2
0
2011
jen
rec
0
journal
Original
Jendrzejczyk-Handzlik, D.[Dominika]
Rechchach, M.[Meryem]
Gierlotka, W.[Wojcieh]
Ipser, H.[Herbert]
Flandorfer, H.[Hans]
Thermochim. Acta
2011
2020-09-29
Enthalpies of mixing of liquid systems for lead free soldering: Cu-Sb-Sn system
Using two different types of high temperature drop calorimeters, partial and integral enthalpies of mixing of liquid alloys were determined in the ternary Cu-Sb-Sn system. The system was investigated along four sections at 1100 K. Experimental data were used to find ternary interaction parameters by applying the Redlich-Kister-Muggianu model for substitutional solutions, and a full set of parameters describing the concentration dependence of the enthalpy of mixing was derived. From these, the isoenthalpy curves were constructed for 1100 K . The entire system shows exothermic enthalpy of mixing at the given temperature.
Cu-Sb-Sn system
enthalpy of mixing
10.1016/j.tca.2010.10.010
1-2
512
217-24
1
InChI=1S/Cu
RYGMFSIKBFXOCR-UHFFFAOYSA-N
copper
copper element
Cu
1
Commercial source
1
99.98
4
Stated by supplier
2
InChI=1S/Sn
ATJFFYVFTNAWJD-UHFFFAOYSA-N
tin
Sn
1
Commercial source
1
99.999
5
Stated by supplier
3
InChI=1S/Sb
WATWJIUSRGPENY-UHFFFAOYSA-N
antimony
Sb
1
Commercial source
1
99.9985
6
Stated by supplier
1
2
1
3
1
1
1
Principal objective of the work
DAS
XXX
12/30/2010
1
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
drop calorimetry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
2
Temperature, K
Liquid
1100
2
1
Mole fraction
2
Liquid
2
Mole fraction
3
Liquid
1
0.2489
4
2
0.083
3
1
-4.003
4
1
0.301
1
0.2596
4
2
0.0866
3
1
-3.804
4
1
0.301
1
0.2709
4
2
0.0903
3
1
-3.574
4
1
0.301
1
0.2825
4
2
0.0942
3
1
-3.357
4
1
0.301
1
0.2948
4
2
0.0983
3
1
-3.126
4
1
0.301
1
0.3076
4
2
0.1026
4
1
-2.898
4
1
0.301
1
0.3211
4
2
0.1071
4
1
-2.679
4
1
0.301
1
0.3259
4
2
0.1086
4
1
-3.494
4
1
0.601
1
0.3351
4
2
0.1117
4
1
-2.464
4
1
0.301
1
0.3383
4
2
0.1124
4
1
-2.626
4
1
0.6
1
0.3411
4
2
0.1136
4
1
-3.236
4
1
0.6
1
0.3499
4
2
0.1166
4
1
-2.228
4
1
0.3
1
0.355
4
2
0.1179
4
1
-2.283
4
1
0.6
1
0.3568
4
2
0.1188
4
1
-2.951
4
1
0.6
1
0.3654
4
2
0.1218
4
1
-2.013
4
1
0.3
1
0.372
4
2
0.1236
4
1
-2.087
4
1
0.6
1
0.3735
4
2
0.1244
4
1
-2.709
4
1
0.6
1
0.3817
4
2
0.1273
4
1
-1.796
4
1
0.3
1
0.3901
4
2
0.1296
4
1
-2.012
4
1
0.6
1
0.3916
4
2
0.1304
4
1
-2.5
4
1
0.6
1
0.3993
4
2
0.1331
4
1
-1.591
4
1
0.3
1
0.4095
4
2
0.136
4
1
-1.704
4
1
0.6
1
0.4105
4
2
0.1367
4
1
-2.229
4
1
0.6
1
0.4178
4
2
0.1393
4
1
-1.396
4
1
0.3
1
0.4299
4
2
0.1428
4
1
-1.427
4
1
0.6
1
0.4303
4
2
0.1433
4
1
-1.958
4
1
0.6
1
0.4375
4
2
0.1458
4
1
-1.212
4
1
0.3
1
0.4503
4
2
0.1496
4
1
-1.309
4
1
0.6
1
0.4514
4
2
0.1503
4
1
-1.833
4
1
0.6
1
0.4582
4
2
0.1527
4
1
-1.041
4
1
0.3
1
0.4717
4
2
0.1567
4
1
-1.139
4
1
0.6
1
0.4731
4
2
0.1576
4
1
-1.687
4
1
0.6
1
0.4803
4
2
0.1601
4
1
-0.886
3
1
0.3
1
0.4933
4
2
0.1639
4
1
-0.958
3
1
0.6
1
0.496
4
2
0.1652
4
1
-1.566
4
1
0.6
1
0.5035
4
2
0.1679
4
1
-0.769
3
1
0.3
1
0.5155
4
2
0.1712
4
1
-0.762
3
1
0.6
1
0.5205
4
2
0.1734
4
1
-1.325
4
1
0.6
1
0.5277
4
2
0.1759
4
1
-0.654
3
1
0.3
1
0.539
4
2
0.1791
4
1
-0.643
3
1
0.6
1
0.5454
4
2
0.1817
4
1
-1.2
4
1
0.6
1
0.5533
4
2
0.1845
4
1
-0.579
3
1
0.3
1
0.562
4
2
0.1867
4
1
-0.51
3
1
0.6
1
0.5712
4
2
0.1903
4
1
-1.009
4
1
0.6
1
0.5792
4
2
0.1931
4
1
-0.543
3
1
0.3
1
0.585
4
2
0.1944
4
1
-0.655
3
1
0.6
1
0.5971
4
2
0.1989
4
1
-1.024
4
1
0.6
1
0.6052
4
2
0.2018
4
1
-0.535
3
1
0.3
1
0.6089
4
2
0.2023
4
1
-0.72
3
1
0.6
1
0.6243
4
2
0.2079
4
1
-0.934
3
1
0.6
1
0.6319
4
2
0.2107
4
1
-0.556
3
1
0.3
1
0.6322
4
2
0.21
4
1
-0.681
3
1
0.6
1
0.6512
4
2
0.2169
4
1
-0.94
3
1
0.6
1
0.6553
4
2
0.2177
4
1
-0.771
3
1
0.6
1
0.6588
4
2
0.2196
4
1
-0.608
3
1
0.3
1
0.6772
4
2
0.2256
4
1
-0.961
3
1
0.6
1
0.6789
4
2
0.2255
4
1
-0.835
3
1
0.6
1
0.6878
4
2
0.2293
4
1
-0.714
3
1
0.3
1
0.7026
4
2
0.2334
4
1
-0.936
3
1
0.6
1
0.7029
4
2
0.2341
4
1
-1.064
4
1
0.6
1
0.7182
4
2
0.2394
4
1
-0.863
3
1
0.3
1
0.7261
4
2
0.2419
4
1
-1.018
4
1
0.6
1
0.7264
4
2
0.2413
4
1
-1.01
4
1
0.6
1
0.75
4
2
0.25
4
1
-1.036
4
1
0.3
1
0.7502
4
2
0.2498
4
1
-1.035
4
1
0.6
1
0.7506
4
2
0.2494
4
1
-1.034
4
1
0.6
2
2
1
3
1
1
1
Principal objective of the work
DAS
XXX
12/30/2010
1
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
drop calorimetry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
2
Temperature, K
Liquid
1100
2
1
Mole fraction
1
Liquid
2
Mole fraction
3
Liquid
1
0.2404
4
2
0.2409
4
1
-0.999
3
1
0.3
1
0.2476
4
2
0.2482
4
1
-1.05
4
1
0.3
1
0.2551
4
2
0.2556
4
1
-1.113
4
1
0.3
1
0.2629
4
2
0.2635
4
1
-1.186
4
1
0.3
1
0.2709
4
2
0.2715
4
1
-1.249
4
1
0.3
1
0.2791
4
2
0.2797
4
1
-1.311
4
1
0.3
1
0.2873
4
2
0.288
4
1
-1.412
4
1
0.3
1
0.2901
4
2
0.2892
4
1
-1.462
4
1
0.6
1
0.2959
4
2
0.2965
4
1
-1.461
4
1
0.3
1
0.2963
4
2
0.2955
4
1
-1.527
4
1
0.6
1
0.3043
4
2
0.3035
4
1
-1.592
4
1
0.6
1
0.3048
4
2
0.3055
4
1
-1.561
4
1
0.3
1
0.3127
4
2
0.3119
4
1
-1.527
4
1
0.6
1
0.3141
4
2
0.3148
4
1
-1.637
4
1
0.3
1
0.3212
4
2
0.3203
4
1
-1.598
4
1
0.6
1
0.3237
4
2
0.3244
4
1
-1.722
4
1
0.3
1
0.3289
4
2
0.3279
4
1
-1.648
4
1
0.6
1
0.3335
4
2
0.3342
4
1
-1.803
4
1
0.3
1
0.3386
4
2
0.3376
4
1
-1.795
4
1
0.6
1
0.3437
4
2
0.3444
4
1
-1.91
4
1
0.3
1
0.3486
4
2
0.3476
4
1
-1.937
4
1
0.6
1
0.3591
4
2
0.358
4
1
-2.09
4
1
0.6
1
0.3651
4
2
0.3659
4
1
-2.028
4
1
0.3
1
0.3714
4
2
0.3703
4
1
-2.239
4
1
0.6
1
0.3768
4
2
0.3776
4
1
-2.135
4
1
0.3
1
0.3821
4
2
0.381
4
1
-2.239
4
1
0.6
1
0.3887
4
2
0.3896
4
1
-2.234
4
1
0.3
1
0.3948
4
2
0.3937
4
1
-2.243
4
1
0.6
1
0.4007
4
2
0.4016
4
1
-2.344
4
1
0.3
1
0.4086
4
2
0.4074
4
1
-2.403
4
1
0.6
1
0.4131
4
2
0.414
4
1
-2.437
4
1
0.301
1
0.421
4
2
0.4198
4
1
-2.441
4
1
0.6
1
0.4259
4
2
0.4268
4
1
-2.518
4
1
0.301
1
0.4371
4
2
0.4359
4
1
-2.605
4
1
0.6
1
0.4387
4
2
0.4396
4
1
-2.597
4
1
0.301
1
0.4505
4
2
0.4492
4
1
-2.617
4
1
0.6
1
0.4508
4
2
0.4518
4
1
-2.68
4
1
0.301
1
0.4629
4
2
0.4639
4
1
-2.714
4
1
0.301
1
0.4649
4
2
0.4636
4
1
-2.708
4
1
0.6
1
0.4749
4
2
0.4759
4
1
-2.78
4
1
0.301
1
0.4801
4
2
0.4787
4
1
-2.763
4
1
0.6
1
0.4872
4
2
0.4882
4
1
-2.849
4
1
0.301
1
0.4911
4
2
0.4897
4
1
-2.904
4
1
0.6
1
0.4995
4
2
0.5005
4
1
-2.974
4
1
0.301
1
0.5007
4
2
0.4993
4
1
-2.993
4
1
0.6
3
2
1
3
1
1
1
Principal objective of the work
DAS
XXX
12/30/2010
1
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
drop calorimetry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
2
Temperature, K
Liquid
1100
2
1
Mole fraction
1
Liquid
2
Mole fraction
2
Liquid
1
0.1262
4
2
0.2574
4
1
-1.759
4
1
0.6
1
0.1303
4
2
0.2657
4
1
-1.772
4
1
0.6
1
0.1326
4
2
0.2695
4
1
-2.035
4
1
0.6
1
0.1344
4
2
0.2742
4
1
-1.789
4
1
0.6
1
0.1373
4
2
0.279
4
1
-2.058
4
1
0.6
1
0.1388
4
2
0.2832
4
1
-1.813
4
1
0.6
1
0.1423
4
2
0.2892
4
1
-2.09
4
1
0.6
1
0.1435
4
2
0.2927
4
1
-1.838
4
1
0.6
1
0.1474
4
2
0.2995
4
1
-2.093
4
1
0.6
1
0.1484
4
2
0.3026
4
1
-1.861
4
1
0.6
1
0.1527
4
2
0.3104
4
1
-2.036
4
1
0.6
1
0.1535
4
2
0.3131
4
1
-1.886
4
1
0.6
1
0.1585
4
2
0.3221
4
1
-2.075
4
1
0.6
1
0.1589
4
2
0.3242
4
1
-1.922
4
1
0.6
1
0.1645
4
2
0.3356
4
1
-1.93
4
1
0.6
1
0.1646
4
2
0.3345
4
1
-2.128
4
1
0.6
1
0.1706
4
2
0.3479
4
1
-1.954
4
1
0.6
1
0.1712
4
2
0.3478
4
1
-2.172
4
1
0.6
1
0.177
4
2
0.3611
4
1
-1.97
4
1
0.6
1
0.1775
4
2
0.3607
4
1
-2.035
4
1
0.6
1
0.184
4
2
0.3753
4
1
-1.966
4
1
0.6
1
0.1843
4
2
0.3745
4
1
-2.117
4
1
0.6
1
0.1911
4
2
0.3899
4
1
-1.969
4
1
0.6
1
0.1915
4
2
0.3891
4
1
-2.037
4
1
0.6
1
0.1988
4
2
0.4056
4
1
-1.965
4
1
0.6
1
0.199
4
2
0.4044
4
1
-2
4
1
0.6
1
0.2069
4
2
0.4204
4
1
-1.996
4
1
0.6
1
0.2072
4
2
0.4226
4
1
-1.948
4
1
0.6
1
0.2153
4
2
0.4375
4
1
-1.983
4
1
0.6
1
0.2159
4
2
0.4405
4
1
-1.907
4
1
0.6
1
0.2244
4
2
0.456
4
1
-1.952
4
1
0.6
1
0.2247
4
2
0.4585
4
1
-1.868
4
1
0.6
1
0.2338
4
2
0.4768
4
1
-1.806
4
1
0.6
1
0.234
4
2
0.4756
4
1
-1.914
4
1
0.6
1
0.2434
4
2
0.4965
4
1
-1.74
4
1
0.6
1
0.2445
4
2
0.4968
4
1
-1.741
4
1
0.6
1
0.2538
4
2
0.5178
4
1
-1.634
4
1
0.6
1
0.2553
4
2
0.5187
4
1
-1.675
4
1
0.6
1
0.2646
4
2
0.5397
4
1
-1.522
4
1
0.6
1
0.267
4
2
0.5425
4
1
-1.574
4
1
0.6
1
0.2765
4
2
0.5641
4
1
-1.396
4
1
0.6
1
0.2787
4
2
0.5664
4
1
-1.439
4
1
0.6
1
0.2894
4
2
0.5903
4
1
-1.243
4
1
0.6
1
0.2909
4
2
0.5912
4
1
-1.286
4
1
0.6
1
0.3034
4
2
0.6189
4
1
-1.087
4
1
0.6
1
0.3035
4
2
0.6167
4
1
-1.138
4
1
0.6
1
0.3163
4
2
0.6452
4
1
-0.938
3
1
0.6
1
0.3164
4
2
0.6429
4
1
-0.966
3
1
0.6
1
0.329
4
2
0.671
4
1
-0.786
3
1
0.6
1
0.3298
4
2
0.6702
4
1
-0.792
3
1
0.6
4
2
1
3
1
1
1
Principal objective of the work
DAS
XXX
12/30/2010
1
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
drop calorimetry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
2
Temperature, K
Liquid
1100
2
1
Mole fraction
1
Liquid
2
Mole fraction
2
Liquid
1
0.2627
4
2
0.1292
4
1
-1.981
4
1
0.6
1
0.2677
4
2
0.1312
4
1
-1.96
4
1
0.6
1
0.2707
4
2
0.1331
4
1
-2.036
4
1
0.6
1
0.2762
4
2
0.1354
4
1
-2.012
4
1
0.6
1
0.2791
4
2
0.1373
4
1
-2.102
4
1
0.6
1
0.2851
4
2
0.1398
4
1
-2.081
4
1
0.6
1
0.2881
4
2
0.1416
4
1
-2.202
4
1
0.6
1
0.2946
4
2
0.1444
4
1
-2.182
4
1
0.6
1
0.2975
4
2
0.1463
4
1
-2.258
4
1
0.6
1
0.3047
4
2
0.1493
4
1
-2.26
4
1
0.6
1
0.3073
4
2
0.1511
4
1
-2.322
4
1
0.6
1
0.3154
4
2
0.1546
4
1
-2.335
4
1
0.6
1
0.3176
4
2
0.1562
4
1
-2.359
4
1
0.6
1
0.3265
4
2
0.16
4
1
-2.389
4
1
0.6
1
0.3286
4
2
0.1616
4
1
-2.376
4
1
0.6
1
0.3384
4
2
0.1659
4
1
-2.442
4
1
0.6
1
0.3403
4
2
0.1673
4
1
-2.461
4
1
0.6
1
0.3507
4
2
0.1719
4
1
-2.531
4
1
0.6
1
0.3528
4
2
0.1735
4
1
-2.555
4
1
0.6
1
0.3639
4
2
0.1784
4
1
-2.609
4
1
0.6
1
0.3659
4
2
0.1799
4
1
-2.527
4
1
0.6
1
0.3782
4
2
0.1854
4
1
-2.718
4
1
0.6
1
0.3798
4
2
0.1868
4
1
-2.613
4
1
0.6
1
0.3926
4
2
0.1924
4
1
-2.813
4
1
0.6
1
0.3938
4
2
0.1937
4
1
-2.782
4
1
0.6
1
0.408
4
2
0.2
4
1
-2.921
4
1
0.6
1
0.4086
4
2
0.2009
4
1
-2.77
4
1
0.6
1
0.4245
4
2
0.2081
4
1
-3.035
4
1
0.6
1
0.4245
4
2
0.2088
4
1
-2.89
4
1
0.6
1
0.4413
4
2
0.2163
4
1
-3.088
4
1
0.6
1
0.4413
4
2
0.217
4
1
-2.959
4
1
0.6
1
0.459
4
2
0.225
4
1
-3.202
4
1
0.6
1
0.4591
4
2
0.2258
4
1
-3.078
4
1
0.6
1
0.478
4
2
0.235
4
1
-3.15
4
1
0.6
1
0.4781
4
2
0.2344
4
1
-3.327
4
1
0.6
1
0.4982
4
2
0.245
4
1
-3.235
4
1
0.6
1
0.4987
4
2
0.2444
4
1
-3.378
4
1
0.601
1
0.5201
4
2
0.2557
4
1
-3.357
4
1
0.6
1
0.5202
4
2
0.255
4
1
-3.434
4
1
0.601
1
0.5425
4
2
0.2659
4
1
-3.45
4
1
0.601
1
0.5435
4
2
0.2673
4
1
-3.455
4
1
0.601
1
0.5665
4
2
0.2776
4
1
-3.558
4
1
0.601
1
0.5684
4
2
0.2795
4
1
-3.551
4
1
0.601
1
0.59
4
2
0.2892
4
1
-3.671
4
1
0.601
1
0.5933
4
2
0.2917
4
1
-3.642
4
1
0.601
1
0.6152
4
2
0.3015
4
1
-3.765
4
1
0.601
1
0.6177
4
2
0.3037
4
1
-3.794
4
1
0.601
1
0.6422
4
2
0.3148
4
1
-3.911
4
1
0.601
1
0.6439
4
2
0.3167
4
1
-3.945
4
1
0.601
1
0.6704
4
2
0.3296
4
1
-4.188
4
1
0.601
1
0.6711
4
2
0.3289
4
1
-4.193
4
1
0.601