density and refractive index data were fitted with the second order polynomial equation whereas viscosity data have been fitted well according to Arrhenius equation. The correlation between density and refractive index has also been quantified through a set of empirical equations. The molar refraction parameter has been estimated by Lorenz Lorentz equation. Finally, the critical properties have been estimated with the modified Lydersen Joback Reid method and used to correlate the density of studied benzylamines.
10.1021/acs.jced.6b00667
4
62
1189-1197
1
InChI=1S/C7H9N/c8-6-7-4-2-1-3-5-7/h1-5H,6,8H2
WGQKYBSKWIADBV-UHFFFAOYSA-N
benzylamine
(aminomethyl)benzene
(phenylmethyl)amine
.alpha.-aminotoluene
aminomethylbenzene
benzene, aminomethyl-
benzenemethanamine
C7H9N
1
Commercial source
1
99.5
3
Stated by supplier
2
InChI=1S/C8H11N/c1-9-7-8-5-3-2-4-6-8/h2-6,9H,7H2,1H3
RIWRFSMVIUAEBX-UHFFFAOYSA-N
N-methyl-1-phenylmethanamine
N-methylbenzylamine
C8H11N
1
Commercial source
1
97
2
Stated by supplier
3
InChI=1S/C9H13N/c1-10(2)8-9-6-4-3-5-7-9/h3-7H,8H2,1-2H3
XXBDWLFCJWSEKW-UHFFFAOYSA-N
N,N-dimethylbenzylamine
benzylamine, N,N-dimethyl-
benzyldimethylamine
C9H13N
1
Commercial source
1
99
2
Stated by supplier
4
InChI=1S/C14H15N/c1-3-7-13(8-4-1)11-15-12-14-9-5-2-6-10-14/h1-10,15H,11-12H2
BWLUMTFWVZZZND-UHFFFAOYSA-N
dibenzylamine
bis(phenylmethyl)amine
C14H15N
1
Commercial source
1
97
2
Stated by supplier
1
1
1
Principal objective of the work
EP
EP
3/17/2017
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
983.4
4
1
2
1
298.15
5
1
978.9
4
1
2
1
303.15
5
1
974.4
4
1
2
1
308.15
5
1
970
4
1
2
1
313.15
5
1
965.7
4
1
2
1
318.15
5
1
961.3
4
1
2
1
323.15
5
1
956.9
4
1
2
1
328.15
5
1
952.5
4
1
2
1
333.15
5
1
948.2
4
1
2
1
338.15
5
1
943.7
4
1
2
1
343.15
5
1
939.4
4
1
2
1
348.15
5
1
935
4
1
2
1
353.15
5
1
930.6
4
1
2
1
358.15
5
1
926.2
4
1
2
1
363.15
5
1
921.8
4
1
2
1
368.15
5
1
917.3
4
1
2
1
373.15
5
1
912.9
4
1
2
1
378.15
5
1
908.5
4
1
2
1
383.15
5
1
904
4
1
2
1
388.15
5
1
899.7
4
1
2
1
393.15
5
1
895.2
4
1
2
1
398.15
5
1
890.6
4
1
2
1
403.15
5
1
886.2
4
1
2
1
408.15
5
1
881.6
4
1
2
1
413.15
5
1
877.1
4
1
2
1
418.15
5
1
872.5
4
1
2
1
423.15
5
1
867.9
4
1
2
1
428.15
5
1
863.3
4
1
2
1
433.15
5
1
858.7
4
1
2
1
438.15
5
1
854
4
1
2
1
443.15
5
1
849.3
4
1
2
1
293.15
5
1
983.66
5
1
2
1
298.15
5
1
979.35
5
1
2
1
303.15
5
1
975.01
5
1
2
1
308.15
5
1
970.67
5
1
2
1
313.15
5
1
966.33
5
1
2
1
318.15
5
1
961.98
5
1
2
1
323.15
5
1
957.63
5
1
2
1
328.15
5
1
953.27
5
1
2
1
333.15
5
1
948.9
5
1
2
1
338.15
5
1
944.53
5
1
2
1
343.15
5
1
940.14
5
1
2
2
1
1
Principal objective of the work
EP
EP
3/16/2017
1
Speed of sound, m/s
Sing-around technique in a fixed-path interferometer
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1580.59
6
1
1.32
1
298.15
5
1
1561.06
6
1
1.32
1
303.15
5
1
1541.2
6
1
1.31
1
308.15
5
1
1521.44
6
1
1.31
1
313.15
5
1
1501.89
6
1
1.31
1
318.15
5
1
1482.42
6
1
1.3
1
323.15
5
1
1462.9
6
1
1.3
1
328.15
5
1
1443.46
6
1
1.3
1
333.15
5
1
1424.09
6
1
1.29
1
338.15
5
1
1404.8
6
1
1.29
1
343.15
5
1
1385.58
6
1
1.29
3
1
1
Principal objective of the work
BDH
TRC
3/6/2017
1
Viscosity, Pa*s
Falling or rolling sphere viscometry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
0.00203
3
1
0.00014
1
298.15
5
1
0.00183
3
1
0.00014
1
303.15
5
1
0.00165
3
1
0.00014
1
308.15
5
1
0.0015
3
1
0.00014
1
313.15
5
1
0.00137
3
1
0.00014
1
318.15
5
1
0.00126
3
1
0.00014
1
323.15
5
1
0.00117
3
1
0.00014
1
328.15
5
1
0.00108
3
1
0.00014
1
333.15
5
1
0.001
3
1
0.00014
1
338.15
5
1
0.00094
2
1
0.00014
1
343.15
5
1
0.00087
2
1
0.00014
4
1
1
Principal objective of the work
BDH
TRC
3/6/2017
1
Refractive index (Na D-line)
Standard Abbe refractometry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1.54271
6
1
0.00041
1
298.15
5
1
1.53875
6
1
0.00041
1
303.15
5
1
1.53518
6
1
0.00041
1
308.15
5
1
1.53226
6
1
0.00041
1
313.15
5
1
1.52948
6
1
0.00041
1
318.15
5
1
1.52706
6
1
0.00041
1
323.15
5
1
1.525
6
1
0.00041
1
328.15
5
1
1.523
6
1
0.00041
1
333.15
5
1
1.52068
6
1
0.00041
1
338.15
5
1
1.51906
6
1
0.00041
1
343.15
5
1
1.51728
6
1
0.00041
5
2
1
Principal objective of the work
EP
EP
3/17/2017
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
283.15
5
1
952.8
4
1
6.2
1
288.15
5
1
948.4
4
1
6.2
1
293.15
5
1
944
4
1
6.2
1
298.15
5
1
939.6
4
1
6.2
1
303.15
5
1
935.1
4
1
6.2
1
308.15
5
1
930.7
4
1
6.2
1
313.15
5
1
926.4
4
1
6.2
1
318.15
5
1
922
4
1
6.2
1
323.15
5
1
917.6
4
1
6.2
1
328.15
5
1
913.3
4
1
6.2
1
333.15
5
1
908.9
4
1
6.2
1
338.15
5
1
904.5
4
1
6.2
1
343.15
5
1
900
4
1
6.2
1
348.15
5
1
895.6
4
1
6.2
1
353.15
5
1
891.2
4
1
6.2
1
358.15
5
1
886.7
4
1
6.2
1
363.15
5
1
882.3
4
1
6.2
1
368.15
5
1
877.8
4
1
6.2
1
373.15
5
1
873.4
4
1
6.2
1
378.15
5
1
868.9
4
1
6.2
1
383.15
5
1
864.4
4
1
6.1
1
388.15
5
1
860
4
1
6.1
1
393.15
5
1
855.4
4
1
6.1
1
398.15
5
1
851
4
1
6.1
1
403.15
5
1
846.4
4
1
6.1
1
408.15
5
1
841.8
4
1
6.1
1
413.15
5
1
837.3
4
1
6.1
1
418.15
5
1
832.6
4
1
6.1
1
293.15
5
1
944.55
5
1
6.2
1
298.15
5
1
940.23
5
1
6.2
1
303.15
5
1
935.9
5
1
6.19
1
308.15
5
1
931.57
5
1
6.19
1
313.15
5
1
927.24
5
1
6.19
1
318.15
5
1
922.9
5
1
6.18
1
323.15
5
1
918.55
5
1
6.18
1
328.15
5
1
914.19
5
1
6.18
1
333.15
5
1
909.83
5
1
6.18
1
338.15
5
1
905.5
5
1
6.17
1
343.15
5
1
901.19
5
1
6.17
6
2
1
Principal objective of the work
BDH
TRC
3/6/2017
1
Speed of sound, m/s
Sing-around technique in a fixed-path interferometer
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1472.73
6
1
3.23
1
298.15
5
1
1452.86
6
1
3.23
1
303.15
5
1
1433.1
6
1
3.23
1
308.15
5
1
1413.47
6
1
3.23
1
313.15
5
1
1393.98
6
1
3.23
1
318.15
5
1
1374.57
6
1
3.22
1
323.15
5
1
1355.29
6
1
3.22
1
328.15
5
1
1336.13
6
1
3.22
1
333.15
5
1
1317.13
6
1
3.22
1
338.15
5
1
1298.4
6
1
3.22
1
343.15
5
1
1280.2
6
1
3.22
7
2
1
Principal objective of the work
BDH
TRC
3/6/2017
1
Viscosity, Pa*s
Falling or rolling sphere viscometry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
0.00176
3
1
0.00014
1
298.15
5
1
0.00158
3
1
0.00014
1
303.15
5
1
0.0014
3
1
0.00014
1
308.15
5
1
0.00127
3
1
0.00014
1
313.15
5
1
0.00116
3
1
0.00014
1
318.15
5
1
0.00107
3
1
0.00014
1
323.15
5
1
0.00099
2
1
0.00014
1
328.15
5
1
0.00091
2
1
0.00014
1
333.15
5
1
0.00085
2
1
0.00014
1
338.15
5
1
0.00079
2
1
0.00014
1
343.15
5
1
0.00074
2
1
0.00014
8
2
1
Principal objective of the work
BDH
TRC
3/6/2017
1
Refractive index (Na D-line)
Standard Abbe refractometry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1.52243
6
1
0.00072
1
298.15
5
1
1.51947
6
1
0.00072
1
303.15
5
1
1.51678
6
1
0.00072
1
308.15
5
1
1.51432
6
1
0.00072
1
313.15
5
1
1.51211
6
1
0.00072
1
318.15
5
1
1.51003
6
1
0.00072
1
323.15
5
1
1.50783
6
1
0.00072
1
328.15
5
1
1.50565
6
1
0.00072
1
333.15
5
1
1.50339
6
1
0.00072
1
338.15
5
1
1.50103
6
1
0.00072
1
343.15
5
1
1.49856
6
1
0.00072
9
3
1
Principal objective of the work
EP
EP
3/17/2017
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
283.15
5
1
907.6
4
1
2
1
288.15
5
1
903.2
4
1
2
1
293.15
5
1
898.9
4
1
2
1
298.15
5
1
894.6
4
1
2
1
303.15
5
1
890.2
4
1
2
1
308.15
5
1
885.9
4
1
2
1
313.15
5
1
881.7
4
1
2
1
318.15
5
1
877.4
4
1
2
1
323.15
5
1
873.2
4
1
2
1
328.15
5
1
868.9
4
1
2
1
333.15
5
1
864.6
4
1
2
1
338.15
5
1
860.4
4
1
2
1
343.15
5
1
856
4
1
2
1
348.15
5
1
851.8
4
1
2
1
353.15
5
1
847.5
4
1
2
1
358.15
5
1
843.2
4
1
2
1
363.15
5
1
838.9
4
1
2
1
368.15
5
1
834.6
4
1
2
1
373.15
5
1
830.2
4
1
2
1
378.15
5
1
825.9
4
1
2
1
383.15
5
1
821.5
4
1
2
1
388.15
5
1
817.1
4
1
2
1
393.15
5
1
812.7
4
1
2
1
398.15
5
1
808.2
4
1
2
1
403.15
5
1
803.7
4
1
2
1
408.15
5
1
799.2
4
1
2
1
413.15
5
1
794.7
4
1
2
1
418.15
5
1
790.1
4
1
2
1
293.15
5
1
899.32
5
1
2.01
1
298.15
5
1
895.1
5
1
2.01
1
303.15
5
1
890.88
5
1
2.01
1
308.15
5
1
886.65
5
1
2.01
1
313.15
5
1
882.42
5
1
2.01
1
318.15
5
1
878.18
5
1
2.01
1
323.15
5
1
873.94
5
1
2.01
1
328.15
5
1
869.68
5
1
2.01
1
333.15
5
1
865.43
5
1
2.01
1
338.15
5
1
861.16
5
1
2.01
1
343.15
5
1
856.89
5
1
2.01
10
3
1
Principal objective of the work
BDH
TRC
3/6/2017
1
Speed of sound, m/s
Sing-around technique in a fixed-path interferometer
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1348.15
6
1
1.55
1
298.15
5
1
1329
6
1
1.54
1
303.15
5
1
1309.58
6
1
1.54
1
308.15
5
1
1290.3
6
1
1.54
1
313.15
5
1
1271.18
6
1
1.53
1
318.15
5
1
1252.23
6
1
1.53
1
323.15
5
1
1233.46
6
1
1.53
1
328.15
5
1
1214.83
6
1
1.53
1
333.15
5
1
1196.38
6
1
1.52
1
338.15
5
1
1178.08
6
1
1.52
1
343.15
5
1
1159.94
6
1
1.52
11
3
1
Principal objective of the work
BDH
TRC
3/6/2017
1
Viscosity, Pa*s
Falling or rolling sphere viscometry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
0.00131
3
1
0.00014
1
298.15
5
1
0.00119
3
1
0.00014
1
303.15
5
1
0.00109
3
1
0.00014
1
308.15
5
1
0.00101
3
1
0.00014
1
313.15
5
1
0.00093
2
1
0.00014
1
318.15
5
1
0.00087
2
1
0.00014
1
323.15
5
1
0.00081
2
1
0.00014
1
328.15
5
1
0.00076
2
1
0.00014
1
333.15
5
1
0.00071
2
1
0.00014
1
338.15
5
1
0.00067
2
1
0.00014
1
343.15
5
1
0.00063
2
1
0.00014
12
3
1
Principal objective of the work
BDH
TRC
3/6/2017
1
Refractive index (Na D-line)
Standard Abbe refractometry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1.50236
6
1
0.00045
1
298.15
5
1
1.49986
6
1
0.00045
1
303.15
5
1
1.49733
6
1
0.00045
1
308.15
5
1
1.49523
6
1
0.00045
1
313.15
5
1
1.4927
6
1
0.00045
1
318.15
5
1
1.49036
6
1
0.00045
1
323.15
5
1
1.48799
6
1
0.00045
1
328.15
5
1
1.48559
6
1
0.00045
1
333.15
5
1
1.48321
6
1
0.00045
1
338.15
5
1
1.48088
6
1
0.00045
1
343.15
5
1
1.47851
6
1
0.00045
13
4
1
Principal objective of the work
EP
EP
3/17/2017
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
283.15
5
1
1034.3
5
1
6.3
1
288.15
5
1
1030.3
5
1
6.3
1
293.15
5
1
1026.2
5
1
6.3
1
298.15
5
1
1022.2
5
1
6.3
1
303.15
5
1
1018.1
5
1
6.3
1
308.15
5
1
1014.2
5
1
6.3
1
313.15
5
1
1010.2
5
1
6.3
1
318.15
5
1
1006.3
5
1
6.2
1
323.15
5
1
1002.4
5
1
6.2
1
328.15
5
1
998.5
4
1
6.2
1
333.15
5
1
994.6
4
1
6.2
1
338.15
5
1
990.8
4
1
6.2
1
343.15
5
1
986.9
4
1
6.2
1
348.15
5
1
983.1
4
1
6.2
1
353.15
5
1
979.3
4
1
6.2
1
358.15
5
1
975.4
4
1
6.2
1
363.15
5
1
971.6
4
1
6.2
1
368.15
5
1
967.8
4
1
6.2
1
373.15
5
1
964
4
1
6.2
1
378.15
5
1
960.2
4
1
6.2
1
383.15
5
1
956.4
4
1
6.2
1
388.15
5
1
952.6
4
1
6.2
1
393.15
5
1
948.8
4
1
6.2
1
398.15
5
1
945
4
1
6.2
1
403.15
5
1
941.2
4
1
6.2
1
408.15
5
1
937.4
4
1
6.2
1
413.15
5
1
933.6
4
1
6.2
1
418.15
5
1
929.8
4
1
6.2
1
423.15
5
1
926
4
1
6.2
1
428.15
5
1
922.2
4
1
6.2
1
433.15
5
1
918.5
4
1
6.2
1
438.15
5
1
914.6
4
1
6.2
1
443.15
5
1
910.8
4
1
6.2
1
448.15
5
1
907
4
1
6.2
1
293.15
5
1
1026.48
6
1
6.27
1
298.15
5
1
1022.59
6
1
6.27
1
303.15
5
1
1018.7
6
1
6.26
1
308.15
5
1
1014.82
6
1
6.26
1
313.15
5
1
1010.94
6
1
6.25
1
318.15
5
1
1007.07
6
1
6.25
1
323.15
5
1
1003.2
6
1
6.24
1
328.15
5
1
999.34
5
1
6.24
1
333.15
5
1
995.48
5
1
6.24
1
338.15
5
1
991.63
5
1
6.23
1
343.15
5
1
987.79
5
1
6.23
14
4
1
Principal objective of the work
BDH
TRC
3/6/2017
1
Speed of sound, m/s
Sing-around technique in a fixed-path interferometer
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1575.43
6
1
3.24
1
298.15
5
1
1557.24
6
1
3.24
1
303.15
5
1
1538.83
6
1
3.24
1
308.15
5
1
1520.57
6
1
3.24
1
313.15
5
1
1502.43
6
1
3.23
1
318.15
5
1
1484.47
6
1
3.23
1
323.15
5
1
1466.36
6
1
3.23
1
328.15
5
1
1448.75
6
1
3.23
1
333.15
5
1
1431.32
6
1
3.23
1
338.15
5
1
1414.03
6
1
3.23
1
343.15
5
1
1397.25
6
1
3.23
15
4
1
Principal objective of the work
BDH
TRC
3/6/2017
1
Viscosity, Pa*s
Falling or rolling sphere viscometry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
0.0092
3
1
0.00021
1
298.15
5
1
0.0076
3
1
0.00019
1
303.15
5
1
0.00646
3
1
0.00018
1
308.15
5
1
0.00565
3
1
0.00017
1
313.15
5
1
0.00482
3
1
0.00016
1
318.15
5
1
0.00417
3
1
0.00016
1
323.15
5
1
0.00366
3
1
0.00015
1
328.15
5
1
0.00321
3
1
0.00015
1
333.15
5
1
0.00287
3
1
0.00015
1
338.15
5
1
0.00259
3
1
0.00015
1
343.15
5
1
0.00239
3
1
0.00015
16
4
1
Principal objective of the work
BDH
TRC
3/6/2017
1
Refractive index (Na D-line)
Standard Abbe refractometry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1.57402
6
1
0.00072
1
298.15
5
1
1.57173
6
1
0.00072
1
303.15
5
1
1.56948
6
1
0.00072
1
308.15
5
1
1.56723
6
1
0.00072
1
313.15
5
1
1.56505
6
1
0.00072
1
318.15
5
1
1.56287
6
1
0.00072
1
323.15
5
1
1.56075
6
1
0.00072
1
328.15
5
1
1.55865
6
1
0.00072
1
333.15
5
1
1.55656
6
1
0.00072
1
338.15
5
1
1.55446
6
1
0.00072
1
343.15
5
1
1.55234
6
1
0.00072