2
0
2009
roy
ban
0
journal
Original
Roy, M. N.[Mahendra Nath]
Banerjee, A.[Ashis]
Roy, P. K.[Pran Kumar]
Int. J. Thermophys.
2009
2020-09-29
Partial Molar Volumes and Viscosity B-Coefficients of Nicotinamide in Aqueous Resorcinol Solutions at T=(298.15, 308.15, and 318.15)K
Partial molar volumes (oo v ) and viscosity B-coefficients for nicotinamide in (0.00, 0.05, 0.10, 0.15, and 0.20) mol*dm.3 aqueous resorcinol solutions have been determined from solution density and viscosity measurements at (298.15, 308.15, and 318.15)K as a function of the concentration of nicotinamide (NA). Here the relation oo v = a0 + a1T + a2T 2, has been used to describe the temperature dependence of the partial molar volume oo v . These results and the results obtained in pure water were used to calculate the standard volumes of transfer oo v and viscosity B-coefficients of transfer of nicotinamide from water to aqueous resorcinol solutions to study various interactions in the ternary solutions. The partial molar volume (oo v ) and experimental slopes obtained from the Masson equation have been interpreted in terms of solute solvent and solute solute interactions, respectively. The viscosity data have been analyzed using the Jones Dole equation, and the derived parameters B and A have also been interpreted in terms of solute solvent and solute solute interactions, respectively, in the ternary solutions.The structure making or breaking ability of nicotinamide has been discussed in terms of the sign of (a2oo v /aT 2)P. The activation parameters of viscous flow for the ternary solutions studied were also calculated and explained by the application of transition state theory.
Density
Nicotinamide
Partial molar volume
Resorcinol
Solute-solvent and solute-solute interactions
Viscosity
Viscosity B-coefficient
10.1007/s10765-009-0567-5
2
30
515-528
1
InChI=1S/C6H6O2/c7-5-2-1-3-6(8)4-5/h1-4,7-8H
GHMLBKRAJCXXBS-UHFFFAOYSA-N
1,3-benzenediol
1,3-dihydroxybenzene
3-hydroxyphenol
m-benzenediol
m-dihydroxybenzene
resorcinol
C6H6O2
1
Commercial source
1
Dried in a desiccator
2
InChI=1S/C6H6N2O/c7-6(9)5-2-1-3-8-4-5/h1-4H,(H2,7,9)
DFPAKSUCGFBDDF-UHFFFAOYSA-N
3-pyridinecarboxamide
niacinamide
nicotinamide
nicotinic acid amide
C6H6N2O
1
Commercial source
1
98
2
Stated by supplier
2
None used
3
InChI=1S/H2O/h1H2
XLYOFNOQVPJJNP-UHFFFAOYSA-N
water
H2O
1
Synthesized by the authors
1
Fractional distillation
2
99.8
3
Estimated by the compiler
1
1
1
3
1
Principal objective of the work
RDC
TRC
4/6/2009
1
Viscosity, Pa*s
Capillary tube (Ostwald; Ubbelohde) method
Liquid
Direct value, X
3
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Amount concentration (molarity), mol/dm3
1
Liquid
2
Temperature, K
Liquid
1
0.05
1
2
298.15
5
1
0.0009
3
1
7e-06
1
0.05
1
2
308.15
5
1
0.00074
3
1
6e-06
1
0.05
1
2
318.15
5
1
0.000621
3
1
6e-06
1
0.1
2
2
298.15
5
1
0.00095
3
1
7e-06
1
0.1
2
2
308.15
5
1
0.000801
3
1
6e-06
1
0.1
2
2
318.15
5
1
0.000697
3
1
6e-06
1
0.15
2
2
298.15
5
1
0.001001
4
1
7e-06
1
0.15
2
2
308.15
5
1
0.000862
3
1
7e-06
1
0.15
2
2
318.15
5
1
0.00075
3
1
6e-06
1
0.2
2
2
298.15
5
1
0.001051
4
1
7e-06
1
0.2
2
2
308.15
5
1
0.000901
3
1
7e-06
1
0.2
2
2
318.15
5
1
0.000801
3
1
6e-06
2
1
1
3
1
Principal objective of the work
RDC
TRC
4/6/2009
1
Mass density, kg/m3
Pycnometric method
Liquid
Direct value, X
3
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Amount concentration (molarity), mol/dm3
1
Liquid
2
Temperature, K
Liquid
1
0.05
1
2
298.15
5
1
999.2
4
1
0.5
1
0.05
1
2
308.15
5
1
998.5
4
1
0.5
1
0.05
1
2
318.15
5
1
997.5
4
1
0.5
1
0.1
2
2
298.15
5
1
1000.5
5
1
0.5
1
0.1
2
2
308.15
5
1
1000.3
5
1
0.5
1
0.1
2
2
318.15
5
1
998.6
4
1
0.5
1
0.15
2
2
298.15
5
1
1001.7
5
1
0.5
1
0.15
2
2
308.15
5
1
1001.5
5
1
0.5
1
0.15
2
2
318.15
5
1
1000.4
5
1
0.5
1
0.2
2
2
298.15
5
1
1003.2
5
1
0.5
1
0.2
2
2
308.15
5
1
1002.7
5
1
0.5
1
0.2
2
2
318.15
5
1
1001
5
1
0.5
3
2
1
1
1
3
1
Principal objective of the work
RDC
TRC
4/6/2009
1
Viscosity, Pa*s
Capillary tube (Ostwald; Ubbelohde) method
Liquid
Direct value, X
1
3
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
2
Solvent: Amount concentration (molarity), mol/dm3
1
Liquid
3
Amount concentration (molarity), mol/dm3
2
Liquid
1
298.15
5
2
0.05
1
3
0.0252
3
1
0.0009081
4
1
1.27e-05
1
298.15
5
2
0.05
1
3
0.0453
3
1
0.0009122
4
1
1.28e-05
1
298.15
5
2
0.05
1
3
0.0654
3
1
0.0009165
4
1
1.28e-05
1
298.15
5
2
0.05
1
3
0.0755
3
1
0.0009185
4
1
1.28e-05
1
298.15
5
2
0.05
1
3
0.0855
3
1
0.00092
4
1
1.29e-05
1
298.15
5
2
0.05
1
3
0.0956
3
1
0.0009219
4
1
1.29e-05
1
298.15
5
2
0.1
2
3
0.025
3
1
0.0009563
4
1
1.33e-05
1
298.15
5
2
0.1
2
3
0.045
3
1
0.0009604
4
1
1.34e-05
1
298.15
5
2
0.1
2
3
0.065
3
1
0.0009644
4
1
1.34e-05
1
298.15
5
2
0.1
2
3
0.075
3
1
0.0009661
4
1
1.34e-05
1
298.15
5
2
0.1
2
3
0.085
3
1
0.0009681
4
1
1.35e-05
1
298.15
5
2
0.1
2
3
0.095
3
1
0.0009699
4
1
1.35e-05
1
298.15
5
2
0.15
2
3
0.0251
3
1
0.0010078
5
1
1.39e-05
1
298.15
5
2
0.15
2
3
0.0452
3
1
0.0010126
5
1
1.4e-05
1
298.15
5
2
0.15
2
3
0.0652
3
1
0.0010174
5
1
1.41e-05
1
298.15
5
2
0.15
2
3
0.0753
3
1
0.0010199
5
1
1.41e-05
1
298.15
5
2
0.15
2
3
0.0853
3
1
0.0010226
5
1
1.41e-05
1
298.15
5
2
0.15
2
3
0.0953
3
1
0.0010251
5
1
1.42e-05
1
298.15
5
2
0.2
2
3
0.025
3
1
0.0010577
5
1
1.46e-05
1
298.15
5
2
0.2
2
3
0.0451
3
1
0.0010629
5
1
1.46e-05
1
298.15
5
2
0.2
2
3
0.065
3
1
0.0010682
5
1
1.47e-05
1
298.15
5
2
0.2
2
3
0.0751
3
1
0.0010711
5
1
1.47e-05
1
298.15
5
2
0.2
2
3
0.085
3
1
0.001074
5
1
1.48e-05
1
298.15
5
2
0.2
2
3
0.0951
3
1
0.0010769
5
1
1.48e-05
1
308.15
5
2
0.05
1
3
0.025
3
1
0.0007453
4
1
1.07e-05
1
308.15
5
2
0.05
1
3
0.045
3
1
0.0007496
4
1
1.08e-05
1
308.15
5
2
0.05
1
3
0.0649
3
1
0.0007541
4
1
1.08e-05
1
308.15
5
2
0.05
1
3
0.0749
3
1
0.0007569
4
1
1.09e-05
1
308.15
5
2
0.05
1
3
0.085
3
1
0.0007595
4
1
1.09e-05
1
308.15
5
2
0.05
1
3
0.0949
3
1
0.0007619
4
1
1.09e-05
1
308.15
5
2
0.1
2
3
0.0249
3
1
0.0008042
4
1
1.14e-05
1
308.15
5
2
0.1
2
3
0.0449
3
1
0.0008083
4
1
1.15e-05
1
308.15
5
2
0.1
2
3
0.065
3
1
0.0008127
4
1
1.16e-05
1
308.15
5
2
0.1
2
3
0.0749
3
1
0.0008151
4
1
1.16e-05
1
308.15
5
2
0.1
2
3
0.0849
3
1
0.0008175
4
1
1.16e-05
1
308.15
5
2
0.1
2
3
0.095
3
1
0.0008199
4
1
1.16e-05
1
308.15
5
2
0.15
2
3
0.0249
3
1
0.0008653
4
1
1.22e-05
1
308.15
5
2
0.15
2
3
0.0449
3
1
0.0008701
4
1
1.25e-05
1
308.15
5
2
0.15
2
3
0.065
3
1
0.0008755
4
1
1.23e-05
1
308.15
5
2
0.15
2
3
0.075
3
1
0.0008783
4
1
1.23e-05
1
308.15
5
2
0.15
2
3
0.0849
3
1
0.0008811
4
1
1.24e-05
1
308.15
5
2
0.15
2
3
0.0949
3
1
0.000884
4
1
1.24e-05
1
308.15
5
2
0.2
2
3
0.0249
3
1
0.0009048
4
1
1.27e-05
1
308.15
5
2
0.2
2
3
0.0449
3
1
0.0009099
4
1
1.27e-05
1
308.15
5
2
0.2
2
3
0.065
3
1
0.0009159
4
1
1.28e-05
1
308.15
5
2
0.2
2
3
0.0749
3
1
0.0009192
4
1
1.29e-05
1
308.15
5
2
0.2
2
3
0.085
3
1
0.0009218
4
1
1.29e-05
1
308.15
5
2
0.2
2
3
0.095
3
1
0.0009251
4
1
1.29e-05
1
318.15
5
2
0.05
1
3
0.025
3
1
0.0006225
4
1
9.3e-06
1
318.15
5
2
0.05
1
3
0.045
3
1
0.0006259
4
1
9.3e-06
1
318.15
5
2
0.05
1
3
0.0649
3
1
0.0006298
4
1
9.4e-06
1
318.15
5
2
0.05
1
3
0.0749
3
1
0.0006319
4
1
9.4e-06
1
318.15
5
2
0.05
1
3
0.085
3
1
0.0006336
4
1
9.4e-06
1
318.15
5
2
0.05
1
3
0.095
3
1
0.000636
4
1
9.4e-06
1
318.15
5
2
0.1
2
3
0.025
3
1
0.0006991
4
1
1.02e-05
1
318.15
5
2
0.1
2
3
0.0449
3
1
0.0007035
4
1
1.02e-05
1
318.15
5
2
0.1
2
3
0.065
3
1
0.000709
4
1
1.03e-05
1
318.15
5
2
0.1
2
3
0.0749
3
1
0.0007115
4
1
1.03e-05
1
318.15
5
2
0.1
2
3
0.085
3
1
0.0007144
4
1
1.04e-05
1
318.15
5
2
0.1
2
3
0.0949
3
1
0.0007172
4
1
1.04e-05
1
318.15
5
2
0.15
2
3
0.025
3
1
0.0007517
4
1
1.08e-05
1
318.15
5
2
0.15
2
3
0.0449
3
1
0.0007568
4
1
1.09e-05
1
318.15
5
2
0.15
2
3
0.0649
3
1
0.0007628
4
1
1.09e-05
1
318.15
5
2
0.15
2
3
0.075
3
1
0.0007657
4
1
1.1e-05
1
318.15
5
2
0.15
2
3
0.0849
3
1
0.0007685
4
1
1.1e-05
1
318.15
5
2
0.15
2
3
0.0949
3
1
0.000772
4
1
1.11e-05
1
318.15
5
2
0.2
2
3
0.0249
3
1
0.0008031
4
1
1.14e-05
1
318.15
5
2
0.2
2
3
0.045
3
1
0.0008084
4
1
1.15e-05
1
318.15
5
2
0.2
2
3
0.0649
3
1
0.000815
4
1
1.16e-05
1
318.15
5
2
0.2
2
3
0.075
3
1
0.0008186
4
1
1.16e-05
1
318.15
5
2
0.2
2
3
0.0849
3
1
0.0008217
4
1
1.17e-05
1
318.15
5
2
0.2
2
3
0.0249
3
1
0.0008252
4
1
1.17e-05
4
2
1
1
1
3
1
Principal objective of the work
RDC
TRC
4/6/2009
1
Mass density, kg/m3
Pycnometric method
Liquid
Direct value, X
1
3
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
2
Solvent: Amount concentration (molarity), mol/dm3
1
Liquid
3
Amount concentration (molarity), mol/dm3
2
Liquid
1
298.15
5
2
0.05
1
3
0.0252
3
1
1001.9
5
1
1.4
1
298.15
5
2
0.05
1
3
0.0453
3
1
1004.1
5
1
1.4
1
298.15
5
2
0.05
1
3
0.0654
3
1
1005.7
5
1
1.4
1
298.15
5
2
0.05
1
3
0.0755
3
1
1006.1
5
1
1.4
1
298.15
5
2
0.05
1
3
0.0855
3
1
1006.2
5
1
1.4
1
298.15
5
2
0.05
1
3
0.0956
3
1
1006.3
5
1
1.4
1
298.15
5
2
0.1
2
3
0.025
3
1
1003
5
1
1.4
1
298.15
5
2
0.1
2
3
0.045
3
1
1005
5
1
1.4
1
298.15
5
2
0.1
2
3
0.065
3
1
1006.5
5
1
1.4
1
298.15
5
2
0.1
2
3
0.075
3
1
1006.8
5
1
1.4
1
298.15
5
2
0.1
2
3
0.085
3
1
1006.9
5
1
1.4
1
298.15
5
2
0.1
2
3
0.095
3
1
1007
5
1
1.4
1
298.15
5
2
0.15
2
3
0.0251
3
1
1004.1
5
1
1.4
1
298.15
5
2
0.15
2
3
0.0452
3
1
1006
5
1
1.4
1
298.15
5
2
0.15
2
3
0.0652
3
1
1007.5
5
1
1.4
1
298.15
5
2
0.15
2
3
0.0753
3
1
1007.7
5
1
1.4
1
298.15
5
2
0.15
2
3
0.0853
3
1
1007.9
5
1
1.4
1
298.15
5
2
0.15
2
3
0.0953
3
1
1008
5
1
1.4
1
298.15
5
2
0.2
2
3
0.025
3
1
1005.2
5
1
1.4
1
298.15
5
2
0.2
2
3
0.0451
3
1
1006.8
5
1
1.4
1
298.15
5
2
0.2
2
3
0.065
3
1
1008.3
5
1
1.4
1
298.15
5
2
0.2
2
3
0.0751
3
1
1008.7
5
1
1.4
1
298.15
5
2
0.2
2
3
0.085
3
1
1008.9
5
1
1.4
1
298.15
5
2
0.2
2
3
0.0951
3
1
1009.1
5
1
1.4
1
308.15
5
2
0.05
1
3
0.025
3
1
1000.9
5
1
1.4
1
308.15
5
2
0.05
1
3
0.045
3
1
1002.7
5
1
1.4
1
308.15
5
2
0.05
1
3
0.0649
3
1
1004.2
5
1
1.5
1
308.15
5
2
0.05
1
3
0.0749
3
1
1004.5
5
1
1.5
1
308.15
5
2
0.05
1
3
0.085
3
1
1004.6
5
1
1.5
1
308.15
5
2
0.05
1
3
0.0949
3
1
1004.7
5
1
1.5
1
308.15
5
2
0.1
2
3
0.0249
3
1
1002.3
5
1
1.4
1
308.15
5
2
0.1
2
3
0.0449
3
1
1003.9
5
1
1.5
1
308.15
5
2
0.1
2
3
0.065
3
1
1005.4
5
1
1.5
1
308.15
5
2
0.1
2
3
0.0749
3
1
1005.8
5
1
1.5
1
308.15
5
2
0.1
2
3
0.0849
3
1
1005.9
5
1
1.5
1
308.15
5
2
0.1
2
3
0.095
3
1
1006.1
5
1
1.5
1
308.15
5
2
0.15
2
3
0.0249
3
1
1003.4
5
1
1.4
1
308.15
5
2
0.15
2
3
0.0449
3
1
1004.9
5
1
1.5
1
308.15
5
2
0.15
2
3
0.065
3
1
1006.2
5
1
1.5
1
308.15
5
2
0.15
2
3
0.075
3
1
1006.3
5
1
1.5
1
308.15
5
2
0.15
2
3
0.0849
3
1
1006.5
5
1
1.5
1
308.15
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2
0.15
2
3
0.0949
3
1
1006.6
5
1
1.5
1
308.15
5
2
0.2
2
3
0.0249
3
1
1004.1
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1
1.5
1
308.15
5
2
0.2
2
3
0.0449
3
1
1005.3
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1
1.5
1
308.15
5
2
0.2
2
3
0.065
3
1
1006.4
5
1
1.5
1
308.15
5
2
0.2
2
3
0.0749
3
1
1006.7
5
1
1.5
1
308.15
5
2
0.2
2
3
0.085
3
1
1006.8
5
1
1.5
1
308.15
5
2
0.2
2
3
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3
1
1006.9
5
1
1.5
1
318.15
5
2
0.05
1
3
0.025
3
1
999.8
4
1
1.5
1
318.15
5
2
0.05
1
3
0.045
3
1
1001.6
5
1
1.5
1
318.15
5
2
0.05
1
3
0.0649
3
1
1003.2
5
1
1.5
1
318.15
5
2
0.05
1
3
0.0749
3
1
1003.5
5
1
1.5
1
318.15
5
2
0.05
1
3
0.085
3
1
1003.7
5
1
1.5
1
318.15
5
2
0.05
1
3
0.095
3
1
1003.8
5
1
1.5
1
318.15
5
2
0.1
2
3
0.025
3
1
1000.3
5
1
1.5
1
318.15
5
2
0.1
2
3
0.0449
3
1
1001.7
5
1
1.5
1
318.15
5
2
0.1
2
3
0.065
3
1
1003.1
5
1
1.5
1
318.15
5
2
0.1
2
3
0.0749
3
1
1003.3
5
1
1.5
1
318.15
5
2
0.1
2
3
0.085
3
1
1003.4
5
1
1.5
1
318.15
5
2
0.1
2
3
0.0949
3
1
1003.5
5
1
1.5
1
318.15
5
2
0.15
2
3
0.025
3
1
1001.7
5
1
1.5
1
318.15
5
2
0.15
2
3
0.0449
3
1
1003.1
5
1
1.5
1
318.15
5
2
0.15
2
3
0.0649
3
1
1003.6
5
1
1.5
1
318.15
5
2
0.15
2
3
0.075
3
1
1003.7
5
1
1.5
1
318.15
5
2
0.15
2
3
0.0849
3
1
1003.8
5
1
1.5
1
318.15
5
2
0.15
2
3
0.0949
3
1
1003.9
5
1
1.5
1
318.15
5
2
0.2
2
3
0.0249
3
1
1002.1
5
1
1.5
1
318.15
5
2
0.2
2
3
0.045
3
1
1003
5
1
1.5
1
318.15
5
2
0.2
2
3
0.0649
3
1
1003.9
5
1
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1
318.15
5
2
0.2
2
3
0.075
3
1
1004
5
1
1.5
1
318.15
5
2
0.2
2
3
0.0849
3
1
1004.1
5
1
1.5
1
318.15
5
2
0.2
2
3
0.0949
3
1
1004.2
5
1
1.5