2
0
2016
kro
kro
0
journal
Original
Krolikowski, M.[Marek]
Krolikowska, M.[Marta]
Wisniewski, C.[Cezary]
J. Chem. Thermodyn.
2016
2020-09-29
Separation of aliphatic from aromatic hydrocarbons and sulphur compounds from fuel based on measurements of activity coefficients at infinite dilution for organic solutes and water in the ionic liquid N,N-diethyl-N-methyl-N-(2-methoxy-ethyl)ammonium bis(trifluoromethylsulfonyl)imide
The activity coefficients at infinite dilution, c1 13, for 53 different solutes including alkanes, cycloalkanes, alkenes, alkynes, aromatic hydrocarbons, alcohols, ethers, ketones, thiophene, acetonitrile, pyridine, 1-nitropropane and water in the ionic liquid N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium bis(trifluoromethylsulfonyl)imide, [COC2N1,2,2][NTf2] were determined using inverse gas-liquid chromatography. The experiment has been performed at five temperatures over the range of (318.15 to 358.15) K. From experimental results, the partial molar excess Gibbs energy, DGE;1 1 , enthalpy DHE;1 1 and entropy term TrefDSE;1 1 at infinite dilution were calculated. Additionally, the gas-liquid partition coefficients of the solutes, KL were calculated. The value of selectivity, S1 12 and capacity, k1 2 at infinite dilution for hexane/benzene, cyclohexane/benzene, heptane/thiophene and heptane/pyridine separation processes were calculated directly from c1 13. These parameters are compared to literature values of S1 12 and k1 2 for other ionic liquids and NMP, or sulfolane solvents commercially used on an industrial scale in separation processes. Moreover, physicochemical properties of pure ILs that is: density, viscosity and surface tension have been determined as a function of temperature and basic thermal properties of pure [COC2N1,2,2][NTf2] were measured using DSC technique.
Activity coefficient at infinite dilution
Ionic liquid
[COC2N1,2,2][NTf2]
Density
Viscosity
Surface tension
Thermodynamics properties at infinite dilution
10.1016/j.jct.2016.07.017
103
115-124
1
InChI=1S/C8H20NO.C2F6NO4S2/c1-5-9(3,6-2)7-8-10-4;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h5-8H2,1-4H3;/q+1;-1
WUFQNPMBKMKEHN-UHFFFAOYSA-N
N,N-diethyl-2-methoxy-N-methylethan-1-aminium bis((trifluoromethyl)sulfonyl)amide
N,N-diethyl-2-methoxy-N-methylethan-1-aminium bis((trifluoromethyl)sulfonyl)amide [DEME][TFSA]
C10H20F6N2O5S2
1
Commercial source
1
99
2
Stated by supplier
2
Dried by vacuum heating
3
0.043
3
Karl Fischer titration
2
InChI=1S/C6H14/c1-3-5-6-4-2/h3-6H2,1-2H3
VLKZOEOYAKHREP-UHFFFAOYSA-N
hexane
n-hexane
C6H14
1
Commercial source
1
99
2
Stated by supplier
3
InChI=1S/C6H14/c1-4-6(3)5-2/h6H,4-5H2,1-3H3
PFEOZHBOMNWTJB-UHFFFAOYSA-N
3-methylpentane
C6H14
1
Commercial source
1
99
2
Stated by supplier
4
InChI=1S/C6H14/c1-5-6(2,3)4/h5H2,1-4H3
HNRMPXKDFBEGFZ-UHFFFAOYSA-N
2,2-dimethylbutane
neohexane
C6H14
1
Commercial source
1
99
2
Stated by supplier
5
InChI=1S/C7H16/c1-3-5-7-6-4-2/h3-7H2,1-2H3
IMNFDUFMRHMDMM-UHFFFAOYSA-N
heptane
n-heptane
C7H16
1
Commercial source
1
99.5
3
Stated by supplier
6
InChI=1S/C8H18/c1-3-5-7-8-6-4-2/h3-8H2,1-2H3
TVMXDCGIABBOFY-UHFFFAOYSA-N
octane
n-octane
C8H18
1
Commercial source
1
99
2
Stated by supplier
7
InChI=1S/C8H18/c1-7(2)6-8(3,4)5/h7H,6H2,1-5H3
NHTMVDHEPJAVLT-UHFFFAOYSA-N
2,2,4-trimethylpentane
isooctane
C8H18
1
Commercial source
1
99
2
Stated by supplier
8
InChI=1S/C9H20/c1-3-5-7-9-8-6-4-2/h3-9H2,1-2H3
BKIMMITUMNQMOS-UHFFFAOYSA-N
nonane
n-nonane
C9H20
1
Commercial source
1
99
2
Stated by supplier
9
InChI=1S/C10H22/c1-3-5-7-9-10-8-6-4-2/h3-10H2,1-2H3
DIOQZVSQGTUSAI-UHFFFAOYSA-N
decane
n-decane
C10H22
1
Commercial source
1
99
2
Stated by supplier
10
InChI=1S/C5H10/c1-2-4-5-3-1/h1-5H2
RGSFGYAAUTVSQA-UHFFFAOYSA-N
cyclopentane
C5H10
1
Commercial source
1
99
2
Stated by supplier
11
InChI=1S/C6H12/c1-2-4-6-5-3-1/h1-6H2
XDTMQSROBMDMFD-UHFFFAOYSA-N
cyclohexane
C6H12
1
Commercial source
1
99
2
Stated by supplier
12
InChI=1S/C7H14/c1-7-5-3-2-4-6-7/h7H,2-6H2,1H3
UAEPNZWRGJTJPN-UHFFFAOYSA-N
methylcyclohexane
hexahydrotoluene
C7H14
1
Commercial source
1
99
2
Stated by supplier
13
InChI=1S/C7H14/c1-2-4-6-7-5-3-1/h1-7H2
DMEGYFMYUHOHGS-UHFFFAOYSA-N
cycloheptane
C7H14
1
Commercial source
1
98
2
Stated by supplier
14
InChI=1S/C8H16/c1-2-4-6-8-7-5-3-1/h1-8H2
WJTCGQSWYFHTAC-UHFFFAOYSA-N
cyclooctane
C8H16
1
Commercial source
1
99
2
Stated by supplier
15
InChI=1S/C6H12/c1-3-5-6-4-2/h3H,1,4-6H2,2H3
LIKMAJRDDDTEIG-UHFFFAOYSA-N
hex-1-ene
1-hexene
C6H12
1
Commercial source
1
99
2
Stated by supplier
16
InChI=1S/C6H10/c1-2-4-6-5-3-1/h1-2H,3-6H2
HGCIXCUEYOPUTN-UHFFFAOYSA-N
cyclohexene
1,2,3,4-tetrahydrobenzene
benzene tetrahydride
cyclohex-1-ene
tetrahydrobenzene
C6H10
1
Commercial source
1
99
2
Stated by supplier
17
InChI=1S/C7H14/c1-3-5-7-6-4-2/h3H,1,4-7H2,2H3
ZGEGCLOFRBLKSE-UHFFFAOYSA-N
1-heptene
hept-1-ene
C7H14
1
Commercial source
1
99
2
Stated by supplier
18
InChI=1S/C8H16/c1-3-5-7-8-6-4-2/h3H,1,4-8H2,2H3
KWKAKUADMBZCLK-UHFFFAOYSA-N
oct-1-ene
1-octene
caprylene
C8H16
1
Commercial source
1
98
2
Stated by supplier
19
InChI=1S/C10H20/c1-3-5-7-9-10-8-6-4-2/h3H,1,4-10H2,2H3
AFFLGGQVNFXPEV-UHFFFAOYSA-N
1-decene
dec-1-ene
C10H20
1
Commercial source
1
97
2
Stated by supplier
20
InChI=1S/C5H8/c1-3-5-4-2/h1H,4-5H2,2H3
IBXNCJKFFQIKKY-UHFFFAOYSA-N
1-pentyne
pent-1-yne
C5H8
1
Commercial source
1
97
2
Stated by supplier
21
InChI=1S/C6H10/c1-3-5-6-4-2/h1H,4-6H2,2H3
CGHIBGNXEGJPQZ-UHFFFAOYSA-N
1-hexyne
butylacetylene
hex-1-yne
n-butylacetylene
C6H10
1
Commercial source
1
97
2
Stated by supplier
22
InChI=1S/C7H12/c1-3-5-7-6-4-2/h1H,4-7H2,2H3
YVXHZKKCZYLQOP-UHFFFAOYSA-N
1-heptyne
hept-1-yne
C7H12
1
Commercial source
1
98
2
Stated by supplier
23
InChI=1S/C8H14/c1-3-5-7-8-6-4-2/h1H,4-8H2,2H3
UMIPWJGWASORKV-UHFFFAOYSA-N
1-octyne
hexylacetylene
oct-1-yne
C8H14
1
Commercial source
1
97
2
Stated by supplier
24
InChI=1S/C6H6/c1-2-4-6-5-3-1/h1-6H
UHOVQNZJYSORNB-UHFFFAOYSA-N
benzene
C6H6
1
Commercial source
1
99.8
3
Stated by supplier
25
InChI=1S/C7H8/c1-7-5-3-2-4-6-7/h2-6H,1H3
YXFVVABEGXRONW-UHFFFAOYSA-N
toluene
methylbenzene
C7H8
1
Commercial source
1
99.8
3
Stated by supplier
26
InChI=1S/C8H10/c1-2-8-6-4-3-5-7-8/h3-7H,2H2,1H3
YNQLUTRBYVCPMQ-UHFFFAOYSA-N
ethylbenzene
.alpha.-methyltoluene
phenylethane
C8H10
1
Commercial source
1
99.8
3
Stated by supplier
27
InChI=1S/C8H10/c1-7-5-3-4-6-8(7)2/h3-6H,1-2H3
CTQNGGLPUBDAKN-UHFFFAOYSA-N
1,2-dimethylbenzene
1,2-xylene
o-xylene
ortho-xylene
C8H10
1
Commercial source
1
99
2
Stated by supplier
28
InChI=1S/C8H10/c1-7-4-3-5-8(2)6-7/h3-6H,1-2H3
IVSZLXZYQVIEFR-UHFFFAOYSA-N
1,3-dimethylbenzene
1,3-xylene
m-xylene
meta-xylene
C8H10
1
Commercial source
1
99
2
Stated by supplier
29
InChI=1S/C8H10/c1-7-3-5-8(2)6-4-7/h3-6H,1-2H3
URLKBWYHVLBVBO-UHFFFAOYSA-N
1,4-dimethylbenzene
1,4-xylene
p-xylene
para-xylene
C8H10
1
Commercial source
1
99
2
Stated by supplier
30
InChI=1S/C8H8/c1-2-8-6-4-3-5-7-8/h2-7H,1H2
PPBRXRYQALVLMV-UHFFFAOYSA-N
styrene
benzene, ethenyl-
ethenylbenzene
phenylethene
phenylethylene
vinylbenzene
C8H8
1
Commercial source
1
99.9
3
Stated by supplier
31
InChI=1S/CH4O/c1-2/h2H,1H3
OKKJLVBELUTLKV-UHFFFAOYSA-N
methanol
methyl alcohol
CH4O
1
Commercial source
1
99.9
3
Stated by supplier
32
InChI=1S/C2H6O/c1-2-3/h3H,2H2,1H3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N
ethanol
ethyl alcohol
C2H6O
1
Commercial source
1
99.8
3
Stated by supplier
33
InChI=1S/C3H8O/c1-2-3-4/h4H,2-3H2,1H3
BDERNNFJNOPAEC-UHFFFAOYSA-N
propan-1-ol
1-propanol
n-propanol
n-propyl alcohol
C3H8O
1
Commercial source
1
99.9
3
Stated by supplier
34
InChI=1S/C3H8O/c1-3(2)4/h3-4H,1-2H3
KFZMGEQAYNKOFK-UHFFFAOYSA-N
propan-2-ol
2-propanol
isopropanol
isopropyl alcohol
sec-propyl alcohol
C3H8O
1
Commercial source
1
99.9
3
Stated by supplier
35
InChI=1S/C4H10O/c1-2-3-4-5/h5H,2-4H2,1H3
LRHPLDYGYMQRHN-UHFFFAOYSA-N
butan-1-ol
1-butanol
n-butanol
n-butyl alcohol
C4H10O
1
Commercial source
1
99.8
3
Stated by supplier
36
InChI=1S/H2O/h1H2
XLYOFNOQVPJJNP-UHFFFAOYSA-N
water
H2O
1
Commercial source
1
Fractional distillation
2
99.8
3
Estimated by the compiler
37
InChI=1S/C4H4S/c1-2-4-5-3-1/h1-4H
YTPLMLYBLZKORZ-UHFFFAOYSA-N
thiophene
C4H4S
1
Commercial source
1
99
2
Stated by supplier
38
InChI=1S/C4H8O/c1-2-4-5-3-1/h1-4H2
WYURNTSHIVDZCO-UHFFFAOYSA-N
tetrahydrofuran
1,4-epoxybutane
THF
oxacyclopentane
oxolane
tetramethylene oxide
C4H8O
1
Commercial source
1
99.9
3
Stated by supplier
39
InChI=1S/C4H8O2/c1-2-6-4-3-5-1/h1-4H2
RYHBNJHYFVUHQT-UHFFFAOYSA-N
1,4-dioxane
1,4-dioxacyclohexane
dioxane
p-dioxane
tetrahydro-1,4-dioxin
C4H8O2
1
Commercial source
1
99.8
3
Stated by supplier
40
InChI=1S/C5H12O/c1-5(2,3)6-4/h1-4H3
BZLVMXJERCGZMT-UHFFFAOYSA-N
2-methoxy-2-methylpropane
1,1-dimethyl-1-methoxyethane
1,1-dimethylethyl methyl ether
3,3-dimethyl-2-oxabutane
methyl 1,1-dimethylethyl ether
methyl tert-butyl ether
tert-butyl methyl ether
C5H12O
1
Commercial source
1
99.8
3
Stated by supplier
41
InChI=1S/C6H14O/c1-5-6(2,3)7-4/h5H2,1-4H3
HVZJRWJGKQPSFL-UHFFFAOYSA-N
2-methoxy-2-methylbutane
1,1-dimethylpropyl methyl ether
methyl 1,1-dimethylpropyl ether
methyl tert-amyl ether
methyl tert-pentyl ether
tert-amyl methyl ether
tert-pentyl methyl ether
C6H14O
1
Commercial source
1
99
2
Stated by supplier
42
InChI=1S/C6H14O/c1-5-7-6(2,3)4/h5H2,1-4H3
NUMQCACRALPSHD-UHFFFAOYSA-N
2-ethoxy-2-methylpropane
4,4-dimethyl-3-oxapentane
ethyl 1,1-dimethylethyl ether
ethyl tert-butyl ether
tert-butyl ethyl ether
C6H14O
1
Commercial source
1
99
2
Stated by supplier
43
InChI=1S/C4H10O/c1-3-5-4-2/h3-4H2,1-2H3
RTZKZFJDLAIYFH-UHFFFAOYSA-N
diethyl ether
1,1'-oxybis-ethane
ethoxyethane
ethyl ether
C4H10O
1
Commercial source
1
99.9
3
Stated by supplier
44
InChI=1S/C6H14O/c1-3-5-7-6-4-2/h3-6H2,1-2H3
POLCUAVZOMRGSN-UHFFFAOYSA-N
dipropyl ether
1-propoxypropane
4-oxaheptane
propyl ether
C6H14O
1
Commercial source
1
99
2
Stated by supplier
45
InChI=1S/C6H14O/c1-5(2)7-6(3)4/h5-6H,1-4H3
ZAFNJMIOTHYJRJ-UHFFFAOYSA-N
diisopropyl ether
1-methyl-1-(1-methylethoxy)ethane
2,4-dimethyl-3-oxapentane
2-isopropoxypropane
bis(1-methylethyl) ether
isopropyl ether
C6H14O
1
Commercial source
1
99
2
Stated by supplier
46
InChI=1S/C8H18O/c1-3-5-7-9-8-6-4-2/h3-8H2,1-2H3
DURPTKYDGMDSBL-UHFFFAOYSA-N
dibutyl ether
1,1'-oxybisbutane
1-butoxybutane
5-oxanonane
butyl ether
butyl oxide
di-n-butyl ether
dibutyl oxide
n-butyl ether
C8H18O
1
Commercial source
1
99.3
3
Stated by supplier
47
InChI=1S/C3H6O/c1-3(2)4/h1-2H3
CSCPPACGZOOCGX-UHFFFAOYSA-N
acetone
2-propanone
dimethyl ketone
propan-2-one
propanone
pyroacetic ether
C3H6O
1
Commercial source
1
99.9
3
Stated by supplier
48
InChI=1S/C5H10O/c1-3-4-5(2)6/h3-4H2,1-2H3
XNLICIUVMPYHGG-UHFFFAOYSA-N
pentan-2-one
2-pentanone
methyl n-propyl ketone
methyl propyl ketone
propyl methyl ketone
C5H10O
1
Commercial source
1
99
2
Stated by supplier
49
InChI=1S/C5H10O/c1-3-5(6)4-2/h3-4H2,1-2H3
FDPIMTJIUBPUKL-UHFFFAOYSA-N
pentan-3-one
3-pentanone
diethyl ketone
C5H10O
1
Commercial source
1
99
2
Stated by supplier
50
InChI=1S/C6H12O/c1-3-4-5-6(2)7/h3-5H2,1-2H3
QQZOPKMRPOGIEB-UHFFFAOYSA-N
2-hexanone
butyl methyl ketone
hexanone-2
methyl butyl ketone
methyl n-butyl ketone
C6H12O
1
Commercial source
1
99
2
Stated by supplier
51
InChI=1S/C6H12O/c1-3-5-6(7)4-2/h3-5H2,1-2H3
PFCHFHIRKBAQGU-UHFFFAOYSA-N
3-hexanone
ethyl propyl ketone
C6H12O
1
Commercial source
1
99
2
Stated by supplier
52
InChI=1S/C2H3N/c1-2-3/h1H3
WEVYAHXRMPXWCK-UHFFFAOYSA-N
acetonitrile
cyanomethane
ethanenitrile
ethanonitrile
methanecarbonitrile
methyl cyanide
C2H3N
1
Commercial source
1
99.9
3
Stated by supplier
53
InChI=1S/C5H5N/c1-2-4-6-5-3-1/h1-5H
JUJWROOIHBZHMG-UHFFFAOYSA-N
pyridine
azine
C5H5N
1
Commercial source
1
99.8
3
Stated by supplier
54
InChI=1S/C3H7NO2/c1-2-3-4(5)6/h2-3H2,1H3
JSZOAYXJRCEYSX-UHFFFAOYSA-N
1-nitropropane
propane, 1-nitro-
C3H7NO2
1
Commercial source
1
98.5
3
Stated by supplier
1
1
1
Principal objective of the work
AB
TRC
1/31/2017
1
Triple point temperature, K
DSC
Glass
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Glass
Liquid
Air at 1 atmosphere
1
179.4
4
1
0.8
2
1
1
Principal objective of the work
AB
TRC
1/31/2017
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
288.15
5
1
1416.6
6
1
1.14
1
298.15
5
1
1407.33
6
1
1.13
1
308.15
5
1
1398.12
6
1
1.13
1
318.15
5
1
1389
6
1
1.13
1
328.15
5
1
1379.94
6
1
1.12
1
338.15
5
1
1370.78
6
1
1.12
1
348.15
5
1
1361.55
6
1
1.12
1
358.15
5
1
1352.39
6
1
1.11
1
368.15
5
1
1343.38
6
1
1.11
3
1
1
Principal objective of the work
AB
TRC
1/31/2017
1
Viscosity, Pa*s
Falling or rolling sphere viscometry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
288.15
5
1
0.1206
4
1
0.0041
1
298.15
5
1
0.07096
4
1
0.00169
1
308.15
5
1
0.04536
4
1
0.00101
1
318.15
5
1
0.03096
4
1
0.00068
1
328.15
5
1
0.02223
4
1
0.00049
1
338.15
5
1
0.01658
4
1
0.00036
1
348.15
5
1
0.01279
4
1
0.00028
1
358.15
5
1
0.01018
4
1
0.00022
1
368.15
5
1
0.00819
4
1
0.00018
4
1
1
Principal objective of the work
AB
TRC
1/31/2017
1
Surface tension liquid-gas, N/m
Ring tensiometer
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Air at 1 atmosphere
1
Temperature, K
Liquid
1
298.15
5
1
0.0336
3
1
0.0008
1
308.15
5
1
0.0326
3
1
0.0008
1
318.15
5
1
0.0321
3
1
0.0007
1
328.15
5
1
0.0316
3
1
0.0007
1
338.15
5
1
0.0313
3
1
0.0007
5
2
1
1
1
Principal objective of the work
AB
TRC
1/31/2017
1
Activity coefficient
Chromatography
2
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
2
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
18.2
3
1
1.6
1
328.15
5
1
16.9
3
1
1.5
1
338.15
5
1
15.8
3
1
1.4
1
348.15
5
1
14.9
3
1
1.3
1
358.15
5
1
14
3
1
1.2
6
3
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
3
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
3
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
16.1
3
1
1.4
1
328.15
5
1
14.9
3
1
1.3
1
338.15
5
1
14
3
1
1.2
1
348.15
5
1
13.1
3
1
1.1
1
358.15
5
1
12.5
3
1
1.1
7
4
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
4
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
4
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
15.1
3
1
1.3
1
328.15
5
1
14
3
1
1.2
1
338.15
5
1
13.3
3
1
1.2
1
348.15
5
1
12.5
3
1
1.1
1
358.15
5
1
11.9
3
1
1
8
5
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
5
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
5
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
26.4
3
1
2.3
1
328.15
5
1
24.4
3
1
2.1
1
338.15
5
1
22.3
3
1
1.9
1
348.15
5
1
21
3
1
1.8
1
358.15
5
1
19.3
3
1
1.7
9
6
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
6
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
6
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
38.3
3
1
3.3
1
328.15
5
1
34.8
3
1
3
1
338.15
5
1
31.9
3
1
2.8
1
348.15
5
1
29.5
3
1
2.6
1
358.15
5
1
27
3
1
2.3
10
7
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
7
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
7
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
25.7
3
1
2.2
1
328.15
5
1
23.8
3
1
2.1
1
338.15
5
1
21.7
3
1
1.9
1
348.15
5
1
21
3
1
1.8
1
358.15
5
1
20
3
1
1.7
11
8
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
8
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
8
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
55.7
3
1
4.8
1
328.15
5
1
50
3
1
4.3
1
338.15
5
1
45.3
3
1
3.9
1
348.15
5
1
41
3
1
3.5
1
358.15
5
1
37.7
3
1
3.3
12
9
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
9
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
9
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
82
3
1
7.1
1
328.15
5
1
72.7
3
1
6.3
1
338.15
5
1
65.4
3
1
5.7
1
348.15
5
1
58.1
3
1
5
1
358.15
5
1
52.6
3
1
4.6
13
10
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
10
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
10
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
7.28
3
1
0.63
1
328.15
5
1
6.85
3
1
0.59
1
338.15
5
1
6.47
3
1
0.56
1
348.15
5
1
6.12
3
1
0.53
1
358.15
5
1
5.79
3
1
0.5
14
11
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
11
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
11
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
10.8
3
1
0.9
1
328.15
5
1
10
3
1
0.9
1
338.15
5
1
9.39
3
1
0.81
1
348.15
5
1
8.74
3
1
0.75
1
358.15
5
1
8.3
3
1
0.72
15
12
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
12
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
12
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
14.9
3
1
1.3
1
328.15
5
1
13.8
3
1
1.2
1
338.15
5
1
12.9
3
1
1.1
1
348.15
5
1
12
3
1
1
1
358.15
5
1
11.2
3
1
1
16
13
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
13
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
13
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
14.9
3
1
1.3
1
328.15
5
1
13.7
3
1
1.2
1
338.15
5
1
12.7
3
1
1.1
1
348.15
5
1
11.8
3
1
1
1
358.15
5
1
11
3
1
1
17
14
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
14
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
14
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
20.4
3
1
1.8
1
328.15
5
1
18.6
3
1
1.6
1
338.15
5
1
17
3
1
1.5
1
348.15
5
1
15.7
3
1
1.4
1
358.15
5
1
14.5
3
1
1.3
18
15
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
15
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
15
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
9.21
3
1
0.8
1
328.15
5
1
8.78
3
1
0.76
1
338.15
5
1
8.33
3
1
0.72
1
348.15
5
1
8.07
3
1
0.7
1
358.15
5
1
7.64
3
1
0.66
19
16
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
16
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
16
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
5.83
3
1
0.5
1
328.15
5
1
5.56
3
1
0.48
1
338.15
5
1
5.33
3
1
0.46
1
348.15
5
1
5.16
3
1
0.45
1
358.15
5
1
4.93
3
1
0.43
20
17
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
17
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
17
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
13.3
3
1
1.2
1
328.15
5
1
12.6
3
1
1.1
1
338.15
5
1
11.9
3
1
1
1
348.15
5
1
11.4
3
1
1
1
358.15
5
1
10.9
3
1
0.9
21
18
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
18
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
18
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
19.6
3
1
1.7
1
328.15
5
1
18.3
3
1
1.6
1
338.15
5
1
17.1
3
1
1.5
1
348.15
5
1
16.2
3
1
1.4
1
358.15
5
1
15.2
3
1
1.3
22
19
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
19
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
19
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
40.4
3
1
3.5
1
328.15
5
1
37.4
3
1
3.2
1
338.15
5
1
34.4
3
1
3
1
348.15
5
1
32.2
3
1
2.8
1
358.15
5
1
29.8
3
1
2.6
23
20
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
20
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
20
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
2.15
3
1
0.19
1
328.15
5
1
2.17
3
1
0.19
1
338.15
5
1
2.18
3
1
0.19
1
348.15
5
1
2.19
3
1
0.19
1
358.15
5
1
2.21
3
1
0.19
24
21
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
21
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
21
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
3.11
3
1
0.27
1
328.15
5
1
3.11
3
1
0.27
1
338.15
5
1
3.1
3
1
0.27
1
348.15
5
1
3.1
3
1
0.27
1
358.15
5
1
3.08
3
1
0.27
25
22
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
22
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
22
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
4.47
3
1
0.39
1
328.15
5
1
4.43
3
1
0.38
1
338.15
5
1
4.39
3
1
0.38
1
348.15
5
1
4.35
3
1
0.38
1
358.15
5
1
4.29
3
1
0.37
26
23
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
23
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
23
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
6.47
3
1
0.56
1
328.15
5
1
6.36
3
1
0.55
1
338.15
5
1
6.21
3
1
0.54
1
348.15
5
1
6.11
3
1
0.53
1
358.15
5
1
5.97
3
1
0.52
27
24
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
24
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
24
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
1.03
3
1
0.08
1
328.15
5
1
1.04
3
1
0.09
1
338.15
5
1
1.05
3
1
0.09
1
348.15
5
1
1.07
3
1
0.09
1
358.15
5
1
1.07
3
1
0.09
28
25
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
25
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
25
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
1.47
3
1
0.12
1
328.15
5
1
1.48
3
1
0.13
1
338.15
5
1
1.5
3
1
0.13
1
348.15
5
1
1.52
3
1
0.13
1
358.15
5
1
1.53
3
1
0.13
29
26
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
26
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
26
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
2.24
3
1
0.19
1
328.15
5
1
2.25
3
1
0.19
1
338.15
5
1
2.26
3
1
0.19
1
348.15
5
1
2.28
3
1
0.2
1
358.15
5
1
2.29
3
1
0.2
30
27
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
27
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
27
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
1.93
3
1
0.17
1
328.15
5
1
1.94
3
1
0.17
1
338.15
5
1
1.95
3
1
0.17
1
348.15
5
1
1.96
3
1
0.17
1
358.15
5
1
1.97
3
1
0.17
31
28
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
28
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
28
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
2.12
3
1
0.18
1
328.15
5
1
2.14
3
1
0.18
1
338.15
5
1
2.14
3
1
0.18
1
348.15
5
1
2.17
3
1
0.19
1
358.15
5
1
2.18
3
1
0.19
32
29
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
29
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
29
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
2.12
3
1
0.18
1
328.15
5
1
2.15
3
1
0.19
1
338.15
5
1
2.15
3
1
0.19
1
348.15
5
1
2.17
3
1
0.19
1
358.15
5
1
2.18
3
1
0.19
33
30
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
30
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
30
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
1.3
3
1
0.11
1
328.15
5
1
1.3
3
1
0.11
1
338.15
5
1
1.31
3
1
0.11
1
348.15
5
1
1.34
3
1
0.11
1
358.15
5
1
1.36
3
1
0.11
34
31
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
31
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
31
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
1.33
3
1
0.11
1
328.15
5
1
1.26
3
1
0.11
1
338.15
5
1
1.15
3
1
0.1
1
348.15
5
1
1.09
3
1
0.09
1
358.15
5
1
1.01
3
1
0.08
35
32
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
32
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
32
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
1.77
3
1
0.15
1
328.15
5
1
1.62
3
1
0.14
1
338.15
5
1
1.5
3
1
0.13
1
348.15
5
1
1.38
3
1
0.12
1
358.15
5
1
1.28
3
1
0.11
36
33
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
33
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
33
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
2.26
3
1
0.19
1
328.15
5
1
2.04
3
1
0.18
1
338.15
5
1
1.87
3
1
0.16
1
348.15
5
1
1.72
3
1
0.15
1
358.15
5
1
1.59
3
1
0.13
37
34
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
34
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
34
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
2.04
3
1
0.18
1
328.15
5
1
1.84
3
1
0.16
1
338.15
5
1
1.7
3
1
0.14
1
348.15
5
1
1.56
3
1
0.13
1
358.15
5
1
1.44
3
1
0.12
38
35
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
35
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
35
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
2.96
3
1
0.26
1
328.15
5
1
2.63
3
1
0.23
1
338.15
5
1
2.39
3
1
0.21
1
348.15
5
1
2.18
3
1
0.19
1
358.15
5
1
2
3
1
0.17
39
36
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
36
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
36
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
1.9
3
1
0.16
1
328.15
5
1
1.73
3
1
0.15
1
338.15
5
1
1.6
3
1
0.14
1
348.15
5
1
1.46
3
1
0.12
1
358.15
5
1
1.32
3
1
0.11
40
37
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
37
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
37
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
0.906
3
1
0.075
1
328.15
5
1
0.912
3
1
0.075
1
338.15
5
1
0.925
3
1
0.076
1
348.15
5
1
0.937
3
1
0.077
1
358.15
5
1
0.94
3
1
0.077
41
38
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
38
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
38
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
0.817
3
1
0.068
1
328.15
5
1
0.83
3
1
0.069
1
338.15
5
1
0.845
3
1
0.07
1
348.15
5
1
0.862
3
1
0.072
1
358.15
5
1
0.867
3
1
0.072
42
39
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
39
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
39
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
0.66
3
1
0.057
1
328.15
5
1
0.679
3
1
0.058
1
338.15
5
1
0.704
3
1
0.06
1
348.15
5
1
0.723
3
1
0.061
1
358.15
5
1
0.734
3
1
0.062
43
40
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
40
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
40
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
2.62
3
1
0.23
1
328.15
5
1
2.63
3
1
0.23
1
338.15
5
1
2.65
3
1
0.23
1
348.15
5
1
2.67
3
1
0.23
1
358.15
5
1
2.67
3
1
0.23
44
41
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
41
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
41
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
3.87
3
1
0.33
1
328.15
5
1
3.86
3
1
0.33
1
338.15
5
1
3.83
3
1
0.33
1
348.15
5
1
3.8
3
1
0.33
1
358.15
5
1
3.76
3
1
0.32
45
42
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
42
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
42
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
6.09
3
1
0.53
1
328.15
5
1
5.94
3
1
0.51
1
338.15
5
1
5.86
3
1
0.51
1
348.15
5
1
5.71
3
1
0.49
1
358.15
5
1
5.59
3
1
0.48
46
43
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
43
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
43
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
2.62
3
1
0.23
1
328.15
5
1
2.6
3
1
0.22
1
338.15
5
1
2.6
3
1
0.22
1
348.15
5
1
2.59
3
1
0.22
1
358.15
5
1
2.57
3
1
0.22
47
44
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
44
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
44
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
6.84
3
1
0.59
1
328.15
5
1
6.58
3
1
0.57
1
338.15
5
1
6.41
3
1
0.55
1
348.15
5
1
6.25
3
1
0.54
1
358.15
5
1
6.07
3
1
0.52
48
45
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
45
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
45
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
6.4
3
1
0.55
1
328.15
5
1
6.28
3
1
0.54
1
338.15
5
1
6.16
3
1
0.53
1
348.15
5
1
6.03
3
1
0.52
1
358.15
5
1
5.88
3
1
0.51
49
46
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
46
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
46
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
15.1
3
1
1.3
1
328.15
5
1
14.2
3
1
1.2
1
338.15
5
1
13.4
3
1
1.2
1
348.15
5
1
12.6
3
1
1.1
1
358.15
5
1
12
3
1
1
50
47
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
47
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
47
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
0.484
3
1
0.045
1
328.15
5
1
0.491
3
1
0.046
1
338.15
5
1
0.499
3
1
0.046
1
348.15
5
1
0.509
3
1
0.047
1
358.15
5
1
0.518
3
1
0.047
51
48
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
48
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
48
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
0.853
3
1
0.071
1
328.15
5
1
0.862
3
1
0.072
1
338.15
5
1
0.87
3
1
0.072
1
348.15
5
1
0.884
3
1
0.073
1
358.15
5
1
0.896
3
1
0.074
52
49
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
49
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
49
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
0.852
3
1
0.071
1
328.15
5
1
0.873
3
1
0.072
1
338.15
5
1
0.889
3
1
0.074
1
348.15
5
1
0.906
3
1
0.075
1
358.15
5
1
0.916
3
1
0.076
53
50
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
50
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
50
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
1.14
3
1
0.09
1
328.15
5
1
1.15
3
1
0.1
1
338.15
5
1
1.16
3
1
0.1
1
348.15
5
1
1.18
3
1
0.1
1
358.15
5
1
1.19
3
1
0.1
54
51
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
51
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
51
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
1.21
3
1
0.1
1
328.15
5
1
1.22
3
1
0.1
1
338.15
5
1
1.23
3
1
0.1
1
348.15
5
1
1.24
3
1
0.1
1
358.15
5
1
1.25
3
1
0.1
55
52
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
52
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
52
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
0.488
3
1
0.045
1
328.15
5
1
0.488
3
1
0.045
1
338.15
5
1
0.488
3
1
0.045
1
348.15
5
1
0.49
3
1
0.045
1
358.15
5
1
0.49
3
1
0.045
56
53
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
53
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
53
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
0.6
3
1
0.053
1
328.15
5
1
0.604
3
1
0.053
1
338.15
5
1
0.607
3
1
0.053
1
348.15
5
1
0.615
3
1
0.054
1
358.15
5
1
0.619
3
1
0.054
57
54
1
1
1
Principal objective of the work
PB
PB
5/26/2016
1
Activity coefficient
Chromatography
54
Liquid
Direct value, X
Pure liquid solute
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Mole fraction
54
Liquid
0
1
2
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
318.15
5
1
0.78
3
1
0.066
1
328.15
5
1
0.778
3
1
0.065
1
338.15
5
1
0.775
3
1
0.065
1
348.15
5
1
0.772
3
1
0.065
1
358.15
5
1
0.77
3
1
0.065