2
0
2017
dru
pim
0
journal
Original
Druzhinina, A. I.
Pimenova, S. M.
Lukyanova, V. A.
J. Chem. Thermodyn.
2017
2020-09-29
Low temperature heat capacity and thermodynamic parameters of phase transitions of 4-nitro-4'-tert-butyl-diphenyl oxide
The low-temperature heat capacity of 4-nitro-40-tert-butyl-diphenyl oxide was measured by vacuum adiabatic calorimetry over the temperature range (7-372) K. The temperature, the enthalpy and the entropy of fusion and the temperature, the jump of the heat capacity, and the range of devitrification of the glasstransition were determined. Heat capacity and main thermodynamic functions (changes of entropy, enthalpy, and Gibbs energy) in condensed state are tabulated as a function of temperature from 5 K to 370 K. The entropy of formation at T = 298.15 K of 4-nitro-40-tert-butyl-diphenyl oxide in the crystal state was computed on the basis of the experimental results obtained.
Adiabatic calorimetry
Heat capacity
Thermodynamic functions
Entropy of formation
4-nitro-4'-tert-butyl-diphenyl oxide
10.1016/j.jct.2016.10.031
105
312-316
1
InChI=1S/C16H17NO3/c1-16(2,3)12-4-8-14(9-5-12)20-15-10-6-13(7-11-15)17(18)19/h4-11H,1-3H3
ZWOYWHYRFBLDEV-UHFFFAOYSA-N
1-(tert-butyl)-4-(4-nitrophenoxy)benzene
1-(1,1-dimethylethyl)-4-(4-nitrophenoxy)benzene
4-nitro-4'-tert-butyldiphenyl ether
4-tert-butylphenyl 4-nitrophenyl ether
C16H17NO3
1
Synthesized by others
1
99.98
4
Gas chromatography
2
99.24
4
Fraction melting in an adiabatic calorimeter
1
1
1
Principal objective of the work
AB
TRC
4/21/2017
1
Triple point temperature, K
Adiabatic calorimetry
Crystal
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Crystal
Liquid
Gas
1
334.8
5
1
0.08
2
1
1
Principal objective of the work
AB
TRC
4/21/2017
1
Triple point temperature, K
Adiabatic calorimetry
Glass
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Glass
Liquid
Gas
1
233.8
4
1
0.2
3
1
1
Principal objective of the work
AB
TRC
4/21/2017
1
Molar enthalpy of transition or fusion, kJ/mol
Adiabatic calorimetry
Crystal
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Crystal
Liquid
Gas
1
20.09
4
1
0.17
4
1
1
Principal objective of the work
AB
TRC
4/21/2017
1
Molar heat capacity at constant pressure, J/K/mol
Small (less than 1 g) adiabatic calorimetry
Crystal
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Crystal
1
Pressure, kPa
Crystal
101.325
6
1
Temperature, K
Crystal
1
7.47
3
1
4.0990286814
3
1
0.1829181156
1
7.73
3
1
4.3567769352
3
1
0.1912325754
1
7.99
3
1
4.8057577644
3
1
0.207861495
1
8.25
3
1
4.9304746614
3
1
0.2161759548
1
8.5
3
1
5.3794554906
3
1
0.2328048744
1
8.76
3
1
5.6787760434
3
1
0.249433794
1
9
3
1
6.111127953
3
1
0.2660627136
1
9.25
3
1
6.5434798626
3
1
0.2826916332
1
9.5
3
1
6.7180835184
3
1
0.291006093
1
9.74
3
1
6.9342594732
3
1
0.2993205528
1
9.98
3
1
7.6160451768
3
1
0.3242639322
1
10.29
4
1
7.940309109
3
1
0.3408928518
1
10.67
4
1
8.647038192
4
1
0.374150691
1
11.05
4
1
9.2373648378
4
1
0.3907796106
1
11.43
4
1
9.9025216218
4
1
0.4240374498
1
11.82
4
1
10.7173386822
4
1
0.457295289
1
12.19
4
1
11.5487846622
4
1
0.4905531282
1
12.56
4
1
12.1474257678
4
1
0.5154965076
1
12.94
4
1
12.7044945744
4
1
0.5321254272
1
13.31
4
1
13.5691983936
4
1
0.5653832664
1
13.67
4
1
14.3258142354
4
1
0.5986411056
1
14.04
4
1
15.2071469742
4
1
0.6402134046
1
14.41
4
1
15.4898386074
4
1
0.6485278644
1
14.78
4
1
16.587347301
4
1
0.6901001634
1
15.14
4
1
17.377220982
4
1
0.7233580026
1
15.51
4
1
17.7347427534
4
1
0.7399869222
1
15.87
4
1
18.6160754922
4
1
0.7732447614
1
16.23
4
1
19.2978611958
4
1
0.7981881408
1
16.59
4
1
20.0129047386
4
1
0.83144598
1
16.95
4
1
20.5866024648
4
1
0.8563893594
1
17.31
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1
21.2185014096
4
1
0.8813327388
1
17.67
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1
21.9584883318
4
1
0.9062761182
1
18.02
4
1
23.1723994626
4
1
0.956162877
1
18.38
4
1
23.4717200154
4
1
0.9644773368
1
18.74
4
1
23.9207008446
4
1
0.9894207162
1
19.09
4
1
24.860234802
4
1
1.0226785554
1
19.44
4
1
25.525391586
4
1
1.0476219348
1
19.8
4
1
26.1406616112
4
1
1.0725653142
1
20.15
4
1
27.1633401666
4
1
0.457295289
1
20.82
4
1
28.3356789984
4
1
0.4739242086
1
21.6
4
1
29.765766084
4
1
0.4905531282
1
22.37
4
1
31.3205700666
4
1
0.5154965076
1
23.15
4
1
32.6841414738
4
1
0.5321254272
1
23.93
4
1
34.1973731574
4
1
0.5570688066
1
24.7
4
1
35.7854349792
4
1
0.5736977262
1
25.47
4
1
37.6146161352
4
1
0.5986411056
1
26.25
4
1
38.454376575
4
1
0.6069555654
1
27.02
4
1
40.2170420526
4
1
0.6318989448
1
27.78
4
1
41.322865206
4
1
0.6402134046
1
28.55
4
1
43.0439583846
4
1
0.665156784
1
29.31
4
1
44.4158442516
4
1
0.6817857036
1
30.07
4
1
45.7627867392
4
1
0.6901001634
1
30.84
4
1
47.5753389756
4
1
0.7150435428
1
31.6
4
1
48.7476778074
4
1
0.7233580026
1
32.37
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1
49.720469604
4
1
0.7399869222
1
33.14
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1
51.0840410112
4
1
0.7649303016
1
33.9
4
1
52.672102833
4
1
0.7815592212
1
34.66
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1
54.0523031598
4
1
0.8065026006
1
35.42
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1
55.2994721298
4
1
0.8231315202
1
36.18
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1
57.1120243662
4
1
0.8480748996
1
36.94
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1
57.8520112884
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1
0.8563893594
1
37.7
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1
58.9744633614
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1
0.873018279
1
38.45
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1
60.5957830224
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1
0.8979616584
1
39.21
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1
61.485430221
4
1
0.9062761182
1
39.97
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1
62.8822594674
4
1
0.9312194976
1
40.73
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1
64.3871766912
4
1
0.5986411056
1
41.49
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1
65.8172637768
4
1
0.6069555654
1
42.25
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1
66.474106101
4
1
0.6152700252
1
43.01
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1
68.17857036
4
1
0.6318989448
1
43.76
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1
69.2095633752
4
1
0.6402134046
1
44.52
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1
70.631336001
4
1
0.6568423242
1
45.29
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1
71.9117628102
4
1
0.665156784
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46.05
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1
72.6351208128
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1
0.665156784
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1
0.6817857036
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47.56
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1
0.6901001634
1
48.32
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1
0.6984146232
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0.706729083
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49.84
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1
77.5240231752
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1
0.7150435428
1
50.59
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1
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1
0.7233580026
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52.11
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0.7316724624
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52.86
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0.997735176
1
143.53
5
1
182.834971002
4
1
0.997735176
1
144.33
5
1
183.832706178
4
1
0.997735176
1
145.13
5
1
184.747296756
4
1
0.997735176
1
145.93
5
1
185.661887334
4
1
0.997735176
1
146.73
5
1
186.493333314
4
1
0.997735176
1
147.54
5
1
187.324779294
4
1
0.997735176
1
148.34
5
1
188.156225274
4
1
0.997735176
1
149.14
5
1
188.904526656
4
1
0.997735176
1
149.94
5
1
189.819117234
4
1
0.997735176
1
150.74
5
1
190.567418616
4
1
0.997735176
1
151.54
5
1
191.482009194
4
1
0.997735176
1
152.35
5
1
192.313455174
4
1
0.997735176
1
153.15
5
1
193.228045752
4
1
0.997735176
1
153.95
5
1
194.14263633
4
1
1.080879774
1
154.75
5
1
194.807793114
4
1
1.080879774
1
155.55
5
1
195.888672888
4
1
1.080879774
1
156.35
5
1
196.720118868
4
1
1.080879774
1
157.15
5
1
197.46842025
4
1
1.080879774
1
157.95
5
1
198.133577034
4
1
1.080879774
1
158.75
5
1
199.214456808
4
1
1.080879774
1
159.55
5
1
200.212191984
4
1
1.080879774
1
160.35
5
1
201.126782562
4
1
1.080879774
1
161.15
5
1
202.124517738
4
1
1.080879774
1
161.95
5
1
202.706529924
4
1
1.080879774
1
162.75
5
1
203.621120502
4
1
1.080879774
1
163.55
5
1
204.369421884
4
1
1.080879774
1
164.35
5
1
205.616590854
4
1
1.080879774
1
165.15
5
1
206.531181432
4
1
1.080879774
1
165.95
5
1
207.362627412
4
1
1.080879774
1
166.75
5
1
208.110928794
4
1
1.080879774
1
167.55
5
1
209.10866397
4
1
1.080879774
1
168.34
5
1
210.106399146
4
1
1.080879774
1
169.14
5
1
210.438977538
4
1
1.080879774
1
169.94
5
1
211.436712714
4
1
1.164024372
1
170.73
5
1
212.933315478
4
1
1.164024372
1
171.53
5
1
213.099604674
4
1
1.164024372
1
172.33
5
1
214.014195252
4
1
1.164024372
1
173.12
5
1
214.762496634
4
1
1.164024372
1
173.92
5
1
215.677087212
4
1
1.164024372
1
174.72
5
1
216.59167779
4
1
1.164024372
1
175.51
5
1
218.005135956
4
1
1.164024372
1
176.31
5
1
218.337714348
4
1
1.164024372
1
177.11
5
1
219.252304926
4
1
1.164024372
1
177.91
5
1
219.834317112
4
1
1.164024372
1
178.7
5
1
220.3331847
4
1
1.164024372
1
179.5
5
1
221.497209072
4
1
1.164024372
1
180.3
5
1
222.328655052
4
1
1.164024372
1
181.08
5
1
223.575824022
4
1
1.164024372
1
181.88
5
1
224.407270002
4
1
1.164024372
1
182.67
5
1
224.989282188
4
1
1.164024372
1
183.47
5
1
225.820728168
4
1
1.164024372
1
184.26
5
1
226.735318746
4
1
1.164024372
1
185.06
5
1
227.566764726
4
1
1.164024372
1
185.85
5
1
228.481355304
4
1
1.24716897
1
186.65
5
1
229.146512088
4
1
1.24716897
1
187.44
5
1
230.476825656
4
1
1.24716897
1
188.22
5
1
231.308271636
4
1
1.24716897
1
189.02
5
1
232.139717616
4
1
1.24716897
1
189.81
5
1
233.303741988
4
1
1.24716897
1
190.6
5
1
233.968898772
4
1
1.24716897
1
191.39
5
1
234.634055556
4
1
1.24716897
1
192.19
5
1
235.382356938
4
1
1.24716897
1
192.98
5
1
236.296947516
4
1
1.24716897
1
193.75
5
1
236.9621043
4
1
1.24716897
1
194.54
5
1
237.79355028
4
1
1.24716897
1
195.33
5
1
238.541851662
4
1
1.24716897
1
196.12
5
1
239.45644224
4
1
1.24716897
1
196.91
5
1
240.620466612
4
1
1.24716897
1
197.7
5
1
241.285623396
4
1
1.24716897
1
198.49
5
1
242.117069376
4
1
1.24716897
1
199.28
5
1
243.031659954
4
1
1.24716897
1
200.07
5
1
244.02939513
4
1
1.24716897
1
201.06
5
1
245.2765641
4
1
1.330313568
1
202.26
5
1
246.856311462
4
1
1.330313568
1
203.46
5
1
247.937191236
4
1
1.330313568
1
204.66
5
1
249.184360206
4
1
1.330313568
1
205.86
5
1
250.847252166
4
1
1.330313568
1
207.05
5
1
252.260710332
4
1
1.330313568
1
208.26
5
1
253.258445508
4
1
1.330313568
1
209.45
5
1
254.42246988
4
1
1.330313568
1
210.65
5
1
255.66963885
4
1
1.330313568
1
211.85
5
1
256.999952418
4
1
1.330313568
1
213.05
5
1
258.496555182
4
1
1.330313568
1
214.26
5
1
259.910013348
4
1
1.330313568
1
215.46
5
1
261.07403772
4
1
1.330313568
1
216.66
5
1
262.404351288
4
1
1.413458166
1
217.87
5
1
263.651520258
4
1
1.413458166
1
219.07
5
1
265.563846012
4
1
1.413458166
1
220.27
5
1
266.395291992
4
1
1.413458166
1
221.47
5
1
268.058183952
4
1
1.413458166
1
222.68
5
1
269.471642118
4
1
1.413458166
1
223.88
5
1
270.801955686
4
1
1.413458166
1
225.09
5
1
272.132269254
4
1
1.413458166
1
226.29
5
1
273.379438224
4
1
1.413458166
1
227.5
5
1
274.876040988
4
1
1.413458166
1
228.7
5
1
276.372643752
4
1
1.413458166
1
229.91
5
1
277.70295732
4
1
1.413458166
1
231.12
5
1
278.700692496
4
1
1.413458166
1
232.32
5
1
280.031006064
4
1
1.496602764
1
233.53
5
1
281.777042622
4
1
1.496602764
1
234.74
5
1
283.356789984
4
1
1.496602764
1
235.95
5
1
284.687103552
4
1
1.496602764
1
237.15
5
1
286.765718502
4
1
1.496602764
1
238.37
5
1
287.514019884
4
1
1.496602764
1
239.58
5
1
289.093767246
4
1
1.496602764
1
240.79
5
1
290.507225412
4
1
1.496602764
1
242
5
1
291.504960588
4
1
1.496602764
1
243.21
5
1
292.835274156
4
1
1.496602764
1
244.43
5
1
294.581310714
4
1
1.496602764
1
245.64
5
1
295.99476888
4
1
1.496602764
1
246.85
5
1
297.24193785
4
1
1.579747362
1
248.06
5
1
298.572251418
4
1
1.579747362
1
249.28
5
1
300.068854182
4
1
1.579747362
1
250.5
5
1
301.731746142
4
1
1.579747362
1
251.71
5
1
302.729481318
4
1
1.579747362
1
252.92
5
1
304.392373278
4
1
1.579747362
1
254.14
5
1
305.888976042
4
1
1.579747362
1
255.35
5
1
307.718157198
4
1
1.579747362
1
256.57
5
1
309.048470766
4
1
1.579747362
1
257.78
5
1
310.54507353
4
1
1.579747362
1
259
5
1
311.958531696
4
1
1.579747362
1
260.22
5
1
313.45513446
4
1
1.66289196
1
261.44
5
1
315.11802642
4
1
1.66289196
1
262.65
5
1
316.282050792
4
1
1.66289196
1
263.87
5
1
317.61236436
4
1
1.66289196
1
265.09
5
1
319.108967124
4
1
1.66289196
1
266.31
5
1
320.52242529
4
1
1.66289196
1
267.53
5
1
322.933618632
4
1
1.66289196
1
268.76
5
1
323.515630818
4
1
1.66289196
1
269.98
5
1
324.596510592
4
1
1.66289196
1
271.2
5
1
326.675125542
4
1
1.66289196
1
272.42
5
1
327.922294512
4
1
1.66289196
1
273.64
5
1
329.917764864
4
1
1.66289196
1
274.86
5
1
331.081789236
4
1
1.746036558
1
276.09
5
1
332.578392
4
1
1.746036558
1
277.31
5
1
333.991850166
4
1
1.746036558
1
278.53
5
1
335.405308332
4
1
1.746036558
1
279.76
5
1
336.818766498
4
1
1.746036558
1
280.98
5
1
337.98279087
4
1
1.746036558
1
282.21
5
1
338.980526046
4
1
1.746036558
1
283.43
5
1
341.059140996
4
1
1.746036558
1
284.66
5
1
342.55574376
4
1
1.746036558
1
285.89
5
1
344.135491122
4
1
1.746036558
1
287.11
5
1
345.216370896
4
1
1.746036558
1
288.31
5
1
347.045552052
4
1
1.746036558
1
289.54
5
1
348.37586562
4
1
1.829181156
1
290.77
5
1
349.955612982
4
1
1.829181156
1
291.99
5
1
351.202781952
4
1
1.829181156
1
293.22
5
1
353.198252304
4
1
1.829181156
1
294.45
5
1
354.445421274
4
1
1.829181156
1
295.68
5
1
355.942024038
4
1
1.829181156
1
296.91
5
1
357.688060596
4
1
1.829181156
1
298.15
5
1
359.018374164
4
1
1.829181156
1
299.38
5
1
360.348687732
4
1
1.829181156
1
300.82
5
1
363.009314868
4
1
1.829181156
1
302.44
5
1
364.838496024
4
1
1.912325754
1
304.06
5
1
367.748556954
4
1
1.912325754
1
305.69
5
1
370.076605698
4
1
1.912325754
1
307.33
5
1
372.48779904
4
1
1.912325754
1
308.97
5
1
374.649558588
4
1
1.912325754
1
310.62
5
1
377.227041126
4
1
1.912325754
1
312.28
5
1
379.97081286
4
1
1.912325754
1
313.94
5
1
385.624645524
4
1
1.995470352
1
315.6
5
1
386.705525298
4
1
1.995470352
1
317.26
5
1
392.775080952
4
1
1.995470352
1
318.94
5
1
397.181744646
4
1
1.995470352
1
320.63
5
1
403.085011104
4
1
2.07861495
1
322.32
5
1
412.147772286
4
1
2.07861495
1
324.01
5
1
420.794810478
4
1
2.161759548
1
325.71
5
1
441.664104576
4
1
2.328048744
1
327.44
5
1
477.915149304
4
1
2.577482538
5
1
1
Principal objective of the work
AB
TRC
4/21/2017
1
Molar heat capacity at constant pressure, J/K/mol
Small (less than 1 g) adiabatic calorimetry
Metastable liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Metastable liquid
1
Pressure, kPa
Metastable liquid
101.325
6
1
Temperature, K
Metastable liquid
1
340.68
5
1
450.394287366
4
1
2.328048744
1
344.79
5
1
449.978564376
4
1
2.328048744
1
346.59
5
1
452.639191512
4
1
2.328048744
1
348.4
5
1
452.389757718
4
1
2.328048744
1
350.22
5
1
454.884095658
4
1
2.328048744
1
352.05
5
1
456.214409226
4
1
2.328048744
1
353.89
5
1
457.045855206
4
1
2.328048744
1
355.75
5
1
456.962710608
4
1
2.328048744
1
357.6
5
1
459.207614754
4
1
2.328048744
1
359.66
5
1
460.704217518
4
1
2.328048744
1
361.55
5
1
460.20534993
4
1
2.328048744
1
363.45
5
1
461.618808096
4
1
2.328048744
1
365.36
5
1
462.28396488
4
1
2.328048744
1
367.28
5
1
462.865977066
4
1
2.328048744
1
369.21
5
1
463.94685684
4
1
2.328048744
1
371.16
5
1
464.861447418
4
1
2.328048744
1
234.33
5
1
313.122556068
4
1
1.66289196
1
235.47
5
1
327.506571522
4
1
1.995470352
1
236.57
5
1
370.076605698
4
1
2.07861495
1
237.72
5
1
379.13936688
4
1
1.912325754
1
238.92
5
1
380.053957458
4
1
1.912325754
1
240.13
5
1
380.220246654
4
1
1.912325754
1
241.35
5
1
381.301126428
4
1
1.912325754
1
242.56
5
1
382.298861604
4
1
1.995470352
1
243.77
5
1
383.462885976
4
1
1.995470352
1
244.99
5
1
384.211187358
4
1
1.995470352
6
1
1
Principal objective of the work
AB
TRC
4/21/2017
1
Molar heat capacity at constant pressure, J/K/mol
Small (less than 1 g) adiabatic calorimetry
Glass
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Glass
1
Pressure, kPa
Glass
101.325
6
1
Temperature, K
Glass
1
79.87
4
1
115.903569612
4
1
1.080879774
1
80.67
4
1
116.651870994
4
1
0.665156784
1
81.47
4
1
117.400172376
4
1
0.665156784
1
82.27
4
1
118.314762954
4
1
0.665156784
1
83.08
4
1
119.229353532
4
1
0.665156784
1
83.88
4
1
120.060799512
4
1
0.665156784
1
84.68
4
1
120.97539009
4
1
0.665156784
1
85.48
4
1
121.973125266
4
1
0.665156784
1
86.29
4
1
122.887715844
4
1
0.748301382
1
87.09
4
1
123.802306422
4
1
0.748301382
1
87.89
4
1
124.550607804
4
1
0.748301382
1
88.7
4
1
125.631487578
4
1
0.748301382
1
89.5
4
1
126.546078156
4
1
0.748301382
1
90.3
4
1
127.294379538
4
1
0.748301382
1
91.1
4
1
128.375259312
4
1
0.748301382
1
91.91
4
1
129.28984989
4
1
0.748301382
1
92.71
4
1
130.12129587
4
1
0.748301382
1
93.52
4
1
131.119031046
4
1
0.748301382
1
94.32
4
1
132.033621624
4
1
0.748301382
1
95.13
4
1
132.865067604
4
1
0.748301382
1
95.93
4
1
133.696513584
4
1
0.748301382
1
96.73
4
1
134.69424876
4
1
0.748301382
1
97.54
4
1
135.442550142
4
1
0.748301382
1
98.34
4
1
136.440285318
4
1
0.748301382
1
99.14
4
1
137.354875896
4
1
0.748301382
1
99.95
4
1
138.352611072
4
1
0.748301382
1
100.75
5
1
139.433490846
4
1
0.748301382
1
101.55
5
1
140.181792228
4
1
0.748301382
1
102.35
5
1
141.013238208
4
1
0.748301382
1
103.16
5
1
142.010973384
4
1
0.748301382
1
103.96
5
1
142.759274766
4
1
0.83144598
1
104.76
5
1
143.673865344
4
1
0.83144598
1
105.56
5
1
144.67160052
4
1
0.83144598
1
106.36
5
1
145.419901902
4
1
0.83144598
1
107.16
5
1
146.168203284
4
1
0.83144598
1
107.96
5
1
147.249083058
4
1
0.83144598
1
108.77
5
1
148.246818234
4
1
0.83144598
1
109.57
5
1
148.995119616
4
1
0.83144598
1
110.37
5
1
149.826565596
4
1
0.83144598
1
111.17
5
1
150.741156174
4
1
0.83144598
1
111.97
5
1
151.655746752
4
1
0.83144598
1
112.78
5
1
152.736626526
4
1
0.83144598
1
113.58
5
1
153.568072506
4
1
0.83144598
1
114.38
5
1
154.316373888
4
1
0.83144598
1
115.18
5
1
155.230964466
4
1
0.83144598
1
115.99
5
1
156.228699642
4
1
0.83144598
1
116.79
5
1
156.893856426
4
1
0.83144598
1
117.59
5
1
157.808447004
4
1
0.83144598
1
118.4
5
1
158.723037582
4
1
0.83144598
1
119.2
5
1
159.803917356
4
1
0.914590578
1
120
5
1
160.635363336
4
1
0.914590578
1
120.81
5
1
161.466809316
4
1
0.914590578
1
121.61
5
1
162.215110698
4
1
0.914590578
1
122.41
5
1
163.129701276
4
1
0.914590578
1
123.21
5
1
164.21058105
4
1
0.914590578
1
124.02
5
1
164.875737834
4
1
0.914590578
1
124.82
5
1
165.956617608
4
1
0.914590578
1
125.62
5
1
166.538629794
4
1
0.914590578
1
126.42
5
1
167.370075774
4
1
0.914590578
1
127.23
5
1
168.201521754
4
1
0.914590578
1
128.03
5
1
169.19925693
4
1
0.914590578
1
128.83
5
1
170.03070291
4
1
0.914590578
1
129.63
5
1
170.945293488
4
1
0.914590578
1
130.43
5
1
171.943028664
4
1
0.914590578
1
131.24
5
1
172.52504085
4
1
0.914590578
1
132.04
5
1
173.273342232
4
1
0.914590578
1
132.84
5
1
174.354222006
4
1
0.914590578
1
133.64
5
1
175.185667986
4
1
0.914590578
1
134.44
5
1
176.017113966
4
1
0.914590578
1
135.25
5
1
176.931704544
4
1
0.997735176
1
136.05
5
1
177.846295122
4
1
0.997735176
1
136.85
5
1
178.7608857
4
1
0.997735176
1
137.65
5
1
179.758620876
4
1
0.997735176
1
138.45
5
1
180.673211454
4
1
0.997735176
1
139.25
5
1
181.504657434
4
1
0.997735176
1
140.06
5
1
182.419248012
4
1
0.997735176
1
140.86
5
1
183.250693992
4
1
0.997735176
1
141.66
5
1
183.998995374
4
1
0.997735176
1
142.46
5
1
184.830441354
4
1
0.997735176
1
143.25
5
1
185.82817653
4
1
0.997735176
1
144.06
5
1
186.65962251
4
1
0.997735176
1
144.86
5
1
187.574213088
4
1
0.997735176
1
145.66
5
1
188.405659068
4
1
0.997735176
1
146.46
5
1
189.320249646
4
1
0.997735176
1
147.26
5
1
190.151695626
4
1
0.997735176
1
148.06
5
1
190.81685241
4
1
0.997735176
1
148.86
5
1
191.64829839
4
1
0.997735176
1
149.66
5
1
192.646033566
4
1
0.997735176
1
150.46
5
1
193.560624144
4
1
0.997735176
1
151.26
5
1
194.308925526
4
1
1.080879774
1
152.06
5
1
195.140371506
4
1
1.080879774
1
152.86
5
1
195.971817486
4
1
1.080879774
1
153.66
5
1
196.886408064
4
1
1.080879774
1
154.46
5
1
197.88414324
4
1
1.080879774
1
155.26
5
1
198.632444622
4
1
1.080879774
1
156.06
5
1
199.630179798
4
1
1.080879774
1
156.86
5
1
200.37848118
4
1
1.080879774
1
157.66
5
1
201.20992716
4
1
1.080879774
1
158.46
5
1
201.958228542
4
1
1.080879774
1
159.26
5
1
202.87281912
4
1
1.080879774
1
160.06
5
1
203.787409698
4
1
1.080879774
1
160.85
5
1
204.702000276
4
1
1.080879774
1
162.45
5
1
206.697470628
4
1
1.080879774
1
163.25
5
1
207.279482814
4
1
1.080879774
1
164.04
5
1
208.360362588
4
1
1.080879774
1
164.84
5
1
209.10866397
4
1
1.080879774
1
165.64
5
1
209.94010995
4
1
1.080879774
1
166.44
5
1
210.522122136
4
1
1.080879774
1
167.23
5
1
211.353568116
4
1
1.164024372
1
168.03
5
1
212.351303292
4
1
1.164024372
1
168.81
5
1
213.349038468
4
1
1.164024372
1
169.61
5
1
214.180484448
4
1
1.164024372
1
170.41
5
1
214.92878583
4
1
1.164024372
1
171.2
5
1
216.1759548
4
1
1.164024372
1
172
5
1
217.00740078
4
1
1.164024372
1
172.79
5
1
217.672557564
4
1
1.164024372
1
173.59
5
1
218.420858946
4
1
1.164024372
1
174.38
5
1
219.584883318
4
1
1.164024372
1
175.18
5
1
220.250040102
4
1
1.164024372
1
175.97
5
1
221.247775278
4
1
1.164024372
1
176.77
5
1
221.829787464
4
1
1.164024372
1
177.56
5
1
222.494944248
4
1
1.164024372
1
178.36
5
1
223.492679424
4
1
1.164024372
1
179.15
5
1
224.324125404
4
1
1.164024372
1
179.94
5
1
224.989282188
4
1
1.164024372
1
180.74
5
1
225.73758357
4
1
1.164024372
1
181.52
5
1
226.98475254
4
1
1.164024372
1
183.09
5
1
227.733053922
4
1
1.164024372
1
183.89
5
1
229.728524274
4
1
1.24716897
1
184.68
5
1
230.393681058
4
1
1.24716897
1
185.47
5
1
231.55770543
4
1
1.24716897
1
186.26
5
1
232.139717616
4
1
1.24716897
1
187.05
5
1
232.971163596
4
1
1.24716897
1
187.84
5
1
233.968898772
4
1
1.24716897
1
188.63
5
1
234.634055556
4
1
1.24716897
1
189.42
5
1
235.465501536
4
1
1.24716897
1
190.21
5
1
236.463236712
4
1
1.24716897
1
190.99
5
1
237.294682692
4
1
1.24716897
1
191.78
5
1
237.876694878
4
1
1.24716897
1
192.57
5
1
238.874430054
4
1
1.24716897
1
193.36
5
1
239.789020632
4
1
1.24716897
1
194.13
5
1
240.953045004
4
1
1.24716897
1
194.91
5
1
241.451912592
4
1
1.24716897
1
195.7
5
1
241.95078018
4
1
1.24716897
1
196.49
5
1
243.19794915
4
1
1.24716897
1
197.27
5
1
243.946250532
4
1
1.24716897
1
198.06
5
1
245.110274904
4
1
1.330313568
1
198.84
5
1
245.941720884
4
1
1.330313568
1
199.63
5
1
246.690022266
4
1
1.330313568
1
200.62
5
1
248.020335834
4
1
1.330313568
1
203
5
1
251.262975156
4
1
1.330313568
1
204.2
5
1
252.177565734
4
1
1.330313568
1
205.4
5
1
253.424734704
4
1
1.330313568
1
206.6
5
1
254.755048272
4
1
1.330313568
1
207.79
5
1
256.08536184
4
1
1.330313568
1
208.99
5
1
257.498820006
4
1
1.330313568
1
210.18
5
1
258.745988976
4
1
1.330313568
1
211.38
5
1
260.076302544
4
1
1.330313568
1
212.58
5
1
261.240326916
4
1
1.330313568
1
213.78
5
1
262.570640484
4
1
1.413458166
1
214.99
5
1
263.98409865
4
1
1.413458166
1
216.19
5
1
265.397556816
4
1
1.413458166
1
217.4
5
1
266.561581188
4
1
1.413458166
1
218.61
5
1
267.891894756
4
1
1.413458166
1
221.02
5
1
272.132269254
4
1
1.413458166
1
222.24
5
1
272.71428144
4
1
1.413458166
1
223.45
5
1
273.712016616
4
1
1.413458166
1
224.67
5
1
275.458053174
4
1
1.413458166
1
225.88
5
1
277.370378928
4
1
1.413458166
1
227.1
5
1
279.448993878
4
1
1.496602764
1
228.32
5
1
281.527608828
4
1
1.496602764
1
229.54
5
1
283.606223778
4
1
1.496602764
1
230.75
5
1
286.516284708
4
1
1.496602764
1
231.96
5
1
291.089237598
4
1
1.496602764
1
233.16
5
1
296.82621486
4
1
1.579747362
7
1
1
Principal objective of the work
AB
TRC
4/21/2017
1
Molar heat capacity at constant pressure, J/K/mol
Small (less than 1 g) adiabatic calorimetry
Crystal
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Crystal
1
Pressure, kPa
Crystal
101.325
6
1
Temperature, K
Crystal
1
5
1
1
1.3552569474
3
1
0.1413458166
1
10
1
1
7.48301382
2
1
0.332578392
1
15
2
1
16.878353394
3
1
0.665156784
1
20
1
1
26.689415958
3
1
0.41572299
1
25
2
1
36.334189326
3
1
0.582012186
1
30
1
1
45.7295289
3
1
0.748301382
1
35
2
1
54.542856288
3
1
0.914590578
1
40
1
1
63.106749882
3
1
0.914590578
1
45
2
1
71.171775888
3
1
0.582012186
1
50
1
1
77.906488326
3
1
0.748301382
1
60
1
1
89.546732046
4
1
0.748301382
1
70
1
1
101.186975766
4
1
0.914590578
1
80
1
1
113.159797878
4
1
0.83144598
1
90
1
1
123.802306422
4
1
0.665156784
1
100
1
1
135.52569474
4
1
0.748301382
1
110
2
1
146.417637078
4
1
0.83144598
1
120
2
1
157.309579416
4
1
0.914590578
1
130
2
1
168.201521754
4
1
0.914590578
1
140
2
1
179.010319494
4
1
0.914590578
1
150
2
1
189.819117234
4
1
0.914590578
1
160
2
1
200.627914974
4
1
1.080879774
1
170
2
1
211.436712714
4
1
1.080879774
1
180
2
1
222.328655052
4
1
1.164024372
1
190
2
1
233.22059739
4
1
1.24716897
1
200
1
1
244.278828924
4
1
1.330313568
1
210
2
1
255.337060458
4
1
1.330313568
1
220
2
1
266.47843659
4
1
1.330313568
1
230
2
1
277.786101918
4
1
1.496602764
1
240
2
1
289.260056442
4
1
1.496602764
1
250
2
1
300.900300162
4
1
1.496602764
1
260
2
1
312.62368848
4
1
1.66289196
1
270
2
1
324.596510592
4
1
1.66289196
1
280
2
1
336.818766498
4
1
1.746036558
1
290
2
1
349.2073116
4
1
1.746036558
1
298.15
5
1
359.517241752
4
1
1.912325754
1
300
1
1
361.845290496
4
1
1.912325754
1
310
2
1
376.395595146
4
1
1.912325754
1
320
2
1
390.447032208
4
1
1.912325754
1
330
2
1
404.49846927
4
1
2.07861495
1
334.8
4
1
411.233181708
4
1
2.07861495
8
1
1
Principal objective of the work
AB
TRC
4/21/2017
1
Molar enthalpy function {Hm(T)-Hm(0)}/T, J/K/mol
Small (less than 1 g) adiabatic calorimetry
Crystal
Direct value, X
Crystal
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Crystal
1
Pressure, kPa
Crystal
101.325
6
1
Temperature, K
Crystal
1
5
1
1
0.35419598748
3
1
0.04074085302
1
10
1
1
2.2698475254
3
1
0.2411193342
1
15
2
1
5.5374302268
3
1
0.166289196
1
20
1
1
9.644773368
3
1
0.166289196
1
25
2
1
13.968292464
3
1
0.249433794
1
30
1
1
18.541245354
3
1
0.332578392
1
35
2
1
23.031053646
3
1
0.332578392
1
40
1
1
27.520861938
3
1
0.498867588
1
45
2
1
31.927525632
3
1
0.498867588
1
50
1
1
36.16790013
3
1
0.665156784
1
60
1
1
44.149781538
3
1
0.665156784
1
70
1
1
51.466506162
3
1
0.748301382
1
80
1
1
58.367507796
3
1
0.914590578
1
90
1
1
65.019075636
3
1
0.914590578
1
100
1
1
71.50435428
3
1
1.080879774
1
110
2
1
77.823343728
3
1
1.080879774
1
120
2
1
83.97604398
4
1
1.080879774
1
130
2
1
90.128744232
4
1
1.080879774
1
140
2
1
96.03201069
4
1
1.24716897
1
150
2
1
101.935277148
4
1
1.24716897
1
160
2
1
107.755399008
4
1
1.24716897
1
170
2
1
113.49237627
4
1
1.24716897
1
180
2
1
119.229353532
4
1
1.24716897
1
190
2
1
124.966330794
4
1
1.413458166
1
200
1
1
130.703308056
4
1
1.413458166
1
210
2
1
136.35714072
4
1
1.413458166
1
220
2
1
142.010973384
4
1
1.413458166
1
230
2
1
147.664806048
4
1
1.579747362
1
240
2
1
153.40178331
4
1
1.579747362
1
250
2
1
159.055615974
4
1
1.579747362
1
260
2
1
164.709448638
4
1
1.579747362
1
270
2
1
170.4464259
4
1
1.746036558
1
280
2
1
176.183403162
4
1
1.746036558
1
290
2
1
181.920380424
4
1
1.829181156
1
298.15
5
1
186.65962251
4
1
1.829181156
1
300
1
1
187.740502284
4
1
1.829181156
1
310
2
1
193.560624144
4
1
1.829181156
1
320
2
1
199.463890602
4
1
1.829181156
1
330
2
1
205.450301658
4
1
1.829181156
1
334.8
4
1
208.443507186
4
1
1.829181156
9
1
1
Principal objective of the work
AB
TRC
4/21/2017
1
Molar entropy, J/K/mol
Small (less than 1 g) adiabatic calorimetry
Crystal
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Crystal
1
Pressure, kPa
Crystal
101.325
6
1
Temperature, K
Crystal
1
5
1
1
0.46394685684
3
1
0.083144598
1
10
1
1
3.1096079652
3
1
0.5071820478
1
15
2
1
7.8821078904
3
1
0.7649303016
1
20
1
1
14.051437062
3
1
1.496602764
1
25
2
1
21.035583294
3
1
0.83144598
1
30
1
1
28.518597114
3
1
0.997735176
1
35
2
1
36.251044728
3
1
1.24716897
1
40
1
1
44.06663694
3
1
1.746036558
1
45
2
1
51.96537375
3
1
1.579747362
1
50
1
1
59.86411056
3
1
1.829181156
1
60
1
1
75.079571994
3
1
2.328048744
1
70
1
1
89.79616584
4
1
2.826916332
1
80
1
1
104.097036696
4
1
3.32578392
1
90
1
1
117.982184562
4
1
1.912325754
1
100
1
1
131.701043232
4
1
2.161759548
1
110
2
1
145.08732351
4
1
2.411193342
1
120
2
1
158.307314592
4
1
2.411193342
1
130
2
1
171.361016478
4
1
2.660627136
1
140
2
1
184.16528457
4
1
2.91006093
1
150
2
1
196.886408064
4
1
3.159494724
1
160
2
1
209.52438696
4
1
3.408928518
1
170
2
1
221.99607666
4
1
3.408928518
1
180
2
1
234.384621762
4
1
3.658362312
1
190
2
1
246.690022266
4
1
3.907796106
1
200
1
1
258.99542277
4
1
3.990940704
1
210
2
1
271.134534078
4
1
4.240374498
1
220
2
1
283.273645386
4
1
4.489808292
1
230
2
1
295.329612096
4
1
4.739242086
1
240
2
1
307.468723404
4
1
4.98867588
1
250
2
1
319.441545516
4
1
4.98867588
1
260
2
1
331.497512226
4
1
5.238109674
1
270
2
1
343.553478936
4
1
5.238109674
1
280
2
1
355.526301048
4
1
5.487543468
1
290
2
1
367.582267758
4
1
5.736977262
1
298.15
5
1
377.393330322
4
1
5.82012186
1
300
1
1
379.638234468
4
1
5.986411056
1
310
2
1
391.777345776
4
1
6.23584485
1
320
2
1
403.916457084
4
1
6.318989448
1
330
2
1
416.13871299
4
1
6.568423242
1
334.8
4
1
422.041979448
4
1
6.568423242
10
1
1
Principal objective of the work
AB
TRC
4/21/2017
1
Molar heat capacity at constant pressure, J/K/mol
Small (less than 1 g) adiabatic calorimetry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
334.8
4
1
446.569635858
4
1
2.161759548
1
340
2
1
449.230262994
4
1
2.161759548
1
350
2
1
454.38522807
4
1
2.161759548
1
360
2
1
459.540193146
4
1
2.161759548
1
370
2
1
464.695158222
4
1
2.244904146
11
1
1
Principal objective of the work
AB
TRC
4/21/2017
1
Molar enthalpy function {Hm(T)-Hm(0)}/T, J/K/mol
Small (less than 1 g) adiabatic calorimetry
Liquid
Direct value, X
Crystal
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
334.8
4
1
268.473906942
4
1
2.660627136
1
340
2
1
271.134534078
4
1
2.826916332
1
350
2
1
276.289499154
4
1
2.993205528
1
360
2
1
281.278175034
4
1
2.993205528
1
370
2
1
286.183706316
4
1
2.993205528
12
1
1
Principal objective of the work
AB
TRC
4/21/2017
1
Molar entropy, J/K/mol
Small (less than 1 g) adiabatic calorimetry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
334.8
4
1
482.072379204
4
1
7.316724624
1
340
2
1
488.973380838
4
1
7.566158418
1
350
2
1
502.027082724
4
1
7.815592212
1
360
2
1
514.914495414
4
1
8.065026006
1
370
2
1
527.55247431
4
1
8.3144598