2
0
2009
gar
tro
1
journal
Original
Garcia-Miaja, G.[Gonzalo]
Troncoso, J.[Jacobo]
Romani, L.[Luis]
J. Chem. Thermodyn.
2009
2020-09-29
Excess molar properties for binary systems of alkylimidazolium-based ionic liquids + nitromethane. Experimental results and ERAS-model calculations
Density, isobaric molar heat capacity, and excess molar enthalpy were experimentally determined at atmospheric pressure for a set of binary systems ionic liquid + nitromethane. The studied ionic liquids were: 1-butyl-3-methylimidazolium tetrafluoroborate, 1-hexyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylpyridinium tetrafluoroborate, 1-ethyl-3-methylimidazolium ethylsulfate, 1-butyl-3- methylimidazolium methylsulfate, 1-ethyl-3-methylimidazolium trifluoromethanesulfonate, and 1- butyl-3-methylimidazolium trifluoromethanesulfonate. Density and heat capacity were obtained within the temperature range (293.15 to 318.15) K whereas excess molar enthalpy was measured at 303.15 K; excess molar volume and excess molar isobaric heat capacity were calculated from experimental data. The ERAS-model was applied in order to study the microscopic mechanisms involved in the mixing process. Although the studied compounds are not self-associated, ERAS-model describe adequately the experimental results if cross-association between both compounds is considered.
Excess molar enthalpy Isobaric molar heat capacity Ionic liquid Nitromethane ERAS
10.1016/j.jct.2008.09.002
3
41
334-341
1
InChI=1S/C8H15N2.BF4/c1-3-4-5-10-7-6-9(2)8-10;2-1(3,4)5/h6-8H,3-5H2,1-2H3;/q+1;-1
LSBXQLQATZTAPE-UHFFFAOYSA-N
1-butyl-3-methylimidazolium tetrafluoroborate
1-butyl-3-methyl-1H-imidazol-3-ium tetrafluoroborate
1-butyl-3-methylimidazolium tetrafluoroborate [BMIM][BF4]
1-n-butyl-3-methylimidazolium tetrafluoroborate
C8H15BF4N2
1
Commercial source
1
Dried by vacuum heating
2
0.13
2
Karl Fischer titration
3
98
2
Estimated by the compiler
2
InChI=1S/C10H19N2.BF4/c1-3-4-5-6-7-12-9-8-11(2)10-12;2-1(3,4)5/h8-10H,3-7H2,1-2H3;/q+1;-1
MFXLOVLEQJRXFP-UHFFFAOYSA-N
1-hexyl-3-methylimidazolium tetrafluoroborate
1-hexyl-3-methylimidazolium tetrafluoroborate [HMIM][BF4]
C10H19BF4N2
1
Commercial source
1
Dried by vacuum heating
2
0.13
2
Karl Fischer titration
3
98
2
Estimated by the compiler
3
InChI=1S/C6H11N2.C2H6O4S/c1-3-8-5-4-7(2)6-8;1-2-6-7(3,4)5/h4-6H,3H2,1-2H3;2H2,1H3,(H,3,4,5)/q+1;/p-1
VRFOKYHDLYBVAL-UHFFFAOYSA-M
1-ethyl-3-methylimidazolium ethyl sulfate
1-ethyl-3-methyl-1H-imidazol-3-ium ethyl sulfate
1-ethyl-3-methylimidazolium ethyl sulfate [EMIM][EtSO4]
C8H16N2O4S
1
Commercial source
1
Dried by vacuum heating
2
0.13
2
Karl Fischer titration
3
98
2
Estimated by the compiler
4
InChI=1S/C8H15N2.CH4O4S/c1-3-4-5-10-7-6-9(2)8-10;1-5-6(2,3)4/h6-8H,3-5H2,1-2H3;1H3,(H,2,3,4)/q+1;/p-1
MEMNKNZDROKJHP-UHFFFAOYSA-M
1-butyl-3-methylimidazolium methyl sulfate
1-butyl-3-methyl-1H-imidazolium methyl sulfate
1-butyl-3-methylimidazolium methyl sulfate [BMIM][MeSO4]
C9H18N2O4S
1
Commercial source
1
Dried by vacuum heating
2
0.13
2
Karl Fischer titration
3
98
2
Estimated by the compiler
5
InChI=1S/C6H11N2.CHF3O3S/c1-3-8-5-4-7(2)6-8;2-1(3,4)8(5,6)7/h4-6H,3H2,1-2H3;(H,5,6,7)/q+1;/p-1
ZPTRYWVRCNOTAS-UHFFFAOYSA-M
1-ethyl-3-methylimidazolium trifluoromethanesulfonate
1-ethyl-3-methyl-1H-imidazol-3-ium trifluoromethanesulfonate
1-ethyl-3-methylimidazolium triflate
C7H11F3N2O3S
1
Commercial source
1
Dried by vacuum heating
2
0.13
2
Karl Fischer titration
3
98
2
Estimated by the compiler
6
InChI=1S/C8H15N2.CHF3O3S/c1-3-4-5-10-7-6-9(2)8-10;2-1(3,4)8(5,6)7/h6-8H,3-5H2,1-2H3;(H,5,6,7)/q+1;/p-1
FRZPYEHDSAQGAS-UHFFFAOYSA-M
1-butyl-3-methylimidazolium trifluoromethanesulfonate
1-butyl-3-methylimidazolium 1,1,1-trifluoromethanesulfonate
1-butyl-3-methylimidazolium triflate
C9H15F3N2O3S
1
Commercial source
1
Dried by vacuum heating
2
0.13
2
Karl Fischer titration
3
98
2
Estimated by the compiler
7
InChI=1S/CH3NO2/c1-2(3)4/h1H3
LYGJENNIWJXYER-UHFFFAOYSA-N
nitromethane
nitrocarbol
nitromethane [NM]
CH3NO2
1
Commercial source
1
98.5
3
Stated by supplier
2
Molecular sieve treatment
8
InChI=1S/C10H16N.BF4/c1-3-4-7-11-8-5-6-10(2)9-11;2-1(3,4)5/h5-6,8-9H,3-4,7H2,1-2H3;/q+1;-1
UQEAMJVKASNOMA-UHFFFAOYSA-N
1-butyl-3-methylpyridinium tetrafluoroborate
C10H16BF4N
1
Commercial source
1
Dried by vacuum heating
2
0.13
2
Karl Fischer titration
3
98
2
Estimated by the compiler
1
1
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Molar heat capacity at constant pressure, J/K/mol
Small sample (50 mg) DSC
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
359.8
4
1
5.6
1
298.15
5
1
363.1
4
1
5.6
1
303.15
5
1
366.1
4
1
5.7
1
308.15
5
1
368.7
4
1
5.7
1
313.15
5
1
371
4
1
5.7
1
318.15
5
1
372.9
4
1
5.8
2
1
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Speed of sound, m/s
Anton-Paar DSA48 sound analyzer
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1594.9
5
1
2
1
298.15
5
1
1576.1
5
1
2
1
303.15
5
1
1555.5
5
1
2
1
308.15
5
1
1543.9
5
1
2
1
313.15
5
1
1532.5
5
1
2
1
318.15
5
1
1521.2
5
1
2
3
1
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1207.6
5
1
1.3
1
298.15
5
1
1204.1
5
1
1.3
1
303.15
5
1
1200.5
5
1
1.3
1
308.15
5
1
1197
5
1
1.3
1
313.15
5
1
1193.4
5
1
1.3
1
318.15
5
1
1189.9
5
1
1.3
4
2
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Molar heat capacity at constant pressure, J/K/mol
Small sample (50 mg) DSC
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
425.1
4
1
6.6
1
298.15
5
1
427.8
4
1
6.6
1
303.15
5
1
430.4
4
1
6.7
1
308.15
5
1
433
4
1
6.7
1
313.15
5
1
435.5
4
1
6.7
1
318.15
5
1
438.1
4
1
6.8
5
2
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Speed of sound, m/s
Anton-Paar DSA48 sound analyzer
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1532.7
5
1
2
1
298.15
5
1
1519.5
5
1
2
1
303.15
5
1
1506.9
5
1
2
1
308.15
5
1
1494.5
5
1
2
1
313.15
5
1
1482.3
5
1
2
1
318.15
5
1
1470.5
5
1
2
6
2
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1148.8
5
1
1.2
1
298.15
5
1
1145.3
5
1
1.1
1
303.15
5
1
1141.8
5
1
1.1
1
308.15
5
1
1138.4
5
1
1.1
1
313.15
5
1
1135
5
1
1.1
1
318.15
5
1
1131.6
5
1
1.1
7
3
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Molar heat capacity at constant pressure, J/K/mol
Small sample (50 mg) DSC
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
392.2
4
1
6.1
1
298.15
5
1
394.4
4
1
6.1
1
303.15
5
1
396.8
4
1
6.1
1
308.15
5
1
399.3
4
1
6.2
1
313.15
5
1
402
4
1
6.2
1
318.15
5
1
404.9
4
1
6.3
8
3
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Speed of sound, m/s
Anton-Paar DSA48 sound analyzer
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1691.4
5
1
2
1
298.15
5
1
1679
5
1
2
1
303.15
5
1
1666.6
5
1
2
1
308.15
5
1
1654
5
1
2
1
313.15
5
1
1641.6
5
1
2
1
318.15
5
1
1629.2
5
1
2
9
3
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1240.6
5
1
1.4
1
298.15
5
1
1237.2
5
1
1.4
1
303.15
5
1
1233.8
5
1
1.4
1
308.15
5
1
1230.4
5
1
1.3
1
313.15
5
1
1227
5
1
1.3
1
318.15
5
1
1223.7
5
1
1.3
10
4
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Molar heat capacity at constant pressure, J/K/mol
Small sample (50 mg) DSC
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
413.7
4
1
6.4
1
298.15
5
1
416.2
4
1
6.4
1
303.15
5
1
418.5
4
1
6.5
1
308.15
5
1
420.9
4
1
6.5
1
313.15
5
1
423.3
4
1
6.6
1
318.15
5
1
425.6
4
1
6.6
11
4
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Speed of sound, m/s
Anton-Paar DSA48 sound analyzer
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1670.9
5
1
2
1
298.15
5
1
1658.4
5
1
2
1
303.15
5
1
1646
5
1
2
1
308.15
5
1
1633.5
5
1
2
1
313.15
5
1
1621.1
5
1
2
1
318.15
5
1
1608.6
5
1
2
12
4
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1210.7
5
1
1.3
1
298.15
5
1
1207.4
5
1
1.3
1
303.15
5
1
1204.1
5
1
1.3
1
308.15
5
1
1200.8
5
1
1.3
1
313.15
5
1
1197.5
5
1
1.3
1
318.15
5
1
1194.2
5
1
1.3
13
5
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Molar heat capacity at constant pressure, J/K/mol
Small sample (50 mg) DSC
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
361.1
4
1
5.6
1
298.15
5
1
363.2
4
1
5.6
1
303.15
5
1
365.3
4
1
5.7
1
308.15
5
1
367.4
4
1
5.7
1
313.15
5
1
369.6
4
1
5.7
1
318.15
5
1
371.8
4
1
5.8
14
5
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Speed of sound, m/s
Anton-Paar DSA48 sound analyzer
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1447
5
1
2
1
298.15
5
1
1435.6
5
1
2
1
303.15
5
1
1424.3
5
1
2
1
308.15
5
1
1413.1
5
1
2
1
313.15
5
1
1402.1
5
1
2
1
318.15
5
1
1391.1
5
1
2
15
5
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1389.5
5
1
1.7
1
298.15
5
1
1385.3
5
1
1.7
1
303.15
5
1
1381.1
5
1
1.7
1
308.15
5
1
1376.9
5
1
1.7
1
313.15
5
1
1372.7
5
1
1.7
1
318.15
5
1
1368.6
5
1
1.7
16
6
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Molar heat capacity at constant pressure, J/K/mol
Small sample (50 mg) DSC
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
421.6
4
1
6.5
1
298.15
5
1
424.1
4
1
6.6
1
303.15
5
1
426.7
4
1
6.6
1
308.15
5
1
429.5
4
1
6.7
1
313.15
5
1
432.4
4
1
6.7
1
318.15
5
1
435.5
4
1
6.7
17
6
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Speed of sound, m/s
Anton-Paar DSA48 sound analyzer
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1403.4
5
1
2
1
298.15
5
1
1392.1
5
1
2
1
303.15
5
1
1380.9
5
1
2
1
308.15
5
1
1369.8
5
1
2
1
313.15
5
1
1358.8
5
1
2
1
318.15
5
1
1348.1
5
1
2
18
6
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1301.6
5
1
1.5
1
298.15
5
1
1297.6
5
1
1.5
1
303.15
5
1
1293.7
5
1
1.5
1
308.15
5
1
1289.7
5
1
1.5
1
313.15
5
1
1285.8
5
1
1.5
1
318.15
5
1
1281.9
5
1
1.5
19
7
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Molar heat capacity at constant pressure, J/K/mol
Small sample (50 mg) DSC
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
106.6
4
1
1.7
1
298.15
5
1
106.9
4
1
1.7
1
303.15
5
1
107.3
4
1
1.7
1
308.15
5
1
107.7
4
1
1.7
1
313.15
5
1
108.2
4
1
1.7
1
318.15
5
1
108.6
4
1
1.7
20
7
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Speed of sound, m/s
Anton-Paar DSA48 sound analyzer
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1339.6
5
1
1.5
1
298.15
5
1
1320.1
5
1
1.5
1
303.15
5
1
1300.5
5
1
1.5
1
308.15
5
1
1280.7
5
1
1.5
1
313.15
5
1
1261.1
5
1
1.5
1
318.15
5
1
1241.6
5
1
1.5
21
7
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1140.2
5
1
0.7
1
298.15
5
1
1133.4
5
1
0.7
1
303.15
5
1
1126.6
5
1
0.7
1
308.15
5
1
1119.7
5
1
0.6
1
313.15
5
1
1112.9
5
1
0.6
1
318.15
5
1
1106
5
1
0.6
22
8
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Speed of sound, m/s
Anton-Paar DSA48 sound analyzer
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.325
6
1
Temperature, K
Liquid
1
293.15
5
1
1599.8
5
1
2
1
298.15
5
1
1587
5
1
2
1
303.15
5
1
1574.8
5
1
2
1
308.15
5
1
1562.6
5
1
2
1
313.15
5
1
1550.7
5
1
2
1
318.15
5
1
1538.9
5
1
2
23
7
1
8
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
Calvet calorimetry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
2
Temperature, K
Liquid
303.15
5
1
Mole fraction
8
Liquid
1
0.0992
3
1
-0.252
3
1
0.02
1
0.1547
4
1
-0.328
3
1
0.026
1
0.1998
4
1
-0.401
3
1
0.032
1
0.3029
4
1
-0.443
3
1
0.036
1
0.3978
4
1
-0.476
3
1
0.038
1
0.4973
4
1
-0.47
3
1
0.038
1
0.6053
4
1
-0.396
3
1
0.032
1
0.7038
4
1
-0.336
3
1
0.027
1
0.795
4
1
-0.233
3
1
0.019
1
0.8525
4
1
-0.162
3
1
0.013
24
7
1
2
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
Calvet calorimetry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
2
Temperature, K
Liquid
303.15
5
1
Mole fraction
2
Liquid
1
0.1
4
1
-0.073
2
1
0.006
1
0.2074
4
1
-0.124
3
1
0.01
1
0.3028
4
1
-0.146
3
1
0.012
1
0.4096
4
1
-0.16
3
1
0.013
1
0.5095
4
1
-0.159
3
1
0.013
1
0.6072
4
1
-0.143
3
1
0.012
1
0.7148
4
1
-0.113
3
1
0.009
1
0.7891
4
1
-0.094
2
1
0.008
1
0.8821
4
1
-0.05
2
1
0.004
25
7
1
2
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Molar heat capacity at constant pressure, J/K/mol
Small sample (50 mg) DSC
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mole fraction
2
Liquid
1
293.15
5
2
0.098
3
1
136.3
4
1
2.1
1
293.15
5
2
0.1933
4
1
166.4
4
1
2.6
1
293.15
5
2
0.3062
4
1
202.6
4
1
3.1
1
293.15
5
2
0.3988
4
1
232.4
4
1
3.6
1
293.15
5
2
0.4936
4
1
262.8
4
1
4.1
1
293.15
5
2
0.5941
4
1
295.4
4
1
4.6
1
293.15
5
2
0.6917
4
1
326.6
4
1
5.1
1
293.15
5
2
0.7702
4
1
351.4
4
1
5.4
1
293.15
5
2
0.8665
4
1
382.6
4
1
5.9
1
298.15
5
2
0.098
3
1
136.7
4
1
2.1
1
298.15
5
2
0.1933
4
1
167
4
1
2.6
1
298.15
5
2
0.3062
4
1
203.5
4
1
3.2
1
298.15
5
2
0.3988
4
1
233.4
4
1
3.6
1
298.15
5
2
0.4936
4
1
264
4
1
4.1
1
298.15
5
2
0.5941
4
1
296.8
4
1
4.6
1
298.15
5
2
0.6917
4
1
328.3
4
1
5.1
1
298.15
5
2
0.7702
4
1
353.4
4
1
5.5
1
298.15
5
2
0.8665
4
1
384.8
4
1
6
1
303.15
5
2
0.098
3
1
137.2
4
1
2.1
1
303.15
5
2
0.1933
4
1
167.7
4
1
2.6
1
303.15
5
2
0.3062
4
1
204.4
4
1
3.2
1
303.15
5
2
0.3988
4
1
234.5
4
1
3.6
1
303.15
5
2
0.4936
4
1
265.4
4
1
4.1
1
303.15
5
2
0.5941
4
1
298.3
4
1
4.6
1
303.15
5
2
0.6917
4
1
330
4
1
5.1
1
303.15
5
2
0.7702
4
1
355.4
4
1
5.5
1
303.15
5
2
0.8665
4
1
387
4
1
6
1
308.15
5
2
0.098
3
1
137.7
4
1
2.1
1
308.15
5
2
0.1933
4
1
168.4
4
1
2.6
1
308.15
5
2
0.3062
4
1
205.3
4
1
3.2
1
308.15
5
2
0.3988
4
1
235.6
4
1
3.7
1
308.15
5
2
0.4936
4
1
266.7
4
1
4.1
1
308.15
5
2
0.5941
4
1
299.8
4
1
4.6
1
308.15
5
2
0.6917
4
1
331.7
4
1
5.1
1
308.15
5
2
0.7702
4
1
357.3
4
1
5.5
1
308.15
5
2
0.8665
4
1
389.1
4
1
6
1
313.15
5
2
0.098
3
1
138.3
4
1
2.1
1
313.15
5
2
0.1933
4
1
169.2
4
1
2.6
1
313.15
5
2
0.3062
4
1
206.3
4
1
3.2
1
313.15
5
2
0.3988
4
1
236.9
4
1
3.7
1
313.15
5
2
0.4936
4
1
268.2
4
1
4.2
1
313.15
5
2
0.5941
4
1
301.3
4
1
4.7
1
313.15
5
2
0.6917
4
1
333.4
4
1
5.2
1
313.15
5
2
0.7702
4
1
359.2
4
1
5.6
1
313.15
5
2
0.8665
4
1
391.3
4
1
6.1
1
318.15
5
2
0.098
3
1
138.8
4
1
2.2
1
318.15
5
2
0.1933
4
1
169.9
4
1
2.6
1
318.15
5
2
0.3062
4
1
207.3
4
1
3.2
1
318.15
5
2
0.3988
4
1
238.1
4
1
3.7
1
318.15
5
2
0.4936
4
1
269.6
4
1
4.2
1
318.15
5
2
0.5941
4
1
302.8
4
1
4.7
1
318.15
5
2
0.6917
4
1
335
4
1
5.2
1
318.15
5
2
0.7702
4
1
361.1
4
1
5.6
1
318.15
5
2
0.8665
4
1
393.4
4
1
6.1
26
7
1
2
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mole fraction
2
Liquid
1
293.15
5
2
0.098
3
1
1148.7
5
1
0.7
1
293.15
5
2
0.1933
4
1
1150.7
5
1
0.8
1
293.15
5
2
0.3062
4
1
1151.2
5
1
0.8
1
293.15
5
2
0.3988
4
1
1151.1
5
1
0.9
1
293.15
5
2
0.4936
4
1
1150.9
5
1
0.9
1
293.15
5
2
0.5941
4
1
1150.5
5
1
1
1
293.15
5
2
0.5973
4
1
1150.5
5
1
1
1
293.15
5
2
0.6839
4
1
1150.1
5
1
1
1
293.15
5
2
0.6917
4
1
1150
5
1
1
1
293.15
5
2
0.7702
4
1
1149.8
5
1
1
1
293.15
5
2
0.7767
4
1
1149.7
5
1
1
1
293.15
5
2
0.786
4
1
1149.6
5
1
1
1
293.15
5
2
0.8514
4
1
1149.3
5
1
1.1
1
293.15
5
2
0.8665
4
1
1149.2
5
1
1.1
1
293.15
5
2
0.8727
4
1
1149.2
5
1
1.1
1
298.15
5
2
0.098
3
1
1143.2
5
1
0.7
1
298.15
5
2
0.1933
4
1
1145.8
5
1
0.8
1
298.15
5
2
0.3062
4
1
1146.7
5
1
0.8
1
298.15
5
2
0.3988
4
1
1146.9
5
1
0.9
1
298.15
5
2
0.4936
4
1
1146.8
5
1
0.9
1
298.15
5
2
0.5941
4
1
1146.6
5
1
0.9
1
298.15
5
2
0.5973
4
1
1146.6
5
1
0.9
1
298.15
5
2
0.6839
4
1
1146.4
5
1
1
1
298.15
5
2
0.6917
4
1
1146.2
5
1
1
1
298.15
5
2
0.7702
4
1
1146.1
5
1
1
1
298.15
5
2
0.7767
4
1
1146
5
1
1
1
298.15
5
2
0.786
4
1
1146
5
1
1
1
298.15
5
2
0.8514
4
1
1145.8
5
1
1.1
1
298.15
5
2
0.8665
4
1
1145.7
5
1
1.1
1
298.15
5
2
0.8727
4
1
1145.7
5
1
1.1
1
303.15
5
2
0.098
3
1
1137.7
5
1
0.7
1
303.15
5
2
0.1933
4
1
1140.9
5
1
0.8
1
303.15
5
2
0.3062
4
1
1142.3
5
1
0.8
1
303.15
5
2
0.3988
4
1
1142.7
5
1
0.8
1
303.15
5
2
0.4936
4
1
1142.8
5
1
0.9
1
303.15
5
2
0.5941
4
1
1142.8
5
1
0.9
1
303.15
5
2
0.5973
4
1
1142.8
5
1
0.9
1
303.15
5
2
0.6839
4
1
1142.6
5
1
1
1
303.15
5
2
0.6917
4
1
1142.5
5
1
1
1
303.15
5
2
0.7702
4
1
1142.5
5
1
1
1
303.15
5
2
0.7767
4
1
1142.4
5
1
1
1
303.15
5
2
0.786
4
1
1142.4
5
1
1
1
303.15
5
2
0.8514
4
1
1142.3
5
1
1.1
1
303.15
5
2
0.8665
4
1
1142.1
5
1
1.1
1
303.15
5
2
0.8727
4
1
1142.2
5
1
1.1
1
308.15
5
2
0.098
3
1
1132.1
5
1
0.7
1
308.15
5
2
0.1933
4
1
1136
5
1
0.7
1
308.15
5
2
0.3062
4
1
1137.8
5
1
0.8
1
308.15
5
2
0.3988
4
1
1138.5
5
1
0.8
1
308.15
5
2
0.4936
4
1
1138.8
5
1
0.9
1
308.15
5
2
0.5941
4
1
1138.9
5
1
0.9
1
308.15
5
2
0.5973
4
1
1138.9
5
1
0.9
1
308.15
5
2
0.6839
4
1
1138.9
5
1
1
1
308.15
5
2
0.6917
4
1
1138.8
5
1
1
1
308.15
5
2
0.7702
4
1
1138.9
5
1
1
1
308.15
5
2
0.7767
4
1
1138.8
5
1
1
1
308.15
5
2
0.786
4
1
1138.8
5
1
1
1
308.15
5
2
0.8514
4
1
1138.7
5
1
1.1
1
308.15
5
2
0.8665
4
1
1138.6
5
1
1.1
1
308.15
5
2
0.8727
4
1
1138.6
5
1
1.1
1
313.15
5
2
0.098
3
1
1126.6
5
1
0.7
1
313.15
5
2
0.1933
4
1
1131.1
5
1
0.7
1
313.15
5
2
0.3062
4
1
1133.4
5
1
0.8
1
313.15
5
2
0.3988
4
1
1134.3
5
1
0.8
1
313.15
5
2
0.4936
4
1
1134.8
5
1
0.9
1
313.15
5
2
0.5941
4
1
1135.1
5
1
0.9
1
313.15
5
2
0.5973
4
1
1135.1
5
1
0.9
1
313.15
5
2
0.6839
4
1
1135.2
5
1
1
1
313.15
5
2
0.6917
4
1
1135.1
5
1
1
1
313.15
5
2
0.7702
4
1
1135.3
5
1
1
1
313.15
5
2
0.7767
4
1
1135.2
5
1
1
1
313.15
5
2
0.786
4
1
1135.2
5
1
1
1
313.15
5
2
0.8514
4
1
1135.2
5
1
1
1
313.15
5
2
0.8665
4
1
1135.1
5
1
1.1
1
313.15
5
2
0.8727
4
1
1135.1
5
1
1.1
1
318.15
5
2
0.098
3
1
1121
5
1
0.7
1
318.15
5
2
0.1933
4
1
1126.2
5
1
0.7
1
318.15
5
2
0.3062
4
1
1129
5
1
0.8
1
318.15
5
2
0.3988
4
1
1130.2
5
1
0.8
1
318.15
5
2
0.4936
4
1
1130.9
5
1
0.9
1
318.15
5
2
0.5941
4
1
1131.3
5
1
0.9
1
318.15
5
2
0.5973
4
1
1131.3
5
1
0.9
1
318.15
5
2
0.6839
4
1
1131.5
5
1
1
1
318.15
5
2
0.6917
4
1
1131.4
5
1
1
1
318.15
5
2
0.7702
4
1
1131.6
5
1
1
1
318.15
5
2
0.7767
4
1
1131.6
5
1
1
1
318.15
5
2
0.786
4
1
1131.6
5
1
1
1
318.15
5
2
0.8514
4
1
1131.7
5
1
1
1
318.15
5
2
0.8665
4
1
1131.6
5
1
1
1
318.15
5
2
0.8727
4
1
1131.6
5
1
1.1
27
7
1
3
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
Calvet calorimetry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
2
Temperature, K
Liquid
303.15
5
1
Mole fraction
3
Liquid
1
0.1001
4
1
-0.288
3
1
0.023
1
0.1977
4
1
-0.485
3
1
0.039
1
0.3075
4
1
-0.594
3
1
0.048
1
0.4001
4
1
-0.644
3
1
0.052
1
0.5071
4
1
-0.62
3
1
0.05
1
0.6026
4
1
-0.547
3
1
0.044
1
0.6953
4
1
-0.451
3
1
0.036
1
0.8026
4
1
-0.308
3
1
0.025
1
0.8668
4
1
-0.209
3
1
0.017
28
7
1
3
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Molar heat capacity at constant pressure, J/K/mol
Small sample (50 mg) DSC
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mole fraction
3
Liquid
1
293.15
5
2
0.0513
3
1
120.8
4
1
1.9
1
293.15
5
2
0.0991
3
1
134.3
4
1
2.1
1
293.15
5
2
0.2013
4
1
164
4
1
2.5
1
293.15
5
2
0.3095
4
1
195.4
4
1
3
1
293.15
5
2
0.4073
4
1
223.5
4
1
3.5
1
293.15
5
2
0.5489
4
1
264
4
1
4.1
1
293.15
5
2
0.689
4
1
304
4
1
4.7
1
293.15
5
2
0.7805
4
1
329.9
4
1
5.1
1
293.15
5
2
0.8817
4
1
358.6
4
1
5.6
1
298.15
5
2
0.0513
3
1
121.1
4
1
1.9
1
298.15
5
2
0.0991
3
1
134.7
4
1
2.1
1
298.15
5
2
0.2013
4
1
164.6
4
1
2.6
1
298.15
5
2
0.3095
4
1
196.1
4
1
3
1
298.15
5
2
0.4073
4
1
224.4
4
1
3.5
1
298.15
5
2
0.5489
4
1
265.2
4
1
4.1
1
298.15
5
2
0.689
4
1
305.5
4
1
4.7
1
298.15
5
2
0.7805
4
1
331.6
4
1
5.1
1
298.15
5
2
0.8817
4
1
360.5
4
1
5.6
1
303.15
5
2
0.0513
3
1
121.6
4
1
1.9
1
303.15
5
2
0.0991
3
1
135.3
4
1
2.1
1
303.15
5
2
0.2013
4
1
165.3
4
1
2.6
1
303.15
5
2
0.3095
4
1
196.9
4
1
3.1
1
303.15
5
2
0.4073
4
1
225.5
4
1
3.5
1
303.15
5
2
0.5489
4
1
266.6
4
1
4.1
1
303.15
5
2
0.689
4
1
307.2
4
1
4.8
1
303.15
5
2
0.7805
4
1
333.5
4
1
5.2
1
303.15
5
2
0.8817
4
1
362.6
4
1
5.6
1
308.15
5
2
0.0513
3
1
122.1
4
1
1.9
1
308.15
5
2
0.0991
3
1
135.9
4
1
2.1
1
308.15
5
2
0.2013
4
1
166
4
1
2.6
1
308.15
5
2
0.3095
4
1
197.8
4
1
3.1
1
308.15
5
2
0.4073
4
1
226.7
4
1
3.5
1
308.15
5
2
0.5489
4
1
268.1
4
1
4.2
1
308.15
5
2
0.689
4
1
308.9
4
1
4.8
1
308.15
5
2
0.7805
4
1
335.5
4
1
5.2
1
308.15
5
2
0.8817
4
1
364.8
4
1
5.7
1
313.15
5
2
0.0513
3
1
122.7
4
1
1.9
1
313.15
5
2
0.0991
3
1
136.6
4
1
2.1
1
313.15
5
2
0.2013
4
1
166.8
4
1
2.6
1
313.15
5
2
0.3095
4
1
198.7
4
1
3.1
1
313.15
5
2
0.4073
4
1
227.9
4
1
3.5
1
313.15
5
2
0.5489
4
1
269.7
4
1
4.2
1
313.15
5
2
0.689
4
1
310.9
4
1
4.8
1
313.15
5
2
0.7805
4
1
337.7
4
1
5.2
1
313.15
5
2
0.8817
4
1
367.1
4
1
5.7
1
318.15
5
2
0.0513
3
1
123.2
4
1
1.9
1
318.15
5
2
0.0991
3
1
137.2
4
1
2.1
1
318.15
5
2
0.2013
4
1
167.6
4
1
2.6
1
318.15
5
2
0.3095
4
1
199.7
4
1
3.1
1
318.15
5
2
0.4073
4
1
229.2
4
1
3.6
1
318.15
5
2
0.5489
4
1
271.4
4
1
4.2
1
318.15
5
2
0.689
4
1
312.9
4
1
4.8
1
318.15
5
2
0.7805
4
1
340
4
1
5.3
1
318.15
5
2
0.8817
4
1
369.6
4
1
5.7
29
7
1
3
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mole fraction
3
Liquid
1
293.15
5
2
0.0513
3
1
1162.5
5
1
0.7
1
293.15
5
2
0.0991
3
1
1176.4
5
1
0.8
1
293.15
5
2
0.2013
4
1
1196.4
5
1
0.8
1
293.15
5
2
0.3095
4
1
1209.6
5
1
0.9
1
293.15
5
2
0.4073
4
1
1217.8
5
1
1
1
293.15
5
2
0.5056
4
1
1223.9
5
1
1
1
293.15
5
2
0.5489
4
1
1226.3
5
1
1.1
1
293.15
5
2
0.5944
4
1
1228.3
5
1
1.1
1
293.15
5
2
0.689
4
1
1232.1
5
1
1.2
1
293.15
5
2
0.7805
4
1
1235.1
5
1
1.2
1
293.15
5
2
0.8817
4
1
1237.9
5
1
1.3
1
293.15
5
2
0.9398
4
1
1239.3
5
1
1.3
1
293.15
5
2
0.9522
4
1
1239.6
5
1
1.3
1
298.15
5
2
0.0513
3
1
1156.4
5
1
0.7
1
298.15
5
2
0.0991
3
1
1170.9
5
1
0.8
1
298.15
5
2
0.2013
4
1
1191.5
5
1
0.8
1
298.15
5
2
0.3095
4
1
1205.1
5
1
0.9
1
298.15
5
2
0.4073
4
1
1213.6
5
1
1
1
298.15
5
2
0.5056
4
1
1220
5
1
1
1
298.15
5
2
0.5489
4
1
1222.4
5
1
1.1
1
298.15
5
2
0.5944
4
1
1224.5
5
1
1.1
1
298.15
5
2
0.689
4
1
1228.4
5
1
1.2
1
298.15
5
2
0.7805
4
1
1231.5
5
1
1.2
1
298.15
5
2
0.8817
4
1
1234.4
5
1
1.3
1
298.15
5
2
0.9398
4
1
1235.8
5
1
1.3
1
298.15
5
2
0.9522
4
1
1236.2
5
1
1.3
1
303.15
5
2
0.0513
3
1
1150.4
5
1
0.7
1
303.15
5
2
0.0991
3
1
1165.3
5
1
0.8
1
303.15
5
2
0.2013
4
1
1186.6
5
1
0.8
1
303.15
5
2
0.3095
4
1
1200.7
5
1
0.9
1
303.15
5
2
0.4073
4
1
1209.5
5
1
1
1
303.15
5
2
0.5056
4
1
1216
5
1
1
1
303.15
5
2
0.5489
4
1
1218.5
5
1
1.1
1
303.15
5
2
0.5944
4
1
1220.7
5
1
1.1
1
303.15
5
2
0.689
4
1
1224.7
5
1
1.1
1
303.15
5
2
0.7805
4
1
1228
5
1
1.2
1
303.15
5
2
0.8817
4
1
1230.9
5
1
1.3
1
303.15
5
2
0.9398
4
1
1232.4
5
1
1.3
1
303.15
5
2
0.9522
4
1
1232.7
5
1
1.3
1
308.15
5
2
0.0513
3
1
1144.3
5
1
0.7
1
308.15
5
2
0.0991
3
1
1159.7
5
1
0.7
1
308.15
5
2
0.2013
4
1
1181.7
5
1
0.8
1
308.15
5
2
0.3095
4
1
1196.2
5
1
0.9
1
308.15
5
2
0.4073
4
1
1205.3
5
1
1
1
308.15
5
2
0.5056
4
1
1212.1
5
1
1
1
308.15
5
2
0.5489
4
1
1214.6
5
1
1
1
308.15
5
2
0.5944
4
1
1216.9
5
1
1.1
1
308.15
5
2
0.689
4
1
1221
5
1
1.1
1
308.15
5
2
0.7805
4
1
1224.4
5
1
1.2
1
308.15
5
2
0.8817
4
1
1227.5
5
1
1.3
1
308.15
5
2
0.9398
4
1
1229
5
1
1.3
1
308.15
5
2
0.9522
4
1
1229.3
5
1
1.3
1
313.15
5
2
0.0513
3
1
1138.2
5
1
0.7
1
313.15
5
2
0.0991
3
1
1154.2
5
1
0.7
1
313.15
5
2
0.2013
4
1
1176.9
5
1
0.8
1
313.15
5
2
0.3095
4
1
1191.8
5
1
0.9
1
313.15
5
2
0.4073
4
1
1201.2
5
1
1
1
313.15
5
2
0.5056
4
1
1208.2
5
1
1
1
313.15
5
2
0.5489
4
1
1210.8
5
1
1
1
313.15
5
2
0.5944
4
1
1213.1
5
1
1.1
1
313.15
5
2
0.689
4
1
1217.4
5
1
1.1
1
313.15
5
2
0.7805
4
1
1220.9
5
1
1.2
1
313.15
5
2
0.8817
4
1
1224
5
1
1.3
1
313.15
5
2
0.9398
4
1
1225.6
5
1
1.3
1
313.15
5
2
0.9522
4
1
1225.9
5
1
1.3
1
318.15
5
2
0.0513
3
1
1132.2
5
1
0.7
1
318.15
5
2
0.0991
3
1
1148.6
5
1
0.7
1
318.15
5
2
0.2013
4
1
1172
5
1
0.8
1
318.15
5
2
0.3095
4
1
1187.4
5
1
0.9
1
318.15
5
2
0.4073
4
1
1197.1
5
1
0.9
1
318.15
5
2
0.5056
4
1
1204.2
5
1
1
1
318.15
5
2
0.5489
4
1
1207
5
1
1
1
318.15
5
2
0.5944
4
1
1209.3
5
1
1.1
1
318.15
5
2
0.689
4
1
1213.8
5
1
1.1
1
318.15
5
2
0.7805
4
1
1217.3
5
1
1.2
1
318.15
5
2
0.8817
4
1
1220.6
5
1
1.2
1
318.15
5
2
0.9398
4
1
1222.2
5
1
1.3
1
318.15
5
2
0.9522
4
1
1222.5
5
1
1.3
30
7
1
5
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
Calvet calorimetry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
2
Temperature, K
Liquid
303.15
5
1
Mole fraction
5
Liquid
1
0.1234
4
1
-0.126
3
1
0.01
1
0.2533
4
1
-0.191
3
1
0.015
1
0.3774
4
1
-0.196
3
1
0.016
1
0.5026
4
1
-0.201
3
1
0.016
1
0.6253
4
1
-0.167
3
1
0.014
1
0.7438
4
1
-0.125
3
1
0.01
1
0.8668
4
1
-0.058
2
1
0.005
31
7
1
5
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Molar heat capacity at constant pressure, J/K/mol
Small sample (50 mg) DSC
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mole fraction
5
Liquid
1
293.15
5
2
0.0525
3
1
119.2
4
1
1.8
1
293.15
5
2
0.0981
3
1
130.6
4
1
2
1
293.15
5
2
0.2013
4
1
157
4
1
2.4
1
293.15
5
2
0.3063
4
1
183.7
4
1
2.8
1
293.15
5
2
0.4027
4
1
208.2
4
1
3.2
1
293.15
5
2
0.4995
4
1
233.2
4
1
3.6
1
293.15
5
2
0.5934
4
1
257.3
4
1
4
1
293.15
5
2
0.6847
4
1
280.5
4
1
4.3
1
293.15
5
2
0.7698
4
1
301.6
4
1
4.7
1
293.15
5
2
0.8671
4
1
326.9
4
1
5.1
1
298.15
5
2
0.0525
3
1
119.5
4
1
1.9
1
298.15
5
2
0.0981
3
1
130.9
4
1
2
1
298.15
5
2
0.2013
4
1
157.6
4
1
2.4
1
298.15
5
2
0.3063
4
1
184.4
4
1
2.9
1
298.15
5
2
0.4027
4
1
209.1
4
1
3.2
1
298.15
5
2
0.4995
4
1
234.3
4
1
3.6
1
298.15
5
2
0.5934
4
1
258.5
4
1
4
1
298.15
5
2
0.6847
4
1
281.9
4
1
4.4
1
298.15
5
2
0.7698
4
1
303.3
4
1
4.7
1
298.15
5
2
0.8671
4
1
328.8
4
1
5.1
1
303.15
5
2
0.0525
3
1
120
4
1
1.9
1
303.15
5
2
0.0981
3
1
131.4
4
1
2
1
303.15
5
2
0.2013
4
1
158.3
4
1
2.5
1
303.15
5
2
0.3063
4
1
185.2
4
1
2.9
1
303.15
5
2
0.4027
4
1
210.1
4
1
3.3
1
303.15
5
2
0.4995
4
1
235.5
4
1
3.6
1
303.15
5
2
0.5934
4
1
259.9
4
1
4
1
303.15
5
2
0.6847
4
1
283.3
4
1
4.4
1
303.15
5
2
0.7698
4
1
305
4
1
4.7
1
303.15
5
2
0.8671
4
1
330.7
4
1
5.1
1
308.15
5
2
0.0525
3
1
120.4
4
1
1.9
1
308.15
5
2
0.0981
3
1
131.8
4
1
2
1
308.15
5
2
0.2013
4
1
159.1
4
1
2.5
1
308.15
5
2
0.3063
4
1
186.1
4
1
2.9
1
308.15
5
2
0.4027
4
1
211.1
4
1
3.3
1
308.15
5
2
0.4995
4
1
236.7
4
1
3.7
1
308.15
5
2
0.5934
4
1
261.3
4
1
4
1
308.15
5
2
0.6847
4
1
284.8
4
1
4.4
1
308.15
5
2
0.7698
4
1
306.7
4
1
4.8
1
308.15
5
2
0.8671
4
1
332.7
4
1
5.2
1
313.15
5
2
0.0525
3
1
121
4
1
1.9
1
313.15
5
2
0.0981
3
1
132.4
4
1
2.1
1
313.15
5
2
0.2013
4
1
160
4
1
2.5
1
313.15
5
2
0.3063
4
1
187
4
1
2.9
1
313.15
5
2
0.4027
4
1
212.1
4
1
3.3
1
313.15
5
2
0.4995
4
1
238
4
1
3.7
1
313.15
5
2
0.5934
4
1
262.7
4
1
4.1
1
313.15
5
2
0.6847
4
1
286.3
4
1
4.4
1
313.15
5
2
0.7698
4
1
308.5
4
1
4.8
1
313.15
5
2
0.8671
4
1
334.7
4
1
5.2
1
318.15
5
2
0.0525
3
1
121.4
4
1
1.9
1
318.15
5
2
0.0981
3
1
132.8
4
1
2.1
1
318.15
5
2
0.2013
4
1
160.8
4
1
2.5
1
318.15
5
2
0.3063
4
1
188
4
1
2.9
1
318.15
5
2
0.4027
4
1
213
4
1
3.3
1
318.15
5
2
0.4995
4
1
239.2
4
1
3.7
1
318.15
5
2
0.5934
4
1
264.2
4
1
4.1
1
318.15
5
2
0.6847
4
1
287.8
4
1
4.5
1
318.15
5
2
0.7698
4
1
310.3
4
1
4.8
1
318.15
5
2
0.8671
4
1
336.7
4
1
5.2
32
7
1
5
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mole fraction
5
Liquid
1
293.15
5
2
0.0525
3
1
1186.8
5
1
0.8
1
293.15
5
2
0.0981
3
1
1217.2
5
1
0.8
1
293.15
5
2
0.2013
4
1
1266.6
5
1
1
1
293.15
5
2
0.3063
4
1
1300.5
5
1
1.1
1
293.15
5
2
0.4027
4
1
1323.1
5
1
1.2
1
293.15
5
2
0.4995
4
1
1340.5
5
1
1.3
1
293.15
5
2
0.5934
4
1
1353.9
5
1
1.4
1
293.15
5
2
0.6847
4
1
1364.4
5
1
1.4
1
293.15
5
2
0.7698
4
1
1372.6
5
1
1.5
1
293.15
5
2
0.8671
4
1
1380.5
5
1
1.6
1
298.15
5
2
0.0525
3
1
1180.5
5
1
0.8
1
298.15
5
2
0.0981
3
1
1211.2
5
1
0.8
1
298.15
5
2
0.2013
4
1
1261.1
5
1
1
1
298.15
5
2
0.3063
4
1
1295.4
5
1
1.1
1
298.15
5
2
0.4027
4
1
1318.2
5
1
1.2
1
298.15
5
2
0.4995
4
1
1335.7
5
1
1.3
1
298.15
5
2
0.5934
4
1
1349.2
5
1
1.3
1
298.15
5
2
0.6847
4
1
1359.9
5
1
1.4
1
298.15
5
2
0.7698
4
1
1368.2
5
1
1.5
1
298.15
5
2
0.8671
4
1
1376.2
5
1
1.6
1
303.15
5
2
0.0525
3
1
1174.3
5
1
0.8
1
303.15
5
2
0.0981
3
1
1205.3
5
1
0.8
1
303.15
5
2
0.2013
4
1
1255.7
5
1
0.9
1
303.15
5
2
0.3063
4
1
1290.3
5
1
1.1
1
303.15
5
2
0.4027
4
1
1313.3
5
1
1.2
1
303.15
5
2
0.4995
4
1
1331
5
1
1.3
1
303.15
5
2
0.5934
4
1
1344.7
5
1
1.3
1
303.15
5
2
0.6847
4
1
1355.4
5
1
1.4
1
303.15
5
2
0.7698
4
1
1363.8
5
1
1.5
1
303.15
5
2
0.8671
4
1
1371.9
5
1
1.6
1
308.15
5
2
0.0525
3
1
1168
5
1
0.7
1
308.15
5
2
0.0981
3
1
1199.3
5
1
0.8
1
308.15
5
2
0.2013
4
1
1250.2
5
1
0.9
1
308.15
5
2
0.3063
4
1
1285.2
5
1
1
1
308.15
5
2
0.4027
4
1
1308.4
5
1
1.1
1
308.15
5
2
0.4995
4
1
1326.3
5
1
1.2
1
308.15
5
2
0.5934
4
1
1340.1
5
1
1.3
1
308.15
5
2
0.6847
4
1
1351
5
1
1.4
1
308.15
5
2
0.7698
4
1
1359.4
5
1
1.5
1
308.15
5
2
0.8671
4
1
1367.6
5
1
1.6
1
313.15
5
2
0.0525
3
1
1161.7
5
1
0.7
1
313.15
5
2
0.0981
3
1
1193.4
5
1
0.8
1
313.15
5
2
0.2013
4
1
1244.8
5
1
0.9
1
313.15
5
2
0.3063
4
1
1280.1
5
1
1
1
313.15
5
2
0.4027
4
1
1303.6
5
1
1.1
1
313.15
5
2
0.4995
4
1
1321.6
5
1
1.2
1
313.15
5
2
0.5934
4
1
1335.5
5
1
1.3
1
313.15
5
2
0.6847
4
1
1346.5
5
1
1.4
1
313.15
5
2
0.7698
4
1
1355.1
5
1
1.5
1
313.15
5
2
0.8671
4
1
1363.4
5
1
1.6
1
318.15
5
2
0.0525
3
1
1155.4
5
1
0.7
1
318.15
5
2
0.0981
3
1
1187.4
5
1
0.8
1
318.15
5
2
0.2013
4
1
1239.3
5
1
0.9
1
318.15
5
2
0.3063
4
1
1275
5
1
1
1
318.15
5
2
0.4027
4
1
1298.7
5
1
1.1
1
318.15
5
2
0.4995
4
1
1316.9
5
1
1.2
1
318.15
5
2
0.5934
4
1
1331
5
1
1.3
1
318.15
5
2
0.6847
4
1
1342.1
5
1
1.4
1
318.15
5
2
0.7698
4
1
1350.7
5
1
1.5
1
318.15
5
2
0.8671
4
1
1359.1
5
1
1.6
33
7
1
6
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
Calvet calorimetry
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
2
Temperature, K
Liquid
303.15
5
1
Mole fraction
6
Liquid
1
0.1022
4
1
0.039
2
1
0.003
1
0.1994
4
1
0.057
2
1
0.005
1
0.3029
4
1
0.062
2
1
0.005
1
0.4044
4
1
0.059
2
1
0.005
1
0.5067
4
1
0.056
2
1
0.005
1
0.5931
4
1
0.045
2
1
0.004
1
0.703
4
1
0.031
2
1
0.003
1
0.7814
4
1
0.005
1
1
0.001
1
0.8933
4
1
-0.009
1
1
0.001
34
7
1
6
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Molar heat capacity at constant pressure, J/K/mol
Small sample (50 mg) DSC
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mole fraction
6
Liquid
1
293.15
5
2
0.0495
3
1
121.1
4
1
1.9
1
293.15
5
2
0.0972
3
1
136
4
1
2.1
1
293.15
5
2
0.2021
4
1
168.8
4
1
2.6
1
293.15
5
2
0.2955
4
1
198.5
4
1
3.1
1
293.15
5
2
0.4015
4
1
231.5
4
1
3.6
1
293.15
5
2
0.495
4
1
261.4
4
1
4.1
1
293.15
5
2
0.5993
4
1
294.6
4
1
4.6
1
293.15
5
2
0.6939
4
1
324.4
4
1
5
1
293.15
5
2
0.7858
4
1
353.8
4
1
5.5
1
293.15
5
2
0.8697
4
1
380.5
4
1
5.9
1
293.15
5
2
0.9286
4
1
398.8
4
1
6.2
1
298.15
5
2
0.0495
3
1
121.4
4
1
1.9
1
298.15
5
2
0.0972
3
1
136.4
4
1
2.1
1
298.15
5
2
0.2021
4
1
169.4
4
1
2.6
1
298.15
5
2
0.2955
4
1
199.4
4
1
3.1
1
298.15
5
2
0.4015
4
1
232.6
4
1
3.6
1
298.15
5
2
0.495
4
1
262.6
4
1
4.1
1
298.15
5
2
0.5993
4
1
296.1
4
1
4.6
1
298.15
5
2
0.6939
4
1
326.1
4
1
5.1
1
298.15
5
2
0.7858
4
1
355.6
4
1
5.5
1
298.15
5
2
0.8697
4
1
382.7
4
1
5.9
1
298.15
5
2
0.9286
4
1
400.9
4
1
6.2
1
303.15
5
2
0.0495
3
1
121.8
4
1
1.9
1
303.15
5
2
0.0972
3
1
137
4
1
2.1
1
303.15
5
2
0.2021
4
1
170.1
4
1
2.6
1
303.15
5
2
0.2955
4
1
200.3
4
1
3.1
1
303.15
5
2
0.4015
4
1
233.9
4
1
3.6
1
303.15
5
2
0.495
4
1
263.9
4
1
4.1
1
303.15
5
2
0.5993
4
1
297.8
4
1
4.6
1
303.15
5
2
0.6939
4
1
327.9
4
1
5.1
1
303.15
5
2
0.7858
4
1
357.5
4
1
5.5
1
303.15
5
2
0.8697
4
1
385
4
1
6
1
303.15
5
2
0.9286
4
1
403.3
4
1
6.2
1
308.15
5
2
0.0495
3
1
122.3
4
1
1.9
1
308.15
5
2
0.0972
3
1
137.5
4
1
2.1
1
308.15
5
2
0.2021
4
1
170.9
4
1
2.6
1
308.15
5
2
0.2955
4
1
201.4
4
1
3.1
1
308.15
5
2
0.4015
4
1
235.2
4
1
3.6
1
308.15
5
2
0.495
4
1
265.3
4
1
4.1
1
308.15
5
2
0.5993
4
1
299.5
4
1
4.6
1
308.15
5
2
0.6939
4
1
329.8
4
1
5.1
1
308.15
5
2
0.7858
4
1
359.6
4
1
5.6
1
308.15
5
2
0.8697
4
1
387.4
4
1
6
1
308.15
5
2
0.9286
4
1
405.7
4
1
6.3
1
313.15
5
2
0.0495
3
1
122.8
4
1
1.9
1
313.15
5
2
0.0972
3
1
138.2
4
1
2.1
1
313.15
5
2
0.2021
4
1
171.7
4
1
2.7
1
313.15
5
2
0.2955
4
1
202.5
4
1
3.1
1
313.15
5
2
0.4015
4
1
236.6
4
1
3.7
1
313.15
5
2
0.495
4
1
266.8
4
1
4.1
1
313.15
5
2
0.5993
4
1
301.3
4
1
4.7
1
313.15
5
2
0.6939
4
1
331.8
4
1
5.1
1
313.15
5
2
0.7858
4
1
361.8
4
1
5.6
1
313.15
5
2
0.8697
4
1
389.9
4
1
6
1
313.15
5
2
0.9286
4
1
408.3
4
1
6.3
1
318.15
5
2
0.0495
3
1
123.3
4
1
1.9
1
318.15
5
2
0.0972
3
1
138.7
4
1
2.2
1
318.15
5
2
0.2021
4
1
172.5
4
1
2.7
1
318.15
5
2
0.2955
4
1
203.6
4
1
3.2
1
318.15
5
2
0.4015
4
1
238
4
1
3.7
1
318.15
5
2
0.495
4
1
268.3
4
1
4.2
1
318.15
5
2
0.5993
4
1
303.2
4
1
4.7
1
318.15
5
2
0.6939
4
1
334
4
1
5.2
1
318.15
5
2
0.7858
4
1
364.1
4
1
5.6
1
318.15
5
2
0.8697
4
1
392.6
4
1
6.1
1
318.15
5
2
0.9286
4
1
411.1
4
1
6.4
35
7
1
6
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mole fraction
6
Liquid
1
293.15
5
2
0.0495
3
1
1173.6
5
1
0.7
1
293.15
5
2
0.0972
3
1
1196.4
5
1
0.8
1
293.15
5
2
0.2021
4
1
1229.9
5
1
0.9
1
293.15
5
2
0.2955
4
1
1249.1
5
1
1
1
293.15
5
2
0.4015
4
1
1264.3
5
1
1.1
1
293.15
5
2
0.495
4
1
1274.2
5
1
1.1
1
293.15
5
2
0.5993
4
1
1282.6
5
1
1.2
1
293.15
5
2
0.6939
4
1
1288.6
5
1
1.3
1
293.15
5
2
0.7858
4
1
1293.3
5
1
1.4
1
293.15
5
2
0.8697
4
1
1296.9
5
1
1.4
1
293.15
5
2
0.9286
4
1
1299.1
5
1
1.5
1
298.15
5
2
0.0495
3
1
1167.4
5
1
0.7
1
298.15
5
2
0.0972
3
1
1190.6
5
1
0.8
1
298.15
5
2
0.2021
4
1
1224.7
5
1
0.9
1
298.15
5
2
0.2955
4
1
1244.2
5
1
1
1
298.15
5
2
0.4015
4
1
1259.7
5
1
1.1
1
298.15
5
2
0.495
4
1
1269.7
5
1
1.1
1
298.15
5
2
0.5993
4
1
1278.2
5
1
1.2
1
298.15
5
2
0.6939
4
1
1284.3
5
1
1.3
1
298.15
5
2
0.7858
4
1
1289.1
5
1
1.3
1
298.15
5
2
0.8697
4
1
1292.8
5
1
1.4
1
298.15
5
2
0.9286
4
1
1295.1
5
1
1.5
1
303.15
5
2
0.0495
3
1
1161.2
5
1
0.7
1
303.15
5
2
0.0972
3
1
1184.8
5
1
0.8
1
303.15
5
2
0.2021
4
1
1219.4
5
1
0.9
1
303.15
5
2
0.2955
4
1
1239.3
5
1
1
1
303.15
5
2
0.4015
4
1
1255
5
1
1
1
303.15
5
2
0.495
4
1
1265.2
5
1
1.1
1
303.15
5
2
0.5993
4
1
1273.9
5
1
1.2
1
303.15
5
2
0.6939
4
1
1280.1
5
1
1.3
1
303.15
5
2
0.7858
4
1
1285
5
1
1.3
1
303.15
5
2
0.8697
4
1
1288.8
5
1
1.4
1
303.15
5
2
0.9286
4
1
1291.1
5
1
1.4
1
308.15
5
2
0.0495
3
1
1154.9
5
1
0.7
1
308.15
5
2
0.0972
3
1
1178.9
5
1
0.8
1
308.15
5
2
0.2021
4
1
1214.2
5
1
0.9
1
308.15
5
2
0.2955
4
1
1234.3
5
1
1
1
308.15
5
2
0.4015
4
1
1250.3
5
1
1
1
308.15
5
2
0.495
4
1
1260.7
5
1
1.1
1
308.15
5
2
0.5993
4
1
1269.6
5
1
1.2
1
308.15
5
2
0.6939
4
1
1275.9
5
1
1.3
1
308.15
5
2
0.7858
4
1
1280.9
5
1
1.3
1
308.15
5
2
0.8697
4
1
1284.7
5
1
1.4
1
308.15
5
2
0.9286
4
1
1287.1
5
1
1.4
1
313.15
5
2
0.0495
3
1
1148.8
5
1
0.7
1
313.15
5
2
0.0972
3
1
1173.2
5
1
0.8
1
313.15
5
2
0.2021
4
1
1209
5
1
0.9
1
313.15
5
2
0.2955
4
1
1229.5
5
1
0.9
1
313.15
5
2
0.4015
4
1
1245.7
5
1
1
1
313.15
5
2
0.495
4
1
1256.3
5
1
1.1
1
313.15
5
2
0.5993
4
1
1265.3
5
1
1.2
1
313.15
5
2
0.6939
4
1
1271.7
5
1
1.2
1
313.15
5
2
0.7858
4
1
1276.8
5
1
1.3
1
313.15
5
2
0.8697
4
1
1280.7
5
1
1.4
1
313.15
5
2
0.9286
4
1
1283.1
5
1
1.4
1
318.15
5
2
0.0495
3
1
1142.5
5
1
0.7
1
318.15
5
2
0.0972
3
1
1167.4
5
1
0.8
1
318.15
5
2
0.2021
4
1
1203.7
5
1
0.9
1
318.15
5
2
0.2955
4
1
1224.6
5
1
0.9
1
318.15
5
2
0.4015
4
1
1241.1
5
1
1
1
318.15
5
2
0.495
4
1
1251.8
5
1
1.1
1
318.15
5
2
0.5993
4
1
1261
5
1
1.2
1
318.15
5
2
0.6939
4
1
1267.5
5
1
1.2
1
318.15
5
2
0.7858
4
1
1272.7
5
1
1.3
1
318.15
5
2
0.8697
4
1
1276.7
5
1
1.4
1
318.15
5
2
0.9286
4
1
1279.1
5
1
1.4
36
7
1
1
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Molar heat capacity at constant pressure, J/K/mol
Small sample (50 mg) DSC
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mole fraction
1
Liquid
1
293.15
5
2
0.0525
3
1
119.2
4
1
1.8
1
293.15
5
2
0.1029
4
1
131.6
4
1
2
1
293.15
5
2
0.1943
4
1
154.9
4
1
2.4
1
293.15
5
2
0.2941
4
1
180.5
4
1
2.8
1
293.15
5
2
0.3911
4
1
205.4
4
1
3.2
1
293.15
5
2
0.5609
4
1
248.8
4
1
3.9
1
293.15
5
2
0.7062
4
1
285.8
4
1
4.4
1
293.15
5
2
0.7578
4
1
299
4
1
4.6
1
293.15
5
2
0.897
4
1
334.5
4
1
5.2
1
293.15
5
2
0.9436
4
1
346.4
4
1
5.4
1
293.15
5
2
0.9716
4
1
353.6
4
1
5.5
1
298.15
5
2
0.0525
3
1
119.6
4
1
1.9
1
298.15
5
2
0.1029
4
1
132.1
4
1
2
1
298.15
5
2
0.1943
4
1
155.6
4
1
2.4
1
298.15
5
2
0.2941
4
1
181.5
4
1
2.8
1
298.15
5
2
0.3911
4
1
206.7
4
1
3.2
1
298.15
5
2
0.5609
4
1
250.6
4
1
3.9
1
298.15
5
2
0.7062
4
1
288.1
4
1
4.5
1
298.15
5
2
0.7578
4
1
301.4
4
1
4.7
1
298.15
5
2
0.897
4
1
337.4
4
1
5.2
1
298.15
5
2
0.9436
4
1
349.5
4
1
5.4
1
298.15
5
2
0.9716
4
1
356.7
4
1
5.5
1
303.15
5
2
0.0525
3
1
120
4
1
1.9
1
303.15
5
2
0.1029
4
1
132.7
4
1
2.1
1
303.15
5
2
0.1943
4
1
156.4
4
1
2.4
1
303.15
5
2
0.2941
4
1
182.5
4
1
2.8
1
303.15
5
2
0.3911
4
1
208
4
1
3.2
1
303.15
5
2
0.5609
4
1
252.3
4
1
3.9
1
303.15
5
2
0.7062
4
1
290.2
4
1
4.5
1
303.15
5
2
0.7578
4
1
303.7
4
1
4.7
1
303.15
5
2
0.897
4
1
340
4
1
5.3
1
303.15
5
2
0.9436
4
1
352.3
4
1
5.5
1
303.15
5
2
0.9716
4
1
359.5
4
1
5.6
1
308.15
5
2
0.0525
3
1
120.5
4
1
1.9
1
308.15
5
2
0.1029
4
1
133.3
4
1
2.1
1
308.15
5
2
0.1943
4
1
157.1
4
1
2.4
1
308.15
5
2
0.2941
4
1
183.3
4
1
2.8
1
308.15
5
2
0.3911
4
1
209.1
4
1
3.2
1
308.15
5
2
0.5609
4
1
253.8
4
1
3.9
1
308.15
5
2
0.7062
4
1
292.1
4
1
4.5
1
308.15
5
2
0.7578
4
1
305.6
4
1
4.7
1
308.15
5
2
0.897
4
1
342.3
4
1
5.3
1
308.15
5
2
0.9436
4
1
354.7
4
1
5.5
1
308.15
5
2
0.9716
4
1
362
4
1
5.6
1
313.15
5
2
0.0525
3
1
121
4
1
1.9
1
313.15
5
2
0.1029
4
1
133.9
4
1
2.1
1
313.15
5
2
0.1943
4
1
157.8
4
1
2.4
1
313.15
5
2
0.2941
4
1
184.1
4
1
2.9
1
313.15
5
2
0.3911
4
1
210.1
4
1
3.3
1
313.15
5
2
0.5609
4
1
255.1
4
1
4
1
313.15
5
2
0.7062
4
1
293.7
4
1
4.6
1
313.15
5
2
0.7578
4
1
307.3
4
1
4.8
1
313.15
5
2
0.897
4
1
344.2
4
1
5.3
1
313.15
5
2
0.9436
4
1
356.8
4
1
5.5
1
313.15
5
2
0.9716
4
1
364.1
4
1
5.6
1
318.15
5
2
0.0525
3
1
121.4
4
1
1.9
1
318.15
5
2
0.1029
4
1
134.3
4
1
2.1
1
318.15
5
2
0.1943
4
1
158.3
4
1
2.5
1
318.15
5
2
0.2941
4
1
184.7
4
1
2.9
1
318.15
5
2
0.3911
4
1
210.9
4
1
3.3
1
318.15
5
2
0.5609
4
1
256.2
4
1
4
1
318.15
5
2
0.7062
4
1
295.1
4
1
4.6
1
318.15
5
2
0.7578
4
1
308.7
4
1
4.8
1
318.15
5
2
0.897
4
1
345.9
4
1
5.4
1
318.15
5
2
0.9436
4
1
358.5
4
1
5.6
1
318.15
5
2
0.9716
4
1
365.8
4
1
5.7
37
7
1
1
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mole fraction
1
Liquid
1
293.15
5
2
0.1007
4
1
1167
5
1
0.8
1
293.15
5
2
0.2066
4
1
1181.1
5
1
0.8
1
293.15
5
2
0.2597
4
1
1185.9
5
1
0.9
1
293.15
5
2
0.3069
4
1
1189.3
5
1
0.9
1
293.15
5
2
0.3957
4
1
1194.4
5
1
0.9
1
293.15
5
2
0.41
4
1
1195
5
1
0.9
1
293.15
5
2
0.4866
4
1
1198.1
5
1
1
1
293.15
5
2
0.5058
4
1
1198.7
5
1
1
1
293.15
5
2
0.6016
4
1
1201.5
5
1
1.1
1
293.15
5
2
0.6455
4
1
1202.6
5
1
1.1
1
293.15
5
2
0.6837
4
1
1203.4
5
1
1.1
1
293.15
5
2
0.7793
4
1
1205.1
5
1
1.2
1
293.15
5
2
0.8867
4
1
1206.5
5
1
1.2
1
298.15
5
2
0.1007
4
1
1161.3
5
1
0.7
1
298.15
5
2
0.2066
4
1
1176.1
5
1
0.8
1
298.15
5
2
0.2597
4
1
1181.1
5
1
0.8
1
298.15
5
2
0.3069
4
1
1184.7
5
1
0.9
1
298.15
5
2
0.3957
4
1
1190
5
1
0.9
1
298.15
5
2
0.41
4
1
1190.6
5
1
0.9
1
298.15
5
2
0.4866
4
1
1193.9
5
1
1
1
298.15
5
2
0.5058
4
1
1194.6
5
1
1
1
298.15
5
2
0.6016
4
1
1197.5
5
1
1
1
298.15
5
2
0.6455
4
1
1198.6
5
1
1.1
1
298.15
5
2
0.6837
4
1
1199.5
5
1
1.1
1
298.15
5
2
0.7793
4
1
1201.3
5
1
1.1
1
298.15
5
2
0.8867
4
1
1202.9
5
1
1.2
1
303.15
5
2
0.1007
4
1
1155.7
5
1
0.7
1
303.15
5
2
0.2066
4
1
1171.1
5
1
0.8
1
303.15
5
2
0.2597
4
1
1176.4
5
1
0.8
1
303.15
5
2
0.3069
4
1
1180.1
5
1
0.9
1
303.15
5
2
0.3957
4
1
1185.6
5
1
0.9
1
303.15
5
2
0.41
4
1
1186.3
5
1
0.9
1
303.15
5
2
0.4866
4
1
1189.7
5
1
1
1
303.15
5
2
0.5058
4
1
1190.4
5
1
1
1
303.15
5
2
0.6016
4
1
1193.5
5
1
1
1
303.15
5
2
0.6455
4
1
1194.7
5
1
1.1
1
303.15
5
2
0.6837
4
1
1195.6
5
1
1.1
1
303.15
5
2
0.7793
4
1
1197.5
5
1
1.1
1
303.15
5
2
0.8867
4
1
1199.2
5
1
1.2
1
308.15
5
2
0.1007
4
1
1150
5
1
0.7
1
308.15
5
2
0.2066
4
1
1166
5
1
0.8
1
308.15
5
2
0.2597
4
1
1171.5
5
1
0.8
1
308.15
5
2
0.3069
4
1
1175.4
5
1
0.9
1
308.15
5
2
0.3957
4
1
1181.2
5
1
0.9
1
308.15
5
2
0.41
4
1
1181.9
5
1
0.9
1
308.15
5
2
0.4866
4
1
1185.5
5
1
1
1
308.15
5
2
0.5058
4
1
1186.3
5
1
1
1
308.15
5
2
0.6016
4
1
1189.5
5
1
1
1
308.15
5
2
0.6455
4
1
1190.8
5
1
1.1
1
308.15
5
2
0.6837
4
1
1191.7
5
1
1.1
1
308.15
5
2
0.7793
4
1
1193.7
5
1
1.1
1
308.15
5
2
0.8867
4
1
1195.6
5
1
1.2
1
313.15
5
2
0.1007
4
1
1144.4
5
1
0.7
1
313.15
5
2
0.2066
4
1
1161.1
5
1
0.8
1
313.15
5
2
0.2597
4
1
1166.8
5
1
0.8
1
313.15
5
2
0.3069
4
1
1170.9
5
1
0.9
1
313.15
5
2
0.3957
4
1
1176.9
5
1
0.9
1
313.15
5
2
0.41
4
1
1177.6
5
1
0.9
1
313.15
5
2
0.4866
4
1
1181.4
5
1
1
1
313.15
5
2
0.5058
4
1
1182.2
5
1
1
1
313.15
5
2
0.6016
4
1
1185.5
5
1
1
1
313.15
5
2
0.6455
4
1
1186.9
5
1
1
1
313.15
5
2
0.6837
4
1
1187.9
5
1
1.1
1
313.15
5
2
0.7793
4
1
1190
5
1
1.1
1
313.15
5
2
0.8867
4
1
1191.9
5
1
1.2
1
318.15
5
2
0.1007
4
1
1138.7
5
1
0.7
1
318.15
5
2
0.2066
4
1
1156.1
5
1
0.8
1
318.15
5
2
0.2597
4
1
1162.1
5
1
0.8
1
318.15
5
2
0.3069
4
1
1166.3
5
1
0.8
1
318.15
5
2
0.3957
4
1
1172.5
5
1
0.9
1
318.15
5
2
0.41
4
1
1173.3
5
1
0.9
1
318.15
5
2
0.4866
4
1
1177.2
5
1
0.9
1
318.15
5
2
0.5058
4
1
1178
5
1
1
1
318.15
5
2
0.6016
4
1
1181.6
5
1
1
1
318.15
5
2
0.6455
4
1
1183
5
1
1
1
318.15
5
2
0.6837
4
1
1184
5
1
1.1
1
318.15
5
2
0.7793
4
1
1186.3
5
1
1.1
1
318.15
5
2
0.8867
4
1
1188.3
5
1
1.2
38
7
1
4
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Molar heat capacity at constant pressure, J/K/mol
Small sample (50 mg) DSC
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mole fraction
4
Liquid
1
293.15
5
2
0.0522
3
1
122.1
4
1
1.9
1
293.15
5
2
0.1
4
1
136.5
4
1
2.1
1
293.15
5
2
0.1966
4
1
166.4
4
1
2.6
1
293.15
5
2
0.3059
4
1
200.5
4
1
3.1
1
293.15
5
2
0.4061
4
1
231.4
4
1
3.6
1
293.15
5
2
0.5025
4
1
261.5
4
1
4.1
1
293.15
5
2
0.5889
4
1
288
4
1
4.5
1
293.15
5
2
0.6844
4
1
317.2
4
1
4.9
1
293.15
5
2
0.7832
4
1
347.4
4
1
5.4
1
293.15
5
2
0.8654
4
1
372.6
4
1
5.8
1
293.15
5
2
0.9289
4
1
392.1
4
1
6.1
1
298.15
5
2
0.0522
3
1
122.4
4
1
1.9
1
298.15
5
2
0.1
4
1
137
4
1
2.1
1
298.15
5
2
0.1966
4
1
167
4
1
2.6
1
298.15
5
2
0.3059
4
1
201.3
4
1
3.1
1
298.15
5
2
0.4061
4
1
232.5
4
1
3.6
1
298.15
5
2
0.5025
4
1
262.7
4
1
4.1
1
298.15
5
2
0.5889
4
1
289.4
4
1
4.5
1
298.15
5
2
0.6844
4
1
318.9
4
1
4.9
1
298.15
5
2
0.7832
4
1
349.2
4
1
5.4
1
298.15
5
2
0.8654
4
1
374.6
4
1
5.8
1
298.15
5
2
0.9289
4
1
394.3
4
1
6.1
1
303.15
5
2
0.0522
3
1
122.8
4
1
1.9
1
303.15
5
2
0.1
4
1
137.5
4
1
2.1
1
303.15
5
2
0.1966
4
1
167.7
4
1
2.6
1
303.15
5
2
0.3059
4
1
202.3
4
1
3.1
1
303.15
5
2
0.4061
4
1
233.6
4
1
3.6
1
303.15
5
2
0.5025
4
1
263.9
4
1
4.1
1
303.15
5
2
0.5889
4
1
290.9
4
1
4.5
1
303.15
5
2
0.6844
4
1
320.6
4
1
5
1
303.15
5
2
0.7832
4
1
351.1
4
1
5.4
1
303.15
5
2
0.8654
4
1
376.7
4
1
5.8
1
303.15
5
2
0.9289
4
1
396.5
4
1
6.1
1
308.15
5
2
0.0522
3
1
123.3
4
1
1.9
1
308.15
5
2
0.1
4
1
138.1
4
1
2.1
1
308.15
5
2
0.1966
4
1
168.4
4
1
2.6
1
308.15
5
2
0.3059
4
1
203.2
4
1
3.1
1
308.15
5
2
0.4061
4
1
234.8
4
1
3.6
1
308.15
5
2
0.5025
4
1
265.1
4
1
4.1
1
308.15
5
2
0.5889
4
1
292.4
4
1
4.5
1
308.15
5
2
0.6844
4
1
322.2
4
1
5
1
308.15
5
2
0.7832
4
1
352.9
4
1
5.5
1
308.15
5
2
0.8654
4
1
378.7
4
1
5.9
1
308.15
5
2
0.9289
4
1
398.7
4
1
6.2
1
313.15
5
2
0.0522
3
1
123.8
4
1
1.9
1
313.15
5
2
0.1
4
1
138.7
4
1
2.2
1
313.15
5
2
0.1966
4
1
169.1
4
1
2.6
1
313.15
5
2
0.3059
4
1
204.1
4
1
3.2
1
313.15
5
2
0.4061
4
1
235.9
4
1
3.7
1
313.15
5
2
0.5025
4
1
266.3
4
1
4.1
1
313.15
5
2
0.5889
4
1
293.8
4
1
4.6
1
313.15
5
2
0.6844
4
1
323.9
4
1
5
1
313.15
5
2
0.7832
4
1
354.7
4
1
5.5
1
313.15
5
2
0.8654
4
1
380.8
4
1
5.9
1
313.15
5
2
0.9289
4
1
400.8
4
1
6.2
1
318.15
5
2
0.0522
3
1
124.2
4
1
1.9
1
318.15
5
2
0.1
4
1
139.1
4
1
2.2
1
318.15
5
2
0.1966
4
1
169.7
4
1
2.6
1
318.15
5
2
0.3059
4
1
205
4
1
3.2
1
318.15
5
2
0.4061
4
1
237
4
1
3.7
1
318.15
5
2
0.5025
4
1
267.4
4
1
4.1
1
318.15
5
2
0.5889
4
1
295.3
4
1
4.6
1
318.15
5
2
0.6844
4
1
325.6
4
1
5
1
318.15
5
2
0.7832
4
1
356.5
4
1
5.5
1
318.15
5
2
0.8654
4
1
382.8
4
1
5.9
1
318.15
5
2
0.9289
4
1
403
4
1
6.2
39
7
1
4
1
Principal objective of the work
BLC
TRC
3/24/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101.3
4
1
Temperature, K
Liquid
2
Mole fraction
4
Liquid
1
293.15
5
2
0.0522
3
1
1158.1
5
1
0.7
1
293.15
5
2
0.1
4
1
1168.5
5
1
0.8
1
293.15
5
2
0.1966
4
1
1182.1
5
1
0.8
1
293.15
5
2
0.3059
4
1
1191.3
5
1
0.9
1
293.15
5
2
0.4061
4
1
1196.9
5
1
0.9
1
293.15
5
2
0.5025
4
1
1200.8
5
1
1
1
293.15
5
2
0.5889
4
1
1203.5
5
1
1
1
293.15
5
2
0.6844
4
1
1205.9
5
1
1.1
1
293.15
5
2
0.7832
4
1
1207.8
5
1
1.2
1
293.15
5
2
0.8654
4
1
1209.1
5
1
1.2
1
293.15
5
2
0.9289
4
1
1210
5
1
1.3
1
298.15
5
2
0.0522
3
1
1152.1
5
1
0.7
1
298.15
5
2
0.1
4
1
1163
5
1
0.7
1
298.15
5
2
0.1966
4
1
1177.3
5
1
0.8
1
298.15
5
2
0.3059
4
1
1186.9
5
1
0.9
1
298.15
5
2
0.4061
4
1
1192.8
5
1
0.9
1
298.15
5
2
0.5025
4
1
1196.9
5
1
1
1
298.15
5
2
0.5889
4
1
1199.8
5
1
1
1
298.15
5
2
0.6844
4
1
1202.2
5
1
1.1
1
298.15
5
2
0.7832
4
1
1204.3
5
1
1.2
1
298.15
5
2
0.8654
4
1
1205.7
5
1
1.2
1
298.15
5
2
0.9289
4
1
1206.7
5
1
1.2
1
303.15
5
2
0.0522
3
1
1146.1
5
1
0.7
1
303.15
5
2
0.1
4
1
1157.5
5
1
0.7
1
303.15
5
2
0.1966
4
1
1172.4
5
1
0.8
1
303.15
5
2
0.3059
4
1
1182.6
5
1
0.9
1
303.15
5
2
0.4061
4
1
1188.7
5
1
0.9
1
303.15
5
2
0.5025
4
1
1193
5
1
1
1
303.15
5
2
0.5889
4
1
1196
5
1
1
1
303.15
5
2
0.6844
4
1
1198.6
5
1
1.1
1
303.15
5
2
0.7832
4
1
1200.8
5
1
1.1
1
303.15
5
2
0.8654
4
1
1202.3
5
1
1.2
1
303.15
5
2
0.9289
4
1
1203.3
5
1
1.2
1
308.15
5
2
0.0522
3
1
1140.1
5
1
0.7
1
308.15
5
2
0.1
4
1
1152
5
1
0.7
1
308.15
5
2
0.1966
4
1
1167.6
5
1
0.8
1
308.15
5
2
0.3059
4
1
1178.2
5
1
0.9
1
308.15
5
2
0.4061
4
1
1184.7
5
1
0.9
1
308.15
5
2
0.5025
4
1
1189.2
5
1
1
1
308.15
5
2
0.5889
4
1
1192.3
5
1
1
1
308.15
5
2
0.6844
4
1
1195
5
1
1.1
1
308.15
5
2
0.7832
4
1
1197.4
5
1
1.1
1
308.15
5
2
0.8654
4
1
1199
5
1
1.2
1
308.15
5
2
0.9289
4
1
1200
5
1
1.2
1
313.15
5
2
0.0522
3
1
1134.1
5
1
0.7
1
313.15
5
2
0.1
4
1
1146.5
5
1
0.7
1
313.15
5
2
0.1966
4
1
1162.8
5
1
0.8
1
313.15
5
2
0.3059
4
1
1173.9
5
1
0.9
1
313.15
5
2
0.4061
4
1
1180.6
5
1
0.9
1
313.15
5
2
0.5025
4
1
1185.3
5
1
1
1
313.15
5
2
0.5889
4
1
1188.6
5
1
1
1
313.15
5
2
0.6844
4
1
1191.5
5
1
1.1
1
313.15
5
2
0.7832
4
1
1193.9
5
1
1.1
1
313.15
5
2
0.8654
4
1
1195.6
5
1
1.2
1
313.15
5
2
0.9289
4
1
1196.6
5
1
1.2
1
318.15
5
2
0.0522
3
1
1128.1
5
1
0.7
1
318.15
5
2
0.1
4
1
1141
5
1
0.7
1
318.15
5
2
0.1966
4
1
1158
5
1
0.8
1
318.15
5
2
0.3059
4
1
1169.5
5
1
0.8
1
318.15
5
2
0.4061
4
1
1176.6
5
1
0.9
1
318.15
5
2
0.5025
4
1
1181.5
5
1
1
1
318.15
5
2
0.5889
4
1
1184.9
5
1
1
1
318.15
5
2
0.6844
4
1
1187.9
5
1
1.1
1
318.15
5
2
0.7832
4
1
1190.4
5
1
1.1
1
318.15
5
2
0.8654
4
1
1192.2
5
1
1.2
1
318.15
5
2
0.9289
4
1
1193.3
5
1
1.2