2
0
2008
gar
osw
1
journal
Original
Gardas, R. L.[Ramesh L.]
Oswal, S.[Shantilal]
Thermochim. Acta
2008
2020-09-29
Volumetric and transport properties of ternary mixtures containing 1-propanol, triethylamine or tri-n-butylamine and cyclohexane at 303.15 K: Experimental data, correlation and prediction by ERAS model
The excess molar volumes (View the MathML source), viscosity deviations (??), and excess Gibbs energies of activation (?G*E) of viscous flow have been investigated from densities and viscosities measurements for two ternary mixtures 1-propanol + triethylamine + cyclohexane and 1-propanol + tri-n-butylamine + cyclohexane and corresponding binaries at 303.15 K and atmospheric pressure over the entire range of composition. The empirical equations due to Redlich Kister, Kohler, Rastogi et al., Jacob Fitzner, Tsao Smith, Lark et al., Heric Brewer, and Singh et al., have been employed to correlate View the MathML source, ??, and ?G*E of ternary mixtures with their corresponding binary parameters. The results are discussed in terms of the molecular interaction between the components of the mixture. Further, the Extended Real Associated Solution (ERAS) model has been applied to View the MathML source for the present binary and ternary mixtures and the results are compared with the experimental data.
Excess molar volume
Viscosity
Ternary mixture
Semi-empirical correlating equations
ERAS model
10.1016/j.tca.2008.09.006
1-2
479
17-27
1
InChI=1S/C6H12/c1-2-4-6-5-3-1/h1-6H2
XDTMQSROBMDMFD-UHFFFAOYSA-N
cyclohexane
C6H12
1
Commercial source
1
Fractional distillation
Molecular sieve treatment
Fractional distillation
Molecular sieve treatment
2
99.9
3
Gas chromatography
2
InChI=1S/C3H8O/c1-2-3-4/h4H,2-3H2,1H3
BDERNNFJNOPAEC-UHFFFAOYSA-N
propan-1-ol
1-propanol
n-propanol
n-propyl alcohol
C3H8O
1
Commercial source
1
Chemical reagent treatment
Fractional distillation
Chemical reagent treatment
Fractional distillation
2
99.5
3
Gas chromatography
3
InChI=1S/C6H15N/c1-4-7(5-2)6-3/h4-6H2,1-3H3
ZMANZCXQSJIPKH-UHFFFAOYSA-N
triethylamine
N,N,N-triethylamine
N,N-diethylethanamine
C6H15N
1
Commercial source
1
Chemical reagent treatment
Fractional distillation
Chemical reagent treatment
Fractional distillation
2
99.5
3
Gas chromatography
4
InChI=1S/C12H27N/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3
IMFACGCPASFAPR-UHFFFAOYSA-N
tributylamine
1-butanamine, N,N-dibutyl-
N,N-dibutyl-1-butanamine
tri-n-butylamine
C12H27N
1
Commercial source
1
Chemical reagent treatment
Fractional distillation
Chemical reagent treatment
Fractional distillation
2
99.5
3
Gas chromatography
1
1
1
3
1
Principal objective of the work
NJS
TRC
6/16/2009
1
Viscosity, Pa*s
Capillary tube (Ostwald; Ubbelohde) method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
303.15
5
2
Pressure, kPa
Liquid
101
3
1
Mole fraction
3
Liquid
1
0
2
1
0.000819
3
1
6e-06
1
0.0995
3
1
0.000697
3
1
6e-06
1
0.1947
4
1
0.000614
3
1
6e-06
1
0.291
4
1
0.000548
3
1
5e-06
1
0.3963
4
1
0.000495
3
1
5e-06
1
0.4999
4
1
0.000453
3
1
5e-06
1
0.5961
4
1
0.00042
3
1
5e-06
1
0.6989
4
1
0.000392
3
1
5e-06
1
0.7968
4
1
0.000374
3
1
5e-06
1
0.8973
4
1
0.000348
3
1
5e-06
1
1
5
1
0.00033
3
1
5e-06
2
1
1
3
1
Principal objective of the work
NJS
TRC
6/16/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
2
Temperature, K
Liquid
303.15
5
1
Mole fraction
3
Liquid
1
0
2
1
769.16
5
1
0.12
1
0.0995
3
1
761.78
5
1
0.13
1
0.1947
4
1
755.57
5
1
0.13
1
0.291
4
1
749.84
5
1
0.14
1
0.3963
4
1
744.18
5
1
0.14
1
0.4999
4
1
739.03
5
1
0.14
1
0.5961
4
1
734.6
5
1
0.15
1
0.6989
4
1
730.17
5
1
0.15
1
0.7968
4
1
726.09
5
1
0.16
1
0.8973
4
1
722.21
5
1
0.16
1
1
5
1
718.45
5
1
0.17
3
4
1
1
1
Principal objective of the work
NJS
TRC
6/16/2009
1
Viscosity, Pa*s
Capillary tube (Ostwald; Ubbelohde) method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
303.15
5
2
Pressure, kPa
Liquid
101
3
1
Mole fraction
4
Liquid
1
0
2
1
0.000819
3
1
6e-06
1
0.1023
4
1
0.000848
3
1
6e-06
1
0.2014
4
1
0.000878
3
1
7e-06
1
0.3008
4
1
0.000914
3
1
7e-06
1
0.4016
4
1
0.000947
3
1
7e-06
1
0.5002
4
1
0.000985
3
1
7e-06
1
0.6018
4
1
0.001025
4
1
7e-06
1
0.7021
4
1
0.001058
4
1
7e-06
1
0.8012
4
1
0.001096
4
1
8e-06
1
0.9024
4
1
0.00113
4
1
8e-06
1
1
5
1
0.001167
4
1
8e-06
4
4
1
1
1
Principal objective of the work
NJS
TRC
6/16/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
2
Temperature, K
Liquid
303.15
5
1
Mole fraction
4
Liquid
1
0
2
1
769.16
5
1
0.12
1
0.1023
4
1
768.32
5
1
0.13
1
0.2014
4
1
768.09
5
1
0.13
1
0.3008
4
1
768.17
5
1
0.13
1
0.4016
4
1
768.42
5
1
0.13
1
0.5002
4
1
768.78
5
1
0.13
1
0.6018
4
1
769.15
5
1
0.14
1
0.7021
4
1
769.57
5
1
0.14
1
0.8012
4
1
769.85
5
1
0.14
1
0.9024
4
1
770.12
5
1
0.15
1
1
5
1
770.39
5
1
0.15
5
2
1
1
1
Principal objective of the work
NJS
TRC
6/16/2009
1
Viscosity, Pa*s
Capillary tube (Ostwald; Ubbelohde) method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
303.15
5
2
Pressure, kPa
Liquid
101
3
1
Mole fraction
2
Liquid
1
0
2
1
0.000819
3
1
6e-06
1
0.1021
4
1
0.000832
3
1
6e-06
1
0.2112
4
1
0.000872
3
1
6e-06
1
0.3122
4
1
0.000922
3
1
7e-06
1
0.4211
4
1
0.000986
3
1
7e-06
1
0.5151
4
1
0.001053
4
1
7e-06
1
0.6203
4
1
0.001148
4
1
8e-06
1
0.7208
4
1
0.001264
4
1
8e-06
1
0.8143
4
1
0.001398
4
1
9e-06
1
0.9079
4
1
0.001555
4
1
1e-05
1
1
5
1
0.001727
4
1
1.1e-05
6
2
1
1
1
Principal objective of the work
NJS
TRC
6/16/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
2
Temperature, K
Liquid
303.15
5
1
Mole fraction
2
Liquid
1
0
2
1
769.16
5
1
0.12
1
0.1021
4
1
769.52
5
1
0.12
1
0.2112
4
1
770.68
5
1
0.13
1
0.3122
4
1
772.37
5
1
0.13
1
0.4211
4
1
774.63
5
1
0.13
1
0.5151
4
1
776.9
5
1
0.13
1
0.6203
4
1
779.94
5
1
0.13
1
0.7208
4
1
783.15
5
1
0.14
1
0.8143
4
1
786.73
5
1
0.14
1
0.9079
4
1
790.83
5
1
0.14
1
1
5
1
795.66
5
1
0.14
7
2
1
3
1
Principal objective of the work
NJS
TRC
6/16/2009
1
Viscosity, Pa*s
Capillary tube (Ostwald; Ubbelohde) method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
303.15
5
2
Pressure, kPa
Liquid
101
3
1
Mole fraction
3
Liquid
1
0
2
1
0.001727
4
1
1.1e-05
1
0.2007
4
1
0.001189
4
1
8e-06
1
0.295
4
1
0.001007
4
1
7e-06
1
0.3226
4
1
0.000954
3
1
7e-06
1
0.393
4
1
0.000845
3
1
7e-06
1
0.4852
4
1
0.000719
3
1
6e-06
1
0.6128
4
1
0.000574
3
1
6e-06
1
0.7308
4
1
0.00047
3
1
5e-06
1
0.7637
4
1
0.000444
3
1
5e-06
1
0.8776
4
1
0.000375
3
1
5e-06
1
1
5
1
0.00033
3
1
5e-06
8
2
1
3
1
Principal objective of the work
NJS
TRC
6/16/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
2
Temperature, K
Liquid
303.15
5
1
Mole fraction
3
Liquid
1
0
2
1
795.66
5
1
0.14
1
0.2007
4
1
783.21
5
1
0.15
1
0.295
4
1
775.99
5
1
0.15
1
0.3226
4
1
773.73
5
1
0.15
1
0.393
4
1
767.95
5
1
0.15
1
0.4852
4
1
760.11
5
1
0.16
1
0.6128
4
1
749.28
5
1
0.16
1
0.7308
4
1
739.53
5
1
0.16
1
0.7637
4
1
736.85
5
1
0.16
1
0.8776
4
1
727.89
5
1
0.17
1
1
5
1
718.45
5
1
0.17
9
2
1
4
1
Principal objective of the work
NJS
TRC
6/16/2009
1
Viscosity, Pa*s
Capillary tube (Ostwald; Ubbelohde) method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
303.15
5
2
Pressure, kPa
Liquid
101
3
1
Mole fraction
4
Liquid
1
0
2
1
0.001727
4
1
1.1e-05
1
0.0986
3
1
0.001695
4
1
1.1e-05
1
0.1991
4
1
0.00166
4
1
1.1e-05
1
0.2978
4
1
0.001619
4
1
1e-05
1
0.4984
4
1
0.001514
4
1
1e-05
1
0.5992
4
1
0.001449
4
1
1e-05
1
0.6031
4
1
0.001445
4
1
1e-05
1
0.6981
4
1
0.001378
4
1
9e-06
1
0.7989
4
1
0.001302
4
1
9e-06
1
0.8988
4
1
0.001233
4
1
8e-06
1
1
5
1
0.001167
4
1
8e-06
10
2
1
4
1
Principal objective of the work
NJS
TRC
6/16/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
2
Temperature, K
Liquid
303.15
5
1
Mole fraction
4
Liquid
1
0
2
1
795.66
5
1
0.14
1
0.0986
3
1
791.71
5
1
0.14
1
0.1991
4
1
788.31
5
1
0.15
1
0.2978
4
1
785.47
5
1
0.15
1
0.4984
4
1
780.18
5
1
0.15
1
0.5992
4
1
777.82
5
1
0.15
1
0.6031
4
1
777.75
5
1
0.15
1
0.6981
4
1
775.71
5
1
0.15
1
0.7989
4
1
773.78
5
1
0.15
1
0.8988
4
1
771.94
5
1
0.15
1
1
5
1
770.39
5
1
0.15
11
2
1
4
1
1
1
Principal objective of the work
NJS
TRC
6/16/2009
1
Viscosity, Pa*s
Capillary tube (Ostwald; Ubbelohde) method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
303.15
5
2
Pressure, kPa
Liquid
101
3
1
Mole fraction
2
Liquid
2
Mole fraction
4
Liquid
1
0.0689
3
2
0.7707
4
1
0.001182
4
1
8e-06
1
0.1127
4
2
0.6251
4
1
0.001182
4
1
8e-06
1
0.1146
4
2
0.769
4
1
0.001232
4
1
8e-06
1
0.1696
4
2
0.7529
4
1
0.001282
4
1
9e-06
1
0.1869
4
2
0.378
4
1
0.00111
4
1
8e-06
1
0.1935
4
2
0.6101
4
1
0.001275
4
1
9e-06
1
0.202
4
2
0.3277
4
1
0.001089
4
1
7e-06
1
0.2119
4
2
0.2948
4
1
0.001067
4
1
7e-06
1
0.2335
4
2
0.2228
4
1
0.00103
4
1
7e-06
1
0.2533
4
2
0.157
4
1
0.000982
3
1
7e-06
1
0.2545
4
2
0.4873
4
1
0.001263
4
1
8e-06
1
0.2697
4
2
0.1024
4
1
0.000957
3
1
7e-06
1
0.2904
4
2
0.0337
3
1
0.000927
3
1
7e-06
1
0.2909
4
2
0.5761
4
1
0.001353
4
1
9e-06
1
0.3097
4
2
0.376
4
1
0.001231
4
1
8e-06
1
0.3547
4
2
0.2853
4
1
0.001188
4
1
8e-06
1
0.3741
4
2
0.4549
4
1
0.001368
4
1
9e-06
1
0.3893
4
2
0.2156
4
1
0.001151
4
1
8e-06
1
0.4235
4
2
0.1468
4
1
0.001107
4
1
8e-06
1
0.4395
4
2
0.3595
4
1
0.001351
4
1
9e-06
1
0.4497
4
2
0.094
3
1
0.001085
4
1
7e-06
1
0.4687
4
2
0.0555
3
1
0.001068
4
1
7e-06
1
0.5016
4
2
0.269
4
1
0.00132
4
1
9e-06
1
0.5529
4
2
0.1942
4
1
0.001301
4
1
9e-06
1
0.5898
4
2
0.1406
4
1
0.001275
4
1
8e-06
1
0.6257
4
2
0.0881
3
1
0.001261
4
1
8e-06
1
0.6683
4
2
0.0261
3
1
0.001239
4
1
8e-06
12
2
1
4
1
1
1
Principal objective of the work
NJS
TRC
6/16/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
313.15
5
2
Pressure, kPa
Liquid
101
3
1
Mole fraction
2
Liquid
2
Mole fraction
4
Liquid
1
0.0689
3
2
0.7707
4
1
771.26
5
1
0.14
1
0.1127
4
2
0.6251
4
1
771.97
5
1
0.14
1
0.1146
4
2
0.769
4
1
772.14
5
1
0.15
1
0.1696
4
2
0.7529
4
1
773.17
5
1
0.15
1
0.1869
4
2
0.378
4
1
772.92
5
1
0.13
1
0.1935
4
2
0.6101
4
1
773.63
5
1
0.14
1
0.202
4
2
0.3277
4
1
773.03
5
1
0.13
1
0.2119
4
2
0.2948
4
1
773.08
5
1
0.13
1
0.2335
4
2
0.2228
4
1
773.11
5
1
0.13
1
0.2533
4
2
0.157
4
1
773.09
5
1
0.13
1
0.2545
4
2
0.4873
4
1
774.71
5
1
0.14
1
0.2697
4
2
0.1024
4
1
772.87
5
1
0.13
1
0.2904
4
2
0.0337
3
1
772.44
5
1
0.13
1
0.2909
4
2
0.5761
4
1
775.51
5
1
0.14
1
0.3097
4
2
0.376
4
1
775.53
5
1
0.14
1
0.3547
4
2
0.2853
4
1
775.96
5
1
0.13
1
0.3741
4
2
0.4549
4
1
777.04
5
1
0.14
1
0.3893
4
2
0.2156
4
1
776.27
5
1
0.13
1
0.4235
4
2
0.1468
4
1
776.42
5
1
0.13
1
0.4395
4
2
0.3595
4
1
778.16
5
1
0.14
1
0.4497
4
2
0.094
3
1
776.49
5
1
0.13
1
0.4687
4
2
0.0555
3
1
776.5
5
1
0.13
1
0.5016
4
2
0.269
4
1
779.09
5
1
0.14
1
0.5529
4
2
0.1942
4
1
779.84
5
1
0.14
1
0.5898
4
2
0.1406
4
1
780.37
5
1
0.14
1
0.6257
4
2
0.0881
3
1
780.98
5
1
0.14
1
0.6683
4
2
0.0261
3
1
781.68
5
1
0.13
13
2
1
1
1
3
1
Principal objective of the work
NJS
TRC
6/16/2009
1
Viscosity, Pa*s
Capillary tube (Ostwald; Ubbelohde) method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
303.15
5
2
Pressure, kPa
Liquid
101
3
1
Mole fraction
2
Liquid
2
Mole fraction
3
Liquid
1
0.0414
3
2
0.8628
4
1
0.000363
3
1
5e-06
1
0.0745
3
2
0.8506
4
1
0.00037
3
1
5e-06
1
0.0792
3
2
0.7375
4
1
0.000413
3
1
5e-06
1
0.1063
4
2
0.8477
4
1
0.000381
3
1
5e-06
1
0.1135
4
2
0.6238
4
1
0.000462
3
1
5e-06
1
0.1371
4
2
0.725
4
1
0.000425
3
1
5e-06
1
0.1463
4
2
0.5151
4
1
0.000518
3
1
5e-06
1
0.1775
4
2
0.4183
4
1
0.000574
3
1
5e-06
1
0.198
4
2
0.6029
4
1
0.000492
3
1
5e-06
1
0.2061
4
2
0.3169
4
1
0.00064
3
1
6e-06
1
0.2087
4
2
0.701
4
1
0.000451
3
1
5e-06
1
0.2337
4
2
0.2254
4
1
0.000708
3
1
6e-06
1
0.251
4
2
0.4966
4
1
0.000559
3
1
5e-06
1
0.2563
4
2
0.1505
4
1
0.000778
3
1
6e-06
1
0.2793
4
2
0.0742
3
1
0.000848
3
1
6e-06
1
0.2914
4
2
0.5825
4
1
0.000535
3
1
5e-06
1
0.2982
4
2
0.4019
4
1
0.000631
3
1
6e-06
1
0.3435
4
2
0.3111
4
1
0.000714
3
1
6e-06
1
0.3684
4
2
0.4721
4
1
0.000616
3
1
6e-06
1
0.3917
4
2
0.2144
4
1
0.000801
3
1
6e-06
1
0.4279
4
2
0.1418
4
1
0.000879
3
1
7e-06
1
0.4325
4
2
0.3803
4
1
0.000714
3
1
6e-06
1
0.4716
4
2
0.0542
3
1
0.000981
3
1
7e-06
1
0.492
4
2
0.295
4
1
0.000811
3
1
6e-06
1
0.5586
4
2
0.1996
4
1
0.000928
3
1
7e-06
1
0.6102
4
2
0.1257
4
1
0.001034
4
1
7e-06
1
0.6578
4
2
0.0575
3
1
0.001141
4
1
8e-06
14
2
1
1
1
3
1
Principal objective of the work
NJS
TRC
6/16/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
313.15
5
2
Pressure, kPa
Liquid
101
3
1
Mole fraction
2
Liquid
2
Mole fraction
3
Liquid
1
0.0414
3
2
0.8628
4
1
725.37
5
1
0.16
1
0.0745
3
2
0.8506
4
1
727.21
5
1
0.16
1
0.0792
3
2
0.7375
4
1
732.25
5
1
0.16
1
0.1063
4
2
0.8477
4
1
728.55
5
1
0.16
1
0.1135
4
2
0.6238
4
1
738.9
5
1
0.15
1
0.1371
4
2
0.725
4
1
735.15
5
1
0.16
1
0.1463
4
2
0.5151
4
1
745.48
5
1
0.15
1
0.1775
4
2
0.4183
4
1
751.39
5
1
0.14
1
0.198
4
2
0.6029
4
1
743.12
5
1
0.15
1
0.2061
4
2
0.3169
4
1
757.44
5
1
0.14
1
0.2087
4
2
0.701
4
1
738.79
5
1
0.16
1
0.2337
4
2
0.2254
4
1
762.5
5
1
0.13
1
0.251
4
2
0.4966
4
1
750.09
5
1
0.15
1
0.2563
4
2
0.1505
4
1
766.24
5
1
0.13
1
0.2793
4
2
0.0742
3
1
769.59
5
1
0.13
1
0.2914
4
2
0.5825
4
1
747.18
5
1
0.15
1
0.2982
4
2
0.4019
4
1
756.22
5
1
0.14
1
0.3435
4
2
0.3111
4
1
761.77
5
1
0.14
1
0.3684
4
2
0.4721
4
1
754.93
5
1
0.15
1
0.3917
4
2
0.2144
4
1
767.24
5
1
0.14
1
0.4279
4
2
0.1418
4
1
770.91
5
1
0.13
1
0.4325
4
2
0.3803
4
1
761.11
5
1
0.15
1
0.4716
4
2
0.0542
3
1
774.64
5
1
0.13
1
0.492
4
2
0.295
4
1
766.6
5
1
0.14
1
0.5586
4
2
0.1996
4
1
772.33
5
1
0.14
1
0.6102
4
2
0.1257
4
1
776.37
5
1
0.14
1
0.6578
4
2
0.0575
3
1
779.77
5
1
0.14