2
0
2009
tam
li
0
journal
Original
Tamura, K.[Kazuhiro]
Li, X.[Xiaoli]
Li, H.[Hengde]
J. Chem. Thermodyn.
2009
2020-09-29
Temperature dependence on mutual solubility of binary (methanol + limonene) mixture and (liquid + liquid) equilibria of ternary (methanol + ethanol + limonene) mixture
Mutual solubility data of the binary (methanol + limonene) mixture at the temperatures ranging from 288.15 K close to upper critical solution temperature, and ternary (liquid + liquid) equilibrium (tie-lines) of the (methanol + ethanol + limonene) mixture at the temperatures (288.15, 298.15, and 308.15) K have been obtained. The experimental results have been represented accurately in terms of the extended and modified UNIQUAC models with binary parameters, compared with the UNIQUAC model. The temperature dependence of binary and ternary (liquid + liquid) equilibrium for the binary (methanol + limonene) and ternary (methanol + ethanol + limonene) mixtures could be calculated successfully using the extended and modified UNIQUAC model.
(Liquid + liquid) equilibria (LLE)
Limonene
Alcohol
UNIQUAC model
10.1016/j.jct.2008.10.013
4
41
564-568
1
InChI=1S/C10H16/c1-8(2)10-6-4-9(3)5-7-10/h4,10H,1,5-7H2,2-3H3/t10-/m0/s1
XMGQYMWWDOXHJM-JTQLQIEISA-N
(R)-1-methyl-4-(1-methylethenyl)cyclohexene
(+)-(4R)-limonene
(+)-.alpha.-limonene
(+)-4-isopropenyl-1-methylcyclohexene
(+)-dipentene
(+)-limonene
(+)-p-mentha-1,8-diene
(4R)-(+)-limonene
(R)-(+)-limonene
(R)-(+)-p-mentha-1,8-diene
(R)-4-isopropenyl-1-methyl-1-cyclohexene
(R)-limonene
(R)-p-mentha-1,8-diene
D-(+)-limonene
D-limonene
carvene
cyclohexene, 1-methyl-4-(1-methylethenyl)-, (R)-,
d-(+)-limonene
d-limonene
limonene, (+)-
p-mentha-1,8-diene, (R)-(+)-
C10H16
1
Commercial source
1
99
2
Stated by supplier
2
None used
2
InChI=1S/CH4O/c1-2/h2H,1H3
OKKJLVBELUTLKV-UHFFFAOYSA-N
methanol
methyl alcohol
CH4O
1
Commercial source
1
99.7
3
Stated by supplier
2
None used
3
InChI=1S/C2H6O/c1-2-3/h3H,2H2,1H3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N
ethanol
ethyl alcohol
C2H6O
1
Commercial source
1
99.5
3
Stated by supplier
2
None used
1
1
1
Principal objective of the work
WZ
TRC
4/3/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.325
6
1
837.31
5
1
0.31
2
2
1
Principal objective of the work
WZ
TRC
4/3/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.325
6
1
786.62
5
1
0.17
3
3
1
Principal objective of the work
WZ
TRC
4/3/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.325
6
1
785.24
5
1
0.19
4
2
1
1
1
Principal objective of the work
WZ
TRC
4/3/2009
1
Mole fraction
Chromatography
2
Liquid mixture 2
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid mixture 2
Liquid mixture 1
1
Pressure, kPa
Liquid mixture 1
101
3
1
Temperature, K
Liquid mixture 1
1
288.15
5
1
0.2076
4
1
0.0021
1
293.3
5
1
0.2317
4
1
0.0023
1
298.15
5
1
0.2769
4
1
0.0028
1
302.94
5
1
0.3128
4
1
0.0031
1
308.15
5
1
0.3839
4
1
0.0038
1
312.14
5
1
0.4712
4
1
0.0047
1
313.37
5
1
0.5473
4
1
0.0045
5
2
1
1
1
Principal objective of the work
WZ
TRC
4/3/2009
1
Mole fraction
Chromatography
2
Liquid mixture 1
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid mixture 1
Liquid mixture 2
1
Pressure, kPa
Liquid mixture 1
101
3
1
Temperature, K
Liquid mixture 1
1
288.15
5
1
0.9062
4
1
0.0009
1
293.3
5
1
0.8957
4
1
0.001
1
298.15
5
1
0.8819
4
1
0.0012
1
302.94
5
1
0.8626
4
1
0.0014
1
308.15
5
1
0.8381
4
1
0.0016
1
312.14
5
1
0.8115
4
1
0.0019
1
313.37
5
1
0.7889
4
1
0.0021
6
3
1
2
1
1
1
Principal objective of the work
JWM
TRC
4/3/2009
1
Mole fraction
Chromatography
3
Liquid mixture 2
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
2
Mole fraction
Chromatography
3
Liquid mixture 1
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
3
Mole fraction
Chromatography
2
Liquid mixture 1
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid mixture 2
Liquid mixture 1
1
Pressure, kPa
Liquid mixture 1
101
3
1
Temperature, K
Liquid mixture 1
2
Mole fraction
2
Liquid mixture 2
1
288.15
5
2
0.2256
4
1
0.0152
3
1
0.0002
2
0.0422
3
1
0.0004
3
0.8452
4
1
288.15
5
2
0.2484
4
1
0.0318
3
1
0.0003
2
0.0882
3
1
0.0009
3
0.7784
4
1
288.15
5
2
0.2705
4
1
0.0557
3
1
0.0006
2
0.1239
4
1
0.0012
3
0.7176
4
1
288.15
5
2
0.372
4
1
0.0841
3
1
0.0008
2
0.1333
4
1
0.0013
3
0.6271
4
1
288.15
5
2
0.4002
4
1
0.101
4
1
0.001
2
0.1403
4
1
0.0014
3
0.5923
4
1
298.15
5
2
0.2715
4
1
0.0082
2
1
0.0001
2
0.0271
3
1
0.0003
3
0.8534
4
1
298.15
5
2
0.2844
4
1
0.0168
3
1
0.0002
2
0.0429
3
1
0.0004
3
0.8261
4
1
298.15
5
2
0.3422
4
1
0.0362
3
1
0.0004
2
0.0728
3
1
0.0007
3
0.748
4
1
298.15
5
2
0.4508
4
1
0.0758
3
1
0.0008
2
0.1097
4
1
0.0011
3
0.6301
4
1
308.15
5
2
0.4105
4
1
0.0053
2
1
0.0001
2
0.0099
2
1
0.0001
3
0.8182
4
1
308.15
5
2
0.433
4
1
0.0132
3
1
0.0001
2
0.0217
3
1
0.0002
3
0.784
4
1
308.15
5
2
0.4524
4
1
0.0157
3
1
0.0002
2
0.0234
3
1
0.0002
3
0.7741
4
1
308.15
5
2
0.4719
4
1
0.0235
3
1
0.0002
2
0.0247
3
1
0.0003
3
0.756
4