ABSTRACT

The liquid-liquid coexistence curves for (dimethyl adipate + n-hexane), (dimethyl adipate + n-heptane) have been measured, from which the critical amplitudes and the critical exponents are deduced. The critical exponent beta corresponding to the coexistence curves are consistent with the 3D-Ising value. The experimental results have also been analyzed to determine the critical amplitudes of Wegner-correction terms when beta and delta are fixed at their theoretical values, and to examine the asymmetry of the diameters for the coexistence curves.

Compounds

#	Formula	Name
1	C8H14O4	dimethyl 1,6-hexanedioate
2	C7H16	heptane
3	C6H14	hexane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	28
POMD	1	Refractive index (other wavelength) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid Wavelength, nm; Liquid	Liquid	Standard Abbe refractometry	7
POMD	3	Refractive index (other wavelength) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid Wavelength, nm; Liquid	Liquid	Standard Abbe refractometry	7
POMD	2 1	Critical temperature, K ; Liquid	Mole fraction - 1; Liquid		Liquid Gas	Visual observation in an unstirred cell	1
POMD	2 1	Mole fraction - 1 ; Liquid mixture 1	Temperature, K; Liquid mixture 1	Pressure, kPa; Liquid mixture 1	Liquid mixture 1 Liquid mixture 2	Index of refraction calibration data	33
POMD	2 1	Mole fraction - 1 ; Liquid mixture 2	Temperature, K; Liquid mixture 1	Pressure, kPa; Liquid mixture 1	Liquid mixture 2 Liquid mixture 1	Index of refraction calibration data	33
POMD	2 1	Refractive index (other wavelength) ; Liquid	Mole fraction - 1; Liquid Temperature, K; Liquid	Pressure, kPa; Liquid Wavelength, nm; Liquid	Liquid	Standard Abbe refractometry	62
POMD	3 1	Refractive index (other wavelength) ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid Wavelength, nm; Liquid	Liquid	Standard Abbe refractometry	9
POMD	3 1	Critical temperature, K ; Liquid	Mole fraction - 1; Liquid		Liquid Gas	Visual observation in an unstirred cell	1
POMD	3 1	Mole fraction - 1 ; Liquid mixture 1	Temperature, K; Liquid mixture 1	Pressure, kPa; Liquid mixture 1	Liquid mixture 1 Liquid mixture 2	Index of refraction calibration data	34
POMD	3 1	Mole fraction - 1 ; Liquid mixture 2	Temperature, K; Liquid mixture 1	Pressure, kPa; Liquid mixture 1	Liquid mixture 2 Liquid mixture 1	Index of refraction calibration data	34

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

The liquid-liquid coexistence curves of {x dimethyl adipate + (1 - x) n-hexane} and {x dimethyl adipate + (1 - x) n-heptane} in the critical region

Chen, Z.[Zhiyun], Cai, L.[Li], Huang, M.[Meijun], Yin, T.[Tianxiang], An, X.[Xueqin], Shen, W.[Weiguo]

ABSTRACT