2
0
2017
jen
0
journal
Original
Jendrzejczyk-Handzlik, D.[Dominika]
J. Chem. Thermodyn.
2017
2020-09-29
Enthalpies of mixing of liquid Ag-Ga, Au-Ga and Ag-Au-Ga alloys
A literature overview of Ag-Au-Ga system shows that the information about the liquid phase of this system does not exist. Therefore, using MHTC 96 Setaram high temperature drop calorimeter, partial and integral enthalpies of mixing of liquid alloys were determined at first in the binary systems Ag-Ga, Au- Ga and finally in ternary Ag-Au-Ga system. Next, the ternary alloys were investigated along two sections at two temperatures: 1223 K and 1323 K. Experimental results were used to find ternary interaction parameters by applying the Redlich Kister Muggianu model for substitutional solutions, and consequently a full set of parameters describing the concentration dependence of the enthalpy of mixing was derived. The experimental results indicate that the heat of mixing in this system is temperature independent, at least in the measured temperature range.
Calorimetry
Au-Ga alloys
Ag-Au-Ga alloys
Thermochemistry
Heat of mixing
10.1016/j.jct.2016.12.020
107
114-125
1
InChI=1S/Au
PCHJSUWPFVWCPO-UHFFFAOYSA-N
gold
gold element
Au
1
Commercial source
1
99.9999
6
Stated by supplier
2
InChI=1S/Ag
BQCADISMDOOEFD-UHFFFAOYSA-N
silver
argentum
silver element
Ag
1
Commercial source
1
99.999
5
Stated by supplier
3
InChI=1S/Ga
GYHNNYVSQQEPJS-UHFFFAOYSA-N
gallium
Ga
1
Commercial source
1
99.99
4
Stated by supplier
1
3
1
1
1
Principal objective of the work
AB
TRC
8/17/2017
1
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
Calvet calorimetry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
100
1
1
Temperature, K
Liquid
2
Mole fraction
1
Liquid
1
1223
4
2
0.03042
4
1
-1.258
4
1
0.011
1
1223
4
2
0.0642
4
1
-2.624
4
1
0.021
1
1223
4
2
0.09685
4
1
-4.072
4
1
0.032
1
1223
4
2
0.12815
5
1
-5.474
4
1
0.043
1
1223
4
2
0.1606
5
1
-6.786
4
1
0.053
1
1223
4
2
0.19154
5
1
-7.979
4
1
0.063
1
1223
4
2
0.22046
5
1
-8.949
4
1
0.07
1
1223
4
2
0.24919
5
1
-9.917
4
1
0.078
1
1223
4
2
0.27624
5
1
-10.831
5
1
0.085
1
1223
4
2
0.30175
5
1
-11.66
4
1
0.091
1
1223
4
2
0.32742
5
1
-12.467
5
1
0.097
1
1223
4
2
0.35157
5
1
-13.193
5
1
0.103
1
1223
4
2
0.37409
5
1
-13.791
5
1
0.108
1
1223
4
2
0.39582
5
1
-14.242
5
1
0.111
1
1223
4
2
0.41638
5
1
-14.68
4
1
0.115
1
1223
4
2
0.43629
5
1
-15.006
5
1
0.122
1
1223
4
2
0.45534
5
1
-15.333
5
1
0.128
1
1223
4
2
0.47365
5
1
-15.62
4
1
0.134
1
1223
4
2
0.48709
5
1
-15.829
5
1
0.138
1
1223
4
2
0.50035
5
1
-15.958
5
1
0.144
1
1223
4
2
0.51386
5
1
-16.008
5
1
0.15
1
1223
4
2
0.52698
5
1
-16.062
5
1
0.157
1
1223
4
2
0.53949
5
1
-16.113
5
1
0.163
1
1223
4
2
0.55153
5
1
-16.159
5
1
0.169
1
1223
4
2
0.56312
5
1
-16.216
5
1
0.175
1
1223
4
2
0.57432
5
1
-16.234
5
1
0.183
1
1223
4
2
0.58496
5
1
-16.235
5
1
0.189
1
1223
4
2
0.59534
5
1
-16.241
5
1
0.196
1
1223
4
2
0.60527
5
1
-16.241
5
1
0.202
1
1223
4
2
0.61469
5
1
-16.214
5
1
0.209
1
1223
4
2
0.62391
5
1
-16.184
5
1
0.217
1
1223
4
2
0.63055
5
1
-16.158
5
1
0.22
1
1223
4
2
0.63702
5
1
-16.116
5
1
0.227
1
1223
4
2
0.64309
5
1
-16.037
5
1
0.232
1
1323
4
2
0.03979
4
1
-1.68
3
1
0.014
1
1323
4
2
0.07894
4
1
-3.295
4
1
0.026
1
1323
4
2
0.11601
5
1
-4.808
4
1
0.038
1
1323
4
2
0.15124
5
1
-6.244
4
1
0.049
1
1323
4
2
0.18433
5
1
-7.508
4
1
0.059
1
1323
4
2
0.2172
5
1
-8.724
4
1
0.068
1
1323
4
2
0.2492
5
1
-9.898
4
1
0.077
1
1323
4
2
0.27847
5
1
-10.861
5
1
0.085
1
1323
4
2
0.30738
5
1
-11.795
5
1
0.092
1
1323
4
2
0.33449
5
1
-12.609
5
1
0.098
1
1323
4
2
0.35968
5
1
-13.303
5
1
0.104
1
1323
4
2
0.38358
5
1
-13.886
5
1
0.108
1
1323
4
2
0.40605
5
1
-14.356
5
1
0.116
1
1323
4
2
0.42833
5
1
-14.771
5
1
0.124
1
1323
4
2
0.44904
5
1
-15.124
5
1
0.132
1
1323
4
2
0.46918
5
1
-15.46
4
1
0.141
1
1323
4
2
0.4882
5
1
-15.7
3
1
0.15
1
1323
4
2
0.49915
5
1
-15.885
5
1
0.155
1
1323
4
2
0.50957
5
1
-16.005
5
1
0.16
1
1323
4
2
0.52028
5
1
-16.104
5
1
0.166
1
1323
4
2
0.53073
5
1
-16.179
5
1
0.172
1
1323
4
2
0.5412
5
1
-16.239
5
1
0.178
1
1323
4
2
0.55145
5
1
-16.263
5
1
0.186
1
1323
4
2
0.56214
5
1
-16.275
5
1
0.194
1
1323
4
2
0.57272
5
1
-16.315
5
1
0.201
1
1323
4
2
0.58291
5
1
-16.301
5
1
0.209
1
1323
4
2
0.59275
5
1
-16.282
5
1
0.217
1
1323
4
2
0.60275
5
1
-16.237
5
1
0.226
1
1323
4
2
0.61293
5
1
-16.186
5
1
0.234
1
1323
4
2
0.62308
5
1
-16.059
5
1
0.244
2
2
1
3
1
Principal objective of the work
AB
TRC
8/17/2017
1
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
Calvet calorimetry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
100
1
1
Temperature, K
Liquid
2
Mole fraction
2
Liquid
1
1223
4
2
0.04915
4
1
0.215
3
1
0.03
1
1223
4
2
0.0956
4
1
0.259
3
1
0.054
1
1223
4
2
0.13833
5
1
0.305
3
1
0.078
1
1223
4
2
0.17924
5
1
0.285
3
1
0.1
1
1223
4
2
0.21778
5
1
0.263
3
1
0.12
1
1223
4
2
0.25522
5
1
0.126
3
1
0.138
1
1223
4
2
0.29055
5
1
-0.009
1
1
0.154
1
1223
4
2
0.32281
5
1
-0.21
2
1
0.168
1
1223
4
2
0.35277
5
1
-0.401
3
1
0.182
1
1223
4
2
0.38094
5
1
-0.585
3
1
0.194
1
1223
4
2
0.40814
5
1
-0.807
3
1
0.206
1
1223
4
2
0.43358
5
1
-1.055
4
1
0.216
1
1223
4
2
0.45717
5
1
-1.288
4
1
0.224
1
1223
4
2
0.47891
5
1
-1.448
4
1
0.234
1
1223
4
2
0.49918
5
1
-1.629
4
1
0.242
1
1223
4
2
0.51888
5
1
-1.872
4
1
0.251
1
1223
4
2
0.53715
5
1
-2.068
4
1
0.257
1
1223
4
2
0.55476
5
1
-2.238
4
1
0.265
1
1223
4
2
0.57119
5
1
-2.403
4
1
0.271
1
1323
4
2
0.05283
4
1
0.223
3
1
0.032
1
1323
4
2
0.10059
5
1
0.415
3
1
0.06
1
1323
4
2
0.14641
5
1
0.469
3
1
0.086
1
1323
4
2
0.18944
5
1
0.449
3
1
0.11
1
1323
4
2
0.22876
5
1
0.409
3
1
0.13
1
1323
4
2
0.26489
5
1
0.354
3
1
0.15
1
1323
4
2
0.29957
5
1
0.217
3
1
0.166
1
1323
4
2
0.33206
5
1
0.025
2
1
0.182
1
1323
4
2
0.36337
5
1
-0.217
3
1
0.196
1
1323
4
2
0.39213
5
1
-0.397
3
1
0.208
1
1323
4
2
0.41888
5
1
-0.602
3
1
0.22
1
1323
4
2
0.44428
5
1
-0.828
3
1
0.232
1
1323
4
2
0.46866
5
1
-0.949
3
1
0.244
1
1323
4
2
0.49638
5
1
-1.147
4
1
0.256
1
1323
4
2
0.51681
5
1
-1.306
4
1
0.264
1
1323
4
2
0.53592
5
1
-1.44
3
1
0.274
1
1323
4
2
0.55584
5
1
-1.613
4
1
0.283
3
2
1
3
1
1
1
Principal objective of the work
AB
TRC
8/17/2017
1
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
Calvet calorimetry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
100
1
1
Temperature, K
Liquid
2
Mole fraction
2
Liquid
3
Mole fraction
1
Liquid
1
1223
4
2
0.50013
5
3
0
6
1
-1.629
4
1
0.243
1
1223
4
2
0.48368
5
3
0.03288
4
1
-2.756
4
1
0.25
1
1223
4
2
0.46746
5
3
0.06531
4
1
-3.871
4
1
0.252
1
1223
4
2
0.45204
5
3
0.09615
4
1
-4.933
4
1
0.255
1
1223
4
2
0.4376
5
3
0.12501
5
1
-5.926
4
1
0.258
1
1223
4
2
0.42267
5
3
0.15487
5
1
-6.953
4
1
0.261
1
1223
4
2
0.40864
5
3
0.18292
5
1
-7.875
4
1
0.262
1
1223
4
2
0.39547
5
3
0.20925
5
1
-8.705
4
1
0.266
1
1223
4
2
0.38294
5
3
0.2343
5
1
-9.426
4
1
0.267
1
1223
4
2
0.37067
5
3
0.25885
5
1
-10.097
5
1
0.268
1
1223
4
2
0.35909
5
3
0.282
5
1
-10.624
5
1
0.273
1
1223
4
2
0.34788
5
3
0.30441
5
1
-11.078
5
1
0.279
1
1223
4
2
0.33704
5
3
0.32609
5
1
-11.508
5
1
0.286
1
1223
4
2
0.32661
5
3
0.34694
5
1
-11.86
4
1
0.293
1
1223
4
2
0.31651
5
3
0.36714
5
1
-12.135
5
1
0.301
1
1223
4
2
0.30631
5
3
0.38754
5
1
-12.416
5
1
0.309
1
1223
4
2
0.29633
5
3
0.4075
5
1
-12.668
5
1
0.317
1
1223
4
2
0.28693
5
3
0.42628
5
1
-12.851
5
1
0.326
1
1223
4
2
0.2774
5
3
0.44533
5
1
-12.976
5
1
0.333
1
1223
4
2
0.27253
5
3
0.45508
5
1
-13.049
5
1
0.339
1
1223
4
2
0.26766
5
3
0.46481
5
1
-13.081
5
1
0.343
1
1223
4
2
0.26277
5
3
0.47458
5
1
-13.11
4
1
0.349
1
1223
4
2
0.25765
5
3
0.48483
5
1
-13.088
5
1
0.355
1
1223
4
2
0.25254
5
3
0.49505
5
1
-13.066
5
1
0.36
1
1223
4
2
0.24746
5
3
0.5052
5
1
-12.99
4
1
0.368
1
1223
4
2
0.24254
5
3
0.51503
5
1
-12.922
5
1
0.376
1
1223
4
2
0.23772
5
3
0.52469
5
1
-12.864
5
1
0.381
1
1223
4
2
0.23306
5
3
0.53399
5
1
-12.813
5
1
0.387
1
1223
4
2
0.2285
5
3
0.54312
5
1
-12.759
5
1
0.393
1
1223
4
2
0.2241
5
3
0.55192
5
1
-12.681
5
1
0.399
1
1223
4
2
0.21964
5
3
0.56083
5
1
-12.623
5
1
0.406
1
1223
4
2
0.2151
5
3
0.56992
5
1
-12.562
5
1
0.412
1
1223
4
2
0.21069
5
3
0.57873
5
1
-12.489
5
1
0.418
1
1223
4
2
0.2064
5
3
0.58731
5
1
-12.389
5
1
0.423
1
1223
4
2
0.20195
5
3
0.5962
5
1
-12.317
5
1
0.431
1
1223
4
2
0.19762
5
3
0.60486
5
1
-12.193
5
1
0.437
1
1223
4
2
0.19332
5
3
0.61345
5
1
-12.049
5
1
0.444
1
1223
4
2
0.49994
5
3
0
6
1
-1.629
4
1
0.243
1
1223
4
2
0.48438
5
3
0.03111
4
1
-3.021
4
1
0.25
1
1223
4
2
0.46955
5
3
0.06079
4
1
-4.121
4
1
0.251
1
1223
4
2
0.45533
5
3
0.08922
4
1
-5.131
4
1
0.251
1
1223
4
2
0.43996
5
3
0.11997
5
1
-6.221
4
1
0.252
1
1223
4
2
0.42546
5
3
0.14898
5
1
-7.213
4
1
0.255
1
1223
4
2
0.41158
5
3
0.17673
5
1
-8.15
3
1
0.257
1
1223
4
2
0.39819
5
3
0.20352
5
1
-8.968
4
1
0.262
1
1223
4
2
0.38556
5
3
0.22878
5
1
-9.673
4
1
0.267
1
1223
4
2
0.3733
5
3
0.25331
5
1
-10.283
5
1
0.274
1
1223
4
2
0.36149
5
3
0.27692
5
1
-10.842
5
1
0.281
1
1223
4
2
0.34962
5
3
0.30068
5
1
-11.327
5
1
0.288
1
1223
4
2
0.33829
5
3
0.32333
5
1
-11.768
5
1
0.296
1
1223
4
2
0.32693
5
3
0.34605
5
1
-12.143
5
1
0.307
1
1223
4
2
0.31631
5
3
0.3673
5
1
-12.457
5
1
0.315
1
1223
4
2
0.306
5
3
0.38792
5
1
-12.698
5
1
0.327
1
1223
4
2
0.29635
5
3
0.40723
5
1
-12.881
5
1
0.337
1
1223
4
2
0.28724
5
3
0.42544
5
1
-13.055
5
1
0.347
1
1223
4
2
0.27804
5
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