2
0
2010
jan
yad
1
journal
Original
Jangra, S. K.[Sunil K]
Yadav, J. S.[Jaibir S.]
Neeti
Dimple
Sharma, V. K.[Vinod Kumar]
Thermochim. Acta
2010
2020-09-29
Thermodynamic properties of liquid mixtures containing 1,3-dioxolane and anilines: Excess molar volumes, excess molar enthalpies, excess Gibb's free energy and isentropic compressibilities changes of mixing
Excess molar volumes VE, excess molar enthalpies HE, speeds of sound , u and vapour-liquid equilibrium data of 1,3-dioxolane (i) + aniline or N-methyl aniline or o-toluidine (j) binary mixtures have been measured as a function of composition at 308.15K. Speeds of sound and vapour-liquid equilibrium data of (i+j) binary mixtures have been utilized to determine isentropic compressibilities changes of mixing, esE and excess Gibb's free energy GE. The observed data have been analyzed in term of Graph theory which involves the topology of the mixture constituents. It has been observed VE, HE,esE and GE values predicted by Graph theory compare well with their corresponding experimental values.
Excess molar enthalpies, HE, Excess Gibb's free energy, GE , Excess molar volumes VE,
isentropic compressibilities changes of mixing,esE , interaction parameter,/, connectivity parameter of
third degree 3i
10.1016/j.tca.2010.07.027
1-2
511
74-81
1
InChI=1S/C3H6O2/c1-2-5-3-4-1/h1-3H2
WNXJIVFYUVYPPR-UHFFFAOYSA-N
1,3-dioxolane
1,3-dioxacyclopentane
1,3-dioxolan
dihydro-1,3-dioxole
ethylene glycol methylene ether
formaldehyde ethylene acetal
C3H6O2
1
Commercial source
1
99
2
Stated by supplier
2
Purification method described elsewhere
2
InChI=1S/C7H9N/c1-8-7-5-3-2-4-6-7/h2-6,8H,1H3
AFBPFSWMIHJQDM-UHFFFAOYSA-N
N-methylaniline
(methylamino)benzene
N-methylbenzenamine
N-methylphenylamine
N-phenylmethylamine
aniline, N-methyl-
anilinomethane
benzenamine, N-methyl-
methylaniline
phenylmethylamine
C7H9N
1
Commercial source
1
98
2
Stated by supplier
2
Purification method described elsewhere
3
InChI=1S/C7H9N/c1-6-4-2-3-5-7(6)8/h2-5H,8H2,1H3
RNVCVTLRINQCPJ-UHFFFAOYSA-N
2-methylaniline
(2-methylphenyl)amine
1-amino-2-methylbenzene
2-amino-1-methylbenzene
2-aminotoluene
2-methyl-1-aminobenzene
2-methylbenzenamine
2-methylphenylamine
2-toluidine
o-toluidine
ortho-aminotoluene
ortho-methylaniline
ortho-methylbenzenamine
ortho-toluidine
ortho-tolylamine
C7H9N
1
Commercial source
1
99
2
Stated by supplier
2
Purification method described elsewhere
4
InChI=1S/C6H7N/c7-6-4-2-1-3-5-6/h1-5H,7H2
PAYRUJLWNCNPSJ-UHFFFAOYSA-N
aniline
aminobenzene
benzeneamine
phenylamine
C6H7N
1
Commercial source
1
99
2
Stated by supplier
2
Purification method described elsewhere
1
1
1
Principal objective of the work
RDC
XXX
3/13/2014
1
Mass density, kg/m3
Pycnometric method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.325
6
1
1047.2
5
1
1.1
2
1
1
Principal objective of the work
RDC
XXX
3/13/2014
1
Vapor or sublimation pressure, kPa
Closed cell (Static) method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Temperature, K
Liquid
1
308.15
5
1
21.5049
4
1
1.067
3
1
1
Principal objective of the work
RDC
XXX
3/13/2014
1
Speed of sound, m/s
Linear variable-path acoustic interferometer
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.325
6
1
1388
4
1
3
4
2
1
Principal objective of the work
RDC
XXX
3/13/2014
1
Mass density, kg/m3
Pycnometric method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.325
6
1
982.4
4
1
1.6
5
2
1
Principal objective of the work
RDC
XXX
3/13/2014
1
Vapor or sublimation pressure, kPa
Closed cell (Static) method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Temperature, K
Liquid
1
308.15
5
1
0.0667
1
1
0.133
6
2
1
Principal objective of the work
RDC
XXX
3/13/2014
1
Speed of sound, m/s
Linear variable-path acoustic interferometer
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.325
6
1
1572
4
1
3
7
3
1
Principal objective of the work
RDC
XXX
3/13/2014
1
Mass density, kg/m3
Pycnometric method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.325
6
1
994.2
4
1
1
8
3
1
Principal objective of the work
RDC
XXX
3/13/2014
1
Vapor or sublimation pressure, kPa
Closed cell (Static) method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Temperature, K
Liquid
1
308.15
5
1
0.1067
1
1
0.133
9
3
1
Principal objective of the work
RDC
XXX
3/13/2014
1
Speed of sound, m/s
Linear variable-path acoustic interferometer
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.325
6
1
1602
4
1
3
10
4
1
Principal objective of the work
RDC
XXX
3/13/2014
1
Mass density, kg/m3
Pycnometric method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.325
6
1
1017.2
5
1
1
11
4
1
Principal objective of the work
RDC
XXX
3/13/2014
1
Vapor or sublimation pressure, kPa
Closed cell (Static) method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Temperature, K
Liquid
1
298.15
5
1
0.0933
1
1
0.08
12
4
1
Principal objective of the work
RDC
XXX
3/13/2014
1
Speed of sound, m/s
Linear variable-path acoustic interferometer
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.325
6
1
1635
4
1
3
13
4
1
1
1
Principal objective of the work
RDC
TRC
11/12/2010
1
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
2-drop calorimeter
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Temperature, K
Liquid
308.15
5
1
Mole fraction
1
Liquid
1
0.0613
3
1
-0.1616
4
1
0.0037
1
0.1622
4
1
-0.4135
4
1
0.009
1
0.2241
4
1
-0.5476
4
1
0.0119
1
0.2774
4
1
-0.6508
4
1
0.0141
1
0.3503
4
1
-0.7685
4
1
0.0166
1
0.4231
4
1
-0.8484
4
1
0.0182
1
0.5511
4
1
-0.9003
4
1
0.0193
1
0.5812
4
1
-0.8962
4
1
0.0193
1
0.6223
4
1
-0.8733
4
1
0.0188
1
0.6816
4
1
-0.8171
4
1
0.0176
1
0.7519
4
1
-0.7151
4
1
0.0154
1
0.8127
4
1
-0.5867
4
1
0.0127
1
0.8928
4
1
-0.3713
4
1
0.0082
1
0.9514
4
1
-0.1822
4
1
0.0042
14
4
1
1
1
Principal objective of the work
RDC
XXX
3/13/2014
1
Vapor or sublimation pressure, kPa
MANOM:UFactor:8
Gas
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Gas
Liquid
1
Temperature, K
Liquid
308.15
5
1
Mole fraction
4
Liquid
1
0
2
1
21.5049
4
1
1.0266
1
0.1324
4
1
17.3719
4
1
0.9466
1
0.2421
4
1
14.5188
4
1
0.8933
1
0.3453
4
1
11.2657
3
1
0.8266
1
0.4443
4
1
8.7193
3
1
0.7866
1
0.5216
4
1
7.2261
3
1
0.7599
1
0.6211
4
1
5.3062
3
1
0.7199
1
0.7435
4
1
3.3597
3
1
0.6799
1
0.8435
4
1
1.6265
3
1
0.6533
1
0.9041
4
1
0.9333
2
1
0.6399
1
1
5
1
0.12
1
1
0.6266
15
4
1
1
1
Principal objective of the work
RDC
XXX
3/13/2014
1
Speed of sound, m/s
Linear variable-path acoustic interferometer
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Temperature, K
Liquid
308.15
5
2
Frequency, MHz
Liquid
2
1
1
Mole fraction
1
Liquid
1
0.0812
3
1
1587
4
1
3
1
0.1413
4
1
1576
4
1
3
1
0.2212
4
1
1557
4
1
3
1
0.2916
4
1
1539
4
1
3
1
0.3488
4
1
1523
4
1
3
1
0.4621
4
1
1489
4
1
3
1
0.5219
4
1
1470
3
1
3
1
0.5928
4
1
1447
4
1
3
1
0.6414
4
1
1431
4
1
3
1
0.7131
4
1
1406
4
1
3
1
0.8001
4
1
1374
4
1
3
1
0.8715
4
1
1347
4
1
3
1
0.9213
4
1
1327
4
1
3
1
0.9711
4
1
1307
4
1
3
16
4
1
1
1
Principal objective of the work
RDC
XXX
3/13/2014
1
Excess molar volume, m3/mol
DIRDIL:UFactor:2
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Temperature, K
Liquid
308.15
5
1
Mole fraction
1
Liquid
1
0.0789
3
1
-1.34e-07
3
1
6e-09
1
0.1132
4
1
-1.88e-07
3
1
6e-09
1
0.2204
4
1
-3.3e-07
3
1
7e-09
1
0.3111
4
1
-4.28e-07
3
1
7e-09
1
0.4281
4
1
-4.97e-07
3
1
7e-09
1
0.4916
4
1
-5.16e-07
3
1
7e-09
1
0.523
4
1
-5.17e-07
3
1
7e-09
1
0.5999
4
1
-4.93e-07
3
1
7e-09
1
0.6342
4
1
-4.77e-07
3
1
7e-09
1
0.7114
4
1
-4.18e-07
3
1
7e-09
1
0.8202
4
1
-2.94e-07
3
1
7e-09
1
0.8913
4
1
-1.9e-07
3
1
6e-09
1
0.9233
4
1
-1.38e-07
3
1
6e-09
1
0.9718
4
1
-5.25e-08
3
1
6.1e-09
17
2
1
1
1
Principal objective of the work
RDC
TRC
11/12/2010
1
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
2-drop calorimeter
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Temperature, K
Liquid
308.15
5
1
Mole fraction
1
Liquid
1
0.0853
3
1
-0.3823
4
1
0.0084
1
0.1423
4
1
-0.5433
4
1
0.0118
1
0.2533
4
1
-0.6782
4
1
0.0146
1
0.3765
4
1
-0.6524
4
1
0.0141
1
0.4531
4
1
-0.5904
4
1
0.0128
1
0.5123
4
1
-0.5316
4
1
0.0115
1
0.5976
4
1
-0.4402
4
1
0.0096
1
0.6432
4
1
-0.3877
4
1
0.0085
1
0.7123
4
1
-0.3134
4
1
0.0069
1
0.7943
4
1
-0.2348
4
1
0.0053
1
0.8543
4
1
-0.1713
4
1
0.0039
1
0.8912
4
1
-0.1345
4
1
0.0032
1
0.9321
4
1
-0.0932
3
1
0.0023
1
0.9721
4
1
-0.0374
3
1
0.0013
18
2
1
1
1
Principal objective of the work
RDC
XXX
3/13/2014
1
Vapor or sublimation pressure, kPa
CCELL:UFactor:16
Gas
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Gas
Liquid
1
Temperature, K
Liquid
308.15
5
1
Mole fraction
2
Liquid
1
0
2
1
21.5049
4
1
1.3199
1
0.1123
4
1
17.4386
4
1
1.1199
1
0.2222
4
1
14.9054
4
1
0.9866
1
0.3343
4
1
12.1457
3
1
0.8533
1
0.4543
4
1
8.9459
3
1
0.6933
1
0.5256
4
1
7.2261
3
1
0.6
1
0.6543
4
1
4.5863
3
1
0.48
1
0.7543
4
1
2.5598
3
1
0.3733
1
0.8432
4
1
1.1466
2
1
0.32
1
0.9001
4
1
1.0532
2
1
0.8
1
1
5
1
0.0667
1
1
0.0933
19
2
1
1
1
Principal objective of the work
RDC
XXX
3/13/2014
1
Speed of sound, m/s
Linear variable-path acoustic interferometer
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Temperature, K
Liquid
308.15
5
2
Frequency, MHz
Liquid
2
1
1
Mole fraction
1
Liquid
1
0.0415
3
1
1521
4
1
3
1
0.1211
4
1
1511
4
1
3
1
0.2001
4
1
1501
4
1
3
1
0.2754
4
1
1490
3
1
3
1
0.3512
4
1
1477
4
1
3
1
0.4222
4
1
1463
4
1
3
1
0.4943
4
1
1447
4
1
3
1
0.5421
4
1
1436
4
1
3
1
0.6213
4
1
1415
4
1
3
1
0.7003
4
1
1393
4
1
3
1
0.7832
4
1
1367
4
1
3
1
0.8632
4
1
1341
4
1
3
1
0.9011
4
1
1329
4
1
3
1
0.9632
4
1
1307
4
1
3
20
2
1
1
1
Principal objective of the work
RDC
XXX
3/13/2014
1
Excess molar volume, m3/mol
DIRDIL:UFactor:2
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Temperature, K
Liquid
308.15
5
1
Mole fraction
1
Liquid
1
0.0709
3
1
-1.8e-08
2
1
6e-09
1
0.1771
4
1
-4.5e-08
2
1
6e-09
1
0.2387
4
1
-6.3e-08
2
1
6e-09
1
0.2958
4
1
-8e-08
2
1
6e-09
1
0.3349
4
1
-8.8e-08
2
1
6e-09
1
0.3916
4
1
-9.5e-08
2
1
6e-09
1
0.4361
4
1
-1.02e-07
3
1
6e-09
1
0.4912
4
1
-1.1e-07
3
1
6e-09
1
0.5531
4
1
-1.12e-07
3
1
6e-09
1
0.6272
4
1
-1.04e-07
3
1
6e-09
1
0.6992
4
1
-9.3e-08
2
1
6e-09
1
0.7417
4
1
-8.8e-08
2
1
6e-09
1
0.8545
4
1
-5.1e-08
2
1
6e-09
1
0.9213
4
1
-3e-08
2
1
6e-09
21
3
1
1
1
Principal objective of the work
RDC
XXX
3/13/2014
1
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
2-drop calorimeter
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Temperature, K
Liquid
308.15
5
1
Mole fraction
1
Liquid
1
0.0754
3
1
-0.2205
4
1
0.005
1
0.1632
4
1
-0.464
4
1
0.0101
1
0.2424
4
1
-0.6468
4
1
0.014
1
0.3213
4
1
-0.7861
4
1
0.0169
1
0.4001
4
1
-0.8728
4
1
0.0188
1
0.4843
4
1
-0.9061
4
1
0.0195
1
0.5655
4
1
-0.8712
4
1
0.0187
1
0.6112
4
1
-0.8266
4
1
0.0178
1
0.6979
4
1
-0.6962
4
1
0.015
1
0.7432
4
1
-0.6087
4
1
0.0132
1
0.808
4
1
-0.4667
4
1
0.0102
1
0.8831
4
1
-0.2811
4
1
0.0063
1
0.9311
4
1
-0.1633
4
1
0.0038
1
0.9621
4
1
-0.0868
3
1
0.0022
22
3
1
1
1
Principal objective of the work
RDC
XXX
3/13/2014
1
Vapor or sublimation pressure, kPa
MANOM:UFactor:8
Gas
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Gas
Liquid
1
Temperature, K
Liquid
308.15
5
1
Mole fraction
3
Liquid
1
0
2
1
21.5049
4
1
1.0266
1
0.1532
4
1
18.5051
4
1
0.9599
1
0.2432
4
1
15.0121
4
1
0.8933
1
0.3553
4
1
12.159
3
1
0.8399
1
0.4432
4
1
9.8925
3
1
0.7999
1
0.5556
4
1
8.026
3
1
0.7733
1
0.6671
4
1
6.1862
3
1
0.7333
1
0.7432
4
1
4.2663
3
1
0.6933
1
0.8654
4
1
2.2665
3
1
0.6666
1
0.901
4
1
1.0799
2
1
0.6399
1
1
5
1
0.1067
1
1
0.6266
23
3
1
1
1
Principal objective of the work
RDC
XXX
3/13/2014
1
Speed of sound, m/s
Linear variable-path acoustic interferometer
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Temperature, K
Liquid
308.15
5
2
Frequency, MHz
Liquid
2
1
1
Mole fraction
1
Liquid
1
0.1122
4
1
1539
4
1
3
1
0.1891
4
1
1526
4
1
3
1
0.2413
4
1
1516
4
1
3
1
0.2911
4
1
1506
4
1
3
1
0.3212
4
1
1500
2
1
3
1
0.4011
4
1
1484
4
1
3
1
0.4513
4
1
1473
4
1
3
1
0.5651
4
1
1444
4
1
3
1
0.6637
4
1
1415
4
1
3
1
0.6989
4
1
1404
4
1
3
1
0.7512
4
1
1386
4
1
3
1
0.8319
4
1
1358
4
1
3
1
0.9071
4
1
1330
3
1
3
1
0.9713
4
1
1306
4
1
3
24
3
1
1
1
Principal objective of the work
RDC
XXX
3/13/2014
1
Excess molar volume, m3/mol
DIRDIL:UFactor:2
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Gas
1
Temperature, K
Liquid
308.15
5
1
Mole fraction
1
Liquid
1
0.0549
3
1
-8.4e-08
2
1
6e-09
1
0.1721
4
1
-2.51e-07
3
1
7e-09
1
0.2239
4
1
-3.12e-07
3
1
7e-09
1
0.2769
4
1
-3.75e-07
3
1
7e-09
1
0.351
4
1
-4.43e-07
3
1
7e-09
1
0.4217
4
1
-4.86e-07
3
1
7e-09
1
0.5518
4
1
-5.12e-07
3
1
7e-09
1
0.5889
4
1
-5.12e-07
3
1
7e-09
1
0.6218
4
1
-4.97e-07
3
1
7e-09
1
0.6831
4
1
-4.66e-07
3
1
7e-09
1
0.7523
4
1
-4.07e-07
3
1
7e-09
1
0.8147
4
1
-3.28e-07
3
1
7e-09
1
0.8916
4
1
-2.16e-07
3
1
6e-09
1
0.9407
4
1
-1.23e-07
3
1
6e-09