2
0
2016
lia
ler
0
journal
Original
Liang, K.-L.[Kai-Ling]
Leron, R. B.[Rhoda B.]
Li, M.-H.[Meng-Hui]
J. Chem. Thermodyn.
2016
2020-09-29
Heat capacities of aqueous binary and ternary mixtures (with piperazine) of N-(2-aminoethyl)-piperazine and N,N,N'-trimethylethylenediamine at temperatures (303.2-353.2) K
A new set of values for the molar heat capacities of N-(2-aminoethyl)piperazine (AEP) and N,N,N'-trime thylethylenediamine (tMEDA) and their aqueous mixtures over the whole range of compositions are reported in the present work. Molar heat capacities of ternary mixtures of each polyamine with piperazine (PZ): (AEP + PZ + H2O) and (tMEDA + PZ + H2O) were also measured. Measurements were done over the temperature range T = (303.2 353.2) K and p = 101.3 kPa by the differential scanning calorimetry technique. Excess molar heat capacities of aqueous binary mixtures were correlated with composition and temperature using a Redlich Kister relation, which was then used to correlate molar heat capacities of the mixtures at different temperatures and compositions. The equation fit the results with the average absolute deviation (AAD) of 2.1% and 0.2% for the excess molar heat capacity and molar heat capacity, respectively. A modified Sohnel and Novotny' equation was applied to represent the composition and temperature dependence of the molar heat capacity of aqueous ternary mixtures at AAD between the correlated and the experimental data of about 0.1%. The correlations proposed here are of acceptable accuracy for application in process design and engineering.
N-(2-Aminoethyl)piperazine
N,N,N'-Trimethylethylenediamine
Piperazine
Molar heat capacity
Excess molar heat capacity
10.1016/j.jct.2016.08.006
103
51-58
1
InChI=1S/C4H10N2/c1-2-6-4-3-5-1/h5-6H,1-4H2
GLUUGHFHXGJENI-UHFFFAOYSA-N
piperazine
diethylenediamine
hexahydro-1,4-diazine
hexahydropyrazine
C4H10N2
1
Commercial source
1
99
2
Stated by supplier
2
0.3326
4
Karl Fischer titration
2
InChI=1S/C6H15N3/c7-1-4-9-5-2-8-3-6-9/h8H,1-7H2
IMUDHTPIFIBORV-UHFFFAOYSA-N
N-(.beta.-aminoethyl)piperazine)
N-(2-aminoethyl)piperazine
piperazine, N-(2-aminoethyl)-
C6H15N3
1
Commercial source
1
99
2
Stated by supplier
2
0.2241
4
Karl Fischer titration
3
InChI=1S/C5H14N2/c1-6-4-5-7(2)3/h6H,4-5H2,1-3H3
HVOYZOQVDYHUPF-UHFFFAOYSA-N
N,N,N'-trimethylethylenediamine
1-(N,N-dimethylamino)-2-(N-methylamino)ethane
N-[2-(dimethylamino)ethyl]-N-methylamine
N1,N1,N2-trimethylethane-1,2-diamine
C5H14N2
1
Commercial source
1
98
2
Stated by supplier
2
0.1945
4
Karl Fischer titration
4
InChI=1S/H2O/h1H2
XLYOFNOQVPJJNP-UHFFFAOYSA-N
water
H2O
1
Commercial source
1
Fractional distillation
2
99.9
3
Estimated by the compiler
5
InChI=1S/C7H8/c1-7-5-3-2-4-6-7/h2-6H,1H3
YXFVVABEGXRONW-UHFFFAOYSA-N
toluene
methylbenzene
C7H8
1
Commercial source
1
99.98
4
Stated by supplier
2
Molecular sieve treatment
3
0.03
1
Karl Fischer titration
1
2
1
Principal objective of the work
AB
TRC
1/26/2017
1
Molar heat capacity at constant pressure, J/K/mol
Small sample (50 mg) DSC
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
1
303.2
4
1
289.7
4
1
9.6
1
308.2
4
1
290.8
4
1
9.6
1
313.2
4
1
293.1
4
1
9.7
1
318.2
4
1
294.7
4
1
9.8
1
323.2
4
1
296.9
4
1
9.8
1
328.2
4
1
298.5
4
1
9.9
1
333.2
4
1
300.7
4
1
10
1
338.2
4
1
302.2
4
1
10
1
343.2
4
1
303.3
4
1
10.1
1
348.2
4
1
303.6
4
1
10.1
1
353.2
4
1
304.6
4
1
10.1
2
3
1
Principal objective of the work
AB
TRC
1/26/2017
1
Molar heat capacity at constant pressure, J/K/mol
Small sample (50 mg) DSC
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
1
303.2
4
1
258.3
4
1
8.6
1
308.2
4
1
260
4
1
8.6
1
313.2
4
1
262.7
4
1
8.7
1
318.2
4
1
265.3
4
1
8.8
1
323.2
4
1
269.2
4
1
8.9
1
328.2
4
1
272.7
4
1
9
1
333.2
4
1
276
4
1
9.2
1
338.2
4
1
278.9
4
1
9.3
1
343.2
4
1
281.3
4
1
9.3
1
348.2
4
1
283.4
4
1
9.4
1
353.2
4
1
286.6
4
1
9.5
3
4
1
Principal objective of the work
AB
TRC
1/26/2017
1
Molar heat capacity at constant pressure, J/K/mol
Small sample (50 mg) DSC
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
1
303.2
4
1
75.26
4
1
2.5
1
308.2
4
1
75.27
4
1
2.5
1
313.2
4
1
75.29
4
1
2.5
1
318.2
4
1
75.31
4
1
2.5
1
323.2
4
1
75.29
4
1
2.5
1
328.2
4
1
75.32
4
1
2.5
1
333.2
4
1
75.41
4
1
2.5
1
338.2
4
1
75.44
4
1
2.5
1
343.2
4
1
75.48
4
1
2.5
1
348.2
4
1
75.55
4
1
2.51
1
353.2
4
1
75.78
4
1
2.51
4
5
1
Principal objective of the work
AB
TRC
1/26/2017
1
Molar heat capacity at constant pressure, J/K/mol
Small sample (50 mg) DSC
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
1
303.2
4
1
159.1
4
1
5.3
1
308.2
4
1
160.4
4
1
5.3
1
313.2
4
1
161.6
4
1
5.4
1
318.2
4
1
163
4
1
5.4
1
323.2
4
1
164.1
4
1
5.4
1
328.2
4
1
165.5
4
1
5.5
1
333.2
4
1
167
4
1
5.5
1
338.2
4
1
168.6
4
1
5.6
1
343.2
4
1
170.4
4
1
5.7
1
348.2
4
1
172.8
4
1
5.7
1
353.2
4
1
175.1
4
1
5.8
5
2
1
4
1
Principal objective of the work
AB
TRC
1/26/2017
1
Molar heat capacity at constant pressure, J/K/mol
Small sample (50 mg) DSC
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mole fraction
2
Liquid
1
303.2
4
2
0.1
3
1
109.7
4
1
4.5
1
308.2
4
2
0.1
3
1
110.2
4
1
4.5
1
313.2
4
2
0.1
3
1
110.7
4
1
4.6
1
318.2
4
2
0.1
3
1
111
4
1
4.6
1
323.2
4
2
0.1
3
1
111.4
4
1
4.7
1
328.2
4
2
0.1
3
1
111.4
4
1
4.7
1
333.2
4
2
0.1
3
1
111.6
4
1
4.8
1
338.2
4
2
0.1
3
1
111.8
4
1
4.8
1
343.2
4
2
0.1
3
1
112.4
4
1
4.8
1
348.2
4
2
0.1
3
1
112.6
4
1
4.9
1
353.2
4
2
0.1
3
1
112.9
4
1
4.9
1
303.2
4
2
0.3
3
1
157.3
4
1
5.7
1
308.2
4
2
0.3
3
1
158.5
4
1
5.7
1
313.2
4
2
0.3
3
1
160.3
4
1
5.8
1
318.2
4
2
0.3
3
1
162.1
4
1
5.9
1
323.2
4
2
0.3
3
1
164.3
4
1
6
1
328.2
4
2
0.3
3
1
165.7
4
1
6
1
333.2
4
2
0.3
3
1
167.3
4
1
6.1
1
338.2
4
2
0.3
3
1
168.7
4
1
6.1
1
343.2
4
2
0.3
3
1
170.1
4
1
6.2
1
348.2
4
2
0.3
3
1
171.4
4
1
6.2
1
353.2
4
2
0.3
3
1
173.1
4
1
6.3
1
303.2
4
2
0.5
3
1
202.1
4
1
7
1
308.2
4
2
0.5
3
1
203.2
4
1
7.1
1
313.2
4
2
0.5
3
1
204.8
4
1
7.1
1
318.2
4
2
0.5
3
1
206.3
4
1
7.2
1
323.2
4
2
0.5
3
1
208.5
4
1
7.2
1
328.2
4
2
0.5
3
1
210
4
1
7.3
1
333.2
4
2
0.5
3
1
211.8
4
1
7.3
1
338.2
4
2
0.5
3
1
213.6
4
1
7.4
1
343.2
4
2
0.5
3
1
215.2
4
1
7.5
1
348.2
4
2
0.5
3
1
216.3
4
1
7.5
1
353.2
4
2
0.5
3
1
217.6
4
1
7.5
1
303.2
4
2
0.7
3
1
242.8
4
1
8.3
1
308.2
4
2
0.7
3
1
244.3
4
1
8.3
1
313.2
4
2
0.7
3
1
246.3
4
1
8.4
1
318.2
4
2
0.7
3
1
248.1
4
1
8.5
1
323.2
4
2
0.7
3
1
250.6
4
1
8.5
1
328.2
4
2
0.7
3
1
252.5
4
1
8.6
1
333.2
4
2
0.7
3
1
253.5
4
1
8.6
1
338.2
4
2
0.7
3
1
254.5
4
1
8.7
1
343.2
4
2
0.7
3
1
255.9
4
1
8.7
1
348.2
4
2
0.7
3
1
256.2
4
1
8.7
1
353.2
4
2
0.7
3
1
257.3
4
1
8.7
1
303.2
4
2
0.9
3
1
278.3
4
1
9.4
1
308.2
4
2
0.9
3
1
279.8
4
1
9.4
1
313.2
4
2
0.9
3
1
281.6
4
1
9.5
1
318.2
4
2
0.9
3
1
283.1
4
1
9.5
1
323.2
4
2
0.9
3
1
285.2
4
1
9.6
1
328.2
4
2
0.9
3
1
287
4
1
9.7
1
333.2
4
2
0.9
3
1
289
4
1
9.7
1
338.2
4
2
0.9
3
1
290.9
4
1
9.8
1
343.2
4
2
0.9
3
1
292
4
1
9.8
1
348.2
4
2
0.9
3
1
292.5
4
1
9.8
1
353.2
4
2
0.9
3
1
293.7
4
1
9.9
1
303.2
4
2
1
4
1
289.7
4
1
9.6
1
308.2
4
2
1
4
1
290.8
4
1
9.6
1
313.2
4
2
1
4
1
293.1
4
1
9.7
1
318.2
4
2
1
4
1
294.7
4
1
9.8
1
323.2
4
2
1
4
1
296.9
4
1
9.8
1
328.2
4
2
1
4
1
298.5
4
1
9.9
1
333.2
4
2
1
4
1
300.7
4
1
10
1
338.2
4
2
1
4
1
302.2
4
1
10
1
343.2
4
2
1
4
1
303.3
4
1
10.1
1
348.2
4
2
1
4
1
303.6
4
1
10.1
1
353.2
4
2
1
4
1
304.6
4
1
10.1
1
303.2
4
2
0
1
1
75.26
4
1
2.5
1
308.2
4
2
0
1
1
75.27
4
1
2.5
1
313.2
4
2
0
1
1
75.29
4
1
2.5
1
318.2
4
2
0
1
1
75.31
4
1
2.5
1
323.2
4
2
0
1
1
75.29
4
1
2.5
1
328.2
4
2
0
1
1
75.32
4
1
2.5
1
333.2
4
2
0
1
1
75.41
4
1
2.5
1
338.2
4
2
0
1
1
75.44
4
1
2.5
1
343.2
4
2
0
1
1
75.48
4
1
2.5
1
348.2
4
2
0
1
1
75.55
4
1
2.51
1
353.2
4
2
0
1
1
75.78
4
1
2.51
6
3
1
4
1
Principal objective of the work
AB
TRC
1/26/2017
1
Molar heat capacity at constant pressure, J/K/mol
Small sample (50 mg) DSC
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mole fraction
3
Liquid
1
303.2
4
2
0.1
3
1
105.2
4
1
4.3
1
308.2
4
2
0.1
3
1
105.5
4
1
4.3
1
313.2
4
2
0.1
3
1
106.1
4
1
4.4
1
318.2
4
2
0.1
3
1
106.5
4
1
4.4
1
323.2
4
2
0.1
3
1
107.3
4
1
4.5
1
328.2
4
2
0.1
3
1
107.6
4
1
4.5
1
333.2
4
2
0.1
3
1
108.1
4
1
4.6
1
338.2
4
2
0.1
3
1
108.5
4
1
4.6
1
343.2
4
2
0.1
3
1
109
4
1
4.6
1
348.2
4
2
0.1
3
1
109.4
4
1
4.7
1
353.2
4
2
0.1
3
1
110.3
4
1
4.7
1
303.2
4
2
0.3
3
1
151
4
1
5.4
1
308.2
4
2
0.3
3
1
152.4
4
1
5.5
1
313.2
4
2
0.3
3
1
154
4
1
5.5
1
318.2
4
2
0.3
3
1
155.6
4
1
5.6
1
323.2
4
2
0.3
3
1
157.8
4
1
5.7
1
328.2
4
2
0.3
3
1
159.5
4
1
5.8
1
333.2
4
2
0.3
3
1
161.4
4
1
5.8
1
338.2
4
2
0.3
3
1
162.7
4
1
5.9
1
343.2
4
2
0.3
3
1
163.8
4
1
5.9
1
348.2
4
2
0.3
3
1
164.8
4
1
6
1
353.2
4
2
0.3
3
1
166.2
4
1
6
1
303.2
4
2
0.5
3
1
188.5
4
1
6.5
1
308.2
4
2
0.5
3
1
190.1
4
1
6.5
1
313.2
4
2
0.5
3
1
192.1
4
1
6.6
1
318.2
4
2
0.5
3
1
193.9
4
1
6.7
1
323.2
4
2
0.5
3
1
196.1
4
1
6.7
1
328.2
4
2
0.5
3
1
198.2
4
1
6.8
1
333.2
4
2
0.5
3
1
200.2
4
1
6.9
1
338.2
4
2
0.5
3
1
201.9
4
1
6.9
1
343.2
4
2
0.5
3
1
203.3
4
1
7
1
348.2
4
2
0.5
3
1
204.4
4
1
7
1
353.2
4
2
0.5
3
1
206.3
4
1
7.1
1
303.2
4
2
0.7
3
1
217.4
4
1
7.4
1
308.2
4
2
0.7
3
1
219.1
4
1
7.4
1
313.2
4
2
0.7
3
1
221.2
4
1
7.5
1
318.2
4
2
0.7
3
1
223.1
4
1
7.5
1
323.2
4
2
0.7
3
1
226
4
1
7.6
1
328.2
4
2
0.7
3
1
228.5
4
1
7.7
1
333.2
4
2
0.7
3
1
231
4
1
7.8
1
338.2
4
2
0.7
3
1
233.3
4
1
7.9
1
343.2
4
2
0.7
3
1
235.3
4
1
8
1
348.2
4
2
0.7
3
1
237.5
4
1
8
1
353.2
4
2
0.7
3
1
239.8
4
1
8.1
1
303.2
4
2
0.9
3
1
245.2
4
1
8.2
1
308.2
4
2
0.9
3
1
246.8
4
1
8.3
1
313.2
4
2
0.9
3
1
249.3
4
1
8.4
1
318.2
4
2
0.9
3
1
251.7
4
1
8.5
1
323.2
4
2
0.9
3
1
255.5
4
1
8.6
1
328.2
4
2
0.9
3
1
258.7
4
1
8.7
1
333.2
4
2
0.9
3
1
261.8
4
1
8.8
1
338.2
4
2
0.9
3
1
264.4
4
1
8.9
1
343.2
4
2
0.9
3
1
267.3
4
1
9
1
348.2
4
2
0.9
3
1
270.2
4
1
9.1
1
353.2
4
2
0.9
3
1
273.1
4
1
9.2
1
303.2
4
2
1
4
1
258.3
4
1
8.6
1
308.2
4
2
1
4
1
260
4
1
8.6
1
313.2
4
2
1
4
1
262.7
4
1
8.7
1
318.2
4
2
1
4
1
265.3
4
1
8.8
1
323.2
4
2
1
4
1
269.2
4
1
8.9
1
328.2
4
2
1
4
1
272.7
4
1
9
1
333.2
4
2
1
4
1
276
4
1
9.2
1
338.2
4
2
1
4
1
278.9
4
1
9.3
1
343.2
4
2
1
4
1
281.3
4
1
9.3
1
348.2
4
2
1
4
1
283.4
4
1
9.4
1
353.2
4
2
1
4
1
286.6
4
1
9.5
1
303.2
4
2
0
1
1
75.26
4
1
2.5
1
308.2
4
2
0
1
1
75.27
4
1
2.5
1
313.2
4
2
0
1
1
75.29
4
1
2.5
1
318.2
4
2
0
1
1
75.31
4
1
2.5
1
323.2
4
2
0
1
1
75.29
4
1
2.5
1
328.2
4
2
0
1
1
75.32
4
1
2.5
1
333.2
4
2
0
1
1
75.41
4
1
2.5
1
338.2
4
2
0
1
1
75.44
4
1
2.5
1
343.2
4
2
0
1
1
75.48
4
1
2.5
1
348.2
4
2
0
1
1
75.55
4
1
2.51
1
353.2
4
2
0
1
1
75.78
4
1
2.51
7
1
1
2
1
4
1
Principal objective of the work
AB
TRC
1/26/2017
1
Molar heat capacity at constant pressure, J/K/mol
Small sample (50 mg) DSC
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mass fraction
2
Liquid
3
Mass fraction
1
Liquid
1
303.2
4
2
0.18
2
3
0.12
2
1
100.2
4
1
3.3
1
308.2
4
2
0.18
2
3
0.12
2
1
100.2
4
1
3.4
1
313.2
4
2
0.18
2
3
0.12
2
1
100.3
4
1
3.4
1
318.2
4
2
0.18
2
3
0.12
2
1
100.5
4
1
3.4
1
323.2
4
2
0.18
2
3
0.12
2
1
100.8
4
1
3.4
1
328.2
4
2
0.18
2
3
0.12
2
1
101
4
1
3.4
1
333.2
4
2
0.18
2
3
0.12
2
1
101.2
4
1
3.4
1
338.2
4
2
0.18
2
3
0.12
2
1
101.4
4
1
3.4
1
343.2
4
2
0.18
2
3
0.12
2
1
101.5
4
1
3.4
1
348.2
4
2
0.18
2
3
0.12
2
1
101.7
4
1
3.4
1
353.2
4
2
0.18
2
3
0.12
2
1
102
4
1
3.4
1
303.2
4
2
0.21
2
3
0.09
1
1
101.4
4
1
3.4
1
308.2
4
2
0.21
2
3
0.09
1
1
101.5
4
1
3.4
1
313.2
4
2
0.21
2
3
0.09
1
1
101.7
4
1
3.4
1
318.2
4
2
0.21
2
3
0.09
1
1
101.7
4
1
3.4
1
323.2
4
2
0.21
2
3
0.09
1
1
102
4
1
3.4
1
328.2
4
2
0.21
2
3
0.09
1
1
102
4
1
3.4
1
333.2
4
2
0.21
2
3
0.09
1
1
102.3
4
1
3.4
1
338.2
4
2
0.21
2
3
0.09
1
1
102.5
4
1
3.4
1
343.2
4
2
0.21
2
3
0.09
1
1
102.7
4
1
3.4
1
348.2
4
2
0.21
2
3
0.09
1
1
102.9
4
1
3.4
1
353.2
4
2
0.21
2
3
0.09
1
1
103.4
4
1
3.4
1
303.2
4
2
0.24
2
3
0.06
1
1
102.9
4
1
3.4
1
308.2
4
2
0.24
2
3
0.06
1
1
103
4
1
3.4
1
313.2
4
2
0.24
2
3
0.06
1
1
103.1
4
1
3.4
1
318.2
4
2
0.24
2
3
0.06
1
1
103.3
4
1
3.5
1
323.2
4
2
0.24
2
3
0.06
1
1
103.4
4
1
3.5
1
328.2
4
2
0.24
2
3
0.06
1
1
103.6
4
1
3.5
1
333.2
4
2
0.24
2
3
0.06
1
1
103.7
4
1
3.5
1
338.2
4
2
0.24
2
3
0.06
1
1
103.8
4
1
3.5
1
343.2
4
2
0.24
2
3
0.06
1
1
103.9
4
1
3.5
1
348.2
4
2
0.24
2
3
0.06
1
1
103.9
4
1
3.5
1
353.2
4
2
0.24
2
3
0.06
1
1
104.2
4
1
3.5
1
303.2
4
2
0.27
2
3
0.03
1
1
104.2
4
1
3.5
1
308.2
4
2
0.27
2
3
0.03
1
1
104.3
4
1
3.5
1
313.2
4
2
0.27
2
3
0.03
1
1
104.4
4
1
3.5
1
318.2
4
2
0.27
2
3
0.03
1
1
104.4
4
1
3.5
1
323.2
4
2
0.27
2
3
0.03
1
1
104.6
4
1
3.5
1
328.2
4
2
0.27
2
3
0.03
1
1
104.7
4
1
3.5
1
333.2
4
2
0.27
2
3
0.03
1
1
104.8
4
1
3.5
1
338.2
4
2
0.27
2
3
0.03
1
1
104.9
4
1
3.5
1
343.2
4
2
0.27
2
3
0.03
1
1
105.1
4
1
3.5
1
348.2
4
2
0.27
2
3
0.03
1
1
105.2
4
1
3.5
1
353.2
4
2
0.27
2
3
0.03
1
1
105.4
4
1
3.5
8
1
1
3
1
4
1
Principal objective of the work
AB
TRC
1/26/2017
1
Molar heat capacity at constant pressure, J/K/mol
Small sample (50 mg) DSC
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mass fraction
3
Liquid
3
Mass fraction
1
Liquid
1
303.2
4
2
0.18
2
3
0.12
2
1
101.3
4
1
3.4
1
308.2
4
2
0.18
2
3
0.12
2
1
101.6
4
1
3.4
1
313.2
4
2
0.18
2
3
0.12
2
1
102.1
4
1
3.4
1
318.2
4
2
0.18
2
3
0.12
2
1
102.3
4
1
3.4
1
323.2
4
2
0.18
2
3
0.12
2
1
102.9
4
1
3.4
1
328.2
4
2
0.18
2
3
0.12
2
1
103.3
4
1
3.4
1
333.2
4
2
0.18
2
3
0.12
2
1
103.7
4
1
3.5
1
338.2
4
2
0.18
2
3
0.12
2
1
104.2
4
1
3.5
1
343.2
4
2
0.18
2
3
0.12
2
1
104.5
4
1
3.5
1
348.2
4
2
0.18
2
3
0.12
2
1
104.7
4
1
3.5
1
353.2
4
2
0.18
2
3
0.12
2
1
105.4
4
1
3.5
1
303.2
4
2
0.21
2
3
0.09
1
1
102.5
4
1
3.4
1
308.2
4
2
0.21
2
3
0.09
1
1
102.9
4
1
3.4
1
313.2
4
2
0.21
2
3
0.09
1
1
103.1
4
1
3.4
1
318.2
4
2
0.21
2
3
0.09
1
1
103.5
4
1
3.5
1
323.2
4
2
0.21
2
3
0.09
1
1
104
4
1
3.5
1
328.2
4
2
0.21
2
3
0.09
1
1
104.3
4
1
3.5
1
333.2
4
2
0.21
2
3
0.09
1
1
104.7
4
1
3.5
1
338.2
4
2
0.21
2
3
0.09
1
1
105.1
4
1
3.5
1
343.2
4
2
0.21
2
3
0.09
1
1
105.5
4
1
3.5
1
348.2
4
2
0.21
2
3
0.09
1
1
105.9
4
1
3.5
1
353.2
4
2
0.21
2
3
0.09
1
1
106.5
4
1
3.5
1
303.2
4
2
0.24
2
3
0.06
1
1
103.7
4
1
3.5
1
308.2
4
2
0.24
2
3
0.06
1
1
104.1
4
1
3.5
1
313.2
4
2
0.24
2
3
0.06
1
1
104.2
4
1
3.5
1
318.2
4
2
0.24
2
3
0.06
1
1
104.7
4
1
3.5
1
323.2
4
2
0.24
2
3
0.06
1
1
105
4
1
3.5
1
328.2
4
2
0.24
2
3
0.06
1
1
105.3
4
1
3.5
1
333.2
4
2
0.24
2
3
0.06
1
1
105.7
4
1
3.5
1
338.2
4
2
0.24
2
3
0.06
1
1
106.1
4
1
3.5
1
343.2
4
2
0.24
2
3
0.06
1
1
106.5
4
1
3.5
1
348.2
4
2
0.24
2
3
0.06
1
1
106.8
4
1
3.6
1
353.2
4
2
0.24
2
3
0.06
1
1
107.3
4
1
3.6
1
303.2
4
2
0.27
2
3
0.03
1
1
104.6
4
1
3.5
1
308.2
4
2
0.27
2
3
0.03
1
1
104.8
4
1
3.5
1
313.2
4
2
0.27
2
3
0.03
1
1
105.1
4
1
3.5
1
318.2
4
2
0.27
2
3
0.03
1
1
105.4
4
1
3.5
1
323.2
4
2
0.27
2
3
0.03
1
1
105.7
4
1
3.5
1
328.2
4
2
0.27
2
3
0.03
1
1
106.1
4
1
3.5
1
333.2
4
2
0.27
2
3
0.03
1
1
106.5
4
1
3.5
1
338.2
4
2
0.27
2
3
0.03
1
1
106.8
4
1
3.6
1
343.2
4
2
0.27
2
3
0.03
1
1
107.2
4
1
3.6
1
348.2
4
2
0.27
2
3
0.03
1
1
107.5
4
1
3.6
1
353.2
4
2
0.27
2
3
0.03
1
1
108
4
1
3.6