2
0
2009
zor
lub
0
journal
Original
Zorebski, E.[Edward]
Lubowiecka-Kostka, B.[Beata]
J. Chem. Thermodyn.
2009
2020-09-29
Thermodynamic and transport properties of (1,2-ethanediol + 1-nonanol) at temperatures from (298.15 to 313.15) K
Densities and kinematic viscosities have been measured for (1,2-ethanediol + 1-nonanol) over the temperature range from (298.15 to 313.15) K. The speeds of sound in those mixtures within the temperature range from (293.15 to 313.15) K have been measured as well. Using the measurement results, the molar volumes, isentropic compressibility coefficients, molar isentropic compressibilities, and the corresponding excess and deviation values (excess molar volumes, excess isentropic compressibility coefficients, excess molar isentropic compressibilities, differently defined deviations of the speed of sound, and dynamic viscosity deviations) were calculated. The excess Gibbs free energies estimated by the use of the UNIQUAC model are also reported. The excess molar volumes and Gibbs free energies are positive, whereas the compressibility excesses are s-shaped. The excess and deviation values are expressed by Redlich Kister polynomials and discussed in terms of variations of the structure of the system caused by the participation of two different alcohol molecules in the dynamic intermolecular association process through hydrogen bonding. The effect of temperature is discussed. The predictive abilities of the McAllister equation for viscosities of the mixtures under test have also been examined.
Density
Speed of sound
Compressibility
Viscosity
Excess
Alcohols
Binary mixtures
10.1016/j.jct.2008.09.018
2
41
197-204
1
InChI=1S/C2H6O2/c3-1-2-4/h3-4H,1-2H2
LYCAIKOWRPUZTN-UHFFFAOYSA-N
1,2-ethanediol
1,2-dihydroxyethane
ethane-1,2-diol
ethylene glycol
C2H6O2
1
Commercial source
1
De-gassed by boiling or ultrasonically
2
99.5
3
Gas chromatography
3
0.1
1
Gas chromatography
2
InChI=1S/C9H20O/c1-2-3-4-5-6-7-8-9-10/h10H,2-9H2,1H3
ZWRUINPWMLAQRD-UHFFFAOYSA-N
nonan-1-ol
1-nonanol
nonanol
nonyl alcohol
C9H20O
1
Commercial source
1
De-gassed by boiling or ultrasonically
2
99
2
Gas chromatography
3
0.1
1
Gas chromatography
1
1
1
Principal objective of the work
KRP
TRC
3/21/2009
1
Refractive index (Na D-line)
Standard Abbe refractometry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.325
6
1
1.4307
5
1
0.0005
2
1
1
Principal objective of the work
KRP
TRC
3/21/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.325
6
1
1109.88
6
1
0.21
3
1
1
Principal objective of the work
KRP
TRC
3/21/2009
1
Viscosity, Pa*s
Capillary tube (Ostwald; Ubbelohde) method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.325
6
1
0.016952
5
1
0.000145
4
1
1
Principal objective of the work
KRP
TRC
3/21/2009
1
Speed of sound, m/s
Pulse-echo method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.325
6
1
1654.89
6
1
1.42
5
1
1
Principal objective of the work
KRP
TRC
3/21/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
283.153
6
1
1120.323
7
1
0.177
1
285.644
6
1
1118.599
7
1
0.176
1
288.145
6
1
1116.86
7
1
0.176
1
290.645
6
1
1115.118
7
1
0.175
1
293.143
6
1
1113.372
7
1
0.175
1
295.644
6
1
1111.624
7
1
0.174
1
298.143
6
1
1109.875
7
1
0.173
1
300.649
6
1
1108.124
7
1
0.173
1
303.146
6
1
1106.365
7
1
0.173
1
305.645
6
1
1104.605
7
1
0.172
1
308.145
6
1
1102.84
7
1
0.171
1
310.646
6
1
1101.073
7
1
0.171
1
313.145
6
1
1099.298
7
1
0.171
1
315.646
6
1
1097.518
7
1
0.17
1
318.145
6
1
1095.736
7
1
0.17
1
320.644
6
1
1093.95
7
1
0.169
1
323.147
6
1
1092.155
7
1
0.169
6
1
1
Principal objective of the work
JWM
TRC
3/21/2009
1
Viscosity, Pa*s
Capillary tube (Ostwald; Ubbelohde) method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
303.15
5
1
0.013834
5
1
0.000101
1
308.15
5
1
0.011444
5
1
8.3e-05
1
313.15
5
1
0.009565
4
1
7.1e-05
7
1
1
Principal objective of the work
JWM
TRC
3/21/2009
1
Speed of sound, m/s
Pulse-echo method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
293.15
5
1
1666.65
6
1
1.36
1
303.15
5
1
1643.08
6
1
1.35
1
308.15
5
1
1631.21
6
1
1.35
1
313.15
5
1
1619.31
6
1
1.35
8
1
1
Principal objective of the work
JWM
TRC
3/21/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
303.15
5
1
1106.46
6
1
0.17
1
308.15
5
1
1102.9
6
1
0.17
1
313.15
5
1
1099.23
6
1
0.17
9
2
1
Principal objective of the work
KRP
TRC
3/21/2009
1
Refractive index (Na D-line)
Standard Abbe refractometry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.325
6
1
1.4323
5
1
0.0005
10
2
1
Principal objective of the work
KRP
TRC
3/21/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.325
6
1
824.48
5
1
0.26
11
2
1
Principal objective of the work
KRP
TRC
3/21/2009
1
Viscosity, Pa*s
Capillary tube (Ostwald; Ubbelohde) method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.325
6
1
0.009494
4
1
8.4e-05
12
2
1
Principal objective of the work
KRP
TRC
3/21/2009
1
Speed of sound, m/s
Pulse-echo method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Temperature, K
Liquid
2
Pressure, kPa
Liquid
1
298.15
5
2
101.325
6
1
1364.41
6
1
1.62
13
2
1
Principal objective of the work
KRP
TRC
3/21/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
283.15
6
1
834.614
6
1
0.246
1
285.644
6
1
832.923
6
1
0.246
1
288.146
6
1
831.224
6
1
0.246
1
290.646
6
1
829.521
6
1
0.246
1
293.144
6
1
827.816
6
1
0.246
1
295.645
6
1
826.106
6
1
0.247
1
298.144
6
1
824.391
6
1
0.247
1
300.646
6
1
822.671
6
1
0.247
1
303.145
6
1
820.949
6
1
0.247
1
305.645
6
1
819.22
6
1
0.247
1
308.144
6
1
817.486
6
1
0.247
1
310.645
6
1
815.748
6
1
0.248
1
313.147
6
1
814.001
6
1
0.248
1
315.646
6
1
812.251
6
1
0.248
1
318.146
6
1
810.496
6
1
0.248
1
320.646
6
1
808.73
6
1
0.248
1
323.146
6
1
806.96
6
1
0.249
14
2
1
Principal objective of the work
JWM
TRC
3/21/2009
1
Viscosity, Pa*s
Capillary tube (Ostwald; Ubbelohde) method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
303.15
5
1
0.007994
4
1
6.8e-05
1
308.15
5
1
0.006713
4
1
5.7e-05
1
313.15
5
1
0.005657
4
1
5e-05
15
2
1
Principal objective of the work
JWM
TRC
3/21/2009
1
Speed of sound, m/s
Pulse-echo method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
293.15
5
1
1381.62
6
1
1.59
1
303.15
5
1
1347.42
6
1
1.58
1
308.15
5
1
1330.45
6
1
1.58
1
313.15
5
1
1313.64
6
1
1.57
16
2
1
Principal objective of the work
JWM
TRC
3/21/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
303.15
5
1
821.05
5
1
0.25
1
308.15
5
1
817.57
5
1
0.25
1
313.15
5
1
814.19
5
1
0.25
17
1
1
2
1
Principal objective of the work
KRP
TRC
3/21/2009
1
Viscosity, Pa*s
Capillary tube (Ostwald; Ubbelohde) method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Mole fraction
1
Liquid
2
Temperature, K
Liquid
1
0
2
2
298.15
5
1
0.009494
4
1
7.9e-05
1
0
2
2
303.15
5
1
0.007994
4
1
6.8e-05
1
0
2
2
308.15
5
1
0.006713
4
1
5.7e-05
1
0
2
2
313.15
5
1
0.005657
4
1
5e-05
1
0.10019
5
2
298.15
5
1
0.009581
4
1
7.9e-05
1
0.10019
5
2
303.15
5
1
0.008014
4
1
6.7e-05
1
0.10019
5
2
308.15
5
1
0.006801
4
1
5.7e-05
1
0.10019
5
2
313.15
5
1
0.005782
4
1
4.9e-05
1
0.19791
5
2
298.15
5
1
0.010006
5
1
8.1e-05
1
0.19791
5
2
303.15
5
1
0.008359
4
1
6.9e-05
1
0.19791
5
2
308.15
5
1
0.007044
4
1
5.8e-05
1
0.19791
5
2
313.15
5
1
0.005984
4
1
5e-05
1
0.29637
5
2
298.15
5
1
0.010668
5
1
8.4e-05
1
0.29637
5
2
303.15
5
1
0.008897
4
1
7.2e-05
1
0.29637
5
2
308.15
5
1
0.007487
4
1
6e-05
1
0.29637
5
2
313.15
5
1
0.006352
4
1
5.2e-05
1
0.36408
5
2
298.15
5
1
0.011256
5
1
8.8e-05
1
0.36408
5
2
303.15
5
1
0.00937
4
1
7.5e-05
1
0.36408
5
2
308.15
5
1
0.007872
4
1
6.3e-05
1
0.36408
5
2
313.15
5
1
0.006667
4
1
5.4e-05
1
0.45332
5
2
298.15
5
1
0.012222
5
1
9.4e-05
1
0.45332
5
2
303.15
5
1
0.010138
5
1
8e-05
1
0.45332
5
2
308.15
5
1
0.008493
4
1
6.7e-05
1
0.45332
5
2
313.15
5
1
0.007176
4
1
5.7e-05
1
0.54316
5
2
298.15
5
1
0.01341
5
1
0.000102
1
0.54316
5
2
303.15
5
1
0.011086
5
1
8.6e-05
1
0.54316
5
2
308.15
5
1
0.009257
4
1
7.1e-05
1
0.54316
5
2
313.15
5
1
0.007796
4
1
6.1e-05
1
0.64413
5
2
298.15
5
1
0.015091
5
1
0.000114
1
0.64413
5
2
303.15
5
1
0.012402
5
1
9.5e-05
1
0.64413
5
2
308.15
5
1
0.010308
5
1
7.8e-05
1
0.64413
5
2
313.15
5
1
0.00865
4
1
6.7e-05
1
0.75168
5
2
298.15
5
1
0.017316
5
1
0.000123
1
0.75168
5
2
303.15
5
1
0.014125
5
1
0.000107
1
0.75168
5
2
308.15
5
1
0.011655
5
1
8.7e-05
1
0.75168
5
2
313.15
5
1
0.009722
4
1
7.7e-05
1
0.93084
5
2
298.15
5
1
0.019276
5
1
0.000127
1
0.93084
5
2
303.15
5
1
0.015472
5
1
0.000116
1
0.93084
5
2
308.15
5
1
0.012667
5
1
9.4e-05
1
0.93084
5
2
313.15
5
1
0.010467
5
1
8.6e-05
1
1
1
2
298.15
5
1
0.016952
5
1
0.00012
1
1
1
2
303.15
5
1
0.013834
5
1
0.000101
1
1
1
2
308.15
5
1
0.011444
5
1
8.3e-05
1
1
1
2
313.15
5
1
0.009565
4
1
7.1e-05
18
1
1
2
1
Principal objective of the work
KRP
TRC
3/21/2009
1
Speed of sound, m/s
Pulse-echo method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Mole fraction
1
Liquid
2
Temperature, K
Liquid
1
0
2
2
293.15
5
1
1381.62
6
1
1.59
1
0
2
2
298.15
5
1
1364.41
6
1
1.58
1
0
2
2
303.15
5
1
1347.42
6
1
1.58
1
0
2
2
308.15
5
1
1330.45
6
1
1.58
1
0
2
2
313.15
5
1
1313.64
6
1
1.57
1
0.10019
5
2
293.15
5
1
1383.89
6
1
1.56
1
0.10019
5
2
298.15
5
1
1366.81
6
1
1.55
1
0.10019
5
2
303.15
5
1
1349.96
6
1
1.55
1
0.10019
5
2
308.15
5
1
1333.17
6
1
1.55
1
0.10019
5
2
313.15
5
1
1316.5
6
1
1.54
1
0.19791
5
2
293.15
5
1
1387.19
6
1
1.53
1
0.19791
5
2
298.15
5
1
1370.28
6
1
1.52
1
0.19791
5
2
303.15
5
1
1353.64
6
1
1.52
1
0.19791
5
2
308.15
5
1
1337.06
6
1
1.52
1
0.19791
5
2
313.15
5
1
1320.61
6
1
1.51
1
0.29637
5
2
293.15
5
1
1391.87
6
1
1.5
1
0.29637
5
2
298.15
5
1
1375.22
6
1
1.49
1
0.29637
5
2
303.15
5
1
1358.79
6
1
1.49
1
0.29637
5
2
308.15
5
1
1342.41
6
1
1.49
1
0.29637
5
2
313.15
5
1
1326.27
6
1
1.48
1
0.36408
5
2
293.15
5
1
1396.23
6
1
1.48
1
0.36408
5
2
298.15
5
1
1379.84
6
1
1.47
1
0.36408
5
2
303.15
5
1
1363.55
6
1
1.47
1
0.36408
5
2
308.15
5
1
1347.35
6
1
1.47
1
0.36408
5
2
313.15
5
1
1331.26
6
1
1.46
1
0.45332
5
2
293.15
5
1
1403.72
6
1
1.46
1
0.45332
5
2
298.15
5
1
1387.6
6
1
1.45
1
0.45332
5
2
303.15
5
1
1371.52
6
1
1.45
1
0.45332
5
2
308.15
5
1
1355.6
6
1
1.44
1
0.45332
5
2
313.15
5
1
1339.81
6
1
1.44
1
0.54316
5
2
293.15
5
1
1414.22
6
1
1.44
1
0.54316
5
2
298.15
5
1
1398.42
6
1
1.43
1
0.54316
5
2
303.15
5
1
1382.68
6
1
1.42
1
0.54316
5
2
308.15
5
1
1367.07
6
1
1.42
1
0.54316
5
2
313.15
5
1
1351.57
6
1
1.41
1
0.64413
5
2
293.15
5
1
1431.52
6
1
1.42
1
0.64413
5
2
298.15
5
1
1416.15
6
1
1.4
1
0.64413
5
2
303.15
5
1
1400.85
6
1
1.4
1
0.64413
5
2
308.15
5
1
1385.61
6
1
1.4
1
0.64413
5
2
313.15
5
1
1370.44
6
1
1.38
1
0.75168
5
2
293.15
5
1
1460.22
6
1
1.48
1
0.75168
5
2
298.15
5
1
1445.44
6
1
1.38
1
0.75168
5
2
303.15
5
1
1430.69
6
1
1.38
1
0.75168
5
2
308.15
5
1
1416.1
6
1
1.37
1
0.75168
5
2
313.15
5
1
1401.61
6
1
1.34
1
0.93084
5
2
293.15
5
1
1571.1
6
1
1.52
1
0.93084
5
2
298.15
5
1
1558.45
6
1
1.35
1
0.93084
5
2
303.15
5
1
1545.69
6
1
1.35
1
0.93084
5
2
308.15
5
1
1532.94
6
1
1.35
1
0.93084
5
2
313.15
5
1
1520.28
6
1
1.34
1
1
1
2
293.15
5
1
1666.65
6
1
1.36
1
1
1
2
298.15
5
1
1654.89
6
1
1.35
1
1
1
2
303.15
5
1
1643.08
6
1
1.35
1
1
1
2
308.15
5
1
1631.21
6
1
1.35
1
1
1
2
313.15
5
1
1619.31
6
1
1.35
19
1
1
2
1
Principal objective of the work
KRP
TRC
3/21/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Mole fraction
1
Liquid
2
Temperature, K
Liquid
1
0
2
2
298.15
5
1
824.48
5
1
0.25
1
0
2
2
303.15
5
1
821.05
5
1
0.25
1
0
2
2
308.15
5
1
817.57
5
1
0.25
1
0
2
2
313.15
5
1
814.19
5
1
0.25
1
0.10019
5
2
298.15
5
1
833.41
5
1
0.24
1
0.10019
5
2
303.15
5
1
830.02
5
1
0.23
1
0.10019
5
2
308.15
5
1
826.58
5
1
0.24
1
0.10019
5
2
313.15
5
1
823.15
5
1
0.23
1
0.19791
5
2
298.15
5
1
843.96
5
1
0.23
1
0.19791
5
2
303.15
5
1
840.61
5
1
0.22
1
0.19791
5
2
308.15
5
1
837.18
5
1
0.22
1
0.19791
5
2
313.15
5
1
833.73
5
1
0.22
1
0.29637
5
2
298.15
5
1
856.32
5
1
0.22
1
0.29637
5
2
303.15
5
1
852.92
5
1
0.21
1
0.29637
5
2
308.15
5
1
849.41
5
1
0.21
1
0.29637
5
2
313.15
5
1
845.93
5
1
0.21
1
0.36408
5
2
298.15
5
1
866.44
5
1
0.21
1
0.36408
5
2
303.15
5
1
863
5
1
0.21
1
0.36408
5
2
308.15
5
1
859.49
5
1
0.21
1
0.36408
5
2
313.15
5
1
855.98
5
1
0.2
1
0.45332
5
2
298.15
5
1
881.71
5
1
0.21
1
0.45332
5
2
303.15
5
1
878.3
5
1
0.2
1
0.45332
5
2
308.15
5
1
874.74
5
1
0.2
1
0.45332
5
2
313.15
5
1
871.22
5
1
0.19
1
0.54316
5
2
298.15
5
1
900.44
5
1
0.2
1
0.54316
5
2
303.15
5
1
896.94
5
1
0.19
1
0.54316
5
2
308.15
5
1
893.37
5
1
0.19
1
0.54316
5
2
313.15
5
1
889.84
5
1
0.18
1
0.64413
5
2
298.15
5
1
926.38
5
1
0.19
1
0.64413
5
2
303.15
5
1
922.82
5
1
0.18
1
0.64413
5
2
308.15
5
1
919.23
5
1
0.18
1
0.64413
5
2
313.15
5
1
915.68
5
1
0.17
1
0.701
5
2
298.15
5
1
944.22
5
1
0.18
1
0.701
5
2
303.15
5
1
940.61
5
1
0.17
1
0.701
5
2
308.15
5
1
937.01
5
1
0.17
1
0.701
5
2
313.15
5
1
933.39
5
1
0.17
1
0.75168
5
2
298.15
5
1
963.14
5
1
0.21
1
0.75168
5
2
303.15
5
1
959.57
5
1
0.17
1
0.75168
5
2
308.15
5
1
956
5
1
0.17
1
0.75168
5
2
313.15
5
1
952.37
5
1
0.16
1
0.93084
5
2
298.15
5
1
1055.33
6
1
0.29
1
0.93084
5
2
303.15
5
1
1051.63
6
1
0.17
1
0.93084
5
2
308.15
5
1
1048.12
6
1
0.17
1
0.93084
5
2
313.15
5
1
1044.52
6
1
0.18
1
1
1
2
298.15
5
1
1109.88
6
1
0.17
1
1
1
2
303.15
5
1
1106.46
6
1
0.17
1
1
1
2
308.15
5
1
1102.9
6
1
0.17
1
1
1
2
313.15
5
1
1099.23
6
1
0.17