2
0
2008
wis
cor
0
journal
Original
Wisniak, J.[Jaime]
Cortez, G.[Gladis]
Peralta, R. D.[Rene D.]
Infante, R.[Ramiro]
Elizalde, L. E.[Luis E.]
Amaro, T. A.[Tlaloc A.]
Garcia, O.[Omar]
Soto, H.[Homero]
J. Chem. Thermodyn.
2008
2020-09-29
Density, excess volume, and excess coefficient of thermal expansion of the binary systems of dimethyl carbonate with butyl methacrylate, allyl methacrylate, styrene, and vinyl acetate at T = (293.15, 303.15, and 313.15) K
Densities of the binary systems of dimethyl carbonate with butyl methacrylate, allyl methacrylate, styrene, and vinyl acetate have been measured as a function of the composition at (293.15, 303.15, and 313.15) K at atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The excess molar volumes are negative for the (dimethyl carbonate + vinyl acetate) system and positive for the three other binaries, and become more so as the temperature increases from (293.15 to 313.15) K. The apparent volumes were used to calculate the values of the partial excess molar volumes at infinite dilution. The excess coefficient of thermal expansion is positive for the four binary systems. The calculated excess molar volumes were correlated with the Redlich Kister equation and with a series of Legendre polynomials. An explanation of the results is offered based on the FT-IR (ATR) spectra of several mixtures of the different systems.
Densities
Excess molar volumes
Apparent properties
Monomers
Dimethyl carbonate
Methacrylates
Styrene
Vinyl acetate
Densimeter
10.1016/j.jct.2008.06.017
12
40
1671-1683
1
InChI=1S/C3H6O3/c1-5-3(4)6-2/h1-2H3
IEJIGPNLZYLLBP-UHFFFAOYSA-N
dimethyl carbonate
C3H6O3
1
Commercial source
1
99.95
4
Stated by supplier
2
InChI=1S/C8H14O2/c1-4-5-6-10-8(9)7(2)3/h2,4-6H2,1,3H3
SOGAXMICEFXMKE-UHFFFAOYSA-N
butyl 2-methyl-2-propenoate
2-propenoic acid, 2-methyl-, butyl ester
butyl 2-methylpropenoate
butyl methacrylate
methacrylic acid, butyl ester
C8H14O2
1
Commercial source
1
99.5
3
Stated by supplier
2
Fractional distillation
3
InChI=1S/C7H10O2/c1-4-5-9-7(8)6(2)3/h4H,1-2,5H2,3H3
FBCQUCJYYPMKRO-UHFFFAOYSA-N
2-propenyl 2-methylpropenoate
2-methylpropenoic acid, allyl ester
allyl 2-methylpropenoate
allyl methacrylate
methacrylic acid, allyl ester
C7H10O2
1
Commercial source
1
99.3
3
Stated by supplier
2
Fractional distillation
4
InChI=1S/C8H8/c1-2-8-6-4-3-5-7-8/h2-7H,1H2
PPBRXRYQALVLMV-UHFFFAOYSA-N
styrene
benzene, ethenyl-
ethenylbenzene
phenylethene
phenylethylene
vinylbenzene
C8H8
1
Commercial source
1
99.9
3
Stated by supplier
2
Fractional distillation
5
InChI=1S/C4H6O2/c1-3-6-4(2)5/h3H,1H2,2H3
XTXRWKRVRITETP-UHFFFAOYSA-N
vinyl acetate
acetic acid, vinyl ester
ethanoic acid, ethenyl ester
ethenyl ethanoate
vinyl ethanoate
C4H6O2
1
Commercial source
1
99.9
3
Stated by supplier
2
Fractional distillation
1
1
1
Principal objective of the work
JWM
TRC
3/6/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Air at 1 atmosphere
1
Temperature, K
Liquid
1
293.15
5
1
1069.794
7
1
0.068
1
303.15
5
1
1056.75
7
1
0.064
1
313.15
5
1
1043.369
7
1
0.06
2
2
1
Principal objective of the work
JWM
TRC
3/6/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Air at 1 atmosphere
1
Temperature, K
Liquid
1
293.15
5
1
895.231
6
1
0.112
1
303.15
5
1
885.991
6
1
0.115
1
313.15
5
1
876.19
6
1
0.118
3
3
1
Principal objective of the work
JWM
TRC
3/6/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Air at 1 atmosphere
1
Temperature, K
Liquid
1
293.15
5
1
932.965
6
1
0.142
1
303.15
5
1
922.525
6
1
0.144
1
313.15
5
1
912.072
6
1
0.146
4
4
1
Principal objective of the work
JWM
TRC
3/6/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Air at 1 atmosphere
1
Temperature, K
Liquid
1
293.15
5
1
906.26
6
1
0.075
1
303.15
5
1
897.392
6
1
0.078
1
313.15
5
1
888.472
6
1
0.081
5
5
1
Principal objective of the work
JWM
TRC
3/6/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Air at 1 atmosphere
1
Temperature, K
Liquid
1
293.15
5
1
931.95
6
1
0.068
1
303.15
5
1
919.089
6
1
0.072
1
313.15
5
1
906.116
6
1
0.076
6
2
1
1
1
Principal objective of the work
PW
TRC
3/6/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Air at 1 atmosphere
1
Temperature, K
Liquid
2
Mole fraction
1
Liquid
1
293.15
5
2
0
2
1
895.231
6
1
0.111
1
293.15
5
2
0.0253
3
1
897.401
6
1
0.11
1
293.15
5
2
0.0496
3
1
899.525
6
1
0.108
1
293.15
5
2
0.1
4
1
904.247
6
1
0.103
1
293.15
5
2
0.1512
4
1
909.195
6
1
0.099
1
293.15
5
2
0.2002
4
1
914.234
6
1
0.095
1
293.15
5
2
0.2501
4
1
919.652
6
1
0.092
1
293.15
5
2
0.3
4
1
925.514
6
1
0.088
1
293.15
5
2
0.3496
4
1
931.664
6
1
0.085
1
293.15
5
2
0.4002
4
1
938.381
6
1
0.082
1
293.15
5
2
0.45
4
1
945.36
6
1
0.079
1
293.15
5
2
0.4998
4
1
952.885
6
1
0.076
1
293.15
5
2
0.5499
4
1
960.906
6
1
0.074
1
293.15
5
2
0.6
4
1
969.499
6
1
0.071
1
293.15
5
2
0.6499
4
1
978.774
6
1
0.07
1
293.15
5
2
0.7003
4
1
988.865
6
1
0.069
1
293.15
5
2
0.7501
4
1
999.691
6
1
0.068
1
293.15
5
2
0.7998
4
1
1011.242
7
1
0.072
1
293.15
5
2
0.8502
4
1
1024.043
7
1
0.076
1
293.15
5
2
0.8997
4
1
1037.815
7
1
0.082
1
293.15
5
2
0.9499
4
1
1053.101
7
1
0.087
1
293.15
5
2
0.9747
4
1
1061.178
7
1
0.091
1
293.15
5
2
1
5
1
1069.794
7
1
0.067
1
303.15
5
2
0
2
1
885.991
6
1
0.114
1
303.15
5
2
0.0255
3
1
888.128
6
1
0.112
1
303.15
5
2
0.0511
3
1
890.378
6
1
0.11
1
303.15
5
2
0.0984
3
1
894.561
6
1
0.106
1
303.15
5
2
0.1496
4
1
899.445
6
1
0.101
1
303.15
5
2
0.1998
4
1
904.542
6
1
0.098
1
303.15
5
2
0.251
4
1
909.93
6
1
0.094
1
303.15
5
2
0.3
4
1
915.538
6
1
0.091
1
303.15
5
2
0.3498
4
1
921.462
6
1
0.087
1
303.15
5
2
0.4002
4
1
927.876
6
1
0.084
1
303.15
5
2
0.4505
4
1
934.768
6
1
0.081
1
303.15
5
2
0.5001
4
1
942.022
6
1
0.078
1
303.15
5
2
0.5497
4
1
949.757
6
1
0.076
1
303.15
5
2
0.6003
4
1
958.326
6
1
0.074
1
303.15
5
2
0.6507
4
1
967.581
6
1
0.072
1
303.15
5
2
0.7003
4
1
977.274
6
1
0.07
1
303.15
5
2
0.7503
4
1
987.854
6
1
0.069
1
303.15
5
2
0.8003
4
1
999.303
6
1
0.069
1
303.15
5
2
0.8497
4
1
1011.722
7
1
0.073
1
303.15
5
2
0.8997
4
1
1025.31
7
1
0.079
1
303.15
5
2
0.95
4
1
1040.302
7
1
0.083
1
303.15
5
2
0.9746
4
1
1048.258
7
1
0.088
1
303.15
5
2
1
5
1
1056.75
7
1
0.063
1
313.15
5
2
0
2
1
876.19
6
1
0.117
1
313.15
5
2
0.0248
3
1
878.23
6
1
0.115
1
313.15
5
2
0.0506
3
1
880.426
6
1
0.113
1
313.15
5
2
0.1009
4
1
884.856
6
1
0.109
1
313.15
5
2
0.1505
4
1
889.457
6
1
0.104
1
313.15
5
2
0.2003
4
1
894.361
6
1
0.1
1
313.15
5
2
0.2512
4
1
899.681
6
1
0.097
1
313.15
5
2
0.3005
4
1
905.153
6
1
0.093
1
313.15
5
2
0.3502
4
1
910.961
6
1
0.09
1
313.15
5
2
0.4009
4
1
917.353
6
1
0.087
1
313.15
5
2
0.4509
4
1
924.075
6
1
0.084
1
313.15
5
2
0.4999
4
1
931.103
6
1
0.081
1
313.15
5
2
0.5506
4
1
938.855
6
1
0.078
1
313.15
5
2
0.6
4
1
947.003
6
1
0.076
1
313.15
5
2
0.6502
4
1
955.954
6
1
0.074
1
313.15
5
2
0.7002
4
1
965.503
6
1
0.072
1
313.15
5
2
0.7503
4
1
975.976
6
1
0.071
1
313.15
5
2
0.7999
4
1
987.089
6
1
0.071
1
313.15
5
2
0.8501
4
1
999.417
6
1
0.071
1
313.15
5
2
0.8998
4
1
1012.692
7
1
0.076
1
313.15
5
2
0.9498
4
1
1027.299
7
1
0.08
1
313.15
5
2
0.9751
4
1
1035.147
7
1
0.085
1
313.15
5
2
1
5
1
1043.369
7
1
0.06
7
3
1
1
1
Principal objective of the work
PW
TRC
3/6/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Air at 1 atmosphere
1
Temperature, K
Liquid
2
Mole fraction
1
Liquid
1
293.15
5
2
0
2
1
932.965
6
1
0.141
1
293.15
5
2
0.0254
3
1
935.07
6
1
0.137
1
293.15
5
2
0.0498
3
1
937.164
6
1
0.133
1
293.15
5
2
0.1006
4
1
941.619
6
1
0.125
1
293.15
5
2
0.1507
4
1
946.22
6
1
0.117
1
293.15
5
2
0.2
4
1
950.913
6
1
0.109
1
293.15
5
2
0.2505
4
1
955.966
6
1
0.102
1
293.15
5
2
0.2999
4
1
961.134
6
1
0.096
1
293.15
5
2
0.3499
4
1
966.623
6
1
0.09
1
293.15
5
2
0.4005
4
1
972.4
6
1
0.084
1
293.15
5
2
0.449
4
1
978.208
6
1
0.08
1
293.15
5
2
0.5
4
1
984.616
6
1
0.075
1
293.15
5
2
0.5499
4
1
991.215
6
1
0.071
1
293.15
5
2
0.5991
4
1
998.042
6
1
0.067
1
293.15
5
2
0.6502
4
1
1005.492
7
1
0.066
1
293.15
5
2
0.7
4
1
1013.175
7
1
0.067
1
293.15
5
2
0.7502
4
1
1021.341
7
1
0.068
1
293.15
5
2
0.8001
4
1
1029.9
7
1
0.069
1
293.15
5
2
0.8499
4
1
1039.003
7
1
0.071
1
293.15
5
2
0.9002
4
1
1048.706
7
1
0.074
1
293.15
5
2
0.9499
4
1
1058.874
7
1
0.076
1
293.15
5
2
0.975
4
1
1064.272
7
1
0.078
1
293.15
5
2
1
1
1
1069.794
7
1
0.067
1
303.15
5
2
0
2
1
922.525
6
1
0.143
1
303.15
5
2
0.0253
3
1
924.591
6
1
0.14
1
303.15
5
2
0.0501
3
1
926.656
6
1
0.136
1
303.15
5
2
0.101
4
1
931.041
6
1
0.127
1
303.15
5
2
0.15
4
1
935.458
6
1
0.12
1
303.15
5
2
0.1999
4
1
940.145
6
1
0.112
1
303.15
5
2
0.2505
4
1
945.101
6
1
0.105
1
303.15
5
2
0.2999
4
1
950.165
6
1
0.098
1
303.15
5
2
0.3499
4
1
955.527
6
1
0.092
1
303.15
5
2
0.4003
4
1
961.195
6
1
0.087
1
303.15
5
2
0.447
4
1
966.662
6
1
0.082
1
303.15
5
2
0.5001
4
1
973.205
6
1
0.077
1
303.15
5
2
0.5501
4
1
979.68
6
1
0.073
1
303.15
5
2
0.5994
4
1
986.387
6
1
0.069
1
303.15
5
2
0.6502
4
1
993.661
6
1
0.066
1
303.15
5
2
0.7001
4
1
1001.189
7
1
0.064
1
303.15
5
2
0.7503
4
1
1009.19
7
1
0.065
1
303.15
5
2
0.8001
4
1
1017.583
7
1
0.066
1
303.15
5
2
0.8499
4
1
1026.466
7
1
0.068
1
303.15
5
2
0.9002
4
1
1035.995
7
1
0.07
1
303.15
5
2
0.9499
4
1
1046.001
7
1
0.073
1
303.15
5
2
0.975
4
1
1051.3
7
1
0.075
1
303.15
5
2
1
1
1
1056.75
7
1
0.063
1
313.15
5
2
0
2
1
912.072
6
1
0.145
1
313.15
5
2
0.0247
3
1
914.028
6
1
0.142
1
313.15
5
2
0.0499
3
1
916.075
6
1
0.138
1
313.15
5
2
0.1002
4
1
920.29
6
1
0.13
1
313.15
5
2
0.1496
4
1
924.626
6
1
0.122
1
313.15
5
2
0.1997
4
1
929.2
6
1
0.115
1
313.15
5
2
0.2495
4
1
933.94
6
1
0.108
1
313.15
5
2
0.2999
4
1
938.979
6
1
0.101
1
313.15
5
2
0.3502
4
1
944.239
6
1
0.095
1
313.15
5
2
0.3999
4
1
949.688
6
1
0.09
1
313.15
5
2
0.4499
4
1
955.431
6
1
0.085
1
313.15
5
2
0.4997
4
1
961.436
6
1
0.08
1
313.15
5
2
0.5503
4
1
967.862
6
1
0.076
1
313.15
5
2
0.6001
4
1
974.504
6
1
0.072
1
313.15
5
2
0.6497
4
1
981.462
6
1
0.069
1
313.15
5
2
0.7001
4
1
988.916
6
1
0.066
1
313.15
5
2
0.7498
4
1
996.664
6
1
0.063
1
313.15
5
2
0.7998
4
1
1004.932
7
1
0.063
1
313.15
5
2
0.85
4
1
1013.713
7
1
0.065
1
313.15
5
2
0.8998
4
1
1022.998
7
1
0.067
1
313.15
5
2
0.9498
4
1
1032.834
7
1
0.069
1
313.15
5
2
0.9746
4
1
1037.942
7
1
0.071
1
313.15
5
2
1
1
1
1043.369
7
1
0.06
8
4
1
1
1
Principal objective of the work
PW
TRC
3/6/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Air at 1 atmosphere
1
Temperature, K
Liquid
2
Mole fraction
1
Liquid
1
293.15
5
2
0
2
1
906.26
6
1
0.075
1
293.15
5
2
0.0246
3
1
909.146
6
1
0.077
1
293.15
5
2
0.0498
3
1
912.112
6
1
0.076
1
293.15
5
2
0.1006
4
1
918.267
6
1
0.075
1
293.15
5
2
0.1506
4
1
924.493
6
1
0.073
1
293.15
5
2
0.2004
4
1
930.891
6
1
0.072
1
293.15
5
2
0.2506
4
1
937.533
6
1
0.07
1
293.15
5
2
0.3008
4
1
944.38
6
1
0.069
1
293.15
5
2
0.3498
4
1
951.272
6
1
0.067
1
293.15
5
2
0.4007
4
1
958.655
6
1
0.066
1
293.15
5
2
0.4498
4
1
966.048
6
1
0.065
1
293.15
5
2
0.5001
4
1
973.84
6
1
0.063
1
293.15
5
2
0.5499
4
1
981.838
6
1
0.062
1
293.15
5
2
0.5996
4
1
990.075
6
1
0.061
1
293.15
5
2
0.6507
4
1
998.871
6
1
0.06
1
293.15
5
2
0.7001
4
1
1007.723
7
1
0.062
1
293.15
5
2
0.7496
4
1
1016.934
7
1
0.065
1
293.15
5
2
0.7997
4
1
1026.611
7
1
0.067
1
293.15
5
2
0.8501
4
1
1036.777
7
1
0.07
1
293.15
5
2
0.9001
4
1
1047.288
7
1
0.074
1
293.15
5
2
0.9499
4
1
1058.267
7
1
0.077
1
293.15
5
2
0.9747
4
1
1063.93
7
1
0.079
1
293.15
5
2
1
1
1
1069.794
7
1
0.067
1
303.15
5
2
0
2
1
897.392
6
1
0.077
1
303.15
5
2
0.0262
3
1
900.37
6
1
0.079
1
303.15
5
2
0.0502
3
1
903.146
6
1
0.079
1
303.15
5
2
0.1004
4
1
909.105
6
1
0.077
1
303.15
5
2
0.1506
4
1
915.204
6
1
0.076
1
303.15
5
2
0.2005
4
1
921.462
6
1
0.074
1
303.15
5
2
0.2502
4
1
927.883
6
1
0.073
1
303.15
5
2
0.3001
4
1
934.514
6
1
0.071
1
303.15
5
2
0.3502
4
1
941.367
6
1
0.07
1
303.15
5
2
0.4
4
1
948.407
6
1
0.068
1
303.15
5
2
0.45
4
1
955.705
6
1
0.067
1
303.15
5
2
0.5003
4
1
963.262
6
1
0.065
1
303.15
5
2
0.5498
4
1
971.001
6
1
0.064
1
303.15
5
2
0.5998
4
1
979.074
6
1
0.063
1
303.15
5
2
0.6497
4
1
987.452
6
1
0.062
1
303.15
5
2
0.7007
4
1
996.305
6
1
0.061
1
303.15
5
2
0.7502
4
1
1005.274
7
1
0.062
1
303.15
5
2
0.8002
4
1
1014.685
7
1
0.065
1
303.15
5
2
0.85
4
1
1024.502
7
1
0.067
1
303.15
5
2
0.8999
4
1
1034.719
7
1
0.07
1
303.15
5
2
0.9502
4
1
1045.498
7
1
0.073
1
303.15
5
2
0.975
4
1
1051.047
7
1
0.076
1
303.15
5
2
1
1
1
1056.75
7
1
0.063
1
313.15
5
2
0
2
1
888.472
6
1
0.08
1
313.15
5
2
0.0256
3
1
891.333
6
1
0.082
1
313.15
5
2
0.0501
3
1
894.082
6
1
0.081
1
313.15
5
2
0.0998
3
1
899.822
6
1
0.08
1
313.15
5
2
0.1514
4
1
905.948
6
1
0.078
1
313.15
5
2
0.2007
4
1
911.977
6
1
0.077
1
313.15
5
2
0.2506
4
1
918.225
6
1
0.075
1
313.15
5
2
0.3008
4
1
924.745
6
1
0.073
1
313.15
5
2
0.3499
4
1
931.26
6
1
0.072
1
313.15
5
2
0.4006
4
1
938.218
6
1
0.07
1
313.15
5
2
0.4501
4
1
945.282
6
1
0.069
1
313.15
5
2
0.5103
4
1
954.115
6
1
0.067
1
313.15
5
2
0.5503
4
1
960.19
6
1
0.066
1
313.15
5
2
0.5995
4
1
967.947
6
1
0.065
1
313.15
5
2
0.6499
4
1
976.16
6
1
0.064
1
313.15
5
2
0.6999
4
1
984.624
6
1
0.063
1
313.15
5
2
0.7503
4
1
993.432
6
1
0.062
1
313.15
5
2
0.8002
4
1
1002.61
7
1
0.062
1
313.15
5
2
0.8499
4
1
1012.093
7
1
0.064
1
313.15
5
2
0.9001
4
1
1022.038
7
1
0.067
1
313.15
5
2
0.9497
4
1
1032.413
7
1
0.07
1
313.15
5
2
0.975
4
1
1037.837
7
1
0.072
1
313.15
5
2
1
1
1
1043.369
7
1
0.06
9
5
1
1
1
Principal objective of the work
PW
TRC
3/6/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
Air at 1 atmosphere
1
Temperature, K
Liquid
2
Mole fraction
1
Liquid
1
293.15
5
2
0
2
1
931.95
6
1
0.067
1
293.15
5
2
0.025
3
1
935.258
6
1
0.071
1
293.15
5
2
0.0504
3
1
938.581
6
1
0.07
1
293.15
5
2
0.1002
4
1
945.231
6
1
0.069
1
293.15
5
2
0.1537
4
1
952.421
6
1
0.067
1
293.15
5
2
0.1999
4
1
958.65
6
1
0.065
1
293.15
5
2
0.25
4
1
965.315
6
1
0.064
1
293.15
5
2
0.3001
4
1
972.123
6
1
0.062
1
293.15
5
2
0.3498
4
1
978.865
6
1
0.061
1
293.15
5
2
0.4002
4
1
985.701
6
1
0.059
1
293.15
5
2
0.4503
4
1
992.611
6
1
0.058
1
293.15
5
2
0.5
4
1
999.443
6
1
0.057
1
293.15
5
2
0.5502
4
1
1006.391
7
1
0.058
1
293.15
5
2
0.6001
4
1
1013.375
7
1
0.059
1
293.15
5
2
0.6495
4
1
1020.263
7
1
0.061
1
293.15
5
2
0.6934
4
1
1026.465
7
1
0.062
1
293.15
5
2
0.7501
4
1
1034.481
7
1
0.064
1
293.15
5
2
0.7971
4
1
1041.095
7
1
0.065
1
293.15
5
2
0.8499
4
1
1048.598
7
1
0.067
1
293.15
5
2
0.9002
4
1
1055.592
7
1
0.069
1
293.15
5
2
0.9493
4
1
1062.611
7
1
0.071
1
293.15
5
2
0.975
4
1
1066.221
7
1
0.071
1
293.15
5
2
1
1
1
1069.794
7
1
0.067
1
303.15
5
2
0
2
1
919.089
6
1
0.071
1
303.15
5
2
0.025
3
1
922.4
6
1
0.074
1
303.15
5
2
0.0501
3
1
925.708
6
1
0.074
1
303.15
5
2
0.0999
3
1
932.33
6
1
0.072
1
303.15
5
2
0.15
4
1
939.009
6
1
0.07
1
303.15
5
2
0.1998
4
1
945.689
6
1
0.068
1
303.15
5
2
0.2499
4
1
952.431
6
1
0.067
1
303.15
5
2
0.3004
4
1
959.251
6
1
0.065
1
303.15
5
2
0.35
4
1
965.996
6
1
0.064
1
303.15
5
2
0.4003
4
1
972.857
6
1
0.062
1
303.15
5
2
0.4488
4
1
979.518
6
1
0.061
1
303.15
5
2
0.4999
4
1
986.544
6
1
0.059
1
303.15
5
2
0.5496
4
1
993.403
6
1
0.058
1
303.15
5
2
0.6
4
1
1000.407
7
1
0.057
1
303.15
5
2
0.6489
4
1
1007.219
7
1
0.058
1
303.15
5
2
0.6986
4
1
1014.134
7
1
0.059
1
303.15
5
2
0.7494
4
1
1021.257
7
1
0.061
1
303.15
5
2
0.8
4
1
1028.361
7
1
0.062
1
303.15
5
2
0.8496
4
1
1035.375
7
1
0.064
1
303.15
5
2
0.8999
4
1
1042.51
7
1
0.066
1
303.15
5
2
0.9496
4
1
1049.558
7
1
0.067
1
303.15
5
2
0.9753
4
1
1053.222
7
1
0.068
1
303.15
5
2
1
1
1
1056.75
7
1
0.063
1
313.15
5
2
0
2
1
906.116
6
1
0.075
1
313.15
5
2
0.0248
3
1
909.387
6
1
0.078
1
313.15
5
2
0.0501
3
1
912.718
6
1
0.077
1
313.15
5
2
0.1003
4
1
919.392
6
1
0.075
1
313.15
5
2
0.1499
4
1
925.976
6
1
0.073
1
313.15
5
2
0.2001
4
1
932.73
6
1
0.072
1
313.15
5
2
0.25
4
1
939.446
6
1
0.07
1
313.15
5
2
0.2999
4
1
946.16
6
1
0.068
1
313.15
5
2
0.3502
4
1
953.002
6
1
0.067
1
313.15
5
2
0.3999
4
1
959.753
6
1
0.065
1
313.15
5
2
0.45
4
1
966.575
6
1
0.063
1
313.15
5
2
0.4996
4
1
973.402
6
1
0.062
1
313.15
5
2
0.5501
4
1
980.351
6
1
0.06
1
313.15
5
2
0.5998
4
1
987.189
6
1
0.059
1
313.15
5
2
0.6502
4
1
994.195
6
1
0.058
1
313.15
5
2
0.7
4
1
1001.115
7
1
0.057
1
313.15
5
2
0.7501
4
1
1008.142
7
1
0.058
1
313.15
5
2
0.7999
4
1
1015.14
7
1
0.059
1
313.15
5
2
0.8499
4
1
1022.146
7
1
0.061
1
313.15
5
2
0.8995
4
1
1029.121
7
1
0.062
1
313.15
5
2
0.9501
4
1
1036.31
7
1
0.064
1
313.15
5
2
0.9746
4
1
1039.752
7
1
0.065
1
313.15
5
2
1
1
1
1043.369
7
1
0.06